JP5931250B2 - Lubricating oil composition - Google Patents

Description

  The present invention relates to a lubricating oil composition having excellent insulating properties and lubricity.

  Various electronic control devices are used for automobile devices. In some cases, it is used in lubricating oil, and the insulating properties of the lubricating oil are becoming important. In particular, transmission lubricating oil mounted on fuel cell vehicles, electric vehicles, or hybrid vehicles, transmission / electric motor combined oil, or transmissions for devices that share a transmission and electric motor lubrication system are used. Since the applied voltage is high, the insulating properties of the lubricating oil used in these are required to be higher. Furthermore, in order to improve fuel economy performance in recent years, improvement in power transmission efficiency and reduction in size and weight have been demanded, and a higher load is applied to the transmission. For this reason, high wear resistance and seizure resistance as well as insulation have been demanded.

  In addition to the above-mentioned performance, the lubricating oil for transmissions has a friction characteristic that matches the characteristics of the clutch, and a viscosity characteristic from low temperature to high temperature, that is, a viscosity that is not affected by temperature as much as possible, so that proper hydraulic pressure control is possible. Oxidation stability and clean dispersibility are required so that the inside of the apparatus can be kept clean so that the maintenance and control apparatus can operate properly. Furthermore, these performances generally need to be maintained over the lifetime of the device. For this reason, various additives are used in transmission lubricating oil.

So far, as such a lubricating oil for transmission, a base oil selected from the group consisting of mineral oil, synthetic oil, and mixtures thereof, and 0.1 to 15.0 mass% on the basis of the total amount of the composition, And a phosphorus compound selected from the group consisting of hydrocarbon group-containing zinc dithiophosphate, triaryl phosphate, triaryl thiophosphate, and mixtures thereof, and has a volume resistivity of 1 × 10 ⁷ Ω · m at 80 ° C. It consists of a transmission oil composition for automobiles (Patent Document 1), mineral oil, poly-α-olefin, poly-α-olefin hydride, alkylbenzene, ester compounds, and mixtures thereof. is selected from the group, kinematic viscosity at 80 ° C. and a base oil is 1.5 to 4.0 mm ² / s, the 0.1 to 4.0 mass% in total basis composition, a hydrocarbon group-containing Zinc dithiophosphate contains a phosphorus compound selected from the group consisting of triaryl thiophosphate, and mixtures thereof, and ashless dispersants, and the volume resistivity at 80 ° C. is at 1 × 10 ⁸ Ω · m or more A transmission oil composition (Patent Document 2) characterized by this is reported.

International Publication No. 2002/097017 JP 2008-285682 A

  As described above, various additives are used in the transmission, but these additives may be used alone or in combination to reduce insulation, wear resistance, and seizure resistance. An object of the present invention is to provide a lubricating oil composition with improved insulation performance, wear resistance, and seizure resistance, which is superior to the prior art, while maintaining the performance required for the transmission.

（一般式（１）において、Ｘ^１、Ｘ^２及びＸ^３は、それぞれ個別に酸素原子を示し、Ｒ^１、Ｒ^２及びＲ^３は、少なくともひとつが水素原子であり、他は炭素数１〜１６の炭化水素基を示す。）

（一般式（２）において、Ｘ^４、Ｘ^５、Ｘ^６及びＸ^７は、それぞれ個別に酸素原子（Ｘ^４、Ｘ^５及びＸ^６の１つ又は２つが単結合又は（ポリ）オキシアルキレン基でもよい。）を示し、Ｒ^４、Ｒ^５及びＲ^６は、少なくともひとつが水素原子であり、他は炭素数１〜１６の炭化水素基を示す。） That is, according to the present invention, (A) the lubricating base oil has (B) at least one hydroxyl group represented by general formula (1) or general formula (2), and the hydrocarbon group has a carbon number of A phosphorus compound that is 16 or less, and at least one phosphorus compound selected from amine salts thereof are blended in an amount of 0.01% by mass or more and 0.1% by mass or less in terms of phosphorus element based on the total amount of the composition. (C) an ashless dispersant having a functional group containing nitrogen as a dispersing group is contained in an amount of nitrogen of less than 0.001% by mass based on the total amount of the composition, or not contained at all, (D) Viscosity index improver containing 2% by mass or more and 15% by mass or less based on the total amount of the composition, and having a volume resistivity of 5 × 10 ⁸ Ω · m or more at 80 ° C. Auto or hybrid Provided is a lubricating oil composition used for use as a lubricating oil for an electric motor mounted on a vehicle, a transmission / electric motor combined oil, or a transmission oil for a device in which a lubricating system for the transmission and the electric motor is shared. .

