ATE413209T1 - Mundpflegezusammensetzungen - Google Patents

Mundpflegezusammensetzungen

Info

Publication number
ATE413209T1
ATE413209T1 AT02737582T AT02737582T ATE413209T1 AT E413209 T1 ATE413209 T1 AT E413209T1 AT 02737582 T AT02737582 T AT 02737582T AT 02737582 T AT02737582 T AT 02737582T AT E413209 T1 ATE413209 T1 AT E413209T1
Authority
AT
Austria
Prior art keywords
oral care
care compositions
polishing
disclosed
methods
Prior art date
Application number
AT02737582T
Other languages
English (en)
Inventor
Donald White
Kathleen Kozak
Vincent Bercovici
Robert Date
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble filed Critical Procter & Gamble
Application granted granted Critical
Publication of ATE413209T1 publication Critical patent/ATE413209T1/de

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/02Stomatological preparations, e.g. drugs for caries, aphtae, periodontitis

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Engineering & Computer Science (AREA)
  • Cosmetics (AREA)
AT02737582T 2001-06-25 2002-06-24 Mundpflegezusammensetzungen ATE413209T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US30076601P 2001-06-25 2001-06-25

Publications (1)

Publication Number Publication Date
ATE413209T1 true ATE413209T1 (de) 2008-11-15

Family

ID=23160491

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02737582T ATE413209T1 (de) 2001-06-25 2002-06-24 Mundpflegezusammensetzungen

Country Status (14)

Country Link
US (1) US6740311B2 (de)
EP (1) EP1399121B1 (de)
CN (1) CN100408016C (de)
AT (1) ATE413209T1 (de)
AU (1) AU2002310504A1 (de)
CA (1) CA2447841C (de)
CZ (1) CZ20033403A3 (de)
DE (1) DE60229745D1 (de)
ES (1) ES2316572T3 (de)
HK (1) HK1069981A1 (de)
MX (1) MXPA03011946A (de)
PL (1) PL205718B1 (de)
RU (1) RU2269337C2 (de)
WO (1) WO2003000217A2 (de)

