JP6152117B2 - 無水制汗剤組成物 - Google Patents
無水制汗剤組成物 Download PDFInfo
- Publication number
- JP6152117B2 JP6152117B2 JP2014545152A JP2014545152A JP6152117B2 JP 6152117 B2 JP6152117 B2 JP 6152117B2 JP 2014545152 A JP2014545152 A JP 2014545152A JP 2014545152 A JP2014545152 A JP 2014545152A JP 6152117 B2 JP6152117 B2 JP 6152117B2
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- JP
- Japan
- Prior art keywords
- composition according
- antiperspirant composition
- anhydrous antiperspirant
- polyethylene glycol
- anhydrous
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 120
- 230000001166 anti-perspirative effect Effects 0.000 title claims description 58
- 239000003213 antiperspirant Substances 0.000 title claims description 58
- 229920001223 polyethylene glycol Polymers 0.000 claims description 33
- 239000012876 carrier material Substances 0.000 claims description 22
- -1 activated aluminum chlorohydrate Chemical class 0.000 claims description 20
- 239000000443 aerosol Substances 0.000 claims description 19
- 150000001768 cations Chemical class 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 11
- 239000011591 potassium Substances 0.000 claims description 11
- 229910052700 potassium Inorganic materials 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000003380 propellant Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 238000004090 dissolution Methods 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 7
- 210000004243 sweat Anatomy 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
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- 239000000126 substance Substances 0.000 claims description 4
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- 229920000867 polyelectrolyte Polymers 0.000 description 13
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
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- 238000003756 stirring Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
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- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 239000002781 deodorant agent Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
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- 239000004471 Glycine Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
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- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 3
- 229910000271 hectorite Inorganic materials 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- CRDAMVZIKSXKFV-UHFFFAOYSA-N farnesol Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 2
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- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 2
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- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
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- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
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- CEZONBVMFRWNCJ-CYGHRXIMSA-N [(3r,3ar,6s,6ar)-3-hydroxy-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-6-yl] dodecanoate Chemical compound O[C@@H]1CO[C@@H]2[C@@H](OC(=O)CCCCCCCCCCC)CO[C@@H]21 CEZONBVMFRWNCJ-CYGHRXIMSA-N 0.000 description 1
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- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- ADGFKRMKSIAMAI-UHFFFAOYSA-L oxygen(2-);zirconium(4+);chloride;hydroxide Chemical compound [OH-].[O-2].[Cl-].[Zr+4] ADGFKRMKSIAMAI-UHFFFAOYSA-L 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 229940057874 phenyl trimethicone Drugs 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229940093424 polyaminopropyl biguanide Drugs 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000035409 positive regulation of cell proliferation Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940116987 ppg-3 myristyl ether Drugs 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000008591 skin barrier function Effects 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 159000000008 strontium salts Chemical class 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012049 topical pharmaceutical composition Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/58—Metal complex; Coordination compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
HO−(CH2−CH2−O)4−H
を有する。
1.好ましくはより少ない量のポリエチレンワックスおよび水素化ヒマシ油の存在下、主成分としてのステアリルアルコール;または
2.好ましくはより少ない量の水素化ヒマシ油の存在下、主成分としてのポリエチレンワックス
を含むことが見出された。
1. R−(SiMe2−O−)x−SiMe2R
