JP6100527B2 - エラストマー組成物及びそれらの製品における使用 - Google Patents
エラストマー組成物及びそれらの製品における使用 Download PDFInfo
- Publication number
- JP6100527B2 JP6100527B2 JP2012526758A JP2012526758A JP6100527B2 JP 6100527 B2 JP6100527 B2 JP 6100527B2 JP 2012526758 A JP2012526758 A JP 2012526758A JP 2012526758 A JP2012526758 A JP 2012526758A JP 6100527 B2 JP6100527 B2 JP 6100527B2
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- JP
- Japan
- Prior art keywords
- succinic anhydride
- elastomer
- alloy
- thermoplastic
- oligomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001971 elastomer Polymers 0.000 title claims description 91
- 239000000806 elastomer Substances 0.000 title claims description 64
- 239000000203 mixture Substances 0.000 title description 49
- 229940014800 succinic anhydride Drugs 0.000 claims description 56
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 50
- 239000000956 alloy Substances 0.000 claims description 38
- 229910045601 alloy Inorganic materials 0.000 claims description 38
- 239000004014 plasticizer Substances 0.000 claims description 32
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 21
- 229920002647 polyamide Polymers 0.000 claims description 16
- 239000004952 Polyamide Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 229920002367 Polyisobutene Polymers 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 229920005652 polyisobutylene succinic anhydride Polymers 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 229940124530 sulfonamide Drugs 0.000 claims description 4
- 150000003456 sulfonamides Chemical group 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 150000004985 diamines Chemical group 0.000 claims description 3
- 229920005555 halobutyl Polymers 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 3
- MHALQPUFCVTXKV-AATRIKPKSA-N 3-[(e)-hex-1-enyl]oxolane-2,5-dione Chemical compound CCCC\C=C\C1CC(=O)OC1=O MHALQPUFCVTXKV-AATRIKPKSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 37
- -1 alkyl styrene Chemical compound 0.000 description 33
- 229920001169 thermoplastic Polymers 0.000 description 33
- 239000004416 thermosoftening plastic Substances 0.000 description 32
- 239000005060 rubber Substances 0.000 description 26
- 239000000178 monomer Substances 0.000 description 21
- 229920005992 thermoplastic resin Polymers 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 229910052736 halogen Inorganic materials 0.000 description 12
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 9
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical group CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 150000002367 halogens Chemical class 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 150000008064 anhydrides Chemical class 0.000 description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
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- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
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- 239000011145 styrene acrylonitrile resin Substances 0.000 description 4
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 3
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- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
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- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 3
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- 238000002360 preparation method Methods 0.000 description 3
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 2
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- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 2
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- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
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- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
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- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
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|---|---|---|---|
| US12/548,797 | 2009-08-27 | ||
| US12/548,797 US8809455B2 (en) | 2009-08-27 | 2009-08-27 | Elastomeric compositions and their use in articles |
| PCT/US2010/041689 WO2011025593A1 (en) | 2009-08-27 | 2010-07-12 | Elastomeric compositions and their use in articles |
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| Publication Number | Publication Date |
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| JP2013502506A JP2013502506A (ja) | 2013-01-24 |
| JP2013502506A5 JP2013502506A5 (enExample) | 2014-06-26 |
| JP6100527B2 true JP6100527B2 (ja) | 2017-03-22 |