(In General Formula (1), X ¹ , X ^2, and X ³ each independently represent an oxygen atom, R ¹ , R ^2, and R ^{3 each} have at least one hydrogen atom; 16 hydrocarbon groups are shown.)

(In General Formula (2), X ⁴ , X ⁵ , X ⁶ and X ⁷ are each independently an oxygen atom (one or two of X ⁴ , X ⁵ and X ⁶ are a single bond or a (poly) oxyalkylene group) And at least one of R ⁴ , R ⁵ and R ⁶ represents a hydrogen atom, and the other represents a hydrocarbon group having 1 to 16 carbon atoms.)

  The lubricating oil composition of the present invention can improve insulation performance, wear resistance, and seizure resistance, which are further superior to those of the prior art, while maintaining the performance necessary for lubricating transmissions and other devices.

  The present invention will be described in detail below.

  As the (A) lubricating base oil in the present invention, a mineral base oil and / or a synthetic base oil can be used, and two or more mineral base oils or a mixture of synthetic oil base oils can be used. However, it may be a mixture of a mineral base oil and a synthetic base oil. And the mixing ratio of 2 or more types of base oil in the said mixture can be chosen arbitrarily.

  As a mineral oil base oil, a lubricating oil fraction obtained by subjecting crude oil to atmospheric distillation and vacuum distillation is subjected to solvent removal, solvent extraction, hydrocracking, solvent dewaxing, catalytic dewaxing, hydrorefining. In addition, paraffinic and naphthenic mineral oil base oils, normal paraffins, isoparaffins, and the like, which are refined alone or in appropriate combination of two or more purification treatments such as sulfuric acid washing and clay treatment, can be mentioned. These base oils may be used alone or in combination of two or more at any ratio.

Preferred mineral oil base oils include the following base oils.
(1) Distilled oil obtained by atmospheric distillation of paraffin-based crude oil and / or mixed-base crude oil;
(2) Vacuum distillation distillate (WVGO) of paraffin-based crude oil and / or mixed-base crude oil at atmospheric distillation residue;
(3) Wax obtained by a lubricant dewaxing step and / or a Fischer-Tropsch wax produced by a GTL process or the like;
(4) Mild hydrocracking treatment oil (MHC) of one or two or more mixed oils selected from (1) to (3);
(5) A mixed oil of two or more oils selected from (1) to (4);
(6) Dried oil (DAO) of (1), (2), (3), (4) or (5);
(7) Mild hydrocracking treatment oil (MHC) of (6);
(8) A mixed oil of two or more kinds of oils selected from (1) to (7) is used as a feedstock oil, and this feedstock oil and / or a lubricating oil fraction recovered from this feedstock oil is used as a normal oil fraction. A lubricating oil obtained by refining by a refining method and collecting a lubricating oil fraction.

  The normal refining method here is not particularly limited, and a refining method used in the production of the lubricating base oil can be arbitrarily employed. Examples of conventional purification methods include (a) hydrorefining such as hydrocracking and hydrofinishing, (b) solvent purification such as furfural solvent extraction, and (c) dewaxing such as solvent dewaxing and catalytic dewaxing. And (d) white clay refining with acid clay and activated clay, and (e) chemical (acid or alkali) purification such as sulfuric acid washing and caustic soda washing. In the present invention, one or more of these can be used in any combination and in any order.

The mineral oil base oil used in the present invention is particularly preferably a base oil obtained by further subjecting the base oil selected from the above (1) to (8) to the following treatment.
That is, the base oil selected from the above (1) to (8) is used as it is, or the lubricating oil fraction recovered from this base oil is hydrocracked or wax isomerized, and the product is used as it is or from now on. Collect the fraction, and then perform dewaxing treatment such as solvent dewaxing or contact dewaxing, and then solvent refining treatment, or after solvent refining treatment, dewaxing such as solvent dewaxing or contact dewaxing Hydrocracked mineral oil and / or wax isomerized isoparaffinic base oil produced by treatment is preferably used. The hydrocracked mineral oil and / or wax isomerized isoparaffin base oil is preferably used in an amount of 30% by mass or more, more preferably 50% by mass or more, and particularly preferably 70% by mass or more based on the total amount of the base oil.

