JP5767662B2 - TERMINAL MATERIAL, ITS MANUFACTURING METHOD AND TERMINAL MANUFACTURING METHOD - Google Patents

Description

The present invention relates to a method for producing a terminal using a terminal member having excellent record over The weldability and its manufacturing method, and it.

  In recent years, there has been a demand for weight reduction of each component in order to improve the fuel efficiency of automobiles. Therefore, replacing the core wire of the electric wire used for the wire harness etc. in a motor vehicle with aluminum or aluminum alloy lighter than copper or copper alloy is advanced. Since a metal material is usually used for a terminal to be crimped and connected to the tip of this aluminum or aluminum alloy electric wire (hereinafter simply referred to as “aluminum electric wire”), these terminals are appropriately connected at the terminal connection portion of the electric wire. It will be necessary.

Generally, the terminal is made of copper or a copper alloy from the viewpoints of mechanical strength and springiness. Since the aluminum or aluminum alloy of the wire conductor is exposed at the crimping part of the terminal, if moisture adheres to the connection part of the aluminum wire and the terminal, the aluminum or aluminum alloy of the aluminum wire and the copper or copper alloy of the terminal Since the potential difference is different between different metals, corrosion (electrocorrosion) may occur, and defects may occur when corrosion progresses. Further, due to the progress of corrosion, the connection portion between the electric wire and the terminal is cracked or has poor contact, and the product life has been shortened.
In order to prevent these problems, it is desirable to block aluminum or an aluminum conductor (hereinafter simply referred to as “aluminum conductor”) from the outside. As an example, there is a method (for example, see Patent Document 1) in which the entire crimped portion of the terminal is molded with resin, and corrosion can be reliably prevented. Moreover, the technique (for example, refer patent document 2) which interrupts | blocks an aluminum conductor from the external environment by the method of crimping | bonding after covering a metal cap on an electric wire conductor is disclosed.

On the other hand, the applicant of the present application forms a terminal caulking portion by butt welding both ends of a terminal base material formed by punching from a copper alloy plate material by laser welding, and an aluminum electric wire is formed in the caulking portion of the tubular body. Caulking after inserting the aluminum conductor, the conductor is housed in the terminal for electrical continuity, and the connection part between the dissimilar metal joint conductor and the tube caulking part does not come into contact with external moisture Proposes a structure.
However, when laser welding copper or copper alloy, copper or copper alloy has a high reflectivity of 90% or more of near-infrared laser light widely used as laser light for welding (absorbability of laser light). Therefore, the efficiency of laser welding is poor and the welding speed cannot be increased (see, for example, Patent Document 3).

JP 2011-222243 A JP 2004-207172 A JP 2011-1117048 A

In the technique described in Patent Document 1, since the mold portion is enlarged, it is necessary to increase the size of the connector housing, and as a result, the connector is enlarged. For this reason, the entire assembled electric wire (for example, a wire harness for automobiles) using this connector cannot be molded in a high density and small size. Moreover, it is necessary to process each crimping | compression-bonding part after a crimping | compression-bonding, the number of processes of manufacturing an assembled electric wire increases greatly, and each operation | work is complicated.
Moreover, in the technique described in Patent Document 2, the process of attaching caps to individual conductors before crimping is complicated, and the cap is broken by the wire barrel during crimping, resulting in a flooded path. There was a fear.

  Therefore, it is a simple welding method by performing a process for lowering the reflectance of the laser beam (increasing the absorbability of the laser beam) on the copper alloy material formed by the terminal, particularly in the tube caulking portion. There has been a demand for a method of efficiently forming a tubular structure of a terminal by laser welding.

The present invention aims to provide a method for producing a terminal using a terminal member having excellent record over The weldability and its manufacturing method, and it.

  As a result of intensive studies in view of the above problems, the present inventors have high laser light absorptivity at least on the end surface and further on the end portion thereof after pressing the terminal material (so-called skeleton) punched by pressing. By providing an Ag layer subjected to sulfiding treatment and laser welding the end portion so as to include this end face, a tube caulking portion is formed, thereby significantly improving laser weldability in the tube caulking portion of the terminal material. I found out that I can make it happen. The present invention has been completed based on this finding.

That is, the said subject is solved by the following means .
(1 ) A terminal material having a developed view shape of a terminal having a tubular caulking portion for crimping and joining an electric wire conductor inserted into the internal space of the tubular body, and the terminal material forms the caulking portion of the tubular body. The terminal material which has a pipe | tube expansion | deployment part and has an Ag layer with a thickness of 1 micrometer or less attached | subjected to the sulfuration process in each edge part of the said pipe | tube expansion part.
( 2 ) From the copper or copper alloy plate material, the terminal material is press-punched into a developed view shape of a terminal having a tubular caulking portion for crimping and joining a wire conductor inserted into the internal space of the tubular body. A step of providing a pipe development part for forming a pipe caulking part in the material;
A method for producing a terminal material, comprising the steps of providing an Ag layer having a thickness of 1 μm or less at each end of the tube development portion and then subjecting the Ag layer to a sulfiding treatment in this order.
( 3 ) The step of bending the tube expanding portion of the terminal material according to ( 1 ), respectively, and matching the ends of the tube expanding portion to form a tubular body shape,
The manufacturing method of a terminal which has the process of joining this butted part by laser welding and forming the said pipe | tube crimping part in this order.

