JP5841400B2 - Honeycomb structure manufacturing method and honeycomb molded body degreasing apparatus - Google Patents

Description

  The present invention relates to a method for manufacturing a honeycomb structure and a degreasing apparatus for a honeycomb formed body.

  Many technologies have been developed for the purification of exhaust gas from automobiles, but due to the increase in traffic, it is difficult to say that sufficient exhaust gas countermeasures have been taken. In Japan and around the world, exhaust gas regulations are becoming more strict.

  In order to comply with such exhaust gas regulations, a catalyst carrier capable of treating predetermined components contained in the exhaust gas is used in the exhaust gas purification system. A honeycomb structure is known as a member for such a catalyst carrier.

  This honeycomb structure has, for example, a plurality of cells (through holes) extending from one end face of the honeycomb structure to the other end face along the longitudinal direction, and these cells carry a catalyst. It is mutually divided by the cell wall comprised by the cell wall or the catalyst. Therefore, when exhaust gas is circulated through such a honeycomb structure, substances such as HC, CO, and / or NOx contained in the exhaust gas are modified by the catalyst supported on the cell wall or the catalyst constituting the cell wall. And can treat these harmful components in the exhaust gas.

  In particular, in a system called an SCR (Selective Catalytic Reduction) system, NOx in exhaust gas can be decomposed into nitrogen and water by using ammonia. For example, Patent Document 1 discloses a honeycomb structure including zeolite that can be used in an SCR system.

International Publication No. WO09 / 141897 Pamphlet

  The honeycomb structure is formed by extruding a raw material paste containing, for example, inorganic particles, an inorganic binder, an organic binder, a forming aid, water, and the like to produce a honeycomb formed body, and then degreasing the honeycomb formed body, Furthermore, it comprises by baking.

  The degreasing treatment is performed in order to decompose and remove the organic binder and the molding aid contained in the honeycomb molded body before the firing treatment of the honeycomb molded body.

However, when inorganic particles having a large number of fine pores and a large specific surface area (for example, a specific surface area of 50 m ² / g or more) are used for the raw material paste, the fine particles of the inorganic particles are degreased after degreasing the honeycomb formed body. There may be a problem that the carbon component of the organic binder and / or molding aid remains in the pores. This is because during the degreasing treatment of the honeycomb formed body, oxygen does not sufficiently spread throughout the fine pores of the inorganic particles, and sufficient oxidative decomposition reaction does not proceed for the organic binder and / or forming aid.

  Further, when the honeycomb formed body is fired in a state where the organic binder and / or the carbon component of the forming aid remains in the fine pores of the inorganic particles, the condensation bond between the inorganic particles via the inorganic binder becomes insufficient, The strength of the obtained honeycomb fired body is lowered.

  The present invention has been made in view of such problems. In the present invention, a honeycomb including a degreasing step capable of more appropriately degreasing a honeycomb formed body including inorganic particles having a relatively large specific surface area. An object of the present invention is to provide a method for manufacturing a structure. Another object of the present invention is to provide a degreasing apparatus for such a honeycomb formed body.

According to the present invention, a method for manufacturing a honeycomb structure having a honeycomb unit includes:
(A) A plurality of cells including inorganic particles having a specific surface area of 50 m ² / g or more, a molding aid and / or an organic binder, and extending from the first end face to the second end face along the longitudinal direction. Forming a honeycomb formed body partitioned by cell walls;
(B) arranging the honeycomb formed body in a degreasing apparatus such that the first end face is on the lower side and the second end face is on the upper side;
(C) supplying an introduction gas into the degreasing device;
(D) degreasing the honeycomb formed body at a temperature of 200 ° C. to 400 ° C .;
(E) firing the degreased honeycomb molded body at a temperature of 500 ° C. to 900 ° C. to obtain a honeycomb unit;
Including
The introduced gas flows through the cells of the honeycomb formed body and flows inside the honeycomb formed body from the first end face toward the second end face,
The introduced gas contains oxygen and nitrogen, and the ratio of oxygen to nitrogen is 1.5: 98.5 (vol%) to 5.5: 94.5 (vol%).

  Here, in the method for manufacturing a honeycomb structured body according to the present invention, in the step (c), at least a part of the introduced gas discharged from the second end face of the honeycomb formed body is a part of the introduced gas. It may be reused as a part.

  In the method for manufacturing a honeycomb structured body according to the present invention, at least a part of the discharged introduced gas may be oxidized through an oxidation catalyst and then reused as a part of the introduced gas.

  In the method for manufacturing a honeycomb structure according to the present invention, the steps (b) to (e) may be performed in a batch type or a continuous type.

  In the method for manufacturing a honeycomb structure according to the present invention, the inorganic particles preferably include zeolite particles.

Further, in the method for manufacturing a honeycomb structured body according to the present invention, the first portion of the introduced gas passes through the cells of the honeycomb formed body and passes through the inside of the honeycomb formed body from the first end face. Flows toward the end face of 2,
The second portion of the introduced gas preferably flows through the outer periphery of the honeycomb formed body in a direction parallel to the direction of the second end surface from the first end surface.

In the method for manufacturing a honeycomb structure according to the present invention, the honeycomb formed body further includes an inorganic binder, and the inorganic binder includes alumina or a precursor of alumina,
In the step (e), an alumina layer is preferably formed on the surface of the cell wall.

  In the method for manufacturing a honeycomb structure according to the present invention, the average pore diameter of the honeycomb unit is preferably in the range of 0.01 μm to 1.0 μm.

  In the method for manufacturing a honeycomb structure according to the present invention, the honeycomb structure may be configured by joining a plurality of the honeycomb units via an adhesive layer.

Furthermore, according to the present invention, a degreasing treatment apparatus for a honeycomb molded body includes:
A support for disposing the honeycomb formed body so that the first end face is on the lower side and the second end face is on the upper side;
Supply means for supplying the introduced gas into the apparatus;
Heating means for heating the honeycomb formed body to a temperature of 200 ° C. to 400 ° C .;
Guiding means for guiding the introduced gas so as to flow through the cells of the honeycomb formed body and flow from the first end face toward the second end face in the honeycomb formed body;
Have
The introduced gas contains oxygen and nitrogen, and the ratio of oxygen to nitrogen is 1.5: 98.5 (vol%) to 5.5: 94.5 (vol%).

Here, the honeycomb molded body degreasing apparatus according to the present invention further reuses at least a part of the introduced gas discharged from the second end face of the honeycomb molded body as a part of the introduced gas. You may have the following circulation path.

