JP5867978B2 - 生物起源のシリカ材料を含む歯磨剤 - Google Patents
生物起源のシリカ材料を含む歯磨剤 Download PDFInfo
- Publication number
- JP5867978B2 JP5867978B2 JP2008548544A JP2008548544A JP5867978B2 JP 5867978 B2 JP5867978 B2 JP 5867978B2 JP 2008548544 A JP2008548544 A JP 2008548544A JP 2008548544 A JP2008548544 A JP 2008548544A JP 5867978 B2 JP5867978 B2 JP 5867978B2
- Authority
- JP
- Japan
- Prior art keywords
- silica
- dentifrice
- rice husk
- abrasive
- polishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 226
- 239000000377 silicon dioxide Substances 0.000 title claims description 104
- 239000000551 dentifrice Substances 0.000 title claims description 91
- 239000000463 material Substances 0.000 title description 19
- 230000000035 biogenic effect Effects 0.000 title description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims description 70
- 235000009566 rice Nutrition 0.000 claims description 70
- 239000010903 husk Substances 0.000 claims description 68
- 239000000203 mixture Substances 0.000 claims description 55
- 238000005498 polishing Methods 0.000 claims description 43
- 238000004519 manufacturing process Methods 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- -1 chalk Chemical compound 0.000 claims description 11
- 239000000741 silica gel Substances 0.000 claims description 9
- 229910002027 silica gel Inorganic materials 0.000 claims description 9
- 239000001506 calcium phosphate Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 5
- 235000019739 Dicalciumphosphate Nutrition 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 claims description 4
- 229940043256 calcium pyrophosphate Drugs 0.000 claims description 4
- 235000019821 dicalcium diphosphate Nutrition 0.000 claims description 4
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 claims description 4
- 229910000390 dicalcium phosphate Inorganic materials 0.000 claims description 4
- 229940038472 dicalcium phosphate Drugs 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 150000004683 dihydrates Chemical group 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 3
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 2
- 241000209094 Oryza Species 0.000 claims 5
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims 1
- 229910001562 pearlite Inorganic materials 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 description 65
- 239000003082 abrasive agent Substances 0.000 description 32
- 238000004140 cleaning Methods 0.000 description 26
- 239000000047 product Substances 0.000 description 20
- 239000000606 toothpaste Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 210000004268 dentin Anatomy 0.000 description 13
- 239000004615 ingredient Substances 0.000 description 13
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
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- 239000012535 impurity Substances 0.000 description 9
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- 229960001866 silicon dioxide Drugs 0.000 description 8
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 208000002925 dental caries Diseases 0.000 description 7
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- 235000011187 glycerol Nutrition 0.000 description 5
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
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- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
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- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
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- 150000002978 peroxides Chemical class 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
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- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 3
- 229940071089 sarcosinate Drugs 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
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- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
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- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- NGOZDSMNMIRDFP-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCC(=O)N(C)CC(O)=O NGOZDSMNMIRDFP-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
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- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 2
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- 229920000084 Gum arabic Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