Families Citing this family (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6861047B1 (en) * 1999-01-27 2005-03-01 Victor Carnell Oral hygiene preparations; associated methods and kit
US8283135B2 (en) 2000-06-30 2012-10-09 The Procter & Gamble Company Oral care compositions containing combinations of anti-bacterial and host-response modulating agents
US8071076B2 (en) * 2002-05-28 2011-12-06 Oral Health Clinical Services Llc Oral lubricating and stain retarding compositions
EP1531786A1 (de) * 2002-08-15 2005-05-25 The Procter & Gamble Company VERFAHREN ZUR AUFHELLUNG VON ZûHNEN
US20060162014A1 (en) * 2003-07-07 2006-07-20 Jaffe Eileen K Alternate morpheeins of allosteric proteins as a target for the development of bioactive molecules
US8153410B2 (en) * 2003-07-07 2012-04-10 Fox Chase Cancer Center Alternate morpheein forms of allosteric proteins as a target for the development of bioactive molecules
US8815215B2 (en) * 2003-08-15 2014-08-26 Colgate-Palmolive Company Hydrophobic tooth whitening system and methods of use
US20050036957A1 (en) * 2003-08-15 2005-02-17 Michael Prencipe Tooth whitening dental tray and method of use
US7220405B2 (en) 2003-09-08 2007-05-22 E. I. Du Pont De Nemours And Company Peptide-based conditioners and colorants for hair, skin, and nails
US20050271602A1 (en) * 2004-06-02 2005-12-08 Nebojsa Milanovich Method for inhibiting chemical staining of teeth
US8894977B2 (en) * 2004-12-16 2014-11-25 Colgate-Palmolive Company Oral treatment compositions containing an anti-adhesion agent, antibacterial agent and incompatible compound
US9023323B2 (en) * 2004-12-16 2015-05-05 Colgate-Palmolive Company Oral compositions for prevention and reduction of bacterial adhesion to oral surfaces
US7297327B2 (en) 2004-12-21 2007-11-20 Colgate-Palmolive Company Oral care malodor composition
US8597617B2 (en) * 2004-12-21 2013-12-03 Colgate-Palmolive Company Coated natural calcium carbonate oral care toothpowder composition
US8545819B2 (en) * 2004-12-21 2013-10-01 Colgate-Palmolive Company Oral care toothpowder composition with fluoride ion source
BRPI0519748A2 (pt) 2005-01-04 2009-03-10 Teikoku Pharma Usa Inc preparaÇço de curativo para resfriamento tàpico
US20060198795A1 (en) * 2005-11-07 2006-09-07 Giniger Martin S Multi-component oral care compositions
US8425881B2 (en) * 2005-03-18 2013-04-23 Colgate-Palmolive Company Antibacterial 3′,5-disubstituted 2,4′-dihydroxybiphenyl compounds, derivatives and related methods
US20060233722A1 (en) * 2005-03-18 2006-10-19 Ravi Subramanyam Antibacterial 5,5'-disubstituted 3,3'-dialkoxy-2,2'-dihydroxy-1,1'-biphenyl compounds and related methods
JP2008533183A (ja) * 2005-03-21 2008-08-21 グラクソ グループ リミテッド フッ化物源およびシリカ歯研磨剤を含む、アルキル硫酸塩およびオルトリン酸塩無配合の歯磨剤組成物
US20060246401A1 (en) * 2005-04-29 2006-11-02 The Procter & Gamble Company Oral care compositions, regimens and device
IL169678A (en) 2005-07-14 2010-11-30 Innova Sa Sweetener compositions
US20070041914A1 (en) * 2005-08-17 2007-02-22 Colgate-Palmolive Company Inhibition of bacterial deposition on oral surfaces
MX2008000486A (es) * 2005-10-24 2008-03-07 Teikoku Pharma Usa Inc Composiciones topicas para el alivio del dolor de n-2,3-trimetil-2-isopropilbutamida y metodos para usar las mismas.
US20070122357A1 (en) * 2005-11-29 2007-05-31 The Procter & Gamble Company Dentifrice composition
US20070254260A1 (en) * 2005-12-02 2007-11-01 Alden Wayne S Iv Oral care compositions, methods, devices and systems
AU2006338180B2 (en) * 2005-12-21 2010-08-26 Colgate-Palmolive Company Abrasive system for oral care compositions
US7513627B2 (en) * 2005-12-30 2009-04-07 Honeywell International Inc. Image projection system with vibration compensation
US20070154412A1 (en) * 2005-12-30 2007-07-05 Nolan Lee Phillips Dentifrices comprising biogenic silica materials