  Moreover, in the degreasing treatment apparatus for a honeycomb formed body according to the present invention, the circulation path may include an oxidation catalyst.

Further, in the degreasing treatment apparatus for a honeycomb molded body according to the present invention, the first portion of the introduced gas passes through the cells of the honeycomb molded body and passes through the inside of the honeycomb molded body from the first end surface. Flowing towards the second end face,
The second portion of the introduced gas preferably flows through the outer periphery of the honeycomb formed body in a direction parallel to the direction of the second end surface from the first end surface.

Moreover, the degreasing treatment apparatus for a honeycomb molded body according to the present invention further includes a housing for accommodating the honeycomb molded body,
The introduced gas is preferably introduced into the housing from an inlet provided in the housing.

Moreover, in the degreasing treatment apparatus for a honeycomb molded body according to the present invention, the inlet is provided at a position higher than ½ of the height of the housing,
It is preferable that the guiding means guides the introduced gas introduced from the inlet to a position lower than the first end face of the honeycomb formed body.

Further, in the degreasing treatment apparatus for a honeycomb molded body according to the present invention, the support base has a plurality of through holes,
The introduced gas may be supplied into the cells of the honeycomb formed body through the plurality of through holes.

  Moreover, in the degreasing treatment apparatus for a honeycomb molded body according to the present invention, the inlet may be connected to an air source or an oxygen source and a nitrogen source outside the housing.

  In the present invention, it is possible to provide a method for manufacturing a honeycomb structure including a degreasing step in which a honeycomb formed body containing inorganic particles having a relatively large specific surface area can be degreased more appropriately. Moreover, a degreasing apparatus for such a honeycomb formed body can be provided.

1 is a perspective view schematically showing an example of a honeycomb structure according to the present invention. FIG. 2 is a perspective view schematically showing an example of a honeycomb unit constituting the honeycomb structure of FIG. 1. It is a flowchart of an example of the manufacturing method of the honeycomb structure by this invention. It is the figure which showed roughly an example of the structure of the degreasing processing apparatus of the honeycomb molded object of this invention. FIG. 3 is a schematic top view of a support base on which a honeycomb formed body is placed in the degreasing treatment apparatus for a honeycomb formed body of the present invention.

  The features of the present invention will be described below with reference to the drawings.

  FIG. 1 schematically shows the structure of the honeycomb structure. FIG. 2 schematically shows an example of a honeycomb unit which is a basic unit of the honeycomb structure shown in FIG.

  As shown in FIG. 1, the honeycomb structure 100 has two end faces 110 and 115 which are not sealed. An outer peripheral coat layer 120 is formed on the outer peripheral surface of the honeycomb structure 100 excluding both end faces 110 and 115.

  For example, the honeycomb structure 100 is formed by joining a plurality of columnar ceramic honeycomb units 130 shown in FIG. 2 via the adhesive layer 150 (in the example shown in FIG. , 115 is formed by cutting the outer peripheral side along a predetermined shape (cylindrical shape in the example of FIG. 1).

  As shown in FIG. 2, the honeycomb unit 130 extends from one end to the other end along the longitudinal direction of the honeycomb unit 130, and has a plurality of cells (through holes) 121 that are open at both end surfaces, and the cells 121. And cell walls 123 to be partitioned. Although not limited to this, in the example of FIG. 2, the cross section perpendicular to the longitudinal direction (Z direction) of the cell 121 is substantially square.

  When alumina, silica, titania, ceria, zirconia, mullite, zeolite, or the like is used as the inorganic particles contained in the honeycomb unit, the honeycomb structure having such a honeycomb unit includes CO, HC, and / or NOx, etc. It can be used as a catalyst carrier (catalyst) for purifying water. In particular, a catalyst carrier (catalyst) using zeolite as inorganic particles can be used in a urea SCR system having a urea tank.

For example, in such a urea SCR system, when exhaust gas is distributed in the system, urea contained in the urea tank reacts with water in the exhaust gas to generate ammonia (formula (1)).

CO (NH ₂ ) ₂ + H ₂ O → 2NH ₃ + CO ₂ Formula (1)

When this ammonia flows into each cell 121 from one of the end faces 110 and 115 of the honeycomb structure 100 (for example, the end face 110) together with the exhaust gas containing NOx, due to the catalytic action of the zeolite contained in the cell wall 123, Reactions of the following formulas (2-1) and (2-2) occur.

4NH ₃ + 4NO + O ₂ → 4N ₂ + 6H ₂ O Formula (2-1)
8NH ₃ + 6NO ₂ → 7N ₂ + 12H ₂ O Formula (2-2)

Thereafter, the exhaust gas from which NOx has been purified is discharged from the other of the end surfaces 110 and 115 of the honeycomb structure 100 (for example, the end surface 115). Thus, NOx in the exhaust gas can be treated by flowing the exhaust gas through the honeycomb structure 100.

  As a honeycomb unit constituting the honeycomb structure, there are a unit having a cell wall on which a catalyst is supported and a unit having a cell wall constituted by a catalyst. In the following description, a honeycomb structure including a honeycomb unit having a cell wall constituted by a catalyst will be described as an example.

  In the honeycomb unit constituting the honeycomb structure, a raw material paste containing, for example, inorganic particles, an inorganic binder, an organic binder, a forming aid, water, and the like is extruded to produce a honeycomb formed body. Thereafter, the honeycomb formed body is manufactured by degreasing and firing.

  The degreasing treatment of the honeycomb formed body is performed to decompose and remove the organic binder and the forming aid contained in the honeycomb formed body before the firing treatment.

However, when particles having a large number of fine pores and a large specific surface area (for example, 50 m ² / g or more) are used as the inorganic particles contained in the raw material paste for the honeycomb molded body, after degreasing the honeycomb molded body, There may be a problem that the carbon component of the organic binder and / or molding aid remains in the fine pores of the inorganic particles. This is because during the degreasing treatment of the honeycomb formed body, oxygen does not sufficiently spread throughout the fine pores of the inorganic particles, and sufficient oxidative decomposition reaction does not proceed for the organic binder and the forming aid.

  Further, when the honeycomb formed body is fired in a state where the organic binder and / or the carbon component of the forming aid remain in the fine pores of the inorganic particles in the subsequent steps, condensation bonding between the inorganic particles via the inorganic binder is performed. Is insufficient. For this reason, the strength of the obtained honeycomb unit (honeycomb fired body) is lowered.

