JP6112892B2 - 粘着性組成物、粘着剤および粘着シート - Google Patents
粘着性組成物、粘着剤および粘着シート Download PDFInfo
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- JP6112892B2 JP6112892B2 JP2013025707A JP2013025707A JP6112892B2 JP 6112892 B2 JP6112892 B2 JP 6112892B2 JP 2013025707 A JP2013025707 A JP 2013025707A JP 2013025707 A JP2013025707 A JP 2013025707A JP 6112892 B2 JP6112892 B2 JP 6112892B2
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- Prior art keywords
- pressure
- sensitive adhesive
- meth
- acrylic acid
- acid ester
- Prior art date
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- 239000000853 adhesive Substances 0.000 title claims description 76
- 230000001070 adhesive effect Effects 0.000 title claims description 76
- 239000000203 mixture Substances 0.000 title claims description 53
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 114
- 229920000642 polymer Polymers 0.000 claims description 77
- 239000000178 monomer Substances 0.000 claims description 68
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 65
- 239000003431 cross linking reagent Substances 0.000 claims description 52
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 39
- 239000010410 layer Substances 0.000 claims description 31
- 230000003287 optical effect Effects 0.000 claims description 26
- 125000002723 alicyclic group Chemical group 0.000 claims description 25
- 239000012790 adhesive layer Substances 0.000 claims description 21
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 19
- 125000000524 functional group Chemical group 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 12
- 239000012948 isocyanate Substances 0.000 claims description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 11
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
- 239000011368 organic material Substances 0.000 claims description 5
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical group C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 4
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 38
- -1 etc.) Chemical group 0.000 description 35
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 238000005259 measurement Methods 0.000 description 13
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- 125000004432 carbon atom Chemical group C* 0.000 description 9
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
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- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 5
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
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- 229910003437 indium oxide Inorganic materials 0.000 description 4
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
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- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 4
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000005370 alkoxysilyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
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- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
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- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- LOOUJXUUGIUEBC-UHFFFAOYSA-N 3-(dimethoxymethylsilyl)propane-1-thiol Chemical compound COC(OC)[SiH2]CCCS LOOUJXUUGIUEBC-UHFFFAOYSA-N 0.000 description 2
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
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- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
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- 230000015572 biosynthetic process Effects 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Polarising Elements (AREA)