US20070154413A1 (en) * 2005-12-30 2007-07-05 Nolan Lee Phillips Dentifrices comprising biogenic silica materials
US7270803B1 (en) * 2006-03-23 2007-09-18 J.M. Huber Corporation High-cleaning, low abrasion, high brightness silica materials for dentrifices
ITMI20061091A1 (it) * 2006-06-05 2007-12-06 Betafarma S P A Composizione antibatterica. utilizzabile come dentifricio per la sanitizzazione del cavo orale.
ES2427161T5 (es) 2006-11-13 2018-01-22 The Procter & Gamble Company Productos y métodos para revelar afecciones en la cavidad oral
US8298516B2 (en) * 2006-12-22 2012-10-30 Douglas Anderson Calculus dissolving dental composition and methods for using same
US20080159967A1 (en) * 2006-12-27 2008-07-03 Fultz William C Dentifrices comprising biogenic silica materials and at least one calcium phosphate
US20080159968A1 (en) * 2006-12-27 2008-07-03 Fultz William C Dentifrices comprising biogenic silica materials and calcium carbonate
US20090087461A1 (en) * 2007-10-01 2009-04-02 Thomas James Boyd Anti-bacterial pyrocatechols and related methods
RU2448680C2 (ru) 2007-11-09 2012-04-27 Дзе Проктер Энд Гэмбл Компани Композиции для полости рта, содержащие олово
PL2246031T3 (pl) 2008-06-10 2017-11-30 The Procter & Gamble Company Kompozycje chlorku cyny i krzemionki
BRPI0917113B1 (pt) * 2008-08-29 2019-10-15 A. Schulman Inc. Composições poliméricas flavorizadas otimizadas, artigo polimérico e processo para produção de uma composição polimérica (termoplástica) flavorizada
AU2015218538B2 (en) * 2008-08-29 2017-10-12 A. Schulman, Inc. Methods of enhancing the flavor of polymeric compositions and flavored articles
US20110230587A1 (en) * 2008-08-29 2011-09-22 A. Schulman, Inc. Flavored polymeric articles
RU2497496C2 (ru) * 2008-11-25 2013-11-10 Дзе Проктер Энд Гэмбл Компани Антибактериальные композиции для ухода за полостью рта, содержащие аморфный кварц
US8697654B2 (en) 2008-12-18 2014-04-15 E I Du Pont De Nemours And Company Peptide linkers for effective multivalent peptide binding
US20100158822A1 (en) 2008-12-18 2010-06-24 E .I. Du Pont De Nemours And Company Peptides that bind to silica-coated particles
US20100158837A1 (en) 2008-12-18 2010-06-24 E. I. Du Pont De Nemours And Company Iron oxide-binding peptides
WO2010114638A1 (en) 2009-03-30 2010-10-07 E. I. Du Pont De Nemours And Company Peptide-based tooth whitening reagents
EP2281543A1 (de) 2009-07-27 2011-02-09 The Procter & Gamble Company Mundpflegezusammensetzungen mit Zinn- und Kaliumsalze
EP2281544A1 (de) 2009-07-27 2011-02-09 The Procter & Gamble Company Mundpflegezusammensetzungen mit Zinn, Kalium und Monofluorphosphat
TWI539969B (zh) * 2009-10-14 2016-07-01 Sunstar Inc Composition for oral use
TWI407975B (zh) * 2009-12-17 2013-09-11 Colgate Palmolive Co 在牙用配製物中控制包覆並釋放疏水性活性物質之高潔淨力及低磨損性的二氧化矽材料
EP2553444B1 (de) 2010-04-01 2018-09-26 The Procter and Gamble Company Bekämpfung von mundgeruch mit einer kombination aus antibakteriellen und desodorierenden mitteln
US8715625B1 (en) 2010-05-10 2014-05-06 The Clorox Company Natural oral care compositions
RU2012158245A (ru) 2010-07-19 2014-08-27 Дзе Проктер Энд Гэмбл Компани Композиции, содержащие производные эфирно-масличных соединений, и их применение в средствах личной гигиены
ES2784495T3 (es) 2010-12-20 2020-09-28 Dupont Us Holding Llc Generación enzimática de perácidos para su uso en productos para el cuidado bucodental
US20130344120A1 (en) 2012-06-21 2013-12-26 Douglas Craig Scott Mouth Rinse Emulsions
US10123953B2 (en) 2012-06-21 2018-11-13 The Procter & Gamble Company Reduction of tooth staining derived from cationic antimicrobials
JP2015535262A (ja) 2012-11-05 2015-12-10 ザ プロクター アンド ギャンブルカンパニー 熱処理沈殿シリカ
RU2015139980A (ru) 2013-04-10 2017-05-15 Дзе Проктер Энд Гэмбл Компани Композиции для ухода за полостью рта, содержащие частицы полиорганосилсесквиоксана
