JP6276687B2 - アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム - Google Patents
アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム Download PDFInfo
- Publication number
- JP6276687B2 JP6276687B2 JP2014506401A JP2014506401A JP6276687B2 JP 6276687 B2 JP6276687 B2 JP 6276687B2 JP 2014506401 A JP2014506401 A JP 2014506401A JP 2014506401 A JP2014506401 A JP 2014506401A JP 6276687 B2 JP6276687 B2 JP 6276687B2
- Authority
- JP
- Japan
- Prior art keywords
- isotopologue
- filter media
- filtrate
- tritium
- filter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 56
- 238000000926 separation method Methods 0.000 title description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 145
- 238000001914 filtration Methods 0.000 claims description 92
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 90
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical group [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims description 65
- 239000000706 filtrate Substances 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 56
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 claims description 53
- 229910052722 tritium Inorganic materials 0.000 claims description 53
- 238000007710 freezing Methods 0.000 claims description 43
- 230000008014 freezing Effects 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 31
- 238000003825 pressing Methods 0.000 claims description 23
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- 238000002844 melting Methods 0.000 claims description 10
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- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
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- 239000002609 medium Substances 0.000 description 38
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- 239000000463 material Substances 0.000 description 17
- 238000002474 experimental method Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 10
- 229910052805 deuterium Inorganic materials 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000006911 nucleation Effects 0.000 description 5
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- 210000002268 wool Anatomy 0.000 description 4
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- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
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- 239000012527 feed solution Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
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- 206010028980 Neoplasm Diseases 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 241000720974 Protium Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000037374 absorbed through the skin Effects 0.000 description 1
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- 231100000693 bioaccumulation Toxicity 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
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- 238000005538 encapsulation Methods 0.000 description 1
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- 230000005226 mechanical processes and functions Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0004—Crystallisation cooling by heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/02—Separation by phase transition
- B01D59/08—Separation by phase transition by fractional crystallisation, by precipitation, by zone freezing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/004—Fractional crystallisation; Fractionating or rectifying columns
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/004—Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/22—Treatment of water, waste water, or sewage by freezing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/006—Radioactive compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/152—Water filtration
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrology & Water Resources (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physical Water Treatments (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/090,879 | 2011-04-20 | ||
| US13/090,879 US8758572B2 (en) | 2011-04-20 | 2011-04-20 | Method for the separation and concentration of isotopologues |
| PCT/US2012/020927 WO2012145046A1 (en) | 2011-04-20 | 2012-01-11 | Methods, devices, and systems for the separation and concentration of isotopologues |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018003011A Division JP2018105869A (ja) | 2011-04-20 | 2018-01-12 | アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014516313A JP2014516313A (ja) | 2014-07-10 |
| JP2014516313A5 JP2014516313A5 (enExample) | 2015-03-05 |
| JP6276687B2 true JP6276687B2 (ja) | 2018-02-07 |
Family
ID=47020217
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014506401A Expired - Fee Related JP6276687B2 (ja) | 2011-04-20 | 2012-01-11 | アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム |
| JP2018003011A Pending JP2018105869A (ja) | 2011-04-20 | 2018-01-12 | アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018003011A Pending JP2018105869A (ja) | 2011-04-20 | 2018-01-12 | アイソトポローグの分離および濃縮のための方法、デバイス、およびシステム |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US8758572B2 (enExample) |
| EP (1) | EP2699326A4 (enExample) |
| JP (2) | JP6276687B2 (enExample) |
| WO (1) | WO2012145046A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8758572B2 (en) | 2011-04-20 | 2014-06-24 | Exelon Generation Company, Llc | Method for the separation and concentration of isotopologues |
| JP2016527079A (ja) * | 2013-07-11 | 2016-09-08 | エクセロン ジェネレーション カンパニー、エルエルシー | 同位体分子の分離及び濃縮 |
| JP5793754B1 (ja) * | 2014-06-11 | 2015-10-14 | 行平 加藤 | トリチウム水捕集器及びトリチウム水捕集システム |
| CN104318969B (zh) * | 2014-11-19 | 2017-02-08 | 清华大学 | 一种高温气冷堆含氚废水优化收集系统及收集工艺 |
| JP2019000847A (ja) * | 2018-06-22 | 2019-01-10 | エクセロン ジェネレーション カンパニー、エルエルシー | 同位体分子の分離及び濃縮 |
| JP6901141B2 (ja) * | 2018-11-01 | 2021-07-14 | 株式会社ケミテック・コンサルタンツ | トリチウム水を含む被処理水からトリチウム水を分離する方法 |
| US11992805B2 (en) | 2019-12-17 | 2024-05-28 | Mosaic Materials, Inc. | Humidity as a method for controlling CO2 adsorption with step-shaped adsorbents |
| JP2023075624A (ja) * | 2021-11-19 | 2023-05-31 | 株式会社イメージワン | トリチウム水と軽水を含む被処理水の処理方法 |
| US12303865B2 (en) | 2022-10-10 | 2025-05-20 | Mosaic Materials, Inc. | Aqueous manufacture of aminated MOF complexes |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50152997A (enExample) * | 1974-05-31 | 1975-12-09 | ||
| US4353871A (en) * | 1979-05-10 | 1982-10-12 | The United States Of America As Represented By The United States Department Of Energy | Hydrogen isotope separation |
| US4411798A (en) * | 1980-05-27 | 1983-10-25 | Standard Oil Company | Process for separating D2 O from H2 O using surfactant systems |
| DE3508503A1 (de) | 1985-03-09 | 1986-09-11 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur anreicherung und abtrennung von oxiden schwerer wasserstoff-isotope aus sauren, waessrigen loesungen oder stoffstroemen |
| US5468462A (en) * | 1993-12-06 | 1995-11-21 | Atomic Energy Of Canada Limited | Geographically distributed tritium extraction plant and process for producing detritiated heavy water using combined electrolysis and catalytic exchange processes |
| US5876596A (en) | 1997-03-14 | 1999-03-02 | Coleman Sudol, Llp | Apparatus for treating water |
| US6190531B1 (en) * | 1999-07-27 | 2001-02-20 | University Of North Carolina | Concentration and removal of tritium and/or deuterium from water contaminated with tritium and/or deuterium |
| JP3505503B2 (ja) * | 2000-11-22 | 2004-03-08 | 康一 浅野 | 分離係数が1に近い混合物の蒸留による分離濃縮方法および装置 |
| US7893377B2 (en) * | 2003-03-04 | 2011-02-22 | Taiyo Nippon Sanso Corporation | Method for concentrating oxygen isotope |
| US7302812B2 (en) * | 2003-09-02 | 2007-12-04 | Air Products And Chemicals, Inc. | Process for production of isotopes |
| US20060016681A1 (en) * | 2004-06-16 | 2006-01-26 | Muchnik Boris J | Apparatus and method for separating tritated and heavy water from light water via a conical configuration |
| US20050279129A1 (en) | 2004-06-16 | 2005-12-22 | Muchnik Boris J | Apparatus and method for seperating tritiated and heavy water from light water |
| US6984327B1 (en) | 2004-11-23 | 2006-01-10 | Patterson James A | System and method for separating heavy isotopes of hydrogen oxide from water |
| US7815890B2 (en) * | 2005-10-11 | 2010-10-19 | Special Separations Application, Inc. | Process for tritium removal from water by transfer of tritium from water to an elemental hydrogen stream, followed by membrane diffusion tritium stripping and enrichment, and final tritium enrichment by thermal diffusion |
| US7470350B2 (en) * | 2006-04-25 | 2008-12-30 | Ge Healthcare Uk Limited | Process for tritium removal from light water |
| US8597471B2 (en) * | 2010-08-19 | 2013-12-03 | Industrial Idea Partners, Inc. | Heat driven concentrator with alternate condensers |
| US8758572B2 (en) | 2011-04-20 | 2014-06-24 | Exelon Generation Company, Llc | Method for the separation and concentration of isotopologues |
| WO2014194331A1 (en) * | 2013-05-31 | 2014-12-04 | Kurion, Inc. | A balanced closed loop continuous extraction process for hydrogen isotopes |
-
2011
- 2011-04-20 US US13/090,879 patent/US8758572B2/en not_active Expired - Fee Related
-
2012
- 2012-01-11 EP EP12774204.7A patent/EP2699326A4/en not_active Withdrawn
- 2012-01-11 JP JP2014506401A patent/JP6276687B2/ja not_active Expired - Fee Related
- 2012-01-11 WO PCT/US2012/020927 patent/WO2012145046A1/en not_active Ceased
-
2014
- 2014-05-27 US US14/287,698 patent/US20150027165A1/en not_active Abandoned
-
2018
- 2018-01-12 JP JP2018003011A patent/JP2018105869A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20150027165A1 (en) | 2015-01-29 |
| EP2699326A1 (en) | 2014-02-26 |
| EP2699326A4 (en) | 2014-10-22 |
| JP2014516313A (ja) | 2014-07-10 |
| US8758572B2 (en) | 2014-06-24 |
| WO2012145046A1 (en) | 2012-10-26 |
| US20120266629A1 (en) | 2012-10-25 |
| JP2018105869A (ja) | 2018-07-05 |
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