According to the terminal material of the present invention, since the Ag subjected to the sulfurization treatment has high laser beam absorbability (low reflectance of the laser beam), laser welding can be performed efficiently. It is suitable for producing efficiently by the method.
The method for producing a terminal material of the present invention is suitable as a method for efficiently producing the terminal material by a simple method.
The terminal manufacturing method of the present invention is suitable as a method for efficiently manufacturing the terminal by a simple method.

It is a cross-sectional view showing a widthwise cross section of the tube crimped portion of the pin. It is a perspective view illustrating a preferred embodiment of a pin. It is a sectional view showing a longitudinal section of the tube crimped portion of the pin. Is a perspective view showing an example of a terminal unit of the wire to be formed with a pin. One state during manufacture of the pin is a perspective view schematically showing. It is the top view which showed the state which unfolded the terminal material (chain type) before shaping | molding of the female terminal produced by stamping and pressing a board | plate material. It is the perspective view which showed the state which processed the terminal material and shape | molded the tubular body crimp part.

  A preferred embodiment of the present invention will be described with reference to the drawings. The embodiment shown below is an example, and various embodiments can be taken within the scope of the present invention.

  According to the present invention, as shown in a schematic cross-sectional view in FIG. 1, each end portion (100) (that is, a pipe expanding portion (101) forming a tube caulking portion (FIGS. 2 and 30 to be described later) of the terminal material (that is, By providing the Ag layer (102) subjected to the sulfiding treatment on the end portion where the tube expanding portion extends from the base material of the terminal material in the width direction at the tube expanding portion), the absorption of the laser beam is improved ( Laser reflectivity can be reduced, and laser welding can be performed efficiently.

The present inventors examined the shape of the end surface of the end portion (100) of the pipe deployment portion (101) in a terminal material punched out of a copper or copper alloy plate material by press working. As a result, it was found that the shape of the end face was composed of four regions of a dowel surface, a shear surface, a fracture surface, and a burr in order from the cutting start side after press cutting.
As described above, the end face has a complicated shape, and an Ag layer (102) subjected to sulfidation treatment is provided thereon by performing sulfidation treatment after, for example, silver plating treatment. As shown schematically in FIG. 5, the entire end face can be made smooth and have a high laser light absorbability. And, by making the end face smooth and having a high laser light absorbency in this way, by increasing the absorption rate of the laser beam at the time of laser beam irradiation (lowering the reflectivity of the laser beam), Laser welding can be performed efficiently.
And when a pipe expansion part edge part was made into the smooth state in this way, in addition to improving weldability since a laser beam was applied efficiently, it turned out that the joint strength after welding also increases.

Here, when an Ag layer subjected to sulfidation treatment is provided on a copper or copper alloy terminal material, the silver subjected to the sulfidation treatment is silver sulfide and has a high laser light absorptance in the wavelength region of the laser light ( Since laser reflectivity is low), laser weldability is greatly improved. This is presumably because silver sulfide exhibits a black color and thus has a high absorption rate in the wavelength region of laser light. The Ag layer may be entirely sulfided to form silver sulfide by sulfidation treatment, or may have metallic silver remaining without being sulfided in a part of the inside.
The action is considered as follows. First, the silver sulfide of the Ag layer subjected to sulfidation is melted by the energy of the laser beam. Subsequently, thermal energy propagates from the molten silver sulfide, and the copper (Cu) of the base material immediately below melts. After the laser light irradiation, the molten metal copper solidifies together with the metal silver, and the joining is completed.
At this time, the silver sulfide of the Ag layer subjected to the sulfidation treatment is melted by laser light irradiation to form a copper (Cu) component of the base material copper or a copper alloy and a Cu—Ag alloy. It seems that it is taken in the weld. Since the welded portion after laser welding is made into a Cu-Ag alloy in this way, the material strength of the welded portion is high, and good processing can be performed that is strong in subsequent processing. Note that silver sulfide may adhere to the outside of the melted portion, and in this case, a part of silver remains on the surface without being taken into the base material.

In the present invention, an Ag layer subjected to sulfidation treatment is provided at the end of the pipe expanding portion so as to include the press-processed end face that is a portion to be welded in this way.
Moreover, although plating should just adhere to the end surface of the pipe | tube expansion | deployment part (101) of the terminal material which carried out the press punching process, the whole surface of the terminal material may be plated. Of these, when plating is performed on the entire surface, plating is performed by immersing the entire punched terminal material in a plating bath. On the other hand, when plating only on the end face, a mask may be applied to a portion that does not require plating and then immersed in a plating bath for plating.
Furthermore, the end part (100) of the tube development part (101) that forms the caulking part (30) is once formed into an intermediate shape in a horseshoe shape (saddle shape), and only both end parts corresponding to both horseshoe-shaped legs are immersed in the plating bath. By doing so, it is also possible to perform partial plating only on the end surface of the tube development portion and its periphery. In this case, after the completion of plating, press forming is performed again so that the end portion of the tube development portion is tubular.

