JP6187715B2 - ダイシングテープ - Google Patents
ダイシングテープ Download PDFInfo
- Publication number
- JP6187715B2 JP6187715B2 JP2017003542A JP2017003542A JP6187715B2 JP 6187715 B2 JP6187715 B2 JP 6187715B2 JP 2017003542 A JP2017003542 A JP 2017003542A JP 2017003542 A JP2017003542 A JP 2017003542A JP 6187715 B2 JP6187715 B2 JP 6187715B2
- Authority
- JP
- Japan
- Prior art keywords
- adhesive layer
- dicing
- meth
- hydroxy
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012790 adhesive layer Substances 0.000 claims description 139
- -1 polyethylene Polymers 0.000 claims description 111
- 239000004065 semiconductor Substances 0.000 claims description 90
- 239000010410 layer Substances 0.000 claims description 75
- 239000000463 material Substances 0.000 claims description 34
- 239000004925 Acrylic resin Substances 0.000 claims description 31
- 229920000178 Acrylic resin Polymers 0.000 claims description 31
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 25
- 239000003431 cross linking reagent Substances 0.000 claims description 24
- 229920006243 acrylic copolymer Polymers 0.000 claims description 17
- 125000003700 epoxy group Chemical group 0.000 claims description 12
- 239000005011 phenolic resin Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 claims description 3
- 229920005630 polypropylene random copolymer Polymers 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011256 inorganic filler Substances 0.000 claims description 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 104
- 238000000034 method Methods 0.000 description 87
- 230000008569 process Effects 0.000 description 50
- 239000000758 substrate Substances 0.000 description 27
- 230000001070 adhesive effect Effects 0.000 description 22
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
- 239000000853 adhesive Substances 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 20
- 239000003822 epoxy resin Substances 0.000 description 19
- 229920000647 polyepoxide Polymers 0.000 description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 17
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 13
- 125000000524 functional group Chemical group 0.000 description 12
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 238000010030 laminating Methods 0.000 description 9
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 229940078552 o-xylene Drugs 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000005520 cutting process Methods 0.000 description 7
- 238000010894 electron beam technology Methods 0.000 description 7
- 239000012948 isocyanate Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 6
- 244000028419 Styrax benzoin Species 0.000 description 5
- 235000000126 Styrax benzoin Nutrition 0.000 description 5
- 235000008411 Sumatra benzointree Nutrition 0.000 description 5