The (A) lubricating base oil in the lubricating oil composition of the present invention is preferably a lubricating base oil whose kinematic viscosity at 100 ° C. is adjusted to 1.5 to 4.5 mm ² / s.
Specifically, as the component (A), it is preferable to use a mixture of one or more selected from the following (Aa) to (Ac).
(Aa) Mineral oil base oil having a kinematic viscosity at 100 ° C. of less than 1.5 to 3.5 mm ² / s, preferably 1.9 to 3.2 mm ² / s (Ab) Kinematic viscosity at 100 ° C. Is less than 3.5 to 7 mm ² / s, preferably 3.6 to 4.5 mm ² / s mineral oil base oil (Ac) The kinematic viscosity at 100 ° C. is less than 1.5 to 7 mm ² / s, preferably Is 3.8 to 4.5 mm ² / s synthetic oil base oil

Here, (A-a) ~ it is preferred that the% C _A of the mineral base oil (A-b) is 2 or less, preferably further 1 or less, further not more than 0.5 It is particularly preferable that it is substantially 0. _{(A-c)% C} A of substantially zero. (A) a% C _A of the lubricating base oil can be obtained more lubricating oil composition excellent in oxidative stability by 2 or less.
Note that the% _{C A} in the present invention, showing the percentage of aromatic carbon atoms in total number of carbon obtained by a method in accordance with ASTM D 3238-85.

  The lubricating base oils (Aa) to (Ac) are not particularly limited in the viscosity index, but the viscosity index is preferably 80 or more, more preferably 100 or more, and particularly preferably 120 or more. It is usually 200 or less, preferably 160 or less. By setting the viscosity index to 80 or more, it is possible to obtain a composition exhibiting good viscosity characteristics from a low temperature to a high temperature. On the other hand, if the viscosity index is too high, the amount of normal paraffin increases in composition and the low temperature fluidity deteriorates.

  Further, the mineral base oils (Aa) to (Ab) in the present invention are not particularly limited in the sulfur content, but are preferably 0.05% by mass or less, and 0.02 The content is more preferably no more than mass%, and particularly preferably no more than 0.005 mass%. The sulfur content of (Ac) is substantially 0%. By reducing the sulfur content of the component (A), it is possible to obtain a composition that is more excellent in oxidative stability of the composition.

  In the present invention, each of the above (Aa) to (Ac) can be used alone, but can be arbitrarily mixed and used. Especially, it is preferable to use (Aa) and (Ab) and / or (Ac) together. In addition, the content of the component (Ac) when the component (Aa) and / or the component (Ab) and the component (Ac) are used in combination is preferably 1 to 4 on a base oil total basis. 50 mass%, More preferably, it is 3-20 mass%, More preferably, it is 3-10 mass%. By blending the component (Ac), an effect excellent in fatigue life, low temperature characteristics, and oxidation stability can be expressed inexpensively and effectively.

Preferably the kinematic viscosity at 100 ° C. of (A) a lubricating base oil in the present invention is 1.5 to 4.5 mm ² / s, more preferably 2.8~4.0mm ² / s, particularly preferably 3.6 to 3.9 mm ² / s. By setting the kinematic viscosity at 100 ° C. to 4.5 mm ² / s or less, it is possible to obtain a lubricating oil composition having a lower frictional resistance at a lubricating location because the fluid resistance becomes smaller, and a composition having excellent low-temperature viscosity. (For example, the Brookfield viscosity at −40 ° C. is 20,000 mPa · s or less). Further, by setting the kinematic viscosity at 100 ° C. to 1.5 mm ² / s or more, the oil film formation is sufficient, the lubricity is excellent, and the lubricating oil composition has a smaller evaporation loss of the base oil under high temperature conditions. Can be obtained.

