JP6033302B2 - インサイチュ有機ペルオキシド生産および酸化的ヘテロ原子変換のための統合されたシステムおよびプロセス - Google Patents
インサイチュ有機ペルオキシド生産および酸化的ヘテロ原子変換のための統合されたシステムおよびプロセス Download PDFInfo
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Description
本発明は、炭化水素の硫黄分および窒素分を効率的に低減し、硫黄レベルおよび窒素レベルが低減された燃料を生産するための統合された酸化プロセスに関する。
本出願は、2011年7月27日に出願された特許文献1の利益を主張するものであり、この特許文献1の開示は参照により本明細書に組み込まれる。
Claims (32)
- 炭化水素原料中のヘテロ原子含有化合物をそれらの酸化生成物へ変換するためのプロセスであって、
前記炭化水素原料を芳香族リーン留分と芳香族リッチ留分に分離すること、
前記芳香族リッチ留分を、有機ペルオキシド発生に有効な条件下で、有効量の気体酸化剤と接触させて、有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を生成すること、
生成された有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を、前記混合物中および前記芳香族リーン留分中のヘテロ原子含有炭化水素のヘテロ原子含有炭化水素酸化生成物への酸化的変換に有効な条件下で、前記芳香族リーン留分と接触させること
を含む、プロセス。 - 前記炭化水素原料を第1の部分と第2の部分に分離すること、および
前記第1の部分にのみ、芳香族リーン留分および芳香族リッチ留分への分離を行うこと
をさらに含み、
この場合、ヘテロ原子含有炭化水素の変換に有効な条件下での接触は、前記第2の部分中のヘテロ原子含有炭化水素をヘテロ原子含有炭化水素酸化生成物へ変換するための第2の部分の接触をさらに含む、請求項1に記載のプロセス。 - 炭化水素原料中のヘテロ原子含有化合物をそれらの酸化生成物へ変換するためのプロセスであって、
前記炭化水素原料を芳香族リーン留分と芳香族リッチ留分に分離すること、
前記芳香族リッチ留分のみを、有機ペルオキシド発生に有効な条件下で、有効量の気体酸化剤及び触媒と共通槽内で接触させて、有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を生成すること、
前記共通槽内の芳香族リッチ留分から生成された有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を、芳香族リッチ留分からのヘテロ原子含有炭化水素のヘテロ原子含有炭化水素酸化生成物への酸化的変換に有効な条件下で、かつ十分な滞留時間で維持することを含む、プロセス。 - 請求項3において、前記芳香族リーン留分の全てまたは一部を水素化処理することを含む、プロセス。
- 前記芳香族リッチ留分炭化水素原料を第1の部分と第2の部分に分離すること、および
前記第1の部分のみを、有機ペルオキシド化合物への反応に有効な条件下で、有効量の気体酸化剤と接触させること
をさらに含み、
この場合、ヘテロ原子含有炭化水素の変換に有効な条件下での接触は、前記第2の部分中のヘテロ原子含有炭化水素をヘテロ原子含有炭化水素酸化生成物へ変換するための第2の部分の接触をさらに含む、請求項3に記載のプロセス。 - 前記炭化水素原料または前記芳香族リッチ留分の第1の部分および第2の部分への分離がダイバーターを用いるものである、請求項2または5のいずれか一項に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約90V%である、請求項6に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約50V%である、請求項6に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約30V%である、請求項6に記載のプロセス。
- 前記炭化水素原料または前記芳香族リッチ留分の第1の部分および第2の部分への分離が、蒸発分離装置または蒸留ユニットを用いて、約300℃〜約360℃の範囲の初期沸点を有する第1の部分を生成するものである、請求項2または5のいずれか一項に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約50V%である、請求項10に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約30V%である、請求項10に記載のプロセス。
- 前記第1の部分が前記炭化水素原料の約1V%〜約5V%である、請求項10に記載のプロセス。
- 有機ペルオキシド発生に有効な条件下での接触およびヘテロ原子含有炭化水素のヘテロ原子含有炭化水素酸化生成物への酸化的変換に有効な条件下での接触が個別槽内で行われる、請求項1または3のいずれか一項に記載のプロセス。
- 有機ペルオキシド発生に有効な条件下での接触が有機ペルオキシド発生装置内で行われる、請求項14に記載のプロセス。
- 前記有機ペルオキシド発生装置内での反応が触媒の存在下で行われる、請求項15に記載のプロセス。