- 229960002130 benzoin Drugs 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 235000019382 gum benzoic Nutrition 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229920003986 novolac Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 4
- DPNXHTDWGGVXID-UHFFFAOYSA-N 2-isocyanatoethyl prop-2-enoate Chemical compound C=CC(=O)OCCN=C=O DPNXHTDWGGVXID-UHFFFAOYSA-N 0.000 description 4
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- MJVAVZPDRWSRRC-UHFFFAOYSA-N Menadione Chemical compound C1=CC=C2C(=O)C(C)=CC(=O)C2=C1 MJVAVZPDRWSRRC-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 206010034972 Photosensitivity reaction Diseases 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 238000007259 addition reaction Methods 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 230000009191 jumping Effects 0.000 description 4
- 125000003566 oxetanyl group Chemical group 0.000 description 4
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 4
- 230000036211 photosensitivity Effects 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000010538 cationic polymerization reaction Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000003456 ion exchange resin Substances 0.000 description 3
- 229920003303 ion-exchange polymer Polymers 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical group CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- XHXSXTIIDBZEKB-UHFFFAOYSA-N 1,2,3,4,5,6,7,8-octamethylanthracene-9,10-dione Chemical compound CC1=C(C)C(C)=C2C(=O)C3=C(C)C(C)=C(C)C(C)=C3C(=O)C2=C1C XHXSXTIIDBZEKB-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- LMGYOBQJBQAZKC-UHFFFAOYSA-N 1-(2-ethylphenyl)-2-hydroxy-2-phenylethanone Chemical compound CCC1=CC=CC=C1C(=O)C(O)C1=CC=CC=C1 LMGYOBQJBQAZKC-UHFFFAOYSA-N 0.000 description 2
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 2
- KIJPZYXCIHZVGP-UHFFFAOYSA-N 2,3-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(C)=C2 KIJPZYXCIHZVGP-UHFFFAOYSA-N 0.000 description 2
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical compound CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- JFWFAUHHNYTWOO-UHFFFAOYSA-N 2-[(2-ethenylphenyl)methoxymethyl]oxirane Chemical compound C=CC1=CC=CC=C1COCC1OC1 JFWFAUHHNYTWOO-UHFFFAOYSA-N 0.000 description 2
- OCKQMFDZQUFKRD-UHFFFAOYSA-N 2-[(3-ethenylphenyl)methoxymethyl]oxirane Chemical compound C=CC1=CC=CC(COCC2OC2)=C1 OCKQMFDZQUFKRD-UHFFFAOYSA-N 0.000 description 2
- ZADXFVHUPXKZBJ-UHFFFAOYSA-N 2-[(4-ethenylphenyl)methoxymethyl]oxirane Chemical compound C1=CC(C=C)=CC=C1COCC1OC1 ZADXFVHUPXKZBJ-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 2
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 2
- VZMLJEYQUZKERO-UHFFFAOYSA-N 2-hydroxy-1-(2-methylphenyl)-2-phenylethanone Chemical compound CC1=CC=CC=C1C(=O)C(O)C1=CC=CC=C1 VZMLJEYQUZKERO-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 2
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- AXYQEGMSGMXGGK-UHFFFAOYSA-N 2-phenoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(=O)C(C=1C=CC=CC=1)OC1=CC=CC=C1 AXYQEGMSGMXGGK-UHFFFAOYSA-N 0.000 description 2