Synthetic oils for component (Ac) include poly-α-olefins (1-octene oligomers, 1-decene oligomers, ethylene-propylene oligomers, etc.) and their hydrides, isobutene oligomers and their hydrides, isoparaffins, alkylbenzenes, Alkylnaphthalene, alkyldiphenylethane, monoisopropylbiphenyl, dimethylsilicone, diester (ditridecyl glutarate, di2-ethylhexyl adipate, diisodecyl adipate, ditridecyl adipate, di-2-ethylhexyl sebacate, etc.), polyol ester (trimethylolpropane capri) Rate, trimethylolpropane pelargonate, pentaerythritol 2-ethylhexanoate, pentaerythritol pelargonate, etc.), polyoxyal Glycol, dialkyl ethers, as well as synthetic lubricating oils and mixtures oils of these polyphenyl ether and the like can be used. Among these, poly-α-olefin and its hydride, isobutene oligomer and its hydride, isoparaffin, alkylbenzene, alkylnaphthalene, alkyldiphenylethane, monoisopropylbiphenyl, dimethylsilicone, etc. have a volume resistivity of 1 × 10 at 80 ° C. ^{It is 13} Ω · m or more, and can be preferably used for enhancing the insulating performance of the lubricating oil composition. The ester compound generally has a volume resistivity of about 1 × 10 ⁹ to 1 × 10 ¹³ Ω · m at 80 ° C., and preferably has a remaining water and impurities sufficiently removed.
In addition, in this specification, the volume resistivity at 80 ° C. means 24. JIS C 2101. What was measured based on (volume resistivity test) is shown.

  The synthetic oil in the present invention is preferably selected from the group consisting of poly-α-olefins, poly-α-olefin hydrides, alkylbenzenes, ester compounds, and mixtures thereof among the above synthetic oils. In this case, low temperature fluidity and low volatility can be maintained in a well-balanced condition under use conditions.

  The poly α-olefin is typically an α-olefin oligomer or co-oligomer having 2 to 32 carbon atoms, preferably 6 to 16 (eg, 1-octene oligomer, 1-decene oligomer, ethylene-propylene co-oligomer). And hydrides thereof.

These synthetic oils may be used alone. Although there is no restriction | limiting in particular in a viscosity, You may combine a thing with a different viscosity so that the kinematic viscosity in 100 degreeC may adjust to 1.5-4.5 mm < ² > / s preferably. This is because a higher base oil viscosity index can be obtained by combining a high viscosity and a low viscosity.

While (A) the lubricant base oil in the present invention is as described above, if there is a problem in fatigue life of the lubricating oil composition, solvent kinematic viscosity 20mm ² / s~50mm ² / s in the base oil It is preferable to use a mixture of refined base oils. Further _{(A)% C} A is 2 or less, it preferably kinematic viscosity at 100 ° C. is used as a mixture in a range comprised adjusted to 1.5 to 4.5 mm ² / s.

  The lubricating oil composition of the present invention contains a specific phosphorus compound as the component (B).

  Examples of the (B) phosphorus compound in the present invention are at least selected from the group consisting of the phosphorus compound represented by the general formula (1), the phosphorus compound represented by the general formula (2), and amine salts thereof. One kind of compound.

In the general formula (1), X ¹ , X ² and X ³ each independently represent an oxygen atom, R ¹ , R ² and R ^{3 each} have at least one hydrogen atom, and the others have 1 to 16 carbon atoms. Represents a hydrocarbon group.

In the general formula (2), X ⁴ , X ⁵ , X ⁶ and X ⁷ are each independently an oxygen atom (wherein one or two of X ⁴ , X ⁵ and X ⁶ are a single bond or a (poly) oxyalkylene group). R ⁴ , R ⁵ and R ^{6 each} represents at least one hydrogen atom, and the other represents a hydrocarbon group having 1 to 16 carbon atoms.

Specific examples of the hydrocarbon group having 1 to 16 carbon atoms represented by R ^{1 to} R ⁶ include an alkyl group, a cycloalkyl group, an alkenyl group, an alkyl-substituted cycloalkyl group, an aryl group, and an alkyl-substituted aryl group. And an arylalkyl group, preferably an alkyl group having 1 to 16 carbon atoms or an aryl group having 6 to 16 carbon atoms, more preferably 3 to 16 carbon atoms, and still more preferably 4 to carbon atoms. 12 alkyl groups.