On the other hand, in the method for manufacturing a honeycomb structure according to the present invention, the degreasing step has the following characteristics:
(I) During the degreasing process, the honeycomb molded body is, for example, in a container, so that the first end face is on the lower side and the second end face is on the upper side (that is, “the honeycomb molded body is upright”). Arranged).
(Ii) Part of the introduced gas for degreasing passes through the cells of the honeycomb formed body, and the inside of the honeycomb formed body is directed from the lower side to the upper side, that is, from the first end face to the second end face of the honeycomb formed body. Flowing.
(Iii) The introduced gas contains oxygen and nitrogen, and the ratio of oxygen to nitrogen is 1.5: 98.5 (vol%) to 5.5: 94.5 (vol%).

  In addition, by preparing the introduction gas control means for adjusting the air amount or the oxygen amount and the nitrogen amount so as to achieve the above ratio, it is possible to obtain the above ratio by using such introduction gas control means. it can.

  Here, when the introduction gas for degreasing is passed through the cells of the honeycomb formed body, the introduced gas becomes a turbulent state in the cells of the honeycomb formed body. When the introduced gas is in a turbulent state, the oxygen component in the introduced gas is easily diffused. Oxygen easily penetrates into the fine pores of the inorganic particles constituting the cell wall by diffusing the oxygen component in the introduced gas, and the organic binder and the molding aid present in the fine pores of the inorganic particles are oxidized. Decomposition reaction becomes possible.

  Here, in the case where the honeycomb molded body is in the “standing state”, when the introduced gas is supplied from the upper side to the lower side, the introduced gas is introduced into the fine pores of the honeycomb molded body. It becomes difficult to supply enough. In general, since the introduced gas is heated by the heat during processing to become a high temperature and tends to rise, in such a method, the introduced gas is supplied to the second end face via the cells formed in the honeycomb molded body. This is because it is difficult to reliably guide from the first end surface to the first end surface.

  On the other hand, when the honeycomb molded body is degreased by supplying an introduction gas to the honeycomb molded body in a state where the honeycomb molded body is not in an “upright” state, but degreased by the introduced gas and degreasing treatment, There arises a problem that the gas is difficult to be discharged from the inside of the honeycomb formed body. This is because the heated introduced gas tends to rise as described above. In this case, the composition of the introduced gas is changed by the degreasing gas, and sufficient degreasing is difficult to be performed at a location located on the downstream side of the introduced gas inside the honeycomb formed body.

  On the other hand, in the manufacturing method of the honeycomb structure of the present invention having the characteristics (i) and (ii), the introduced gas can be sufficiently supplied throughout the inside of the honeycomb formed body. Further, the stagnation of the introduced gas and the degreasing gas inside the honeycomb molded body is unlikely to occur as in the case where the honeycomb molded body is placed sideways.

  Furthermore, in the present invention, due to the feature (iii), an introduced gas having a constant oxygen concentration is always supplied to the honeycomb formed body during the degreasing process.

  Therefore, in the method for manufacturing a honeycomb structure of the present invention, oxygen is sufficiently distributed to the fine pores of the inorganic particles contained in the honeycomb molded body during the degreasing treatment due to the characteristics (i) to (iii). It becomes possible to make it. This also provides an effect that the organic binder and the molding aid contained in the inorganic particles are sufficiently oxidized, and the carbon component hardly remains in the fine pores of the inorganic particles.

As described above, in the method for manufacturing a honeycomb structure according to the present invention, the honeycomb formed body has inorganic particles having a large number of fine pores and a relatively large specific surface area (for example, a specific surface area of 50 m ² / g or more). Even when it is included, the honeycomb formed body can be degreased without leaving the organic binder and / or the carbon component of the forming aid. Thereby, in the honeycomb structure finally obtained, the strength reduction of the honeycomb unit due to the residual components in the degreasing step can be significantly suppressed.

(Configuration of honeycomb structure 100)
Next, the configuration of the honeycomb structure 100 shown in FIG. 1 will be briefly described.

(Honeycomb unit 130)
Here, a case where the honeycomb unit 130 included in the honeycomb structure 100 is made of a material mainly composed of zeolite will be described. However, it will be apparent to those skilled in the art that even when the honeycomb unit 130 is made of other materials such as γ-alumina, at least a part of the following description can be applied.

  The honeycomb unit 130 includes inorganic particles (zeolite particles) and an inorganic binder. That is, the cell wall 123 itself of the honeycomb unit 130 is composed of solid particles of inorganic particles (zeolite particles) and an inorganic binder. Moreover, the honeycomb unit 130 may include inorganic particles other than zeolite particles. Further, the honeycomb unit 130 may include inorganic fibers.

  Examples of the zeolite contained in the honeycomb unit 130 include β-type zeolite, Y-type zeolite, ferrierite, ZSM-5-type zeolite, mordenite, forgesite, zeolite A, zeolite L, or phosphate-based zeolite. The phosphate-based zeolite may be ALPO (aluminophosphate), SAPO (silicoaluminophosphate), or the like. Further, the zeolite may be ion-exchanged with Fe, Cu, Ni, Co, Zn, Mn, Ti, Ag, V, or the like. Among these elements, Fe or Cu is particularly preferable.

  The inorganic binder contained in the honeycomb unit 130 is preferably a solid content of at least one selected from the group consisting of alumina sol, silica sol, titania sol, water glass, sepiolite, attapulgite, and boehmite.

  As inorganic particles other than the zeolite particles contained in the honeycomb unit 130, alumina, silica, zirconia, titania, ceria, mullite and the like are desirable. These particles may be used alone or in combination of two or more.

  Regarding the amount of inorganic particles including zeolite particles contained in the honeycomb unit 130, a desirable lower limit is 30% by weight, a more desirable lower limit is 40% by weight, and a further desirable lower limit is 50% by weight. On the other hand, the desirable upper limit is 90% by weight, the more desirable upper limit is 80% by weight, and the more desirable upper limit is 75% by weight. When the content of inorganic particles is less than 30% by weight, the amount of zeolite that contributes to purification of exhaust gas is relatively small. On the other hand, if it exceeds 90% by weight, the amount of the inorganic binder contributing to the strength is relatively reduced, and thus the strength of the honeycomb unit 130 is lowered.

  In addition, when inorganic fibers are added to the honeycomb unit 130, the material of the inorganic fibers is preferably alumina, silica, silicon carbide, silica alumina, glass, potassium titanate, aluminum borate or the like. These may be used alone or in combination of two or more. Of the above materials, alumina is desirable.

