JP6100757B2 - 5−ヒドロキシメチルフルフラールの製造方法 - Google Patents
5−ヒドロキシメチルフルフラールの製造方法 Download PDFInfo
- Publication number
- JP6100757B2 JP6100757B2 JP2014510810A JP2014510810A JP6100757B2 JP 6100757 B2 JP6100757 B2 JP 6100757B2 JP 2014510810 A JP2014510810 A JP 2014510810A JP 2014510810 A JP2014510810 A JP 2014510810A JP 6100757 B2 JP6100757 B2 JP 6100757B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- hexose
- carboxylic acid
- hmf
- fructose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
- C07D307/50—Preparation from natural products
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1154232 | 2011-05-16 | ||
| FR1154232A FR2975396B1 (fr) | 2011-05-16 | 2011-05-16 | Procede de preparation de 5-hydroxymethylfurfural |
| PCT/EP2012/059193 WO2012156479A1 (fr) | 2011-05-16 | 2012-05-16 | Procédé de préparation de 5-hydroxyméthylfurfural |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014515037A JP2014515037A (ja) | 2014-06-26 |
| JP2014515037A5 JP2014515037A5 (enExample) | 2015-06-11 |
| JP6100757B2 true JP6100757B2 (ja) | 2017-03-22 |
Family
ID=44358206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014510810A Active JP6100757B2 (ja) | 2011-05-16 | 2012-05-16 | 5−ヒドロキシメチルフルフラールの製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9238635B2 (enExample) |
| EP (1) | EP2709994B1 (enExample) |
| JP (1) | JP6100757B2 (enExample) |
| BR (1) | BR112013034001B1 (enExample) |
| FR (1) | FR2975396B1 (enExample) |
| WO (1) | WO2012156479A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105007913B (zh) * | 2013-03-14 | 2017-09-29 | 阿彻丹尼尔斯米德兰德公司 | 以减少的副产物形成从糖制造hmf的方法以及改进稳定性的hmf组合物 |
| CN103694203B (zh) * | 2013-12-24 | 2015-04-22 | 华南理工大学 | 纤维素基磺酸催化剂催化果糖制备5-羟甲基糠醛的方法 |
| US9611241B2 (en) | 2014-01-27 | 2017-04-04 | Rennovia Inc. | Conversion of fructose-containing feedstocks to HMF-containing product |
| JP6006853B1 (ja) * | 2015-10-01 | 2016-10-12 | 新日鉄住金エンジニアリング株式会社 | リグノセルロース系バイオマス中の発酵阻害物質低減装置および発酵阻害物質低減方法 |
| EP3402787A4 (en) | 2016-01-13 | 2019-11-27 | Stora Enso Oyj | PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF |
| CN108239050B (zh) * | 2016-12-23 | 2021-06-01 | 中国科学院大连化学物理研究所 | 以固体酸作为催化剂将生物质糖类化合物转化为5-羟甲基糠醛的方法 |
| SG11201913469PA (en) | 2017-07-12 | 2020-01-30 | Stora Enso Oyj | Purified 2,5-furandicarboxylic acid pathway products |
| CN109836403B (zh) * | 2017-11-29 | 2022-09-13 | 中国科学院大连化学物理研究所 | 以木质素磺酸基-醛型树脂为催化剂将生物质糖类化合物转化为5-羟甲基糠醛的方法 |
| CN110452192A (zh) * | 2018-05-07 | 2019-11-15 | 中国科学院宁波材料技术与工程研究所 | 一种制备5-羟甲基-2-呋喃甲醛的方法 |
| CN108484540B (zh) * | 2018-06-12 | 2021-11-19 | 西北工业大学 | 甲酸/乙酸体系中降解纤维素制备5-羟甲基糠醛的方法 |
| FR3097547B1 (fr) * | 2019-06-24 | 2023-04-28 | Ifp Energies Now | Procede de production de 5-hydroxymethylfurfural |
| USD958832S1 (en) * | 2019-08-28 | 2022-07-26 | Agco Corporation | Display screen with icon |
| KR102347177B1 (ko) * | 2020-02-13 | 2022-01-04 | 한국화학연구원 | 5-알콕시메틸퍼퓨랄 제조방법 |
| CN116813579A (zh) * | 2023-06-30 | 2023-09-29 | 中科国生(杭州)科技有限公司 | 一种低共熔溶剂体系催化果糖及蔗糖转化制备hmf的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB600871A (en) * | 1945-10-17 | 1948-04-21 | Walter Norman Haworth | Improvements relating to the manufacture of 5-hydroxymethyl 2-furfural |
| US2929823A (en) * | 1956-11-26 | 1960-03-22 | Merck & Co Inc | Production of 5-hydroxymethylfurfural |
| DE3601281A1 (de) * | 1986-01-17 | 1987-07-23 | Sueddeutsche Zucker Ag | Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel |
| FR2670209B1 (fr) | 1990-12-07 | 1995-04-28 | Commissariat Energie Atomique | Procede de preparation d'hydroxymethyl-5 furfural par catalyse heterogene. |
| US7317116B2 (en) | 2004-12-10 | 2008-01-08 | Archer-Daniels-Midland-Company | Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives |
| EP1834951A1 (en) * | 2006-03-10 | 2007-09-19 | Avantium International B.V. | Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use |
| EP2032550B1 (en) * | 2006-06-06 | 2013-11-20 | Wisconsin Alumni Research Foundation | Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor |
| EP2944632A1 (en) | 2007-12-12 | 2015-11-18 | Archer Daniels Midland Co. | Oxidation of a mixture of 2-hydroxymethyl-5-furfuraldehyde (hmf) and an ester thereof to 2,5-furandicarboxylic acid (fdca) |
| CN101381351B (zh) * | 2008-10-21 | 2011-05-11 | 华南理工大学 | 葡萄糖的甲酸高温催化脱水联产5-羟甲基糠醛、乙酰丙酸和甲酸的方法 |
-
2011
- 2011-05-16 FR FR1154232A patent/FR2975396B1/fr not_active Expired - Fee Related
-
2012
- 2012-05-16 WO PCT/EP2012/059193 patent/WO2012156479A1/fr not_active Ceased
- 2012-05-16 BR BR112013034001-0A patent/BR112013034001B1/pt active IP Right Grant
- 2012-05-16 EP EP12723154.6A patent/EP2709994B1/fr active Active
- 2012-05-16 JP JP2014510810A patent/JP6100757B2/ja active Active
- 2012-05-16 US US14/117,984 patent/US9238635B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112013034001B1 (pt) | 2019-06-18 |
| FR2975396B1 (fr) | 2013-12-27 |
| EP2709994B1 (fr) | 2018-07-25 |
| BR112013034001A2 (pt) | 2016-08-16 |
| EP2709994A1 (fr) | 2014-03-26 |
| JP2014515037A (ja) | 2014-06-26 |
| FR2975396A1 (fr) | 2012-11-23 |
| US9238635B2 (en) | 2016-01-19 |
| US20140121389A1 (en) | 2014-05-01 |
| WO2012156479A1 (fr) | 2012-11-22 |
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| AU2014241870B2 (en) | Process for making 2,5-furandicarboxylic acid | |
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| US20150183755A1 (en) | Spray oxidation process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural | |
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