As a phosphorus compound represented by General formula (1), the following phosphorus compounds can be mentioned, for example.
Phosphorous acid, monothiophosphorous acid, dithiophosphorous acid; phosphorous acid monoester, monothiophosphorous acid monoester, dithiophosphorous acid monoester, trithiophosphite having one hydrocarbon group having 1 to 16 carbon atoms. Phosphoric acid monoesters; phosphorous diesters, monothiophosphorous diesters, dithiophosphorous diesters, trithiophosphorous diesters having two hydrocarbon groups having 1 to 16 carbon atoms; and mixtures thereof.

In the present invention, it is particularly preferable that all of X ^{1 to} X ³ in the general formula (1) are oxygen atoms in order to further improve performance such as high-temperature cleanliness and oxidation stability.

As a phosphorus compound represented by General formula (2), the following phosphorus compounds can be mentioned, for example.
Phosphoric acid, monothiophosphoric acid, dithiophosphoric acid, trithiophosphoric acid, tetrathiophosphoric acid; phosphoric acid monoester having one hydrocarbon group having 1 to 16 carbon atoms, monothiophosphoric acid monoester, dithiophosphoric acid monoester, trithiophosphoric acid monoester, Tetrathiophosphoric acid monoester; phosphoric acid diester having two hydrocarbon groups having 1 to 16 carbon atoms, monothiophosphoric acid diester, dithiophosphoric acid diester, trithiophosphoric acid diester, tetrathiophosphoric acid diester; hydrocarbon having 1 to 16 carbon atoms Phosphonic acid having 1 to 2 groups, phosphonic acid monoester, phosphonic acid diester; phosphorus compound having a (poly) oxyalkylene group having 1 to 4 carbon atoms; β-dithiophosphorylated propionic acid, dithiophosphoric acid and olefinic cyclo Pentadiene or (meth ) Derivatives of the phosphorus compounds of the reaction product of methacrylic acid; and mixtures thereof.

In the present invention, it is particularly preferable that all of X ^{4 to} X ⁷ in the general formula (2) are oxygen atoms in order to further improve performance such as high-temperature cleanability and oxidation stability. One or two of X ⁴ , X ⁵ and X ⁶ may be a single bond or a (poly) oxyalkylene group.

As the phosphorus compound salt represented by the general formula (1) or (2), the phosphorus compound is ammonia, an amine compound having only a hydrocarbon group having 1 to 16 carbon atoms or a hydroxyl group-containing hydrocarbon group in the molecule. The salt which neutralized one part or all part of the remaining acidic hydrogen by making this nitrogen compound act can be mentioned.
Specific examples of the nitrogen compound include ammonia, monoamine, diamine, and polyamine. More specifically, aliphatic amines having an alkyl group or alkenyl group having 10 to 16 carbon atoms such as decylamine, dodecylamine, dimethyldodecylamine, tridecylamine, etc. (these may be linear or branched). It can be mentioned as a preferred example.

(B) As the phosphorus compound, an amine salt of a phosphorus compound in which X ¹ , X ² and X ³ in the general formula (1) are all oxygen atoms, and X ⁴ , X ⁵ , X ⁶ and X in the general formula (2) ^At least one compound selected from the group consisting of amine salts of phosphorus compounds in which ⁷ is an oxygen atom (one or two of X ⁴ , X ⁵ and X ⁶ may be a single bond or a (poly) oxyalkylene group) It is preferable that it is excellent in oxidation stability.

In addition, (B) the phosphorus compound is such that all of X ⁴ , X ⁵ , X ⁶ and X ^{7 in} the general formula (2) are oxygen atoms (one or two of X ⁴ , X ⁵ and X ⁶ are single bonds or ( Poly) oxyalkylene group), and R ⁴ , R ⁵ and R ⁶ are each a phosphorus compound in which at least one is hydrogen and the other is a hydrocarbon group having 1 to 16 carbon atoms. Preferred for oxidation stability.

  (B) The hydrocarbon group of the phosphorus compound preferably has 16 or less carbon atoms. This is based on the fact that the volume resistivity increases as the number of carbon atoms decreases as shown in Table 1.