  Here, the formation method of the Ag layer is not particularly limited. For example, in addition to electroplating of Ag, electroless plating method, ion plating method, sputtering method, chemical vapor deposition method, or application of silver paste Any of various film formation techniques such as drying and the like can be used. Among these, from the viewpoint of operability and cost, it is preferable to perform an Ag plating treatment to provide an Ag layer.

Hereinafter, the formation of the Ag layer subjected to the sulfidation treatment will be described using the Ag electroplating treatment as a representative example.
As the Ag plating bath, a normal one, for example, a commercially available Ag plating bath can be used. As conditions for the Ag plating treatment, for example, the current density is preferably ¹ to 5 A / dm2. Moreover, it is preferable to perform an Ag stripe plating process before an Ag plating process according to a conventional method.
Moreover, said other methods other than a silver electroplating process can be performed according to the conditions of a conventional method, respectively.
In the present invention, the thickness of the Ag layer subjected to the sulfidation treatment is 1 μm or less, and preferably 0.1 μm or less. The lower limit of the thickness of the Ag layer subjected to the sulfiding treatment is not particularly limited, but is usually 0.05 μm or more. Since the sulfidation of silver proceeds only in a very thin range, if the thickness of the Ag layer subjected to the sulfidation treatment is too thick, the non-sulfurized metal Ag itself has a low laser light absorptivity, so that the effect of improving weldability is obtained. Hateful. On the other hand, if the thickness of the Ag layer subjected to the sulfiding treatment is too thin, the amount of laser light absorbed and converted into heat decreases, and the welding speed decreases. Moreover, when the thickness of the Ag layer is too thin, the Ag plating layer is not formed as a single layer but is formed in an island shape, and the surface of the base material may be exposed.
If the unsulfurized Ag layer is exposed on the surface due to insufficient sulfidation or the like, the laser beam absorptivity is low, so that the laser weldability is degraded. Therefore, in the present invention, it is important to provide a thin Ag layer first, and to convert almost the entire Ag layer into silver sulfide in the subsequent sulfidation treatment.
Next, after an Ag layer is formed, sulfuration treatment is performed. The sulfurization treatment can be performed according to the conditions of a normal sulfurization test, for example, under conditions of H ₂ S 3 ppm, 40 ° C., 80% RH, 24 hours.

In the present invention, it is a terminal material punched from copper or a copper alloy plate material or strip material by press working, and the predetermined shape of the terminal material in a developed shape that has not yet been formed into a terminal shape and is not subjected to subsequent laser welding processing. Is provided with an Ag layer subjected to sulfidation treatment. And by improving the laser weldability of copper or copper alloy by disposing an Ag layer subjected to sulfidation treatment as a material with high absorptance at a specific position of copper or copper alloy material as a base material It is.
Here, as shown in FIG. 1, the Ag layer subjected to the sulfidation treatment may be provided not only on the end face of the opposing pipe development part but also on the peripheral part thereof. Or you may provide only in the end surface of the said pipe | tube expansion | deployment part which opposes.
In the present invention, the Ag layer which is subjected to the subsequent sulfidation treatment to become a silver sulfide layer may be formed on the entire terminal material. In consideration of the manufacturing cost depending on the amount of Ag used and the appearance of the entire terminal, it is preferable to form the Ag layer on the press punched end surface that is a portion subjected to laser welding. For example, from the viewpoint of the work efficiency of Ag layer formation such as silver electroplating, the Ag layer may be provided only on the press punched end face. Furthermore, for example, from the viewpoint of ease of Ag plating treatment, the Ag layer may be provided in a region schematically shown as 102 in FIG. 1 including the press punched end face and its vicinity. . In any case, the Ag layer is provided so as to include the end faces of the end portions (100) of the tube expanding portion (101) of the terminal material formed in the tube caulking portion (30) forming portion. In the present invention, it is sufficient that the Ag layer is provided on the end face, and other regions, for example, the entire pipe expanding portion (101) of the terminal material, the box portion (20), the transition portion (40), etc. The Ag layer may be formed on the entire terminal material including

  FIG. 2 shows a terminal 1 which is a preferred embodiment of a terminal manufactured by the manufacturing method of the present invention. This terminal 1 has a female terminal box portion 20 and a tubular caulking portion 30 for connecting the electric wire and the base material of the terminal by crimping after the aluminum electric wire is inserted. A transition unit 40 that communicates with the body caulking unit 30 is provided. Further, the terminal 1 has a laser welding portion 50 (portion indicated by hatching in the drawing) in the tube caulking portion 30. The terminal 1 is basically made of a base material made of a metal material (such as a copper alloy) in order to ensure conductivity and strength. The shape of the laser weld 50 is not particularly limited. It is preferable to form in a band shape in the longitudinal direction of the tubular caulking portion 30 like the laser welding portion 50.