- NTZCFGZBDDCNHI-UHFFFAOYSA-N 2-phenylanthracene-9,10-dione Chemical compound C=1C=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=1C1=CC=CC=C1 NTZCFGZBDDCNHI-UHFFFAOYSA-N 0.000 description 2
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- BVYPJEBKDLFIDL-UHFFFAOYSA-N 3-(2-phenylimidazol-1-yl)propanenitrile Chemical compound N#CCCN1C=CN=C1C1=CC=CC=C1 BVYPJEBKDLFIDL-UHFFFAOYSA-N 0.000 description 2
- VLJSLTNSFSOYQR-UHFFFAOYSA-N 3-propan-2-ylphenol Chemical compound CC(C)C1=CC=CC(O)=C1 VLJSLTNSFSOYQR-UHFFFAOYSA-N 0.000 description 2
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- YQUQWHNMBPIWGK-UHFFFAOYSA-N 4-isopropylphenol Chemical compound CC(C)C1=CC=C(O)C=C1 YQUQWHNMBPIWGK-UHFFFAOYSA-N 0.000 description 2
- MTRFEWTWIPAXLG-UHFFFAOYSA-N 9-phenylacridine Chemical compound C1=CC=CC=C1C1=C(C=CC=C2)C2=NC2=CC=CC=C12 MTRFEWTWIPAXLG-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NPKSPKHJBVJUKB-UHFFFAOYSA-N N-phenylglycine Chemical compound OC(=O)CNC1=CC=CC=C1 NPKSPKHJBVJUKB-UHFFFAOYSA-N 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- LHMRXAIRPKSGDE-UHFFFAOYSA-N benzo[a]anthracene-7,12-dione Chemical compound C1=CC2=CC=CC=C2C2=C1C(=O)C1=CC=CC=C1C2=O LHMRXAIRPKSGDE-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000012663 cationic photopolymerization Methods 0.000 description 2
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
- H01L2224/321—Disposition
- H01L2224/32151—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/32221—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/32225—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73251—Location after the connecting process on different surfaces
- H01L2224/73265—Layer and wire connectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
- H01L2224/8319—Arrangement of the layer connectors prior to mounting
- H01L2224/83191—Arrangement of the layer connectors prior to mounting wherein the layer connectors are disposed only on the semiconductor or solid-state body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/91—Methods for connecting semiconductor or solid state bodies including different methods provided for in two or more of groups H01L2224/80 - H01L2224/90
- H01L2224/92—Specific sequence of method steps
- H01L2224/922—Connecting different surfaces of the semiconductor or solid-state body with connectors of different types
- H01L2224/9222—Sequential connecting processes
- H01L2224/92242—Sequential connecting processes the first connecting process involving a layer connector
- H01L2224/92247—Sequential connecting processes the first connecting process involving a layer connector the second connecting process involving a wire connector
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/181—Encapsulation
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Description
