JP5838104B2 - 液体含浸固形物の製造方法 - Google Patents
液体含浸固形物の製造方法 Download PDFInfo
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- JP5838104B2 JP5838104B2 JP2012035087A JP2012035087A JP5838104B2 JP 5838104 B2 JP5838104 B2 JP 5838104B2 JP 2012035087 A JP2012035087 A JP 2012035087A JP 2012035087 A JP2012035087 A JP 2012035087A JP 5838104 B2 JP5838104 B2 JP 5838104B2
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Description
粉体原料を圧縮成形して、図1及び図2に示す固形物10と同形状(円柱形状)の固形物を得、該固形物に、液体成分に増粘剤を添加して調製した増粘液体を付与してこれを含浸させ、液体含浸固形物として図3に示す浴用剤20を製造した。尚、図3では、浴用剤20を包装体30内に密封してなる個装体40を示しているところ、この個装体40は、後述する保存安定日数の評価で用いるものである。浴用剤20の具体的な製造方法は下記の通りである。
液体成分及び増粘剤の添加量を適宜変更した以外は実施例1と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、実施例2〜6のサンプルとした。
液体成分に増粘剤を添加せずに該液体成分をそのまま固形物に付与した以外は実施例1と同様にして液体含浸固形物としての浴用剤及びその個装体を製造し、比較例1のサンプルとした。
また、液体成分の添加量を増加した以外は比較例1と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、比較例2のサンプルとした。
実施例1〜6並びに比較例1及び2の製造中間体としての固形物について、液体拡散率を下記方法により評価すると共に、実施例1〜6並びに比較例1及び2で得られた浴用剤(個装体)について保存安定日数を下記方法により評価した。その結果を下記表1に示す。
実施例1の増粘液体の付与方法と同様の方法により、静置した固形物の上面に液体を付与し、その静置状態を維持したままで液体付与から15日経過後に、固形物の上面中心部を通る任意の直線に沿って該固形物を縦に切断し、厚み方向に沿った切断面をCCDカメラで撮影し、画像処理により2値化して総断面積(V1)に対する発色部面積(V2)の比率(V2/V1)を算出し、その算出値に100を乗じた値を液体拡散率(%)と定義した。尚、固形物には色素が含まれており、液体が通過した空隙及び液体が滞留している空隙は、色素が液体と接触すると発色する現象によって、目視でも明確に色差を確認できるので、2値化は容易である。また、総断面積(V1)及び発色部面積(V2)の算出は、ノギス等で寸法を実測することによっても可能である。また、本評価方法において、液体付与後から15日経過後の液体拡散率を評価対象とした理由は、別途評価した、液体付与後から30日経過後の液体拡散率とほとんど変わらなかったためである。
製造直後の個装体5袋を、各個装体内の浴用剤の上面が上になるように積み重ねて、高さ78.5mm〔=15.7(厚みW4)×5〕)の積層体を形成し、該積層体を、温度50℃、湿度なりゆきの環境下に放置する。尚、個装体において、浴用剤を包装している包装体は、Al箔がラミネートされた多層ピロー袋であるため、該個装体を多湿な環境下に放置してもその内部に水分が浸入することはない。この放置期間中に、各個装体内の浴用剤中において、付与された液体が拡散して炭酸ガス発生成分と接触すると、個装体内に炭酸ガスが供給されることになり、結果として個装体の厚みが増加することになる。個装体5袋からなる積層体を形成してから該積層体の厚みが90mmとなるまでの日数を数え、該日数から1日を引いた日数を保存安定日数とした。この日数が長いほど、浴用剤の保存安定性に優れ高評価となる。
粉体原料を圧縮成形する際の打錠圧力を180kg/cm2に設定して、固形物の密度を1.30g/cm3に低下させた以外は実施例1と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、実施例7のサンプルとした。
また、増粘剤の添加量を増加した以外は実施例7と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、実施例8及び9のサンプルとした。
粉体原料を圧縮成形する際の打錠圧力を470kg/cm2に設定して、固形物の密度を1.44g/cm3に上昇させた以外は実施例1と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、実施例10のサンプルとした。
また、増粘剤の添加量を増加した以外は実施例10と同様にして、液体含浸固形物としての浴用剤及びその個装体を製造し、実施例11及び12のサンプルとした。
実施例7〜12の製造中間体としての固形物について、含浸時間を下記方法により評価した。その結果を下記表2に示す。
静置した固形物の上面に、速度0.1g/秒で液体の滴下を開始し、同時にストップウォッチをオンする。液体の滴下が終了し、その後液体全部が固形物内に含浸されたことを目視で確認し、ストップウォッチをオフして、その間を含浸時間とする。
実施例1と同様の製造条件の下、打錠圧力のみを適宜変更して、密度の異なる3種類の固形物(図3に示す浴用剤20と同形状・同寸法の多孔性の固形物)を得、各固形物の上面の凹部に、実施例1で用いた所定量の液体成分のみを、スポイトを用いて滴下速度0.1g/秒で滴下し、液体成分を付与してから15日経過後に、前記方法に従って液体拡散率を測定した。液体成分の総添加量は、各固形物につき、0.2gから0.6gまで、0.1g刻みで5パターンとした。その結果を下記表3に示す。
10a 固形物の上面
11 固形物の上層部(上面及びその近傍)
12 上層部以外の固形物の他の部分(下層部)
15 凹部
20 浴用剤
30 包装体
40 個装体
50 ノズル
Claims (6)
- 炭酸塩及び有機酸を含む粉体原料を圧縮成形して、液体と反応して炭酸ガスを発生する炭酸ガス発生成分を含む固形物を得る工程と、
液体成分に増粘剤を添加して調製した増粘液体を、前記固形物の上面に付与して、該増粘液体を該固形物に含浸させる工程とを有し、
前記液体成分は、香料、油剤及び色素からなる群から選択される1種以上を含む油性の液体である、液体含浸固形物の製造方法。 - 前記固形物は、前記上面及びその近傍を含む上層部が、該上層部以外の該固形物の他の部分に比して密度が低い請求項1記載の液体含浸固形物の製造方法。
- 前記固形物の上面に凹部が形成されており、該凹部に前記増粘液体を付与する請求項1又は2記載の液体含浸固形物の製造方法。
- 前記増粘液体の前記固形物への付与前又は付与直後に、該増粘液体を加温する請求項1〜3の何れか一項に記載の液体含浸固形物の製造方法。
- 前記増粘液体の付与後に、前記固形物の上面を冷却する請求項4記載の液体含浸固形物の製造方法。
- 前記増粘剤がポリシリコーン−9である請求項1〜5の何れか一項に記載の液体含浸固形物の製造方法。
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