  The material of the base material 32 constituting the terminal 1 and the terminal material (FIGS. 6 and 32a) is copper (tough pitch copper, oxygen-free copper, etc.) or a copper alloy, preferably a copper alloy.

Examples of the copper alloy used for the terminal and the terminal material include, for example, brass (for example, C2600 and C2680 of CDA (Copper Development Association)), phosphor bronze (for example, C5210 of CDA), corson-based copper alloy (Cu-Ni -Si- (Sn, Zn, Mg, Cr) -based copper alloy) and the like. Among these, a Corson-based copper alloy is preferable.
Examples of the Corson copper alloy are not limited to these, but include, for example, Furukawa Electric Co., Ltd. copper alloys FAS-680 and FAS-820 (both trade names), Mitsubishi Shindoh copper alloys MAX-375, MAX251 (both are trade names) and the like can be used. Also, CDA C7025 or the like can be used.
An example of the alloy composition of the FAS-680 is 0.15% by mass of tin (Sn), 0.5% by mass of zinc (Zn), 2.3% by mass of nickel (Ni), and 0 of silicon (Si). .55% by mass and 0.1% by mass of magnesium (Mg), with the balance being copper (Cu) and inevitable impurities.
An example of the alloy composition of FAS-820 is as follows: tin (Sn) 0.15 mass%, zinc (Zn) 0.5 mass%, nickel (Ni) 2.3 mass%, silicon (Si) 0.65 mass%, magnesium (Mg) 0.1 mass%, and chromium (Cr) 0.15 mass%, with the balance being copper (Cu) and inevitable impurities.

Examples of other copper alloy compositions include, for example, Cu—Sn—Cr based copper alloys, Cu—Sn—Zn—Cr based copper alloys, Cu—Sn—P based copper alloys, Cu—Sn—P—Ni. Examples thereof include a copper alloy, a Cu—Fe—Sn—P copper alloy, a Cu—Mg—P copper alloy, and a Cu—Fe—Zn—P copper alloy.
Here, it is natural that inevitable impurities may be included in addition to the essential elements described above.

  The thickness of the terminal base material and the terminal material is preferably 0.08 to 0.64 mm.

  Prior to laser welding, an Ag layer that has been subjected to sulfidation in advance is formed on at least the surface of the terminal 1 that becomes the welded portion of the tubular caulking portion 30. After the laser welding, as described above, the metal Ag constituting the Ag layer subjected to the sulfidation treatment is melted in the laser weld 50 and taken in as a Cu-Ag alloy, and apparently from the surface of the laser weld. The Ag layer disappears.

  The box part 20 of the female terminal is a box part that allows insertion of an insertion tab such as a male terminal. In the present invention, the detailed shape of the box portion is not particularly limited. That is, in another embodiment of the terminal of the present invention, the box portion may not be provided. For example, an insertion tab of a male terminal may be used instead of the box portion. Moreover, the edge part of the terminal which concerns on another form may be sufficient. In this specification, in order to explain the terminal of the present invention, an example of a female terminal is shown for convenience. Whatever the terminal having any connecting end, it is sufficient that the tube caulking portion 30 is provided via the transition portion 40. Moreover, it is preferable that the welding part 50 formed in the tubular caulking part 30 is softer than the base material which comprises the tubular caulking part.

The tubular caulking part 30 is a part for crimping and joining the terminal 1 and an electric wire (not shown). One end has an electric wire insertion port (conductor insertion port) 31 into which an electric wire such as an aluminum electric wire or its conductor can be inserted, and the other end is connected to the transition portion 40. The tube caulking portion 30 is formed on the transition portion 40 side by crushing two opposing tube walls (usually upper and lower tube walls) of the tube caulking portion 30 by, for example, crushing processing such as press processing. It is closed by sealing by welding processing such as welding, and has a “can-like” structure having the closed portion as the bottom and opening at the wire or conductor insertion port (31). If moisture adheres to the contact between the terminal 1 base material (copper or copper alloy, etc.) and the aluminum wire, either metal (alloy) will corrode due to the difference in electromotive force between the two metals. 30 has a tubular structure that prevents moisture and the like from entering from the outside. If the crimped portion of the terminal of the present invention is a tubular body, a certain effect against corrosion can be obtained, so the cross section does not necessarily have to be a cylinder in the longitudinal direction. It may be a tubular tube. Further, the cross-sectional diameter does not need to be constant, and the cross-sectional diameter may change in the longitudinal direction.
If the terminal 1 is used, the tube caulking portion 30 is a tube, so that it is difficult for moisture from the outside to adhere to the contact between the aluminum electric wire and the base material of the terminal 1.