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- INVGWHRKADIJHF-UHFFFAOYSA-N Sanguinarin Chemical compound C1=C2OCOC2=CC2=C3[N+](C)=CC4=C(OCO5)C5=CC=C4C3=CC=C21 INVGWHRKADIJHF-UHFFFAOYSA-N 0.000 description 2
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- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 2
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- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/323,662 US20070154412A1 (en) | 2005-12-30 | 2005-12-30 | Dentifrices comprising biogenic silica materials |
| US11/323,662 | 2005-12-30 | ||
| PCT/US2006/047151 WO2007078651A2 (en) | 2005-12-30 | 2006-12-08 | Dentifrices comprising biogenic silica materials |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009522264A JP2009522264A (ja) | 2009-06-11 |
| JP2009522264A5 JP2009522264A5 (enExample) | 2010-02-04 |
| JP5867978B2 true JP5867978B2 (ja) | 2016-02-24 |
Family
ID=38224647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008548544A Active JP5867978B2 (ja) | 2005-12-30 | 2006-12-08 | 生物起源のシリカ材料を含む歯磨剤 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20070154412A1 (enExample) |
| EP (1) | EP1973522A2 (enExample) |
| JP (1) | JP5867978B2 (enExample) |
| CN (1) | CN101351187B (enExample) |
| BR (1) | BRPI0620813B1 (enExample) |
| WO (1) | WO2007078651A2 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070154413A1 (en) * | 2005-12-30 | 2007-07-05 | Nolan Lee Phillips | Dentifrices comprising biogenic silica materials |
| EP2056683A2 (en) * | 2006-08-02 | 2009-05-13 | Neal A. Hammond | Biogenic silica from silica-containing plant material such as rice hulls |
| US20080159967A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and at least one calcium phosphate |
| US20080159968A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and calcium carbonate |
| JP5695560B2 (ja) * | 2008-05-16 | 2015-04-08 | コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ | 口腔用組成物およびその使用 |
| WO2011150004A2 (en) * | 2010-05-25 | 2011-12-01 | The Procter & Gamble Company | Oral care compositions and methods of making oral care compositions comprising silica from plant materials |
| AU2010363052B2 (en) * | 2010-10-27 | 2014-11-20 | Colgate-Palmolive Company | Oral care composition comprising arginine and calcium carbonate |
| AU2011341455B2 (en) * | 2010-12-13 | 2015-07-23 | Colgate-Palmolive Company | Oral compositions |
| MX2013006637A (es) * | 2010-12-13 | 2013-08-01 | Colgate Palmolive Co | Composiciones bucales y metodo para producir las mismas. |
| EP2983796A1 (en) | 2013-04-10 | 2016-02-17 | The Procter & Gamble Company | Oral care compositions containing polyorganosilsesquioxane particles |
| AU2014250971B2 (en) | 2013-04-10 | 2016-07-21 | The Procter & Gamble Company | Oral care compositions containing polyorganosilsesquioxane particles |
| WO2014169083A1 (en) | 2013-04-10 | 2014-10-16 | The Procter & Gamble Company | Oral care compositions containing polyorganosilsesquioxane particles |
| EP2983635A1 (en) | 2013-04-10 | 2016-02-17 | The Procter & Gamble Company | Oral care compositions containing polyorganosilsesquioxane particles |
| CN105120959A (zh) | 2013-04-10 | 2015-12-02 | 宝洁公司 | 包含聚有机倍半硅氧烷颗粒的口腔护理组合物 |
| CA2908663A1 (en) | 2013-04-10 | 2014-10-16 | The Procter & Gamble Company | Oral care compositions containing polyorganosilsesquioxane particles |
| KR102406602B1 (ko) * | 2020-09-09 | 2022-06-08 | (주)바이오나노코리아 | 천연 실리카 및 천연 식이섬유를 함유한 바이오 산업용 소재의 제조방법 및 이를 이용하여 제조된 천연 실리카 및 천연 식이섬유를 함유한 바이오 산업용 소재 |
| PL247492B1 (pl) * | 2021-01-20 | 2025-07-14 | Karpinska Trojanowska Malgorzata Centrum Medicum Poland Mgr Farm Malgorzata Karpinska Trojanowska | Sposób otrzymywania wybielającej pasty do zębów |
| JPWO2023190666A1 (enExample) * | 2022-03-29 | 2023-10-05 | ||
| WO2025176405A1 (en) | 2024-02-23 | 2025-08-28 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2025180682A1 (en) | 2024-02-29 | 2025-09-04 | Unilever Ip Holdings B.V. | Oral care composition |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1617430C3 (de) * | 1966-07-29 | 1980-07-10 | Wuerttembergische Parfuemerie-Fabrik Gmbh, 7332 Eislingen | Schäumende lagerstabile Zahnpaste |
| US3538230A (en) * | 1966-12-05 | 1970-11-03 | Lever Brothers Ltd | Oral compositions containing silica xerogels as cleaning and polishing agents |
| US3988162A (en) * | 1972-09-06 | 1976-10-26 | J. M. Huber Corporation | Amorphous precipitated silica products and method for their production |