  The average pore diameter of the honeycomb unit 130 is desirably in the range of 0.01 μm to 1.0 μm.

  When the average pore diameter of the honeycomb unit 130 is less than 0.01 μm, the exhaust gas is not sufficiently penetrated into the cell wall 123, and the exhaust gas purification performance is deteriorated. On the other hand, when the average pore diameter of the honeycomb unit 130 exceeds 1.0 μm, the contact point between the inorganic binder and the inorganic particles decreases, and the strength of the honeycomb unit 130 decreases.

The cell density of the honeycomb unit 130 is preferably in the range of 15.5 to 186 cells / cm ² (100 to 1200 cpsi), and is preferably in the range of 46.5 to 170 cells / cm ² (300 to 1100 cpsi). More preferably, it is in a range of 62 to 155 / cm ² (400 to 1000 cpsi).

When the cell density of the honeycomb unit 130 is less than 15.5 cells / cm ² , the area of the honeycomb unit 130 in contact with the exhaust gas becomes small, and the purification performance of the exhaust gas is deteriorated. On the other hand, when the cell density of the honeycomb unit 130 exceeds 186 cells / cm ² , there is a problem that the pressure loss of the honeycomb structure 100 increases.

  The thickness of the cell wall 123 of the honeycomb unit 130 is not particularly limited, but the lower limit desirable from the viewpoint of strength is 0.1 mm, and the upper limit desirable from the viewpoint of exhaust gas purification performance is 0.4 mm.

(Adhesive layer 150)
The adhesive layer 150 of the honeycomb structure 100 is formed using an adhesive layer paste as a raw material.

  The thickness of the adhesive layer 150 is preferably in the range of 0.3 to 2.0 mm. This is because if the thickness of the adhesive layer 150 is less than 0.3 mm, sufficient bonding strength cannot be obtained for the honeycomb unit 130. On the other hand, when the thickness of the adhesive layer 150 exceeds 2.0 mm, the pressure loss of the honeycomb structure 100 increases. Note that the number of honeycomb units 130 to be joined is appropriately selected according to the size of the honeycomb structure 100.

  Although it does not specifically limit as a paste for contact bonding layers, The mixture of an inorganic binder and an inorganic particle, the mixture of an inorganic binder and an inorganic fiber, an inorganic binder, an inorganic particle, a mixture of an inorganic fiber, etc. are mentioned.

  The adhesive layer paste may further contain an organic binder. Although it does not specifically limit as an organic binder, Polyvinyl alcohol, methylcellulose, ethylcellulose, or carboxymethylcellulose etc. are mentioned, You may use 2 or more types together.

  If necessary, a pore-forming agent such as balloons, spherical acrylic particles, and graphite, which are fine hollow spheres containing oxide ceramics, may be added to the raw material paste.

(Outer peripheral coat layer 120)
The adhesive layer paste can be used for the outer peripheral coat layer 120 of the honeycomb structure 100. The outer peripheral coat layer 120 of the honeycomb structure 100 may be the same material as the adhesive layer 150 or a different material. The final thickness of the outer peripheral coat layer is preferably 0.1 mm to 2.0 mm.

  If the thickness of the outer peripheral coat layer 120 is less than 0.1 mm, sufficient strength cannot be obtained for the outer peripheral coat layer 120. Moreover, when the thickness of the outer peripheral coat layer 120 exceeds 2.0 mm, the pressure loss of the honeycomb structure 100 increases.

  Next, the aggregate of honeycomb units 130 is cut along a predetermined shape (cylindrical in the example of FIG. 1), and the outer peripheral surface is coated with a paste for the outer peripheral coat layer. After drying and solidifying for 600 minutes, the honeycomb structure 100 is manufactured by degreasing and solidifying the adhesive layer paste and the outer peripheral coating layer paste at 600 ° C. for 120 minutes.

  In the above description, as shown in FIG. 1, the characteristics of each member have been described by taking as an example a case where the honeycomb structure is configured by joining a plurality of honeycomb units 130 via the adhesive layer 150. However, it will be apparent to those skilled in the art that the honeycomb structure may be composed of a single honeycomb unit, and that the structure is the same except for the adhesive layer.

(Manufacturing method of honeycomb structure)
Hereinafter, the manufacturing method of the honeycomb structure of the present invention will be described in detail with reference to the drawings.

FIG. 3 shows a flowchart of an example of a method for manufacturing a honeycomb structure according to the present invention. As shown in FIG. 3, the method for manufacturing a honeycomb structure according to the present invention includes:
(A) A plurality of cells including inorganic particles having a specific surface area of 50 m ² / g or more, a molding aid and / or an organic binder, and extending from the first end face to the second end face along the longitudinal direction. Forming a honeycomb formed body divided by cell walls (step S110);
(B) placing the honeycomb formed body in a degreasing apparatus such that the first end face is on the lower side and the second end face is on the upper side (step S120);
(C) supplying the introduced gas into the degreasing apparatus (step S130);
(D) a step of degreasing the honeycomb formed body at a temperature of 200 ° C. to 400 ° C. (Step S140);
(E) Thereafter, the degreased honeycomb molded body is fired at a temperature of 500 ° C. to 900 ° C. to obtain a honeycomb unit (step S150);
Have

  Hereinafter, each step will be described.

(Step S110)
First, a honeycomb formed body is manufactured by the following method.

  First, a raw material paste containing inorganic particles and a molding aid and / or an organic binder is prepared. In addition to these, an inorganic binder, inorganic fibers, and / or a dispersion medium may be added to the raw material paste.

  Examples of the inorganic particles include zeolite, alumina, silica, titania, ceria, zirconia, mullite and the like, and zeolite is preferable.

The specific surface area of the inorganic particles is not particularly limited, but particularly good effects of the present invention can be obtained when inorganic particles having a specific surface area of 50 m ² / g or more are used.

The larger specific surface area of the inorganic particles is preferable, but the upper limit of the specific surface area of the inorganic particles is, for example, 600 m ² / g.

  The molding aid is not particularly limited, and may be, for example, ethylene glycol, dextrin, fatty acid, fatty acid soap and polyalcohol.

  The organic binder is not particularly limited, and examples thereof include one or more organic binders selected from methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, polyethylene glycol, phenol resin, epoxy resin, and the like. The blending amount of the organic binder is preferably 1 to 10 parts by weight with respect to a total of 100 parts by weight of the inorganic particles and the inorganic binder.

  Examples of the inorganic fiber include alumina, silica, silicon carbide, silica alumina, glass, potassium titanate, and aluminum borate. These may be used alone or in combination of two or more. Of the above materials, alumina is desirable.