  In the tubular caulking part 30, the base material constituting the tubular caulking part and the aluminum (aluminum alloy) electric wire are mechanically pressure-bonded to ensure electrical joining at the same time. The caulking is performed by plastic deformation of a base material or an electric wire (core wire). Therefore, the tubular caulking portion 30 needs to be designed to be thick enough to be caulked and joined, but can be freely joined by human processing, machining, or the like, and thus is particularly limited. It is not a thing.

The tube caulking portion 30 of the present invention is configured by abutting plate base materials and has a laser welding portion 50 that joins the abutting portions. That is, the laser welded portion 50 is continuously provided in the longitudinal direction along the butted portion of the tubular caulking portion 30. And it is provided as a linear area | region from the transition part 40 to the electric wire insertion port 31. FIG.
The laser weld 50 is formed with an Ag layer that has been subjected to sulfidation before laser welding, and the Ag that has been subjected to sulfidation can increase the absorption of laser light during laser welding. it can. As described above, after laser welding, part or all of Ag in the Ag layer subjected to the sulfidation treatment is melted and taken into the copper (Cu) or copper alloy of the base material.

  A part of a longitudinal sectional view of the tubular caulking portion 30 is shown in FIG. In this figure, the description of the laser welded portion (annealed portion) 50 is omitted. As described above, the tubular caulking portion 30 is preferably composed of the base material 32 made of a copper alloy. Further, the inner wall surface 33 of the tubular caulking portion may have an electric wire locking groove 34a or 34b for maintaining a contact pressure with the electric wire. Aluminum and aluminum alloy, which are the core wires of electric wires, have an oxide film having higher insulating properties than copper oxide film on the surface compared to copper alloy, so there is anxiety in connection. Therefore, by providing such a groove, the contact pressure is increased by the crest of the groove. In FIG. 3, the wire locking groove 34a is a groove having a rectangular cross section, and the wire locking groove 34b is a groove having a semicircular cross section. Such a wire locking groove is easy to be provided if the base material itself is processed before the tube caulking portion 30 is formed. It can be provided by cutting with a fiber laser or a machine, which will be described later. In addition, if such an electric wire latching groove is provided in advance before the tube caulking portion 30 is formed, efficient production can be achieved.

In addition, since an aluminum electric wire or its conductor is inserted into the tubular caulking portion from the electric wire insertion port 31, it is preferable that the electric wire locking grooves 34a and 34b are provided at positions where they come into contact with the aluminum core wire. An aluminum electric wire is usually composed of an aluminum core wire (conductor) and an insulating coating covering the same. Then, the electrical connection between the electric wire and the terminal is performed by crimping and joining the aluminum core wire from which the insulating coating portion at the tip is removed (peeled) to the tube caulking portion of the terminal. Therefore, ensuring sufficient contact pressure leads to maintenance of electrical performance, so that a groove such as a wire locking groove is required. Such grooves are also called serrations.
And since a terminal and an electric wire are crimped | bonded reliably by providing at least 1 or more electric wire latching groove in the inner surface of the tubular caulking part 30, it can be made more excellent in long-term reliability.

  FIG. 4 shows an end connection structure 10 for an electric wire using the terminal of the present invention. The terminal connection structure 10 has a structure in which a terminal 1 manufactured according to the present invention and an aluminum electric wire (60) are connected. The terminal connection structure 10 inserts the aluminum electric wire 60 or its conductor into the tube caulking portion 30 of the terminal 1 and caulks the tube caulking portion 30 so that the aluminum electric wire 60 is crimped into the tube caulking portion 30. It is joined. Although the manner of crimping is not particularly limited, in FIG. 4, the first crimping reduced diameter portion 35 and the second crimped reduced diameter portion 36 are included. Normally, when crimped and joined, the tube caulking portion 30 undergoes plastic deformation and is crimped to the electric wire 60 by being reduced in diameter from the original diameter. In the example shown in FIG. 4, the first crimped reduced diameter portion 35 is a portion where the diameter reduction rate is the highest. In this way, the pressure bonding may be performed with two stages of diameter reduction, or may be performed with three or more stages of diameter reduction.

  The electric wire 60 includes an insulating coating 61 and a core wire of an aluminum or aluminum alloy electric wire (not shown). Although the electric wire 60 may be a bare wire, from the viewpoint of corrosion prevention, an electric wire with an insulation coating is usually used.

The termination connection structure for electric wires of the present invention contributes to prevention of corrosion between different metals between an electric wire made of an aluminum-based material and a terminal base material made of a copper-based material. In addition, since the laser welded portion 50 and the heat melting portion can be an annealed portion that is softer than the base material, it is possible to prevent the spring back of the crimping portion between the electric wire and the terminal, and this point is also excellent in long-term reliability. .
The spring back is a phenomenon in which the processed part attempts to return to its original shape. That is, since the deformed portion of the crimped portion of the tubular body crimped and joined to the electric wire (not shown) tries to return to its original shape with an elastic force or the like, a gap is created between the inner surface of the tubular crimped portion 30 and the electrical wire. End up. If such a springback occurs at the crimping portion of the terminal, not only will the contact failure between the electric wire 60 and the terminal 1 be caused, but also water may easily enter the gap and cause corrosion.