| US3960586A (en) * | 1973-10-03 | 1976-06-01 | J. M. Huber Corporation | Amorphous precipitated siliceous pigments and improved process for producing such pigments |
| US3967563A (en) * | 1973-10-03 | 1976-07-06 | J. M. Huber Corporation | Process for producing precipitated thickener silica |
| BR7700632A (pt) * | 1976-02-05 | 1977-10-04 | Grace W R & Co | Processo para preparar uma composicao oral de pasta de dentes |
| US4303641A (en) * | 1978-05-24 | 1981-12-01 | W. R. Grace & Co. | Hydrous silica gel containing dentifrice |
| US4420312A (en) * | 1979-05-23 | 1983-12-13 | J. M. Huber Corporation | Method for production of high fluoride compatibility dentifrice abrasives and compositions |
| US4349534A (en) * | 1981-11-16 | 1982-09-14 | Colgate-Palmolive Company | Dentifrice composition |
| DE3425152A1 (de) * | 1984-07-07 | 1986-01-16 | Henkel KGaA, 4000 Düsseldorf | Zahnpasta |
| AU578392B2 (en) * | 1984-07-31 | 1988-10-20 | Lion Corporation | Toothpaste composition containing silica |
| GB8529796D0 (en) * | 1985-12-03 | 1986-01-08 | Unilever Plc | Precipitated silicas |
| DE3639844A1 (de) * | 1986-11-21 | 1988-06-01 | Degussa | Zahnpflegemittel |
| GB8721644D0 (en) * | 1987-09-15 | 1987-10-21 | Unilever Plc | Silicas |
| JPH0712446B2 (ja) * | 1989-09-13 | 1995-02-15 | 工業技術院長 | もみ殻中のシリカ及び有機質分の分離濃縮法 |
| US5234673A (en) * | 1990-02-20 | 1993-08-10 | J. M. Huber Corporation | Low temperature-very high structure silica and methods |
| US5589160A (en) * | 1995-05-02 | 1996-12-31 | The Procter & Gamble Company | Dentifrice compositions |
| US5676932A (en) * | 1995-05-02 | 1997-10-14 | J.M. Huber Corporation | Silica abrasive compositions |
| US5658553A (en) * | 1995-05-02 | 1997-08-19 | The Procter & Gamble Company | Dentifrice compositions |
| US5651958A (en) * | 1995-05-02 | 1997-07-29 | The Procter & Gamble Company | Dentifrice compositions |
| US5647903A (en) * | 1995-10-03 | 1997-07-15 | Mcgill; Patrick D. | Microporous high structure precipitated silicas and methods |
| US5891421A (en) * | 1996-03-22 | 1999-04-06 | J.M. Huber Corporation | Precipitated silicas having improved dentifrice performance characteristics and methods of preparation |
| US20010031245A1 (en) * | 1996-05-31 | 2001-10-18 | Smithkline Beecham Corporation | Compositions |
| KR100501022B1 (ko) * | 1998-07-28 | 2005-07-18 | 다나베 세이야꾸 가부시키가이샤 | 장내 적소 방출형 제제 |
| US6290933B1 (en) * | 2000-05-09 | 2001-09-18 | Colgate-Palmolive Company | High cleaning dentifrice |
| US6896876B1 (en) * | 2001-01-31 | 2005-05-24 | W.R. Grace & Co.-Conn. | High cleaning silica gel dental abrasive, dentifrices prepared therefrom, and a method for preparing the dental abrasive |
| US6406678B1 (en) * | 2001-03-26 | 2002-06-18 | Process Management, Inc. | Process for production of high purity amorphous silica from biogenic material |
| EP1399121B1 (en) * | 2001-06-25 | 2008-11-05 | The Procter & Gamble Company | Oral care compositions |
| CN100396610C (zh) * | 2003-02-18 | 2008-06-25 | 雷吉斯特印度科学院 | 从稻壳灰生产沉淀二氧化硅的方法和装置 |
| CN1596874A (zh) * | 2004-07-23 | 2005-03-23 | 罗少兵 | 一种用稻壳灰制作牙膏或牙粉研磨剂的方法及用途 |
| US20070154413A1 (en) * | 2005-12-30 | 2007-07-05 | Nolan Lee Phillips | Dentifrices comprising biogenic silica materials |
| US20080159967A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and at least one calcium phosphate |
| US20080159968A1 (en) * | 2006-12-27 | 2008-07-03 | Fultz William C | Dentifrices comprising biogenic silica materials and calcium carbonate |
-
2005
- 2005-12-30 US US11/323,662 patent/US20070154412A1/en not_active Abandoned
-
2006
- 2006-12-08 CN CN2006800501210A patent/CN101351187B/zh active Active
- 2006-12-08 EP EP06839288A patent/EP1973522A2/en not_active Withdrawn
- 2006-12-08 JP JP2008548544A patent/JP5867978B2/ja active Active
- 2006-12-08 WO PCT/US2006/047151 patent/WO2007078651A2/en not_active Ceased
- 2006-12-08 BR BRPI0620813-4A patent/BRPI0620813B1/pt active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0620813A2 (pt) | 2011-11-22 |
| CN101351187A (zh) | 2009-01-21 |
| JP2009522264A (ja) | 2009-06-11 |
| CN101351187B (zh) | 2012-07-04 |
| EP1973522A2 (en) | 2008-10-01 |
| US20070154412A1 (en) | 2007-07-05 |
| WO2007078651A3 (en) | 2008-01-24 |
| BRPI0620813B1 (pt) | 2022-06-07 |
| WO2007078651A2 (en) | 2007-07-12 |
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