  Although it does not specifically limit as a dispersion medium, For example, water, an organic solvent (benzene etc.), alcohol (methanol etc.), etc. can be mentioned. Although it does not specifically limit as a shaping | molding adjuvant, For example, ethylene glycol, dextrin, a fatty acid, fatty-acid soap, a polyalcohol etc. can be mentioned.

  The raw material paste is not particularly limited, but is preferably mixed and kneaded. For example, the raw material paste may be mixed using a mixer or an attritor, or may be sufficiently kneaded using a kneader.

  Next, extrusion molding or the like is performed using the raw material paste, and a honeycomb formed body having first and second end faces as shown in FIG. 2 is manufactured.

(Step S120)
Next, the obtained honeycomb formed body is in a state where the honeycomb formed body is erected for degreasing treatment, that is, the first end face of the honeycomb formed body is on the lower side, and the second end face of the honeycomb formed body is on the upper side. It arrange | positions so that it may become.

(Step S130)
Next, the introduced gas is supplied into the degreasing apparatus.

  At least a part of the introduced gas passes through the cells in the honeycomb molded body, and the inside of the honeycomb molded body is directed from the first end surface to the second end surface (that is, from the lower side to the upper side of the honeycomb molded body). ) Provided to flow.

  The introduced gas contains oxygen and nitrogen, and the ratio of oxygen to nitrogen is preferably 1.5: 98.5 (vol%) to 5.5: 94.5 (vol%), and 2.5: 97. 5 (vol%) to 4.5: 95.5 (vol%) is more preferable, and 3.5: 96.5 (vol%) is more preferable.

  In addition, by preparing the introduction gas control means for adjusting the air amount or the oxygen amount and the nitrogen amount so as to achieve the above ratio, it is possible to obtain the above ratio by using such introduction gas control means. it can.

  When the oxygen concentration exceeds 5.5%, the degreasing reaction of the honeycomb formed body is accelerated, and the temperature of the honeycomb formed body rises rapidly, and there is a problem that the zeolite is deactivated. When the oxygen concentration is less than 1.5%, oxygen is not sufficiently supplied into the fine pores of the inorganic particles constituting the honeycomb formed body, degreasing is insufficient, and the strength of the honeycomb unit is lowered.

  A part of the introduced gas may be supplied to the outer peripheral side of the honeycomb formed body. In this case, the introduced gas supplied to the outer peripheral side of the honeycomb formed body is in the same direction as the introduced gas flowing in the honeycomb formed body from the first end face toward the second end face, that is, below the outer periphery of the honeycomb formed body. May flow upward from the top.

(Step S140)
Next, the honeycomb formed body is maintained at a temperature of 200 ° C. to 400 ° C., and degreasing is performed.

(Step S150)
Finally, the honeycomb formed body after the degreasing treatment is fired at a temperature of 500 ° C to 900 ° C. Thereby, for example, a honeycomb unit as shown in FIG. 2 is manufactured.

  Thereafter, a plurality of the obtained honeycomb units are bonded via an adhesive layer. Furthermore, the outer peripheral surface of the joined body of the honeycomb unit is cut into, for example, a cylindrical shape using a diamond cutter or the like. Thereby, a honeycomb structure having a desired shape is manufactured. If necessary, an outer peripheral coat layer is formed on the outer peripheral surface of the honeycomb structure.

  It should be apparent to those skilled in the art that the order of (Step S120) and (Step S130) is not particularly limited in the above-described method. That is, the introduction gas may be supplied after the honeycomb formed body is arranged in an upright state, or the honeycomb formed body may be arranged in the upright state after the introduction gas is supplied.

  When the honeycomb formed body further includes an inorganic binder, the inorganic binder includes alumina or an alumina precursor, and an alumina layer is formed on the surface of the cell wall in the step (e) (ie, step S150). Is done.

  Further, in the above-described method, the step of arranging the honeycomb formed body in the degreasing apparatus (step S120) to the step of obtaining the honeycomb unit (step S150) may be performed in a batch manner or continuously. .

  Here, the honeycomb structure obtained by the method for manufacturing a honeycomb structure according to the present invention may have an alumina layer formed in the longitudinal direction on the cell wall surface of the honeycomb unit.

  When the honeycomb formed body further includes an inorganic binder, the inorganic binder includes alumina or an alumina precursor, and an alumina layer is formed on the surface of the cell wall in the step (e) (ie, step S150). Is done.

  This alumina layer originates from alumina particles contained in the inorganic binder and is expected to be formed by the following phenomenon.

  When the honeycomb molded body includes an inorganic binder, the alumina particles contained in the inorganic binder are formed together with the organic binder, the molding aid, and / or the degreasing gas generated by the decomposition thereof in the degreasing process of the honeycomb molded body. Move towards the surface of the body cell wall. Among these, the organic binder and the forming aid are decomposed and removed on the surface of the cell wall of the honeycomb formed body by a degreasing reaction. Further, the degreasing gas is dissipated as a gas from the surface of the cell wall of the honeycomb formed body. However, as a matter of course, since the alumina particles are not degreased and decomposed, they remain on the surface of the cell wall of the honeycomb formed body. As a result of the residual alumina particles being uniformly deposited on the cell wall surface of the honeycomb formed body, alumina is formed on the cell wall of the honeycomb formed body, and finally an alumina layer is formed on the cell wall of the honeycomb unit. It is done.

(Degreasing device for honeycomb molded body)
Next, an example of the degreasing apparatus of this invention for implementing above-mentioned step S120-S140 is demonstrated. In FIG. 4, an example of a structure of the degreasing | defatting apparatus of the honeycomb molded body of this invention is shown roughly.

  As shown in FIG. 4, the degreasing apparatus 400 includes a housing 410 for housing the honeycomb formed body 425. The interior of the housing 410 is roughly divided into an upper space 429U provided on the upper side, a lower space 429B provided on the lower side, and a central space 429M between the two. The central space 429M is divided into an inner space 429MI in which the honeycomb formed body 425 is disposed and an outer space 429MO surrounding the inner space 429MI by a partition plate 450 installed in the central space 429M. Further, the inner space 429MI and the lower space 429B of the central space 429M are partitioned by the support base 420.

  The housing 410 is provided with a gas inlet 415 and a gas outlet 416.