  In Table 1, the volume resistivity is JIS C 2101 24. The value measured at an oil temperature of 80 ° C. in accordance with (Volume Resistivity Test) is shown. About the measurement example, all are added and dissolved in mineral oil base oil so that it may become 100 mass ppm in phosphorus element amount.

  In the lubricating oil composition of the present invention, the content of the phosphorus compound (B) is not particularly limited, but is 0.01% by mass or more, preferably 0.02% by mass in terms of phosphorus element based on the total amount of the composition. %, Particularly preferably 0.03% by mass or more, while the content thereof is preferably 0.1% by mass or less, more preferably 0.08% by mass or less, particularly preferably 0.05% by mass or less. It is. (B) When content of a phosphorus compound is less than 0.01 mass% as a phosphorus element, an effect is insufficient with respect to wear prevention property. On the other hand, when the content exceeds 0.1% by mass as the phosphorus element, the insulating performance is inferior, the oxidation stability is lowered, and the aggressiveness to the sealing material is increased.

  The lubricating oil composition of the present invention contains (C) an ashless dispersant having a functional group containing nitrogen as a dispersing group and a nitrogen content of less than 0.001% by mass based on the total amount of the composition, or not at all. Features.

  As described above, the lubricating oil composition of the present invention contains (B) at least one phosphorus compound selected from phosphorus compounds having at least one hydroxyl group. By including this, the abrasion resistance and seizure resistance of the composition are greatly improved. However, when this type of phosphorus compound coexists with (C) an ashless dispersant having a functional group containing nitrogen as a dispersing group in comparison with a phosphorus compound having no hydroxyl group, the volumetric efficiency is greatly reduced. Therefore, an ashless dispersant having a functional group containing nitrogen as a dispersing group may contain less than 0.001% by mass of nitrogen based on the total amount of the composition or may contain no ash. Essential for improvement and volume resistivity.

(C) Examples of the ashless dispersant having a functional group containing nitrogen as a dispersing group include succinimide, benzylamine, and polyamine having a hydrocarbon group having 40 to 400 carbon atoms.
However, these compounds do not include those in which nitrogen is modified to a structure that cannot take a salt structure with the phosphorus compound of component (B). For example, an amino group is acylated or modified with a boron compound or a sulfur compound, and does not include a structure that cannot take a salt structure with the phosphorus compound of component (B).
In addition, when an ashless dispersant having a functional group containing nitrogen as a dispersing group contains less than 0.001% by mass of nitrogen based on the total amount of the composition, the phosphorus compound of component (B) and an amino group capable of taking a salt structure remain. However, the level of the added amount is a structure or amount that gives a lubricating oil composition having a volume resistivity of 5 × 10 ⁸ Ω · m or more at 80 ° C. as a composition. The amount of nitrogen is less than 0.001% by mass based on the total amount of matter. More preferably, the nitrogen content is less than 0.0008% by mass based on the total amount of the composition.

  In addition, as long as the amount of addition is 1% by mass or less, compounds having the same structure containing nitrogen, such as amine antioxidants and corrosion inhibitors such as thiadiazole and triazole, can be ignored. There is no limit.

The lubricating oil composition of the present invention contains a viscosity index improver as the component (D).
Viscosity index improvers include non-dispersed or dispersed poly (meth) acrylates, non-dispersed or dispersed ethylene-α-olefin copolymers or hydrides thereof, polyisobutylene or hydrides thereof, and styrene-dienes. Hydrogenated copolymers, styrene-maleic anhydride copolymers, polyalkylstyrenes and (meth) acrylate monomers represented by structural formula (1) and unsaturated monomers such as ethylene / propylene / styrene / maleic anhydride And a viscosity index improver such as a copolymer can be further used.

The blending amount of the viscosity index improver in the lubricating oil composition of the present invention is such that the kinematic viscosity at 100 ° C. of the composition is 5 to 10 mm ² / s, preferably 6 to 9 mm ² / s, and the viscosity index of the composition is The amount is 120 to 270, preferably 150 to 250, more preferably 170 to 220, and more specifically, the blending amount is 15% by mass or less, preferably 10% by mass based on the total amount of the composition. Hereinafter, it is more preferably 8% by mass or less, 2% by mass or more, preferably 4% by mass or more, and more preferably 5% by mass or more. If it exceeds 15% by mass, the viscosity becomes too high, and if it is less than 2% by mass, a sufficient composition viscosity cannot be ensured.