  When manufacturing the terminal connection structure 10 of an electric wire using the terminal manufactured according to this invention, the crimping | bonding which positively plastically deforms the laser welding part 50 of the pipe | tube crimping part 30 is preferable. When crimping the tube caulking portion 30 of the terminal 1 and the electric wire 60, it is performed with a dedicated jig or a press machine. At this time, the entire diameter of the tube caulking portion 30 may be reduced. However, the tube caulking portion may be partially processed to be crimped like a concave shape. At this time, the position may be adjusted so that the amount of plastic deformation of the laser weld 50 is increased. That is, when the adjustment is performed so that the tip of the convex portion at the time of press working is directly above (outside) of the laser weld 50, the amount of deformation of the laser weld 50 increases. If it does in this way, since the comparatively soft laser welding part 50 can bear much plastic deformation, it can contribute to reduction of a springback.

  Next, a method for manufacturing the terminal 1 will be described. The terminal 1 manufactured according to the present invention has a tube caulking portion 30 and is a terminal having a laser welding portion (see FIG. 2 etc.) in the tube caulking portion 30, so that this configuration can be achieved. The manufacturing method is not limited.

The terminal 1 is obtained by punching a plate material made of a base material (copper alloy or the like) into a flattened terminal shape to obtain the shape of the terminal material of the present invention, and providing an Ag layer subjected to the sulfiding treatment on the end face of the tubular caulking portion. Thereafter, the box portion 20 and the transition portion 40 are formed by bending, and the tube expanding portion forming the tube caulking portion that is curved and butted by bending or the like is laser welded to form the tube caulking portion 30. . Therefore, the terminal material punched into the terminal shape integrally has a shape capable of forming the box portion 20, the transition portion 40, and the tubular caulking portion 30 by bending or the like. The shape of the tube development portion of the terminal material that can be formed by bending the tubular caulking portion 30 is typically a rectangle, but is not particularly limited as long as the shape can form a tubular body with one end closed, For example, you may have substantially fan shape, a rectangle, or these combination shapes. The shapes that can form the box portion 20 and the transition portion 40 are appropriately selected according to the shapes of the box portion 20 and the transition portion 40. In addition, in the terminal material, an Ag layer subjected to the specific sulfidation treatment is formed at least on the surface of the tube development portion that forms the tube caulking portion. The terminal material of the present invention having such a shape and an Ag layer subjected to a specific sulfidation treatment is obtained by curving a tube expanding portion serving as a tube caulking portion to be crimped and joined to an electric wire, and abutting each other with each other. It is suitably used in a method for manufacturing a terminal which is formed into a body and the joined portions are joined by laser welding to form a tubular caulking portion.
When the tubular caulking portion 30 is formed, the flat tube unfolded portion has a C-shaped cross section as shown in the schematic cross-sectional view of FIG. 1 by bending, so that the end face of the open portion is abutted and welded. Thus, the tubular caulking portion 30 is formed. As a preferable manufacturing method of the tubular caulking portion 30, laser welding is performed using a fiber laser processing machine that oscillates near infrared laser light.

  Usually, copper alloys have a low absorption efficiency of laser light having an oscillation wavelength in the near-infrared region, so that there are cases where the weld width cannot be reduced or the heat affected zone (HAZ) cannot be reduced. Therefore, an Ag layer subjected to sulfidation treatment in which absorption of near-infrared laser light is better than that of a copper alloy is formed on the end surface of the butt portion of the base material 32 to be the laser weld 50 so that the end surface is smooth, And the above-mentioned subject is overcome by using laser light with high energy density like fiber laser light. Moreover, the laser welding part 50 can also be made into an annealing part, welding the butt | matching part of the tubular caulking part 30 by welding with fiber laser light. Thus, since the welding process and the annealing process of the tubular caulking part 30 can be performed in one process, the terminal 1 can be manufactured efficiently.

  Since the Ag layer subjected to the sulfiding treatment has less near-infrared laser light reflection than the copper alloy surface, the near-infrared laser light absorbability is good. In reflectance measurement of near-infrared light by spectrophotometry, Ag (that is, silver sulfide) subjected to sulfurization treatment used in the present invention has a reflectance of about 10 to 30%, and a reflectance of 90% or more. It is lower than some pure copper or copper alloys. When the region where the Ag layer subjected to the sulfidation treatment with high absorption of near infrared laser light is formed is irradiated with the near infrared laser light, the Ag subjected to the sulfidation treatment melts to form a molten pool. As a result, the absorption of laser light is increased, the base material surface of the base is melted, and the melted region absorbs the laser light to melt the butt portion of the base material, thereby through welding the butt portion. Is progressing.

