JP6222231B2 - 電界効果型化合物半導体装置 - Google Patents
電界効果型化合物半導体装置 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 59
- 150000001875 compounds Chemical class 0.000 title claims description 43
- 230000005669 field effect Effects 0.000 title claims description 17
- 230000004888 barrier function Effects 0.000 claims description 107
- 125000006850 spacer group Chemical group 0.000 claims description 73
- 229910017115 AlSb Inorganic materials 0.000 claims description 47
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 claims description 44
- 239000000758 substrate Substances 0.000 claims description 37
- 229910001218 Gallium arsenide Inorganic materials 0.000 claims description 24
- 239000012535 impurity Substances 0.000 claims description 21
- 229910021478 group 5 element Inorganic materials 0.000 claims description 18
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 claims description 16
- 229910000673 Indium arsenide Inorganic materials 0.000 claims description 2
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 367
- 238000009792 diffusion process Methods 0.000 description 19
- 239000000203 mixture Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 230000009467 reduction Effects 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 238000000151 deposition Methods 0.000 description 4
- 230000003071 parasitic effect Effects 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229910005542 GaSb Inorganic materials 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000000927 vapour-phase epitaxy Methods 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7782—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET
- H01L29/7783—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material
- H01L29/7784—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material with delta or planar doped donor layer
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
- H01L29/201—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys
- H01L29/205—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys in different semiconductor regions, e.g. heterojunctions
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/36—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the concentration or distribution of impurities in the bulk material
- H01L29/365—Planar doping, e.g. atomic-plane doping, delta-doping
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66446—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
- H01L29/66462—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7782—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET
- H01L29/7783—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material
- H01L29/7785—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material with more than one donor layer
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- Computer Hardware Design (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Junction Field-Effect Transistors (AREA)
Description