The volume resistivity at 80 ° C. of the lubricating oil composition of the present invention is preferably 5 × 10 ⁸ Ω · m or more, more preferably 6 × 10 ⁸ Ω · m or more, 10 × 10 ⁸ Ω. -It is especially preferable that it is m or more. By setting the volume resistivity of the composition at 80 ° C. to 5 × 10 ⁸ Ω · m or more, it becomes possible to maintain a higher insulation performance not only during the new oil but also during the deterioration, and it is electrically operated over a long period of time. Troubles such as a short circuit of the motor can be avoided.

  For the purpose of further improving the performance of the lubricating oil composition of the present invention, in order to give the necessary performance, an extreme pressure agent, a dispersant excluding the above-described compounds, a metal detergent, Single or several types of various additives such as friction modifiers, antioxidants, corrosion inhibitors, rust inhibitors, demulsifiers, metal deactivators, pour point depressants, seal swelling agents, antifoaming agents, and colorants You may mix | blend and mix | blend.

Examples of the metal detergent include metal detergents such as alkaline earth metal sulfonate, alkaline earth metal phenate, and alkaline earth metal salicylate.
In the present invention, one or two or more compounds arbitrarily selected from the above metal-based detergents can be contained in any amount, but the content is usually 0 based on the total amount of the composition. 0.01 to 10% by mass, preferably 0.1 to 5% by mass.

As the friction modifier, any compound usually used as a friction modifier for lubricating oils can be used, but an alkyl group or alkenyl group having 6 to 30 carbon atoms, particularly a linear alkyl group having 6 to 30 carbon atoms. Alternatively, amine compounds, imide compounds, fatty acid esters, fatty acid amides, fatty acid metal salts, and the like having at least one linear alkenyl group in the molecule are preferably used.
In the present invention, one kind or two or more kinds of compounds arbitrarily selected from the above friction modifiers can be contained in any amount, but the content is usually 0.00 on the basis of the total amount of the composition. It is 01-5.0 mass%, Preferably it is 0.03-3.0 mass%.

As the antioxidant, any phenolic compound or amine compound that is generally used in lubricating oils can be used.
Specifically, alkylphenols such as 2,6-di-tert-butyl-4-methylphenol and bisphenols such as methylene-4,4-bisphenol (2,6-di-tert-butyl-4-methylphenol) , Naphthylamines such as phenyl-α-naphthylamine, dialkyldiphenylamines, zinc dialkyldithiophosphates such as zinc di-2-ethylhexyldithiophosphate, (3,5-di-tert-butyl-4-hydroxyphenyl) fatty acid ( Propionic acid etc.) or (3-methyl-5-tertbutyl-4-hydroxyphenyl) fatty acid (propionic acid etc.) and mono- or polyhydric alcohols such as methanol, octanol, octadecanol, 1,6-hexadiol, Neopentyl glycol, thiodiethylene glycol Triethylene glycol, esters of pentaerythritol and the like.
One or two or more compounds arbitrarily selected from these can be contained in any amount, but usually the content is 0.01 to 5 mass based on the total amount of the lubricating oil composition. %, Preferably 0.1 to 3% by mass.

  Examples of the corrosion inhibitor include benzotriazole, tolyltriazole, thiadiazole, and imidazole compounds.

  Examples of the rust inhibitor include petroleum sulfonate, alkylbenzene sulfonate, dinonylnaphthalene sulfonate, alkenyl succinic acid ester, and polyhydric alcohol ester.

  Examples of the demulsifier include polyalkylene glycol nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, and polyoxyethylene alkyl naphthyl ether.

  Examples of metal deactivators include imidazoline, pyrimidine derivatives, alkylthiadiazoles, mercaptobenzothiazoles, benzotriazoles or derivatives thereof, 1,3,4-thiadiazole polysulfide, 1,3,4-thiadiazolyl-2,5-bis. Examples include dialkyldithiocarbamate, 2- (alkyldithio) benzimidazole, and β- (o-carboxybenzylthio) propiononitrile.