  Since it varies depending on the material of the base material constituting the terminal 1, it cannot be generally stated. However, if the base material is a copper alloy in which an Ag layer subjected to sulfidation is formed on the butt portion, near infrared laser beam irradiation Thus, the Ag layer subjected to the sulfidation treatment on the surface absorbs the laser beam and melts to form a molten pool. Furthermore, the copper alloy of the base material is melted by the heat and heat energy converted into light energy by laser light irradiation, and the butted portions are joined to form the laser weld 50. Therefore, the laser welding part 50 is provided because a base material is heated up more than melting | fusing point. Specifically, by raising the base material to a temperature not lower than the melting point and not higher than the boiling point, including an Ag layer subjected to sulfidation at the butted portion of the tubular caulking portion 30, and performing laser welding by holding for a predetermined time if necessary. A laser weld 50 is formed. Usually, since the laser light is swept, the temperature of the laser light irradiation region may be set to be equal to or higher than the melting point of the substrate by appropriately determining the sweep speed. When the base material is a copper alloy, the laser light irradiation conditions are preferably adjusted so that the copper alloy of the base material melts and penetrates by laser light irradiation.

  The laser welding uses near infrared laser light. The near-infrared laser beam has an oscillation wavelength of 700 nm to 2.5 μm, and preferably a laser beam having an oscillation wavelength of 1000 nm to 2000 nm. Examples of such laser light include yttrium (Yt) doped glass fiber laser light (oscillation wavelength 1084 nm), erbium (Er) doped glass fiber laser light (oscillation wavelength 1550 nm), and the like.

  For the welding, a fiber laser device that continuously oscillates near-infrared laser light is used, but the tube caulking portion 30 may be formed by welding using a laser device different from this. For example, there are a YAG laser beam oscillation device, a glass laser beam oscillation device, etc. that oscillate continuously, a laser beam oscillation device that oscillates a pulse, etc., but a narrow divergence angle, a narrow beam diameter of the laser beam, In view of stability and the like, it is preferable to use a fiber laser oscillator.

FIG. 5 is a diagram schematically showing one state during manufacture of the terminal 1 of the present invention.
As shown in FIG. 5, a laser beam L emitted from a fiber laser welding apparatus FL that oscillates a laser beam having a near infrared wavelength of 1084 nm ± 5 nm is irradiated so as to weld a butt 37, and this butt is welded through. By doing so, the tubular caulking portion 30 is formed. At the time of this welding, the energy of the laser beam is converted into heat, so that the Ag layer subjected to the sulfiding treatment of the butt portion 37 first, and then the base material itself of the butt portion 37 is melted, and then cooled to perform laser welding. A part 50 is provided. The laser welding part 50 can be provided by a heat treatment at or above the melting point of the material to be welded. However, if the energy of the fiber laser beam L is too high or the energy density is low, the heat-affected zone is formed in a wider range than necessary, and in the extreme case, the entire caulking portion 30 is softened. . Therefore, the fiber laser light L is preferably welded at an output of 100 to 400W. Moreover, the laser welding part 50 is provided in a suitable range by adjusting sweep speed.

  Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited thereto.

As shown in FIG. 6, the plate material (5) made of the following copper alloy is punched into a shape in which the terminals are expanded so as to be continuous in the longitudinal direction (chain type) by pressing, and the chain type terminal material (32a) Formed. Then, as described later, an Ag plating treatment was performed at a predetermined low current density, followed by a sulfidation treatment, and an Ag layer subjected to the sulfidation treatment was provided on an end portion including the end face of the tube development portion (30a). Here, the Ag plating treatment was performed using Ag plating (commercially available bath). Thereafter, the formed Ag layer was subjected to sulfurization treatment.
After that, as shown in FIG. 7, the end faces (30S) of the caulking portions of the tubular bodies are butted together by joining through the welded portions over the entire length of 1 cm by the laser welding, and the tubular caulking portion (30) is joined. Formed (see FIG. 8). In addition, by this welding, an annealed part was also obtained in the caulked part of the tube. Moreover, the weldability and joint strength were evaluated by changing various conditions.

(Examples 1-4)
A copper alloy FAS-680 (trade name, thickness 0.25 mm, H material) manufactured by Furukawa Electric Co., Ltd. was used as a base material for the terminals.
The alloy composition of FAS-680 is 0.15% by mass of tin (Sn), 0.5% by mass of zinc (Zn), 2.3% by mass of nickel (Ni), and 0.55% by mass of silicon (Si). % And magnesium (Mg) 0.1% by mass, the balance being copper (Cu) and inevitable impurities. FAS-680 has a melting point of 1078 ° C. (liquid phase), a specific heat of 377 J / (kg · K), a thermal conductivity of 170 W / (m · K), and a linear expansion coefficient of 17.7 × 10 ⁻⁶ / K (20 ˜300 ° C.), and conductivity 40% IACS. Further, the tensile strength is 600 to 700 N / mm ² , the elongation (tensile elongation at break, the same applies hereinafter) is 15% or more, the 0.2% proof stress is 500 to 600 N / mm ² , and the Vickers hardness is 160 to 220 Hv. is there.