- 前記触媒が不均一系触媒である、請求項16に記載のプロセス。
- 前記不均一系触媒が、一般式MxOy(式中、x=1または2、y=2または5、かつ、Mは周期表の第IVB族、第VB族および第VIB族の元素からなる群から選択される元素である)を有する化合物である、請求項17に記載のプロセス。
- 前記不均一系触媒がCo(サロフェン)またはCo(サロフェン)の錯体である、請求項17に記載のプロセス。
- 前記触媒が均一系触媒である、請求項16に記載のプロセス。
- 前記均一系触媒が遷移金属錯体である、請求項20に記載のプロセス。
- ヘテロ原子含有炭化水素のヘテロ原子含有炭化水素酸化生成物への酸化的変換に有効な条件下での接触が酸化反応装置内で行われる、請求項14に記載のプロセス。
- 前記酸化反応装置内での反応が触媒の存在下で行われる、請求項22に記載のプロセス。
- 前記触媒が1種以上の遷移金属酸化物を含む、請求項16に記載のプロセス。
- 有機ペルオキシド発生に有効な条件下での接触およびヘテロ原子含有炭化水素のヘテロ原子含有炭化水素酸化生成物への酸化的変換に有効な条件下での接触が共通槽内で行われる、請求項1または3のいずれか一項に記載のプロセス。
- 前記共通槽内での反応が二元機能触媒の存在下で行われる、請求項25に記載のプロセス。
- 炭化水素生成物流から硫黄含有炭化水素化合物および窒素含有炭化水素化合物の酸化生成物を除去することをさらに含む、請求項1または3のいずれか一項に記載のプロセス。
- 酸化生成物の除去が、研磨、抽出、吸着またはデカンテーションのうちの1以上によるものである、請求項27に記載のプロセス。
- 炭化水素原料中の硫黄含有炭化水素化合物および窒素含有炭化水素化合物をそれらの個々の酸化生成物へ変換するための装置であって、
前記炭化水素供給材料から芳香族化合物を抽出する機能を果たすことができ、芳香族分離部が前記炭化水素原料を受容するための入口、芳香族リッチ出口および芳香族リーン出口を備えている、芳香族分離装置と、
前記芳香族リッチ出口および気体酸化剤の供給源と流体連通し、かつ、有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を排出するための出口を備え、前記芳香族リッチ留分中の炭化水素と気体酸化剤との反応による有機ペルオキシド生成を促進するのに有効な条件下で機能する、有機ペルオキシド発生装置と、
前記有機ペルオキシド発生装置出口および前記芳香族リーン出口と流体連通し、かつ、ヘテロ原子含有炭化水素の酸化生成物を含有する混合物を排出するための出口を備え、ヘテロ原子含有炭化水素と生成された有機ペルオキシドとの反応によるヘテロ原子含有炭化水素の酸化を促進するのに有効な条件下で機能する、酸化反応装置と
を含む、装置。 - 炭化水素原料中の硫黄含有炭化水素化合物および窒素含有炭化水素化合物をそれらの個々の酸化生成物へ変換するための装置であって、
前記炭化水素原料を第1の部分と第2の部分に分離する機能を果たすことができ、前記炭化水素原料を受容するための入口、第1の部分の出口および第2の部分の出口を備えている、分離装置と、
前記第2の部分から芳香族化合物を抽出する機能を果たすことができ、芳香族分離部が、前記第1の部分の出口と流体連通している入口、芳香族リッチ出口および芳香族リーン出口を備えている、芳香族分離装置と、
前記芳香族リッチ出口および気体酸化剤の供給源と流体連通し、かつ、有機ペルオキシドとヘテロ原子含有炭化水素とを含有する混合物を排出するための出口を備え、前記芳香族リッチ留分中の炭化水素と気体酸化剤との反応による有機ペルオキシド生成を促進するのに有効な条件下で機能する、有機ペルオキシド発生装置と、
前記有機ペルオキシド発生装置出口、前記芳香族リーン出口および前記第2の部分の出口と流体連通し、かつ、ヘテロ原子含有炭化水素の酸化生成物を含有する混合物を排出するための出口を備え、ヘテロ原子含有炭化水素と生成された有機ペルオキシドとの反応によるヘテロ原子含有炭化水素の酸化を促進するのに有効な条件下で機能する、酸化反応装置と
を含む、装置。 - 前記装置において、
前記芳香族リーン出口と流体連通し、かつ、処理された生成物の出口を備えた
水素化処理装置
をさらに含む、請求項29に記載の装置。 - 炭化水素原料中の硫黄含有炭化水素化合物および窒素含有炭化水素化合物をそれらの個々の酸化生成物へ変換するための装置であって、
前記炭化水素供給材料から芳香族化合物を抽出する機能を果たすことができ、芳香族分離部が、前記炭化水素原料を受容するための入口、芳香族リッチ出口および芳香族リーン出口を備えている、芳香族分離装置と、
前記芳香族リッチ出口および気体酸化剤の供給源と流体連通し、かつ、ヘテロ原子含有炭化水素の酸化生成物を含有する混合物を排出するための出口を備え、前記芳香族リッチ留分中の炭化水素と気体酸化剤との反応による有機ペルオキシド生成を促進しかつヘテロ原子含有炭化水素と生成された有機ペルオキシドの反応によるヘテロ原子含有炭化水素の酸化を促進するのに有効な条件下で機能する、有機ペルオキシド発生のための触媒を有する共通槽と、
前記芳香族リーン出口と流体連通し、かつ、処理された生成物の出口を備えている、水素化処理装置と
を含む、装置。
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