EP2983637A1 (de) 2013-04-10 2016-02-17 The Procter & Gamble Company Mundpflegezusammensetzungen mit polyorganosilsesquioxanteilchen
CA2903419A1 (en) 2013-04-10 2014-10-16 The Procter & Gamble Company Oral care compositions containing polyorganosilsesquioxane particles
RU2015141323A (ru) 2013-04-10 2017-05-11 Дзе Проктер Энд Гэмбл Компани Композиции для ухода за полостью рта, содержащие частицы полиорганосилсесквиоксана
RU2639121C2 (ru) 2013-04-10 2017-12-19 Дзе Проктер Энд Гэмбл Компани Композиции для ухода за полостью рта, содержащие частицы полиорганосилсесквиоксана
JP2016520562A (ja) 2013-04-10 2016-07-14 ザ プロクター アンド ギャンブル カンパニー ポリオルガノシルセスキオキサン粒子を含有する口腔ケア組成物
AU2013408425B2 (en) * 2013-12-16 2017-02-02 Colgate-Palmolive Company Oral care compositions comprising calcium carbonate and silica
WO2015106915A1 (en) * 2014-01-14 2015-07-23 Unilever Plc Oral care compositions
US10207004B2 (en) 2014-04-04 2019-02-19 Douxmatok Ltd Method for producing sweetener compositions and sweetener compositions
US10231476B2 (en) 2014-04-04 2019-03-19 Douxmatok Ltd Sweetener compositions and foods, beverages, and consumable products made thereof
CN106413425A (zh) * 2014-04-04 2017-02-15 杜克马塔克有限公司 甜味剂组合物以及由其制成的食品、饮料和可食用产品
US20160242439A1 (en) 2014-04-04 2016-08-25 Douxmatok Ltd Method for producing sweetener compositions and sweetener compositions
WO2015171836A1 (en) 2014-05-09 2015-11-12 The Procter & Gamble Company Oral compositions containing stannous
WO2015171837A1 (en) 2014-05-09 2015-11-12 The Procter & Gamble Company Oral compositions containing zinc
MX2017002097A (es) 2014-08-15 2017-05-04 Procter & Gamble Composiciones y regimenes para el cuidado bucal.
WO2017024110A1 (en) 2015-08-04 2017-02-09 Isp Investments Llc Polymers derived from amino-functional vinyl alcohol ethers and applications thereof
BR112018004094A2 (pt) * 2015-08-28 2019-01-08 Douxmatok Ltd composições de edulcorantes e alimentos, bebidas, e produtos consumíveis produzidos dos mesmos
RU2731096C2 (ru) 2015-12-30 2020-08-28 Колгейт-Палмолив Компани Композиции для личной гигиены
EP3380066B1 (de) 2015-12-30 2021-06-23 Colgate-Palmolive Company Mundpflegezusammensetzungen
BR112018012947B1 (pt) 2015-12-30 2021-08-31 Colgate-Palmolive Company Composições para higiene pessoal
CN109069391B (zh) 2015-12-30 2022-02-11 高露洁-棕榄公司 口腔护理组合物
US11000459B2 (en) 2017-12-15 2021-05-11 Colgate-Palmolive Company Silica abrasives with high stannous fluoride compatibility
JP7135092B2 (ja) 2018-01-17 2022-09-12 ザ プロクター アンド ギャンブル カンパニー エナメル質の硬度及び耐性を増加させる方法及び組成物
CN110742815B (zh) * 2018-07-24 2022-09-27 好维股份有限公司 一种清洁能力高且磨损值小的口腔护理组合物
US11191709B2 (en) 2019-04-26 2021-12-07 The Procter & Gamble Company Reduction of tooth staining derived from cationic antimicrobials
EP3946640A1 (de) 2019-05-06 2022-02-09 Colgate-Palmolive Company Mundpflegezusammensetzungen
AU2020269152B2 (en) 2019-05-06 2023-03-02 Colgate-Palmolive Company Oral care compositions
BR112021021541A2 (pt) * 2019-05-28 2021-12-28 Unilever Ip Holdings Bv Composição de dentifrício, composição de cuidados orais e processo de preparação de composições
EP3996662A1 (de) 2019-07-08 2022-05-18 The Procter & Gamble Company Verfahren und zusammensetzungen zur erhöhung der härte und beständigkeit von email
WO2021059215A2 (en) 2019-09-25 2021-04-01 Church & Dwight Co., Inc. Oral care composition
WO2022072605A1 (en) 2020-09-30 2022-04-07 Lubrizol Advanced Materials, Inc. Oral care compositions with improved stability
CA3138558C (en) 2020-11-16 2024-01-30 Church & Dwight Co., Inc. Teeth cleaning composition comprising banana extract
WO2023191852A1 (en) 2022-03-28 2023-10-05 Lubrizol Advanced Materials, Inc. Stable dentifrice compositions with high sodium bicarbonate loading