  The gas inlet 415 is provided for supplying the introduced gas into the housing 410. The gas inlet 415 is connected to the air source 490 and the nitrogen source 492 outside the housing 410. Note that an oxygen source may be used instead of the air source 490. In the example of FIG. 4, the gas inlet 415 is provided in the upper part of the central space 429M, but the gas inlet 415 may be provided in the upper space 429U. In particular, the gas inlet 415 is preferably provided at a position higher than ½ of the height of the housing 410.

  When the gas inlet 415 is installed at a position that is 1/2 or less of the height of the housing 410, the time during which the introduced gas and the exhaust gas are mixed is shortened. It becomes non-uniform depending on the position and time, and the oxidative decomposition reaction of the organic binder and molding aid becomes insufficient.

  On the other hand, the gas discharge port 416 is provided to discharge the degreasing gas generated by the degreasing process of the honeycomb formed body 425 and the unreacted introduced gas to the outside of the housing 410. In a normal case, the gas discharge port 416 is provided in the upper space 429U.

  Further, in the example of FIG. 4, an oxidation catalyst 480 and a fan 440 are installed in the upper space 429 </ b> U of the housing 410. However, as will be described later, the oxidation catalyst 480 is installed when the exhaust gas is reused, and is not necessarily a member required for the degreasing apparatus 400.

  In the example of FIG. 4, the oxidation catalyst 480 is installed on the outer peripheral side of the housing 410 so as to partition the upper space 429U and the outer space 429MO of the central space 429M. The oxidation catalyst 480 has a large number of fine through holes inside. Accordingly, the upper space 429U and the outer space 429MO of the central space 429M are in gas communication via the through-hole in the oxidation catalyst 480.

  When the oxidation catalyst 480 is not used, a partition plate that can communicate the upper space 429U with the outer space 429MO of the central space 429M may be disposed at the position of the oxidation catalyst 480, for example. In the first place, when the exhaust gas is not reused, a shielding plate for blocking gas communication between the upper space 429U and the outer space 429MO of the central space 429M may be disposed at the position of the oxidation catalyst 480.

  As described above, the support base 420 is disposed so as to partition the inner space 429MI of the central space 429M in the housing 410 and the lower space 429B. However, the support base 420 has a plurality of through-holes 422, whereby the lower space 429B of the housing 410 and the inner space 429MI of the central space 429M are in gas communication.

  Although not shown in FIG. 4, the degreasing apparatus 400 further includes a heating unit for the honeycomb formed body 425.

  Next, the operation at the time of degreasing the honeycomb formed body 425 using the degreasing apparatus 400 will be described.

(Degreasing preparation stage)
First, the honeycomb formed body 425 is placed on the support table 420 in a standing state. At this time, the honeycomb formed body 425 is configured such that each cell provided in the honeycomb formed body 425 and the lower space 429B are in gas communication via the through holes 422 of the support base 420. Placed on top. In other words, the support base 420 has a large number of through holes 422 configured to communicate with the respective cells provided in the honeycomb formed body 425.

  FIG. 5 shows an example of a schematic top view of a support base 420 on which a honeycomb molded body 425 is placed in the honeycomb molded body degreasing apparatus 400 of the present invention. In FIG. 5, the outline of the honeycomb formed body 425 to be degreased is simultaneously shown for reference.

  As shown in FIG. 5, the through holes 422 of the support base 420 are formed in a lattice shape, and the size of each lattice is sufficiently larger than the size of the cells of the honeycomb formed body 425. Therefore, by placing the honeycomb formed body 425 on such a support table 420, gas communication between the through-hole 422 and each cell of the honeycomb formed body 425 becomes possible.

  Next, when the air source 490 and the nitrogen source 492 are opened, as shown by the arrow A1 in FIG. 4, the introduced gas composed of oxygen and nitrogen is introduced from the gas inlet 415 to the outer space 429MO of the central space 429M of the housing 410. Is introduced. At this time, the operation of the fan 440 suppresses the introduction gas from moving in the direction of the upper space 429U via the oxidation catalyst 480. The introduced gas is adjusted to a predetermined oxygen: nitrogen ratio (for example, 3.5: 96.5 (vol%)) by controlling the amount of air from the air source 490 and the amount of nitrogen from the nitrogen source 492. Is done.

  The introduced gas introduced from the gas inlet 415 is moved by the operation of the partition plate 450 and the fan 440 from the outer space 429MO of the central space 429M of the housing 410 toward the lower space 429B as shown by an arrow A2 in FIG. Be guided.

  The introduced gas that has reached the lower space 429B then enters the inner space 429MI of the central space 429M through the plurality of through holes 422 provided in the support base 420. At this time, a part of the introduced gas moves upward through the cells inside the honeycomb formed body 425 as indicated by an arrow A3 in FIG. Further, a part of the introduced gas moves upward through the outer peripheral side of the honeycomb formed body 425 as indicated by an arrow A4 in FIG.

  Thereafter, the respective introduced gases indicated by arrows A3 and A4 are integrated again above the inner space 429MI, and move from the inner space 429MI to the upper space 429U as indicated by an arrow A5 in FIG.

  At this stage, the gas discharge port 416 provided in the upper part of the housing 410 is closed. Therefore, the introduced gas that has reached the upper space 429U is again introduced into the outer space 429MO of the central space 429M as it is through the oxidation catalyst 480 as indicated by an arrow A6.

(Degreasing stage)
Next, the honeycomb formed body 425 is heated to the degreasing temperature with the introduced gas flowing through the housing 410 in this manner. The degreasing temperature is preferably in the range of 200 ° C to 400 ° C. At the same time, the gas outlet 416 is opened.

  At this stage, the honeycomb molded body 425 is degreased by the respective introduced gases indicated by arrows A3 and A4 flowing inside and on the outer peripheral side of the molded body 425.

  Here, in each cell in the honeycomb formed body 425, the introduced gas flows from the lower side to the upper side. In particular, since the introduced gas is warmed when the honeycomb formed body 425 is degreased and easily rises, the movement from the lower side to the upper side of the introduced gas is further promoted. The composition of the introduced gas (the ratio of oxygen to nitrogen) before being supplied to the honeycomb formed body 425 is set to a predetermined value.

  For this reason, by degreasing the honeycomb formed body 425 using such a degreasing apparatus 400, it is possible to sufficiently supply an introduction gas having a predetermined composition throughout the inside of the honeycomb formed body 425.

  Therefore, in the degreasing treatment stage, the introduced gas can be sufficiently spread into the fine pores of the inorganic particles contained in the honeycomb formed body 425. Thereby, the organic binder and the forming aid contained in the honeycomb formed body 425 are sufficiently oxidized, and it is possible to prevent these components from remaining in the fine pores of the inorganic particles. As a result, the condensation bond between the inorganic particles is sufficiently promoted and sufficient strength can be obtained.