- Laminated Bodies (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013025707A JP6112892B2 (ja) | 2013-02-13 | 2013-02-13 | 粘着性組成物、粘着剤および粘着シート |
| TW103102888A TWI634178B (zh) | 2013-02-13 | 2014-01-27 | Adhesive composition, adhesive and adhesive sheet |
| KR1020140009487A KR102246041B1 (ko) | 2013-02-13 | 2014-01-27 | 점착성 조성물, 점착제 및 점착시트 |
| CN201410049205.9A CN103980846B (zh) | 2013-02-13 | 2014-02-13 | 压敏粘合性组合物、压敏粘合剂以及压敏粘合片 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013025707A JP6112892B2 (ja) | 2013-02-13 | 2013-02-13 | 粘着性組成物、粘着剤および粘着シート |
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| Publication Number | Publication Date |
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| JP2014152312A JP2014152312A (ja) | 2014-08-25 |
| JP6112892B2 true JP6112892B2 (ja) | 2017-04-12 |
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| JP2013025707A Active JP6112892B2 (ja) | 2013-02-13 | 2013-02-13 | 粘着性組成物、粘着剤および粘着シート |
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| JP (1) | JP6112892B2 (ko) |
| KR (1) | KR102246041B1 (ko) |
| CN (1) | CN103980846B (ko) |
| TW (1) | TWI634178B (ko) |
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| JP6609405B2 (ja) * | 2014-08-26 | 2019-11-20 | 三星エスディアイ株式会社 | 粘着剤組成物、粘着剤層、粘着型光学フィルム、粘着型偏光板、および画像表示装置 |
| JP6336897B2 (ja) * | 2014-12-09 | 2018-06-06 | 藤森工業株式会社 | 粘着剤層及び粘着フィルム |
| JP6550251B2 (ja) * | 2015-03-03 | 2019-07-24 | リンテック株式会社 | 粘着剤層付き光学フィルム |
| TWI741978B (zh) * | 2015-03-31 | 2021-10-11 | 日商住友化學股份有限公司 | 光學積層體及液晶顯示裝置 |
| KR102665600B1 (ko) * | 2015-03-31 | 2024-05-10 | 스미또모 가가꾸 가부시키가이샤 | 광학 적층체 및 액정 표시 장치 |
| JP6904926B2 (ja) * | 2015-04-15 | 2021-07-21 | 藤森工業株式会社 | 粘着剤層及び粘着フィルム |
| JP2016204406A (ja) * | 2015-04-15 | 2016-12-08 | 藤森工業株式会社 | 粘着剤層及び粘着フィルム |
| KR102350144B1 (ko) * | 2015-06-30 | 2022-01-11 | 린텍 가부시키가이샤 | 점착성 조성물, 점착제, 점착 시트 및 표시체 |
| JP6826362B2 (ja) * | 2015-06-30 | 2021-02-03 | リンテック株式会社 | 粘着シート |
| JP6632821B2 (ja) * | 2015-07-01 | 2020-01-22 | リンテック株式会社 | 粘着剤、粘着シートおよび粘着剤層付き光学フィルム |
| JP6776754B2 (ja) * | 2016-09-14 | 2020-10-28 | 三菱ケミカル株式会社 | 偏光板用粘着剤組成物、偏光板用粘着剤、粘着剤層付偏光板並びに離型フィルム付粘着剤層付偏光板 |
| JP6588596B2 (ja) * | 2018-05-07 | 2019-10-09 | 藤森工業株式会社 | 粘着剤層及び粘着フィルム |
| KR102434825B1 (ko) * | 2018-09-28 | 2022-08-22 | 주식회사 엘지화학 | 아크릴계 점착제 조성물, 편광판 및 디스플레이 장치 |
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| CN100588663C (zh) * | 2002-10-15 | 2010-02-10 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
| JP4381686B2 (ja) * | 2003-01-22 | 2009-12-09 | 日本カーバイド工業株式会社 | 偏光フィルム用感圧接着剤組成物 |
| JP4521520B2 (ja) * | 2003-08-06 | 2010-08-11 | 綜研化学株式会社 | 低極性フィルム用粘着剤 |
| JP2005314453A (ja) * | 2004-04-27 | 2005-11-10 | Sumitomo Chemical Co Ltd | アクリル樹脂及び該樹脂を含有する粘着剤 |
| WO2006009250A1 (ja) * | 2004-07-22 | 2006-01-26 | Soken Chemical & Engineering Co., Ltd. | 偏光板用粘着剤組成物および偏光板 |
| JP2007169329A (ja) * | 2005-12-19 | 2007-07-05 | Saiden Chemical Industry Co Ltd | 光学用粘着剤組成物および粘着シート |
| JP5591477B2 (ja) | 2008-03-13 | 2014-09-17 | 日東電工株式会社 | 光学部材用粘着剤組成物、光学部材用粘着剤層、粘着型光学部材、透明導電性積層体、タッチパネルおよび画像表示装置 |
| JP5407204B2 (ja) * | 2008-07-16 | 2014-02-05 | 王子ホールディングス株式会社 | 粘着剤、両面粘着シート、光学フィルター、及びディスプレイ |
| JP6097473B2 (ja) * | 2010-12-13 | 2017-03-15 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着型光学フィルム、および画像表示装置 |
| JP2012208248A (ja) * | 2011-03-29 | 2012-10-25 | Sumitomo Chemical Co Ltd | 液晶表示装置 |
| JP2013032483A (ja) * | 2011-06-28 | 2013-02-14 | Nitto Denko Corp | 光学用両面粘着シート、光学部材、タッチパネル、画像表示装置、及び剥離方法 |
| KR101595146B1 (ko) * | 2011-07-19 | 2016-02-17 | 주식회사 엘지화학 | 터치 패널 |
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