JP5933072B2 - 合成ガスを製造するための方法および装置 - Google Patents
合成ガスを製造するための方法および装置 Download PDFInfo
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- 238000000034 method Methods 0.000 title claims description 37
- 230000015572 biosynthetic process Effects 0.000 title claims description 16
- 238000003786 synthesis reaction Methods 0.000 title claims description 16
- 238000002309 gasification Methods 0.000 claims description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- 238000002485 combustion reaction Methods 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 15
- 238000000197 pyrolysis Methods 0.000 claims description 14
- 239000000446 fuel Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 15
- 229910002091 carbon monoxide Inorganic materials 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003245 coal Substances 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
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- C10J3/10—Continuous processes using external heating
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- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/80—Other features with arrangements for preheating the blast or the water vapour
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
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- C10J2300/093—Coal
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
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- C10J2300/094—Char
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- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1246—Heating the gasifier by external or indirect heating
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1261—Heating the gasifier by pulse burners
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1269—Heating the gasifier by radiating device, e.g. radiant tubes
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- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
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- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
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- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Carbon And Carbon Compounds (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
2 熱交換器
3 熱交換器
A 排出ガス
Br1・・・Brn バーナ
C 炭素粒子
O 酸化剤
P プロセスガス
S 合成ガス
S1 スラグ
Claims (6)
- 炭素含有材料の熱分解により炭素粒子(C)とバーナ燃料とを入手し、
熱分解からの炭素粒子(C)をプロセスガス(P)と共に反応器(1)に供給し、
反応器(1)に配置される、閉鎖された一端部を有するバーナ(Br1〜Brn)に、熱分解からの燃料を供給し、
反応器(1)内でバーナ(Br1〜Brn)の燃焼とプロセスガス(P)との間に直接的なガス交換が生じないように、バーナ(Br1〜Brn)の燃焼がガス化の流れから分離されたバーナ(Br1〜Brn)からの放射熱により、炭素粒子(C)とプロセスガス(P)とを、炭素粒子(C)が存在する同じ空間で間接的に加熱することにより炭素粒子(C)をガス化し、熱分解はガス化に先行して別の工程で行われ、
ガス化中に生成された合成ガス(S)を前記空間から排出する、
合成ガスを製造するための方法。 - ガス化中に生成される合成ガス(S)による熱交換がプロセスガス(P)を加熱するように用いられ、この加熱はプロセスガス(P)がガス化に携わる前に行われる、請求項1に記載の方法。
- 内部空間を有する反応器(1)と、
反応器(1)の内部に配置される、閉鎖された一端部を有する少なくとも1つの燃焼のためのバーナ(Br1〜Brn)と、
炭素含有材料から炭素粒子(C)とバーナ燃料を製造する分離された熱分解手段と、
熱分解手段からのバーナ燃料を前記少なくとも1つのバーナ(Br1〜Brn)へ燃焼のために供給するための手段と、
炭素粒子(C)とプロセスガス(P)を反応器(1)の内部空間に供給するための手段と、
生成された合成ガス(S)を排出するための手段と
を含み、
前記少なくとも1つのバーナ(Br1〜Brn)の内部におけるバーナ燃料の燃焼は、該バーナ(Br1〜Brn)の燃焼とプロセスガス(P)との間に直接的なガス交換が生じないようにガス化の流れから分離されるように構成される、
合成ガス(S)を製造するための方法を実施するための装置。 - 前記少なくとも1つのバーナ(Br1〜Brn)には燃料を該少なくとも1つのバーナの内部空間に供給するための手段が設けられ、該供給手段は反応器(1)の外部に配置される、請求項3に記載の装置。
- 前記少なくとも1つのバーナ(Br1〜Brn)に供給される酸化剤(O)の加熱のために熱交換器(3)が該少なくとも1つのバーナ(Br1〜Brn)の供給装置に隣接して配置される、請求項4に記載の装置。
- プロセスガス(P)の加熱および合成ガス(S)の冷却のための熱交換器(2)が反応器(1)の外部に配置される、請求項3、4または5に記載の装置。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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SE0801364-1 | 2008-06-11 | ||
SE0801364A SE532711C2 (sv) | 2008-06-11 | 2008-06-11 | Förfarande och anläggning för framställning av syntesgas |
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JP2015180734A JP2015180734A (ja) | 2015-10-15 |
JP5933072B2 true JP5933072B2 (ja) | 2016-06-08 |
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JP2015090065A Active JP5933072B2 (ja) | 2008-06-11 | 2015-04-27 | 合成ガスを製造するための方法および装置 |
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US (1) | US9458397B2 (ja) |
EP (1) | EP2291326B1 (ja) |
JP (2) | JP2011523972A (ja) |
KR (1) | KR101628409B1 (ja) |
CN (1) | CN102056840B (ja) |
BR (1) | BRPI0913416B1 (ja) |
CA (1) | CA2727395C (ja) |
CL (1) | CL2010001379A1 (ja) |
CY (1) | CY1116870T1 (ja) |
DK (1) | DK2291326T3 (ja) |
ES (1) | ES2551556T3 (ja) |
HU (1) | HUE026451T2 (ja) |
PL (1) | PL2291326T3 (ja) |
PT (1) | PT2291326E (ja) |
RU (1) | RU2509052C2 (ja) |
SE (1) | SE532711C2 (ja) |
WO (1) | WO2009151369A1 (ja) |
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SE535222C2 (sv) * | 2010-10-11 | 2012-05-29 | Cortus Ab | Produktion av kol vid indirekt värmd förgasning |
ITTO20110145A1 (it) * | 2011-02-21 | 2012-08-22 | Pierluigi Martini | Apparato per la decomposizione di sostanze organiche vegetali e la produzione di gas combustibile per via termochimica, e relativo gassificatore. |
CN102721485B (zh) * | 2012-06-29 | 2014-05-28 | 新奥气化采煤有限公司 | 煤炭地下气化炉二维平面温度场的实时监测方法 |
KR101907523B1 (ko) | 2012-09-19 | 2018-10-15 | 재단법인 포항산업과학연구원 | 적열 코크스를 이용한 h₂/co 혼합 가스의 제조 방법 |
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US20110099903A1 (en) | 2011-05-05 |
BRPI0913416B1 (pt) | 2019-10-01 |
RU2509052C2 (ru) | 2014-03-10 |
EP2291326B1 (en) | 2015-07-29 |
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CN102056840B (zh) | 2014-06-11 |
EP2291326A4 (en) | 2013-01-16 |
JP2011523972A (ja) | 2011-08-25 |
KR20110018427A (ko) | 2011-02-23 |
CY1116870T1 (el) | 2017-04-05 |
CA2727395C (en) | 2016-08-23 |
CL2010001379A1 (es) | 2011-06-03 |
CN102056840A (zh) | 2011-05-11 |
DK2291326T3 (en) | 2015-11-09 |
EP2291326A1 (en) | 2011-03-09 |
JP2015180734A (ja) | 2015-10-15 |
SE0801364L (sv) | 2009-12-12 |
RU2010152436A (ru) | 2012-07-20 |
SE532711C2 (sv) | 2010-03-23 |
BRPI0913416A2 (pt) | 2015-11-24 |
PL2291326T3 (pl) | 2016-01-29 |
ES2551556T3 (es) | 2015-11-19 |
PT2291326E (pt) | 2015-11-18 |
CA2727395A1 (en) | 2009-12-17 |
KR101628409B1 (ko) | 2016-06-08 |
HUE026451T2 (en) | 2016-05-30 |
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