fT=1/{2π(Lg/ν+τex)} ・・・(1)
で表される。HEMTの高速化は主に、ゲート長Lgの微細化、電子の有効質量の軽い半導体をチャネルに用いることによる電子速度νの増大によりなされる。これらは、HEMTの真性遅延時間(=Lg/ν)の短縮に相当する。
Rsheet=1/(eNsμ) ・・・(2) で表される。高濃度Si−δドーピングが行なった結果、チャネル層中の電子密度を高めることはできた。しかしながら、高濃度Si−δドーピングにより、Siの拡散量が大きくなるという問題が起こったので、この事情を図23を参照して説明する。
n(x、t)=(n0/2){erf(A)+erf(B)} @|x|≦L ・・・(3)
n(x、t)=(n0/2){erf(A)−erf(−B)} @|x|≧L ・・・(4)
で表される。但し、erf(x)は誤差関数であり、A及びBは、それぞれ、
A=(L+|x|)/{2(Dt)1/2}
B=(L−|x|)/{2(Dt)1/2}
である。図に示すように、拡散長が大きくなるに連れて、不純物濃度分布は急峻なδ関数からだれてくる。
Ftotal=ΣF(x)=Σ(4πε)−1×n(x)Δxe2/|x0‐x|2
=e2/(4πε)Σn(x)Δx/|x0‐x|2
となる。
ntotal(with AlSb)/ntotal(without AlSb)≒0.914
となり、AlSbを導入したことによるチャネル電子の減少は1割以下であることが分かる。
Ftotal(with AlSb)/Ftotal(without AlSb)≒0.573
と半分近くまで減少することから、リモートクーロン散乱を抑制できることが分かる。
ntotal(with AlSb)/ntotal(without AlSb)≒0.754
Ftotal(with AlSb)/Ftotal(without AlSb)≒0.410
となり、クーロン力は小さくなるものの、チャネル電子濃度が大幅に低下するので、III-V族化合物半導体スペーサ層の厚さは、チャネル層/上部バリア層界面と面状ドープ層との間の厚さの50%乃至80%とすることが望ましい。
Corp.社製商品名)を用いる。なお、ゲート電極のフット部分の長さをどの程度にするかにより、第1レジスト層34の厚さは変わる。そのため、図9〜14では第1レジスト層34の厚さは、ソース電極31、ドレイン電極32で用いられる金属の最上部として描かれているが、これよりも厚くなったり薄くなったりする。厚い場合は、ソース電極31、ドレイン電極32上にも第1レジスト層34が覆う。また薄い場合には、第2レジスト層35がソース電極31、ドレイン電極32の間にも入り込む。
2 バッファ層
3 下部バリア層
4 チャネル層
5 上部バリア層
6 V族がSbであるIII-V族化合物半導体スペーサ層
7 スペーサ層
8 面状ドープ層
9 バリア層
10 キャップ層
11 ソース電極
12 ドレイン電極
13 ゲート電極
21,71 半絶縁性InP基板
22,72 i型In0.52Al0.48Asバッファ層
23,73 i型In0.52Al0.48As下部バリア層
24,74 i型InGaAsチャネル層
25,46 i型AlSbスペーサ層
26,42,45,48,75 i型In0.52Al0.48Asスペーサ層
27,43,44,47,76 δドープ層
28,77 i型In0.52Al0.48Asバリア層
29,78 i型InP層
30,79 n型InGaAsキャップ層
31,80 ソース電極
32,81 ドレイン電極
33 SiO2膜
34 第1レジスト層
35 第2レジスト層
36 第3レジスト層
37,38,39 開口部
40,82 ゲートリセス部
41,83 ゲート電極
51 半絶縁性GaAs基板
52 i型AlGaAsバッファ層
53 i型AlGaAs下部バリア層
54 i型InGaAsチャネル層
55 i型AlSbスペーサ層
56 i型AlGaAsスペーサ層
57 δドープ層
58 i型AlGaAsバリア層
59 n型GaAsキャップ層
60 ソース電極
61 ドレイン電極
62 SiO2膜
63 ゲートリセス部
64 ゲート電極
Claims (8)
- 半導体基板と、
前記半導体基板上に設けた下部バリア層と、
前記下部バリア層に接して設けたチャネル層と、
前記チャネル層に接して設けた上部バリア層と、
前記上部バリア層に接して設けたキャップ層と、
前記キャップ層上に設けたソース電極及びドレイン電極と、
前記ソース電極とドレイン電極の間に配置されたゲート電極と
を有し、
前記下部バリア層及び前記上部バリア層の少なくとも一方の層中にチャネル電子の供給源となる不純物原子が面状ドーピングされた面状ドープ層を有し、
前記面状ドープ層を設けたバリア層の前記チャネル層に接する部分がV族元素がSbであるIII-V族化合物半導体スペーサ層であり、且つ、前記面状ドープ層を設けたバリア層の他の部分がV族元素としてSbを含まないIII-V族化合物半導体層であり、
前記V族元素がSbであるIII-V族化合物半導体スペーサ層の厚さが、前記面状ドープ層の中心位置と前記チャネル層との間の厚さの50%〜80%であることを特徴とする電界効果型化合物半導体装置。 - 前記半導体基板と前記下部バリア層との間にバッファ層を有することを特徴とする請求項1に記載の電界効果型化合物半導体装置。
- 前記面状ドープ層が、1層のバリア層中に複数層設けられていることを特徴とする請求項1または請求項2に記載の電界効果型化合物半導体装置。
- 前記下部バリア層は前記V族元素がSbであるIII-V族化合物半導体スペーサ層を含まず、且つ、前記上部バリア層は前記V族元素がSbであるIII-V族化合物半導体スペーサ層を含み、
前記下部バリア層はInAlAs層であり、
前記チャネル層はInGaAs層或いはInGaAs層とInAs層の積層構造のいずれかであり、
前記上部バリア層の前記V族元素がSbであるIII-V族化合物半導体スペーサ層を除いた部分はInAlAs層或いはInAlAs層とInP層の積層構造のいずれかであり、
前記キャップ層はn型InGaAs層或いはn型InGaAs層とn型InAlAs層の積層構造のいずれかである
ことを特徴とする請求項1乃至請求項3のいずれか1項に記載の電界効果型化合物半導体装置。 - 前記下部バリア層は前記V族元素がSbであるIII-V族化合物半導体スペーサ層を含まず、且つ、前記上部バリア層は前記V族元素がSbであるIII-V族化合物半導体スペーサ層を含み、
前記下部バリア層はAlGaAs層であり、
前記チャネル層はGaAs層或いはInGaAs層のいずれかであり、
前記上部バリア層の前記V族元素がSbであるIII-V族化合物半導体スペーサ層を除いた部分はAlGaAs層であり、
前記キャップ層はn型GaAs層である