[式中、xは少なくとも10、好ましくは10から50であり、かつRは、少なくとも20個の炭素、好ましくは25から40個の炭素を含有する、特に少なくとも30個の炭素の平均線状鎖長を有するアルキル基を表す];または
2. Y−(SiMe2−O−)y(Si[OR’]Me−O−)z−Y’
[式中、YはSiMe2−Oを、Y’はSiMe2を、R’は、ステアリル等の少なくとも15個、好ましくは18から22個の炭素のアルキルを表し、yおよびzはいずれも合計して好ましくは10から50までの整数である]
を満たす。
下記の例は、本発明のある特定の具体的な実施形態を例証するものであり、本発明の範囲を限定するものではない。本発明による実施例を数字によって指示し、比較例を文字によって指示する。指示されているすべての量は、別段の指示がない限り、重量百分率である。
Claims (14)
- 制汗剤活性物質、前記制汗剤活性物質が不溶性である担体物質、ならびにナトリウム、カリウム、マグネシウム、カルシウム、塩化物および臭化物イオンを含む電解質混合物のポリエチレングリコール溶液を含有する1から50%までのアルミニウムおよび/またはジルコニウムの懸濁液を含み、前記溶液中におけるナトリウム対他の指定されているカチオンの重量比が3未満:2である、無水制汗剤組成物。
- 前記ポリエチレングリコールが、20℃で、100から900までの平均分子量を有する液体である、請求項1に記載の無水制汗剤組成物。
- 前記ポリエチレングリコールが、4つの繰り返し単位を有する、請求項2に記載の無水制汗剤組成物。
- 活性化された制汗剤活性物質を含む、請求項1から3のいずれかに記載の無水制汗剤組成物。
- 噴射剤ガスを含み、エアゾール組成物の形態である、請求項1から4のいずれかに記載の無水制汗剤組成物。
- 活性化されたアルミニウムクロロハイドレートを含む、請求項5に記載の無水制汗剤組成物。
- 構造化剤を含み、スティックまたは軟固体の形態である、請求項1から4のいずれかに記載の無水制汗剤組成物。
- アルミニウム−ジルコニウムテトラクロロハイドレックス−グリシン塩を含む、請求項7に記載の無水制汗剤組成物。
- 前記ポリエチレングリコール溶液中におけるマグネシウム対前記他の指定されているカチオンの前記重量比が1:2以上である、請求項1から8のいずれかに記載の無水制汗剤組成物。
- 前記ポリエチレングリコール溶液中におけるカルシウム対前記溶液中の前記他の指定されているカチオンの前記重量比が1:10以上である、請求項1から9のいずれかに記載の無水制汗剤組成物。
- 前記ポリエチレングリコール溶液中におけるカリウム対前記溶液中の前記他の指定されているカチオンの前記重量比が1:20以上である、請求項1から10のいずれかに記載の無水制汗剤組成物。
- ポリエチレングリコール溶液が、重量で下記の相対量のカチオン:35から45%までのマグネシウム;32から42%までのナトリウム;12から20%までのカルシウム;および5から9%までのカリウムを有する、請求項1から11のいずれかに記載の無水制汗剤組成物。
- 汗を減少させる方法であって、請求項1から12のいずれかに記載の組成物の局所塗布を含む方法。
- ナトリウム、カリウム、マグネシウム、カルシウム、塩化物および臭化物イオンを含む電解質混合物のポリエチレングリコール中への溶解であって、前記混合物中におけるナトリウム対前記他の指定されているカチオンの比が3未満:2である溶解と、
そのようにして形成された電解質混合物のポリエチレングリコール溶液の、担体物質への混合と、
前記混合の前または後に、制汗剤活性物質を含有する1から50%までのアルミニウムおよび/またはジルコニウムの、前記担体物質への導入であって、前記制汗剤活性物質が前記担体物質に不溶性である導入
とを含む、無水制汗剤組成物の製造方法。
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EP11192968.3A EP2604249B1 (en) | 2011-12-12 | 2011-12-12 | Anhydrous antiperspirant compositions |
EP11192968.3 | 2011-12-12 | ||
PCT/EP2012/072627 WO2013087333A1 (en) | 2011-12-12 | 2012-11-14 | Anhydrous antiperspirant compositions |
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JP (1) | JP6152117B2 (ja) |
CN (1) | CN103987361B (ja) |
AR (1) | AR088918A1 (ja) |
AU (2) | AU2012351041B2 (ja) |
BR (1) | BR112014013216B1 (ja) |
CA (1) | CA2856115A1 (ja) |
CL (1) | CL2014001471A1 (ja) |
DE (1) | DE202012011862U1 (ja) |
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IN (1) | IN2014MN00959A (ja) |
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PH (1) | PH22012000673Y1 (ja) |
PL (1) | PL2604249T3 (ja) |
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ZA (1) | ZA201404034B (ja) |
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SE540614C2 (en) * | 2014-12-05 | 2018-10-02 | Stockholms Analytiska Laboratorium Ab | Aluminum-free antiperspirant / deodorant compositions and method of preparing the same |
EP3374032A1 (en) * | 2015-11-09 | 2018-09-19 | Unilever PLC | Anti-perspirant composition |
DE102017006533A1 (de) * | 2017-07-11 | 2019-01-17 | Beiersdorf Ag | Wasserfreie Zusammensetzungen in Aerosolform, die ein oder mehrere suspendierte Elektrolyte enthalten |
WO2019038101A1 (en) | 2017-08-23 | 2019-02-28 | Unilever Plc | ANTI-SHOCK ANHYDROUS COMPOSITION IN THE FORM OF AEROSOL |
WO2020205278A1 (en) * | 2019-04-01 | 2020-10-08 | Honeywell International Inc. | Personal care aerosol compositions, methods and devices |
US20220387275A1 (en) * | 2019-11-15 | 2022-12-08 | Conopco, Inc., D/B/A Unilever | Deodorant compositions |
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AU2012101815B4 (en) | 2013-08-29 |
EA201491157A1 (ru) | 2014-09-30 |
AU2012351041B2 (en) | 2016-05-12 |
EP2604249B1 (en) | 2014-06-11 |
AR088918A1 (es) | 2014-07-16 |
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PH22012000673U1 (en) | 2016-03-28 |
US20150037264A1 (en) | 2015-02-05 |
CA2856115A1 (en) | 2013-06-20 |
IN2014MN00959A (ja) | 2015-04-24 |
ES2501042T3 (es) | 2014-10-01 |
AU2012101815C4 (en) | 2016-08-04 |
AU2012101815A4 (en) | 2013-01-17 |
ZA201404034B (en) | 2015-12-23 |
BR112014013216B1 (pt) | 2018-10-30 |
CN103987361B (zh) | 2016-10-12 |
US9173833B2 (en) | 2015-11-03 |
PL2604249T3 (pl) | 2014-11-28 |
MX2014007097A (es) | 2014-07-22 |
DE202012011862U1 (de) | 2013-03-22 |
MX336387B (es) | 2016-01-18 |
WO2013087333A1 (en) | 2013-06-20 |
BR112014013216A2 (pt) | 2017-06-13 |
EP2604249A1 (en) | 2013-06-19 |
PH22012000673Y1 (en) | 2016-03-28 |
CN103987361A (zh) | 2014-08-13 |
JP2015500252A (ja) | 2015-01-05 |
AU2012351041A1 (en) | 2014-06-12 |
CL2014001471A1 (es) | 2015-01-16 |
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