  As the pour point depressant, a known pour point depressant can be arbitrarily selected according to the lubricating base oil, but the weight average molecular weight is preferably 20,000 to 500,000, more preferably 50,000. Poly (meth) acrylates of ˜300,000, particularly preferably 80,000 to 200,000 are preferred.

  As the antifoaming agent, any compound usually used as an antifoaming agent for lubricating oil can be used, and examples thereof include silicones such as dimethyl silicone and fluorosilicone. One or two or more compounds arbitrarily selected from these can be blended in any amount.

  As the seal swelling agent, any compound usually used as a seal swelling agent for lubricating oil can be used, and examples thereof include ester-based, sulfur-based and aromatic-based seal swelling agents.

  As the colorant, any compound that is usually used can be used, and any amount can be blended. Usually, the blending amount is 0.001 to 1.0% by mass based on the total amount of the composition. is there.

  When these additives are contained in the lubricating oil composition of the present invention, the content is based on the total amount of the composition, and 0.005 to 5% by mass for the corrosion inhibitor, the rust inhibitor, and the demulsifier, respectively. The point depressant and the metal deactivator are usually selected in the range of 0.005 to 2% by mass, the seal swelling agent in the range of 0.01 to 5% by mass, and the antifoaming agent in the range of 0.0005 to 1% by mass.

  Hereinafter, the content of the present invention will be described more specifically with reference to Examples and Comparative Examples, but the present invention is not limited to these.

(Examples 1-5, Comparative Examples 1-5)
According to the composition shown in Table 2, lubricating oil compositions according to the present invention (Examples 1 to 5) and comparative lubricating oil compositions (Comparative Examples 1 to 5) were prepared. These compositions were subjected to performance evaluation tests, and the results are also shown in Table 2.

The lubricating oil composition of the present invention is a composition having excellent anti-seizure performance and excellent insulating performance. Lubricating oil, electric motor oil, transmission / electric motor in an electric motor-equipped vehicle such as an electric vehicle or a hybrid vehicle. The oil can be used for a motor oil or a device oil in which a transmission and an electric motor are packaged, that is, a lubrication system for the transmission and the electric motor is shared.
In addition, the present invention provides the above transmission, electric motor, and apparatus including the lubricating oil composition of the present invention, or the above-described transmission, electric motor, apparatus lubrication method, and insulation by using the lubricating oil composition of the present invention. A method and a cooling method can be provided.

Claims (1)

(A) a lubricating base oil, (B) a phosphorus compound having at least one hydroxyl group represented by general formula (1) or general formula (2) and having a hydrocarbon group having 16 or less carbon atoms, and At least one phosphorus compound selected from those amine salts is blended in an amount of 0.01% by mass or more and 0.1% by mass or less in terms of phosphorus element based on the total amount of the composition (however, a neutral phosphorus compound is not blended). (C) An ashless dispersant having a functional group containing nitrogen as a dispersing group is contained in an amount of nitrogen of less than 0.001% by mass based on the total amount of the composition, or not contained at all, and (D) a viscosity index improver 2% by weight or more and 15% by weight or less based on the total amount of the composition, and the volume resistivity at 80 ° C. is 5 × 10 ⁸ Ω · m or more, (a) transmission oil, (b) fuel cell vehicle, electric vehicle or Installed in hybrid cars That the electric motor lubricating oil, (c) the transmission-electric motor combined oil, or (d) transmission and the lubricating oil composition electric motor lubrication system is used in applications shared by the device for transmission fluid.

(In General Formula (1), X ¹ , X ^2, and X ³ each independently represent an oxygen atom, R ¹ , R ^2, and R ^{3 each} have at least one hydrogen atom; 16 hydrocarbon groups are shown.)

(In General Formula (2), X ⁴ , X ⁵ , X ⁶ and X ⁷ are each independently an oxygen atom (one or two of X ⁴ , X ⁵ and X ⁶ are a single bond or a (poly) oxyalkylene group) And at least one of R ⁴ , R ⁵ and R ⁶ represents a hydrogen atom, and the other represents a hydrocarbon group having 1 to 16 carbon atoms.)