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3574823A (en) 1968-08-05 1971-04-13 Colgate Palmolive Co Dentifrice containing visible agglomerated particles of polishing agents
US4421527A (en) 1977-12-20 1983-12-20 J. M. Huber Corporation High fluoride compatibility dentifrice abrasives and compositions
US4420312A (en) 1979-05-23 1983-12-13 J. M. Huber Corporation Method for production of high fluoride compatibility dentifrice abrasives and compositions
US4340583A (en) * 1979-05-23 1982-07-20 J. M. Huber Corporation High fluoride compatibility dentifrice abrasives and compositions
DE3114492A1 (de) 1981-04-10 1982-10-28 Degussa Ag, 6000 Frankfurt Zahnpflegemittel
US4631184A (en) 1984-01-10 1986-12-23 W. R. Grace & Co. Dialytic silica dentifrice
GB8721644D0 (en) 1987-09-15 1987-10-21 Unilever Plc Silicas
FR2632185B1 (fr) 1988-06-01 1992-05-22 Rhone Poulenc Chimie Silice pour compositions dentifrices compatible notamment avec le zinc
US5225177A (en) 1990-01-19 1993-07-06 J. M. Huber Corporation Dentifrice abrasives and compositions
ATE159232T1 (de) 1990-08-06 1997-11-15 Crosfield Joseph & Sons Kieselsäuren
US5108734A (en) 1991-07-01 1992-04-28 Colgate-Palmolive Company Prophy mouthfeel dentifrice having low RDA value
KR960010781B1 (ko) 1991-10-02 1996-08-08 유니레버 엔브이 실리카
US5603920A (en) * 1994-09-26 1997-02-18 The Proctor & Gamble Company Dentifrice compositions
US5658553A (en) * 1995-05-02 1997-08-19 The Procter & Gamble Company Dentifrice compositions
US5651958A (en) * 1995-05-02 1997-07-29 The Procter & Gamble Company Dentifrice compositions
US5676932A (en) * 1995-05-02 1997-10-14 J.M. Huber Corporation Silica abrasive compositions
US5589160A (en) * 1995-05-02 1996-12-31 The Procter & Gamble Company Dentifrice compositions
DE69612977T2 (de) 1995-06-30 2001-09-06 Crosfield Joseph & Sons Amorphe kieselsäuren und orale zusammensetzungen
US5891421A (en) * 1996-03-22 1999-04-06 J.M. Huber Corporation Precipitated silicas having improved dentifrice performance characteristics and methods of preparation
US5716601A (en) * 1996-03-22 1998-02-10 The Procter & Gamble Company Dentifrice compositions
US5939051A (en) 1998-02-27 1999-08-17 Colgate-Palmolive Company Dental abrasive
US6294155B1 (en) 1998-04-08 2001-09-25 W. R. Grace & Co. -Conn. Abrasive silica compositions and dentifrice compositions prepared therefrom
US6074629A (en) 1998-07-27 2000-06-13 J. M. Huber Corporation Dentifrice with a dye absorbing silica for imparting a speckled appearance thereto
US6342205B1 (en) 1999-10-29 2002-01-29 J. M. Huber Corporation High water content dentifrice composition and method of making the same
US6290933B1 (en) 2000-05-09 2001-09-18 Colgate-Palmolive Company High cleaning dentifrice
US6403059B1 (en) * 2000-08-18 2002-06-11 J. M. Huber Corporation Methods of making dentifrice compositions and products thereof
US6419174B1 (en) * 2000-08-18 2002-07-16 J. M. Huber Corporation Abrasive compositions and methods for making same
US6379654B1 (en) 2000-10-27 2002-04-30 Colgate Palmolive Company Oral composition providing enhanced tooth stain removal

Also Published As

Publication number Publication date
AU2002310504A1 (en) 2003-01-08
RU2004101966A (ru) 2005-03-20
ES2316572T3 (es) 2009-04-16
CA2447841C (en) 2009-12-15
CN1535135A (zh) 2004-10-06
US20030039617A1 (en) 2003-02-27
HK1069981A1 (en) 2005-06-10
EP1399121A2 (de) 2004-03-24
WO2003000217A2 (en) 2003-01-03
PL366547A1 (en) 2005-02-07
US6740311B2 (en) 2004-05-25
MXPA03011946A (es) 2004-03-26
CN100408016C (zh) 2008-08-06
CZ20033403A3 (cs) 2004-10-13
CA2447841A1 (en) 2003-01-03
EP1399121B1 (de) 2008-11-05
DE60229745D1 (de) 2008-12-18
RU2269337C2 (ru) 2006-02-10
WO2003000217A3 (en) 2003-04-03
PL205718B1 (pl) 2010-05-31

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