ことを特徴とする請求項1乃至請求項3のいずれか1項に記載の電界効果型化合物半導体装置。 - 前記面状ドープ層にドープされる不純物原子はSiであることを特徴とする請求項1乃至請求項5のいずれか1項に記載の電界効果型化合物半導体装置。
- 前記V族元素がSbであるIII-V族化合物半導体スペーサ層は、AlSb層、AlGaSb層、AlInSb層或いはAlGaInSb層のいずれかであることを特徴とする請求項1乃至請求項6のいずれか1項に記載の電界効果型化合物半導体装置。
- 前記キャップ層の露出平坦面上に絶縁膜を有し、
前記絶縁膜に設けられた開口部の側端面が前記ゲート電極の側端面に当接していることを特徴とする請求項1乃至請求項7のいずれか1項に記載の電界効果型化合物半導体装置。
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PCT/JP2013/072061 WO2015025349A1 (ja) | 2013-08-19 | 2013-08-19 | 電界効果型化合物半導体装置 |
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US (1) | US20160163845A1 (ja) |
EP (1) | EP3038143A4 (ja) |
JP (1) | JP6222231B2 (ja) |
WO (1) | WO2015025349A1 (ja) |
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US10411125B2 (en) * | 2016-11-23 | 2019-09-10 | Mitsubishi Electric Research Laboratories, Inc. | Semiconductor device having high linearity-transconductance |
US10644142B2 (en) * | 2017-12-22 | 2020-05-05 | Nxp Usa, Inc. | Semiconductor devices with doped regions functioning as enhanced resistivity regions or diffusion barriers, and methods of fabrication therefor |
US12009414B2 (en) * | 2021-12-03 | 2024-06-11 | International Business Machines Corporation | Superconductor gate semiconductor field-effect transistor |
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US5668387A (en) * | 1995-10-26 | 1997-09-16 | Trw Inc. | Relaxed channel high electron mobility transistor |
JP2003203931A (ja) * | 2002-01-09 | 2003-07-18 | Matsushita Electric Ind Co Ltd | ヘテロ接合電界効果型トランジスタ |
JP2005251820A (ja) * | 2004-03-02 | 2005-09-15 | Nippon Telegr & Teleph Corp <Ntt> | ヘテロ接合型電界効果トランジスタ |
JP4284254B2 (ja) * | 2004-09-07 | 2009-06-24 | 富士通株式会社 | 電界効果型半導体装置 |
JP4799966B2 (ja) * | 2005-09-06 | 2011-10-26 | 日本電信電話株式会社 | 電界効果トランジスタ |
US20070248128A1 (en) * | 2006-04-25 | 2007-10-25 | Nl Nanosemiconductor Gmbh | Double-sided monolithically integrated optoelectronic module with temperature compensation |
JP5211471B2 (ja) * | 2006-11-29 | 2013-06-12 | 富士通株式会社 | 化合物半導体装置及びその製造方法 |
US8129749B2 (en) * | 2008-03-28 | 2012-03-06 | Intel Corporation | Double quantum well structures for transistors |
US20100148153A1 (en) * | 2008-12-16 | 2010-06-17 | Hudait Mantu K | Group III-V devices with delta-doped layer under channel region |
JP5504428B2 (ja) * | 2009-03-24 | 2014-05-28 | 旭化成エレクトロニクス株式会社 | 電界効果トランジスタ及びその製造方法 |
JP5580138B2 (ja) * | 2010-08-18 | 2014-08-27 | 日本電信電話株式会社 | 電界効果トランジスタ |
JP2012104738A (ja) * | 2010-11-12 | 2012-05-31 | Hitachi Cable Ltd | 化合物半導体装置 |
JP5924640B2 (ja) * | 2011-09-27 | 2016-05-25 | 富士通株式会社 | 半導体装置 |
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2013
- 2013-08-19 JP JP2015532595A patent/JP6222231B2/ja not_active Expired - Fee Related
- 2013-08-19 EP EP13891799.2A patent/EP3038143A4/en not_active Withdrawn
- 2013-08-19 WO PCT/JP2013/072061 patent/WO2015025349A1/ja active Application Filing
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2016
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