  By the way, degreasing gas is generated from the honeycomb formed body 425 by this degreasing treatment. The generated degreasing gas moves together with the introduced gas from the inner space 429MI to the upper space 429U as shown by an arrow A5 in FIG. 4 (hereinafter, this gas is referred to as “mixed gas”).

  Here, in the case of the most simplified degreasing apparatus, the mixed gas moved to the upper space 429U is opened from the gas discharge port 416 by opening the gas discharge port 416 as shown by an arrow A7 in FIG. It is discharged out of the housing 410.

  However, in such a method, it is necessary to continue supplying a large amount of introduced gas into the housing 410 from the air source 490 and the nitrogen source 492 during the degreasing process, which increases the processing cost.

  Therefore, it is preferable that the degreasing apparatus has a configuration capable of recycling the mixed gas, like the degreasing apparatus 400 shown in FIG.

  In the case of the degreasing apparatus 400, the mixed gas that has moved to the upper space 429U in the degreasing process stage is recycled as follows.

  First, the gas discharge port 416 is opened. Thereby, a part of the mixed gas guided to the upper space 429U is discharged out of the housing 410 through the gas discharge port 416 as indicated by an arrow A7 in FIG. On the other hand, the remaining part of the mixed gas is guided into the oxidation catalyst 480 for recycling as shown by an arrow A6 in FIG.

  The mixed gas introduced into the oxidation catalyst 480 is oxidized here. As a result, gas components such as organic gas contained in the mixed gas are oxidized and decomposed into water vapor and carbon dioxide. Therefore, in this case, it is possible to prevent an increase in the risk of combustion of the mixed gas due to an increase in the amount of the organic gas component in the housing 410 due to the recycling of the mixed gas.

  Note that the ratio of oxygen and nitrogen contained in the mixed gas recycled toward the central space 429M through the oxidation catalyst 480 may be different from the ratio of oxygen and nitrogen in the degreasing preparation stage. . For this reason, for example, in the region between the outer space 429MO and the lower space 429B of the central space 429M, the ratio of oxygen and nitrogen contained in the mixed gas may be constantly monitored by a gas sensor or the like. Further, when the ratio of oxygen and nitrogen deviates from the predetermined range, the ratio of oxygen and nitrogen is controlled within the predetermined range by controlling the amount of air and nitrogen supplied from the air source 490 and the nitrogen source 492. You may adjust so that it becomes. Thereby, even when the mixed gas is recycled, the ratio of oxygen and nitrogen contained in the gas supplied to the honeycomb formed body 425 can be always maintained within a predetermined range.

  Note that the ratio of the mixed gas discharged from the upper space 429U via the gas discharge port 416 and the mixed gas to be reused is not particularly limited. For example, the amount of the mixed gas to be reused may be 90% of the entire mixed gas (in this case, the amount of the mixed gas to be exhausted is 10%).

  In the present application, the specific surface area of the inorganic particles can be measured by the BET multipoint method. Further, the average pore diameter of the honeycomb unit can be measured by a mercury intrusion method.

  Examples of the present invention will be described below.

(Example 1)
A honeycomb unit shown in FIG. 2 was actually produced by the method according to the present invention.

  First, a honeycomb formed body was produced.

As raw materials, zeolite particles (particle diameter 2 μm, specific surface area 250 m ² / g) 3000 parts by weight, alumina fiber 650 parts by weight (average fiber diameter 6 μm, average fiber length 100 μm), inorganic binder (boehmite) 840 parts by weight, organic binder ( Methyl cellulose) 330 parts by weight, lubricant 330 parts by weight, and ion-exchanged water 1800 parts by weight were mixed to prepare a raw material paste for a honeycomb formed body.

Next, this raw material paste was used for extrusion molding with an extruder to obtain a prismatic honeycomb formed body as shown in FIG. The dimensions of the honeycomb formed body are 35 mm × 35 mm × length 50 mm. The cell wall thickness of the honeycomb formed body was 0.25 mm, and the cell density was 71 cells / cm ² .

  Next, the honeycomb formed body was degreased using a degreasing apparatus 400 as shown in FIG.

  The honeycomb formed body was placed on a support stand such that the first end face was on the lower side and the second end face was on the upper side.

Next, the introduced gas was supplied into the degreasing apparatus 400. The composition of the introduced gas is oxygen: nitrogen = 3.5: 96.5 (vol%). The flow rate of the introduced gas was 100 m ³ / hour. In this state, the honeycomb formed body was heated to 400 ° C. at a temperature rising rate of 5 ° C./min to degrease the honeycomb formed body.

  Next, the honeycomb formed body was heated to 700 ° C. at a temperature rising rate of 5 ° C./min, and held at 700 ° C. for 2 hours. Thereafter, it was naturally cooled to obtain a honeycomb unit according to Example 1.

(Example 2)
A honeycomb unit according to Example 2 was manufactured through the same steps as in Example 1. However, in Example 2, the composition of the introduced gas was oxygen: nitrogen = 5.0: 95.0 (vol%). Other manufacturing conditions are the same as those in Example 1.

(Example 3)
A honeycomb unit according to Example 3 was manufactured through the same steps as in Example 1. However, in Example 3, the composition of the introduced gas was oxygen: nitrogen = 1.5: 98.5 (vol%). Other manufacturing conditions are the same as those in Example 1.

(Comparative Example 1)
A honeycomb unit according to Comparative Example 1 was manufactured through the same steps as in Example 1. However, in this comparative example 1, the conventional degreasing apparatus was used. In this degreasing apparatus, the introduced gas is introduced from above the degreasing apparatus. Further, the support base on which the honeycomb formed body is placed is not provided with a through hole. Therefore, the introduced gas cannot flow from the lower end surface toward the upper end surface inside the honeycomb formed body.

  Other manufacturing conditions are the same as those in Example 1.

(Evaluation)
A compression bending test was performed using the honeycomb units manufactured in Examples 1 to 3 and Comparative Example 1, and the strength of each honeycomb unit was evaluated.

  The compression bending test was a three-point bending test based on JIS R1601. The distance between the fulcrums was 30 mm. A load by an indenter was applied from the top to the central portion of the side surface of the honeycomb unit, and the load when the honeycomb unit was damaged was defined as the bending strength.