ダイシング・ダイボンディング一体型テープ1は、半導体ウエハを半導体チップに個片化するダイシング用フィルムとしての機能と、個片化された半導体チップを支持基板に接続する際の接着層を半導体チップに付与する機能と、を一体的に有するフィルムである。
基材層10は、ダイシング時に半導体ウエハを支持する部分である。基材層10としては、既知のポリマーシート又はポリマーテープを用いることができる。基材層10を構成する好ましい化合物としては、ダイボンディング工程中にエキスパンド(放射状延伸)可能なものが挙げられる。具体的には、結晶性ポリプロピレン、非晶性ポリプロピレン、高密度ポリエチレン、中密度ポリエチレン、低密度ポリエチレン、超低密度ポリエチレン、低密度直鎖ポリエチレン、ポリブテン、ポリメチルペンテン等のポリオレフィン、エチレン−酢酸ビニル共重合体、アイオノマー樹脂、エチレン−(メタ)アクリル酸共重合体、エチレン−(メタ)アクリル酸エステル(ランダム、交互)共重合体、エチレン−ブテン共重合体、エチレン−ヘキセン共重合体、ポリウレタン、ポリエチレンテレフタレート、ポリエチレンナフタレート等のポリエステル、ポリカーボネート、ポリイミド、ポリエーテルエーテルケトン、ポリエーテルイミド、ポリアミド、全芳香族ポリアミド、ポリフェニルスルフイド、アラミド(紙)、ガラス、ガラスクロス、フッ素樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、セルロース系樹脂、シリコーン樹脂、又はこれらに可塑剤、シリカ、アンチブロッキング材、スリップ剤、帯電防止剤等を混合した混合物などが挙げられる。これらの混合物のなかでも、ポリプロピレン、ポリエチレン−ポリプロピレンランダム共重合体及びポリエチレン−ポリプロピレンブロック共重合体はヤング率、応力緩和性、融点等の特性に加えて、価格面、使用後の廃材リサイクル等の観点からも良好な基材であり、また紫外線による表面改質効果が得られやすいため、より好適である。なお、基材層10は、上記成分のうちの一種の成分からなるものでもよく、二種以上の成分からなるものでもよい。
粘着層20は、紫外線照射前における破断伸びが140%より大きく200%以下であり、好ましくは150〜190%であり、より好ましくは150〜180%である。紫外線照射前における破断伸びが200%未満であると、ダイシング工程時の切削性が良好であるため、ピックアップ時に突き上げ量が小さい場合でも十分なピックアップ性が得られる。なお、紫外線照射前における破断伸びが140%以下であると、紫外線照射前における粘着層20の粘着力が低下し、被着体を固定する力が弱くなる。そのため、特に小チップサイズの被着体にダイシングを行う際に、リング剥れ及びチップ飛びが起こりやすい。
接着層30は、ダイシング後に個片化された半導体チップを支持基板に接着・接続するためのものである。接着層30は、熱により硬化する熱硬化型の接着剤からなる層であり、エポキシ基含有アクリル共重合体、エポキシ樹脂、エポキシ樹脂硬化剤を含むことが好ましい。このような組成を有する接着層30は、半導体チップ/支持基板間、半導体チップ/半導体チップ間の接着性に優れ、また電極埋め込み性及び/又はワイヤー埋め込み性なども付与可能で、且つダイボンディング工程では低温で接着でき、短時間で優れた硬化が得られる、封止剤でモールド後は優れた信頼性を有する等の特徴があり好ましい。
ダイシング・ダイボンディング一体型テープ1を製造する方法としては、基材層10としてポリマーテープ上に粘着層20及び接着層30を順次塗布して製造する方法、又は、粘着層20及び接着層30をそれぞれフィルム状としたものを張り合わせて製造する方法、等が挙げられる。
次に、ダイシング・ダイボンディング一体型テープ1を用いて半導体装置(半導体パッケージ)を製造する方法について説明する。
先ず、ダイシング・ダイボンディング一体型テープ1を所定の装置に配置する。続いて、図2(a)及び(b)に示されるように、半導体ウエハWの主面Wsに、接着層30を介してダイシング・ダイボンディング一体型テープ1を貼り付ける。また、半導体ウエハWの回路面は、主面Wsとは反対側の面であることが好ましい。
次に、図2(c)に示されるように、半導体ウエハW、粘着層20及び接着層30をダイシングする。このとき、基材層10を途中までダイシングしてもよい。このように、ダイシング・ダイボンディング一体型テープ1は、ダイシングシートとしても機能する。ここで、ダイシング・ダイボンディング一体型テープ1における粘着層20は、紫外線照射前の破断伸びが140%より大きく200%以下である。そのため、ダイシング工程時の切削性が良好である。従って、ダイシングによって得る半導体素子Waが一辺1〜10mm程度(より好ましくは1〜5mm程度)の小チップであっても、ダイシング時におけるチップ飛びを抑制できる。
次に、図2(d)に示されるように、粘着層20に紫外線を照射することにより粘着層20を硬化させ、粘着層20と接着層30との間の接着力を低下させる。本実施形態においては、波長200〜400nmの紫外線を用いることが好ましく、その照射条件としては、照度:30〜240mW/cm2で照射量200〜500mJ/cm2となるように照射することが好ましい。
紫外線を照射した後、図2(e)に示されるように、基材層10をエキスパンドすることにより、切断により得られた各半導体素子を互いに離間させつつ、接着層30側からニードル42で突き上げられた接着層付き半導体素子50を吸引コレット44で吸引してピックアップする。上述のとおり、ダイシング工程における切削が良好に行われているため、突き上げ量が小さくても、接着層付き半導体素子50を十分にピックアップできる。なお、接着層付き半導体素子50は、半導体素子Waと接着層30aとを有する。接着層30aは接着層30を分割して得られるものである。ピックアップ工程にて基材層10をエキスパンドすることにより、接着層付き半導体素子50のピックアップ性をより向上させることができる。
接着層付き半導体素子50をピックアップした後、図2(f)に示されるように、接着層付き半導体素子50を、熱圧着により、接着層30aを介して半導体素子搭載用の支持基板60に接着する。
(ダイシング・ダイボンディング一体型テープの作製)
[粘着層用アクリル樹脂の合成]
スリーワンモータ、撹拌翼及び窒素導入管が備え付けられた容量4000mlのオートクレーブに酢酸エチル1000g、2−エチルヘキシルアクリレート650g、2−ヒドロキシエチルアクリレート350g、アゾビスイソブチロニトリル3.0gを配合し、均一になるまで撹拌した。その後、流量100ml/minにて60分間バブリングを実施し、系中の溶存酸素を脱気した。1時間かけて60℃まで昇温し、昇温後4時間重合させた。その後1時間かけて90℃まで昇温し、更に90℃にて1時間保持後、室温に冷却した。