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| CN103502327B (zh) * | 2011-03-29 | 2015-12-16 | 埃克森美孚化学专利公司 | 动态硫化热塑性弹性体层压件 |
| EP2574635A1 (en) * | 2011-09-28 | 2013-04-03 | Lanxess Inc. | Process for continuous production of halogen-free thermoplastic elastomer compositions |
| CN103998511B (zh) | 2011-12-19 | 2016-07-06 | 埃克森美孚化学专利公司 | 弹性体组合物及其在制品中的应用 |
| EP2821251B1 (en) * | 2012-02-29 | 2017-05-03 | Bridgestone Corporation | Tire |
| JP2013189526A (ja) * | 2012-03-13 | 2013-09-26 | Yokohama Rubber Co Ltd:The | 熱可塑性エラストマー組成物 |
| US9540501B2 (en) * | 2012-04-16 | 2017-01-10 | Zeon Chemicals L.P. | Water swellable rubber composition having stable swelling property at high temperatures |
| CN103030895A (zh) * | 2012-12-12 | 2013-04-10 | 北京化工大学 | 一种高气体阻隔性热塑性硫化胶及其制备方法 |
| WO2014099117A1 (en) * | 2012-12-20 | 2014-06-26 | Exxonmobil Chemical Patents Inc. | Process for preparing dynamically vulcanized alloys |
| EP3303466A1 (en) * | 2015-05-29 | 2018-04-11 | ExxonMobil Chemical Patents Inc. | Dynamically vulcanized alloys |
| RU2714876C2 (ru) * | 2015-07-28 | 2020-02-20 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерные композиции и их применение в изделиях |
| CN108137923B (zh) * | 2015-12-28 | 2021-01-01 | 三菱瓦斯化学株式会社 | 干混混合物 |
| CN105504660A (zh) * | 2016-01-26 | 2016-04-20 | 苏州羽帆新材料科技有限公司 | 一种绝缘塑胶材料及其制备方法 |
| CN109422969B (zh) * | 2017-09-04 | 2020-05-19 | 北京化工大学 | 一种基于evoh的高气体阻隔性热塑性硫化胶及其制备方法 |
| US11999920B2 (en) | 2020-09-14 | 2024-06-04 | Ecolab Usa Inc. | Cold flow additives for plastic-derived synthetic feedstock |
| WO2022192577A1 (en) | 2021-03-10 | 2022-09-15 | Ecolab Usa Inc. | Stabilizer additives for plastic-derived synthetic feedstock |
| WO2023064375A1 (en) | 2021-10-14 | 2023-04-20 | Ecolab Usa Inc. | Antifouling agents for plastic-derived synthetic feedstocks |
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| US5162445A (en) | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US6079465A (en) | 1995-01-23 | 2000-06-27 | The Yokohama Rubber Co., Ltd. | Polymer composition for tire and pneumatic tire using same |
| KR100703576B1 (ko) | 1998-01-13 | 2007-04-05 | 요코하마 고무 가부시키가이샤 | 열가소성 탄성중합체 조성물, 이의 제조방법 및 이를 사용한 공기 타이어 |
| JP2004511606A (ja) * | 2000-10-11 | 2004-04-15 | エクソンモービル・ケミカル・パテンツ・インク | 増大された粘度を有するハロゲン化エラストマー組成物 |
| DE60326176D1 (de) | 2003-03-06 | 2009-03-26 | Yokohama Rubber Co Ltd | Thermoplastische elastomerzusammensetzung mit mässigem härtungszustand |
| US7538158B2 (en) * | 2003-03-06 | 2009-05-26 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer composition having viscosity-enhanced and vulcanized elastomer dispersions |
| WO2004081116A1 (en) * | 2003-03-06 | 2004-09-23 | Exxonmobil Chemical Patents, Inc. | Oriented thermoplastic elastomer film and process for producing the same |
| AU2003213726A1 (en) * | 2003-03-06 | 2004-09-30 | Exxonmobil Chemical Patents, Inc. | A method for controlling dispersion size of elastomer in thermoplastic elastomer composition |
| US20060235156A1 (en) | 2005-04-14 | 2006-10-19 | Griswold Roy M | Silylated thermoplastic vulcanizate compositions |
| CN101296997B (zh) | 2005-10-27 | 2011-12-07 | 埃克森美孚化学专利公司 | 低渗透性热塑性弹性体组合物 |
| JP5690471B2 (ja) * | 2005-12-16 | 2015-03-25 | エクソンモービル・ケミカル・パテンツ・インク | エラストマー組成物の加工助剤 |
| WO2007100157A1 (ja) * | 2006-03-03 | 2007-09-07 | The Yokohama Rubber Co., Ltd. | エラストマー組成物並びにその製造方法及びそれを用いた空気入りタイヤ |
| WO2007111584A1 (en) * | 2006-03-24 | 2007-10-04 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition having excellent low temperature property |
| WO2009048472A1 (en) | 2007-10-11 | 2009-04-16 | Exxonmobil Chemical Patents Inc. | Efficient mixing process for producing thermoplastic elastomer composition |
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- 2010-07-12 RU RU2012107224/04A patent/RU2556992C2/ru active
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- 2010-07-12 WO PCT/US2010/041689 patent/WO2011025593A1/en not_active Ceased
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- 2010-07-12 CN CN201080037872.5A patent/CN102482463B/zh active Active
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|---|---|
| RU2012107224A (ru) | 2013-09-10 |
| JP2013502506A (ja) | 2013-01-24 |
| CA2771419A1 (en) | 2011-03-03 |
| RU2556992C2 (ru) | 2015-07-20 |
| IN2012DN00946A (enExample) | 2015-04-10 |
| US20110054093A1 (en) | 2011-03-03 |
| CA2771419C (en) | 2015-05-12 |
| WO2011025593A1 (en) | 2011-03-03 |
| CN102482463A (zh) | 2012-05-30 |
| EP2470601B1 (en) | 2016-02-17 |
| EP2470601A1 (en) | 2012-07-04 |
| US8809455B2 (en) | 2014-08-19 |
| CN102482463B (zh) | 2014-08-13 |
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