  As a result of the measurement, the bending strengths of the honeycomb units of Examples 1 to 3 were 4.9 MPa, 5.3 MPa, and 4.8 MPa, respectively, and good bending strength was obtained in all cases.

  The bending strength of the honeycomb unit of Comparative Example 1 is 3.4 MPa, which indicates that the honeycomb unit has insufficient strength. This is because in the honeycomb unit manufactured in Comparative Example 1, the carbon component of the organic binder and / or the forming aid remains in the fine pores of the inorganic particles, and the condensation bond between the inorganic particles via the inorganic binder is not good. This is thought to be because it was sufficient.

DESCRIPTION OF SYMBOLS 100 Honeycomb structure 110 1st end surface 115 2nd end surface 120 Outer periphery coat layer 121,122 Cell 123,124 Cell wall 130 Honeycomb unit 150 Adhesive layer 400 Degreasing apparatus 410 Housing 415 Gas inlet 416 Gas discharge port 420 Support stand 422 Through-hole 425 Honeycomb molded body 429U Upper space 429B Lower space 429M Central space 429MI Inner space 429MO Outer space 440 Fan 450 Partition plate 480 Oxidation catalyst 490 Air source 492 Nitrogen source

Claims (10)

A method for manufacturing a honeycomb structure having a honeycomb unit,
The manufacturing method is
(A) A plurality of cells including inorganic particles having a specific surface area of 50 m ² / g or more, a molding aid and / or an organic binder, and extending from the first end face to the second end face along the longitudinal direction. Is a step of forming a honeycomb formed body partitioned by cell walls , wherein the inorganic particles include zeolite ,
(B) placing the honeycomb formed body in a degreasing device such that the first end surface is on the lower side and the second end surface is on the upper side, and the degreasing device includes the honeycomb forming unit Having a housing for housing the body ;
(C) a step of supplying an introduction gas into the degreasing apparatus , wherein the introduction gas is a mixture of nitrogen supplied from a nitrogen source and gas supplied from an oxygen source or an air source; Introduced into the housing from an inlet provided in the housing, the inlet being provided at a position higher than ½ of the height of the housing ;
(D) degreasing the honeycomb formed body at a temperature of 200 ° C. to 400 ° C .;
(E) firing the degreased honeycomb molded body at a temperature of 500 ° C. to 900 ° C. to obtain a honeycomb unit;
Including
The introduced gas contains oxygen and nitrogen, and the ratio of oxygen to nitrogen is 1.5: 98.5 (vol%) to 5.5: 94.5 (vol%);
In the step (c), the introduced gas introduced from the inlet is guided to a position lower than the first end face of the honeycomb molded body, and then at least a part of the introduced gas is the honeycomb molded body. Flowing through the cells of the honeycomb molded body from the first end face toward the second end face,
At least a part of the introduced gas discharged from the second end face of the honeycomb molded body is oxidized through an oxidation catalyst and then mixed with the introduced gas introduced from the inlet, A method for manufacturing a honeycomb structure, wherein the honeycomb structure is guided to a position lower than the first end face . The method for manufacturing a honeycomb structure according to claim 1 , wherein the steps (b) to (e) are performed in a batch type or a continuous type. The first portion of the introduced gas passes through the cells of the honeycomb formed body, flows inside the honeycomb formed body from the first end surface toward the second end surface,
The second portion of the introduced gas, the through outer peripheral portions of the honeycomb molded body, according to claim 1 or 2, characterized in that flow from the first end surface in a direction parallel direction of the second end face A method for manufacturing a honeycomb structured body according to claim 1. The honeycomb formed body further includes an inorganic binder, and the inorganic binder includes alumina or a precursor of alumina,
The method for manufacturing a honeycomb structured body according to any one of claims 1 to 3 , wherein an alumina layer is formed on a surface of the cell wall in the step (e). The method for manufacturing a honeycomb structure according to any one of claims 1 to 4 , wherein an average pore diameter of the honeycomb unit is in a range of 0.01 µm to 1.0 µm. The method for manufacturing a honeycomb structure according to any one of claims 1 to 5 , wherein the honeycomb structure is configured by joining a plurality of the honeycomb units via an adhesive layer. A degreasing apparatus for a honeycomb molded body,
A plurality of cells including inorganic particles containing zeolite having a specific surface area of 50 m ² / g or more, a molding aid and / or an organic binder, and extending from the first end face to the second end face along the longitudinal direction. A support base for arranging the honeycomb formed body divided by the cell walls so that the first end surface is on the lower side and the second end surface is on the upper side,
A housing for housing the honeycomb formed body, the housing having an inlet provided at a position higher than ½ of the height of the housing;
Supply means for supplying an introduction gas into the housing via the inlet , wherein the introduction gas is a mixture of nitrogen supplied from a nitrogen source and gas supplied from an oxygen source or an air source. A supply means to be supplied to the inlet ;
Heating means for heating the honeycomb formed body to a temperature of 200 ° C. to 400 ° C .;
The introduced gas is guided so that at least a part of the introduced gas flows through the cells of the honeycomb formed body and flows in the honeycomb formed body from the first end face toward the second end face. Guiding means for guiding the introduced gas introduced from the inlet to a position lower than the first end face of the honeycomb formed body; and
A circulation path for reusing at least a part of the introduced gas discharged from the second end face of the honeycomb formed body as a part of the introduced gas, the circulation path having an oxidation catalyst;
Have
It said introduction gas comprises oxygen and nitrogen, the ratio of oxygen and nitrogen, 1.5: 98.5 (vol%) ~5.5: 94.5 (vol%) der is,
The introduced gas oxidized by the oxidation catalyst is mixed with the introduced gas introduced from the inlet by the circulation path, and is guided to a position lower than the first end face of the honeycomb formed body by the guiding means. degreasing treatment apparatus of the honeycomb molded body characterized by that. The first portion of the introduced gas passes through the cells of the honeycomb formed body, flows inside the honeycomb formed body from the first end surface toward the second end surface,
Second part of the introduction gas, according to claim 7 through an outer peripheral portion of the honeycomb molded body, characterized in that the flow in the direction parallel to the direction of the second end surface from said first end surface Degreasing apparatus for honeycomb molded bodies. The support base has a plurality of through holes,
The honeycomb molded body degreasing apparatus according to claim 7 or 8 , wherein the introduced gas is supplied into the cells of the honeycomb molded body through the plurality of through holes. The degreasing treatment apparatus for a honeycomb molded body according to any one of claims 7 to 9 , wherein the inlet is connected to an air source or an oxygen source and a nitrogen source outside the housing.

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