上述記載の方法で得られた連鎖重合可能な二重結合を有するアクリル樹脂溶液を固形分として100g、架橋剤として多官能イソシアネート(日本ポリウレタン工業(株)製、コロネートL、固形分75%)を固形分として7.0g、光開始剤として1−ヒドロキシシクロヘキシルフェニルケトン(チバスペシャリティケミカルズ(株)製、イルガキュア184)を1.0g、更に総固形分含有量が27質量%となるように酢酸エチルを加え、10分間均一に撹拌して粘着層用ワニスを得た。
エポキシ樹脂としてYDCN−703(東都化成(株)製商品名、クレゾールノボラック型エポキシ樹脂、エポキシ当量210、分子量1200、軟化点80℃)55質量部、フェノール樹脂としてミレックスXLC−LL(三井化学(株)製商品名、フェノール樹脂、水酸基当量175、吸水率1.8%、350℃における加熱重量減少率4%)45質量部、シランカップリング剤としてNUC A−189(日本ユニカー(株)製商品名、γ−メルカプトプロピルトリメトキシシラン)1.7質量部とNUCA−1160(日本ユニカー(株)製商品名、γ−ウレイドプロピルトリエトキシシラン)3.2質量部、フィラーとしてアエロジルR972(シリカ表面にジメチルジクロロシランを被覆し、400℃の反応器中で加水分解させた、メチル基などの有機基を表面に有するフィラー、日本アエロジル(株)製商品名、シリカ、平均粒径0.016μm)32質量部からなる組成物に、シクロヘキサノンを加えて撹拌混合し、更にビーズミルを用いて90分混練した。これにグリシジルアクリレート又はグリシジルメタクリレート3質量%を含むアクリルゴムHTR−860P−3(ナガセケムテックス(株)製商品名、重量平均分子量80万)を280質量部、及び硬化促進剤としてキュアゾール2PZ−CN(四国化成(株)製商品名、1−シアノエチル−2−フェニルイミダゾール)0.5質量部加え、攪拌混合し、真空脱気し、ワニスを得た。
上記のようにして得たキャリアテープを備えたダイボンディングテープ(接着層)を、キャリアテープごと直径220mmの円形にカットした。ダイボンディングテープを、カバーテープを剥離したダイシングテープの粘着層面に室温で貼り付け後、室温で1日放置した。その後、直径290mmの円形にダイシングテープをカットし、ダイシング・ダイボンディング一体型テープを得た。
破断伸び率の測定には、島津製作所製オートグラフ「AGS−1000」を用いた。紫外線照射前の粘着層を準備し、幅1cm、長さ8cmのサイズでサンプルを切り出した。このサンプルを用いてチャック間距離50mm、引っ張り速度300mm/minにて測定し、紫外線照射前の粘着層の破断伸び率を測定した。
ダイシングテープのSUS基板に対するピール強度の測定には、島津製作所製オートグラフ「AGS−1000」を用いた。粘着層を有するダイシングテープを幅25mm、長さ100mmになるように切り出し、SUS板(SUS430BA)に貼り付けたものを紫外線照射前のサンプルとした。このサンプルに、ダイシングテープ側より紫外線を空冷式高圧水銀灯(80W/cm、照射距離10cm)により500mJ/cm2照射したものを、紫外線照射後のサンプルとした。これらのサンプルに対して、剥離角度90度、剥離速度200mm/minにて剥離を行い、紫外線照射前及び紫外線照射後それぞれにおいてのSUS基板に対するダイシングテープのピール強度を測定した。
ダイシング(DC)時にダイシングテープから接着層(ダイボンディングテープ)の剥がれ及びチップ飛びの有無を評価した。一枚のウエハをダイシングした際に、接着層の剥がれ及びチップ飛びが一回も生じなかったものを「〇」、一回でも生じたものを「×」として評価した。
上述のように作製したダイシング・ダイボンディング一体型テープを70℃にてミラーウエハ(サイズ8インチ、厚さ50μm)にラミネートした。その後、(株)ディスコ製フルオートダイサーDF6361を用い、チップサイズ5mm角にてダイシングした。その際、カット方法はシングルカットとし、ブレードには、NBC−ZH−127F−SE−27HCBBを用い、ブレード回転数40000rpm、カット速度50mm/sec、ブレードハイトをミラーウエハへの切り込み30μmとして実施した。
同様の条件で、架橋剤及び光開始剤の含有量のみを変更し、実施例2〜6及び比較例1,2を実施した。
Claims (10)
- 基材層、粘着層、接着層がこの順で積層されたダイシング・ダイボンディング一体型テープにおける前記基材層及び前記粘着層として用いられるダイシングテープにおいて、
前記粘着層は、アクリル樹脂と、光開始剤と、架橋剤とを含んでおり(ただし、側鎖にシロキサン結合を持つフッ素系グラフト共重合体を含有する前記粘着層を除く)、
前記架橋剤の含有量は、前記アクリル樹脂100質量部に対して5〜9質量部である、
ダイシングテープ。 - 前記架橋剤の含有量は、前記アクリル樹脂100質量部に対して7〜9質量部である、請求項1に記載のダイシングテープ。
- 前記基材層は、多層構造を有しており、
前記基材層に含まれる層であって、ポリエチレン、ポリプロピレン、ポリエチレン−ポリプロピレンランダム共重合体、ポリエチレン−ポリプロピレンブロック共重合体から選ばれる少なくとも1種が主成分である前記層が、前記粘着層と接しており、
前記アクリル樹脂の重量平均分子量は、30万以上であり、
前記接着層は、フェノール樹脂及び無機フィラーを含んでいる、請求項1又は2に記載のダイシングテープ。 - 前記粘着層の厚さは、5μm以上30μm以下である、請求項1〜3のいずれか一項に記載のダイシングテープ。
- 前記基材層の厚さは、50μm以上150μm以下である、請求項1〜4のいずれか一項に記載のダイシングテープ。
- 前記光開始剤は、1−ヒドロキシシクロヘキシルフェニルケトンである、請求項1〜5のいずれか一項に記載のダイシングテープ。
- 前記光開始剤の含有量は、前記アクリル樹脂100質量部に対し0.5〜1.5質量部である、請求項1〜6のいずれか一項に記載のダイシングテープ。
- 前記接着層は、エポキシ基含有アクリル共重合体を含む、請求項1〜7のいずれか一項に記載のダイシングテープ。
- 前記ダイシング・ダイボンディング一体型テープは、30〜50μmの厚さを有する半導体チップに用いられる、請求項1〜8のいずれか一項に記載のダイシングテープ。
- 前記ダイシング・ダイボンディング一体型テープは、半導体チップを1辺1〜5mmのサイズにダイシングする際に用いられる、請求項1〜9のいずれか一項に記載のダイシングテープ。
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