  After subjecting the base material to electrolytic degreasing treatment and subsequent acid dipping treatment, Ag plating treatment and subsequent sulfidation treatment are performed, whereby an Ag layer subjected to sulfidation treatment is formed on the end portion of the pipe development portion of the base material. The thickness was changed.

The experimental conditions are as follows.
<Electrolytic degreasing, acid immersion>
(Electrolytic degreasing)
Treatment liquid: 10% sodium hydroxide aqueous solution Treatment temperature: 60 ° C
Cathode current density: 3.5 A / dm ²
Processing time: 30 seconds (acid dipping)
Treatment liquid: 10% sulfuric acid treatment temperature: 30 ° C
Immersion treatment time: 30 seconds

<Ag plating>
(Ag strike plating)
Treatment liquid KAg (CN) ₂ : 4.45 g / L
KCN: 60g / L
Current density: 5 A / dm ²
Processing temperature: 30 ° C
(Ag plating)
Treatment liquid AgCN: 50 g / L
KCN: 100g / L
K ₂ CO ₃ : 30 g / L
Current density: 1 A / dm ²
Processing temperature: 30 ° C
Treatment time: 3-100 seconds Within the range of the above conditions, the plating time is changed in the Ag plating treatment process, and the sample whose plating thickness is ± 0.02 μm of the target thickness is measured for each thickness level. 10 pieces at a time.
In addition, the thickness of Ag layer measured the average thickness of Ag layer on an edge part with the fluorescent X ray film thickness meter.

<Sulfurization treatment>
According to the conditions of a normal sulfidation test, that is, H ₂ S 3 ppm, 40 ° C., 80% RH, 24 hours.

(Example 5)
It was produced in the same manner as in Example 1 except that in Example 3, a copper alloy FAS-820 (trade name) manufactured by Furukawa Electric Co., Ltd. was used instead of FAS-680.
The alloy composition of FAS-820 is 0.15% by mass of tin (Sn), 0.5% by mass of zinc (Zn), 2.3% by mass of nickel (Ni), and 0.65% by mass of silicon (Si). %, Magnesium (Mg) 0.1 mass%, and chromium (Cr) 0.15 mass%, with the balance being copper (Cu) and inevitable impurities. FAS-820 has a melting point of 1078 ° C. (liquid phase), a specific heat of 377 J / (kg · K), a thermal conductivity of 157 W / (m · K), and a linear expansion coefficient of 17.5 × 10 ⁻⁶ / K (20 ˜300 ° C.), and conductivity 38% IACS. Moreover, tensile strength is 730-830 N / mm < ² >, elongation is 7% or more, 0.2% yield strength is 675-775 N / mm < ² >, and Vickers hardness is 220-260 Hv.

(Example 6)
It was produced in the same manner as in Example 1 except that in Example 3, a copper alloy MAX-375 (trade name) manufactured by Mitsubishi Shindoh was used instead of FAS-680.
The alloy composition of MAX-375 is 0.5 mass% tin (Sn), 0.5 mass% zinc (Zn), 2.85 mass% nickel (Ni), and 0.7 mass silicon (Si). It is contained by mass and the balance is copper (Cu) and inevitable impurities. The melting point of FAS-820 is 1085 ° C. (liquid phase), the specific heat is 382 J / (kg · K), the thermal conductivity is 180 W / (m · K), and the linear expansion coefficient is 17.1 × 10 ⁻⁶ / K (20 ˜300 ° C.), and conductivity 40% IACS. Moreover, tensile strength is 750-850 N / mm < ² >, elongation is 6% or more, 0.2% yield strength is 710-830 N / mm < ² >, and Vickers hardness is 210-270 Hv.

(Example 7)
It was produced in the same manner as in Example 1 except that in Example 3, a copper alloy MAX251 (trade name) manufactured by Mitsubishi Shindoh was used instead of FAS-680.
The alloy composition of MAX251 contains 0.5 mass% tin (Sn), 1 mass% zinc (Zn), 2 mass% nickel (Ni), and 0.5 mass% silicon (Si), and Copper (Cu) is contained by 95% by mass or more, and the balance is inevitable impurities. FAS-820 has a melting point of 1085 ° C. (liquid phase), a specific heat of 382 J / (kg · K), a thermal conductivity of 194 W / (m · K), and a linear expansion coefficient of 17.1 × 10 ⁻⁶ / K (20 ˜300 ° C.), and conductivity 48% IACS. Further, the tensile strength is 500 to 600 N / mm ² , the elongation is 6% or more, the 0.2% proof stress is 440 to 580 N / mm ² , and the Vickers hardness is 140 to 200 Hv.

(Comparative Example 1)
A terminal substrate was prepared in the same manner as in Example 4 except that an Ag layer was provided and the terminal was not subjected to sulfurization treatment.
(Comparative Example 2)
A terminal substrate was prepared in the same manner as in Example 1 except that an Ag layer subjected to sulfurization treatment was not provided.
(Comparative Example 3)
A terminal substrate was prepared in the same manner as in Example 1 except that the thickness of the Ag layer subjected to the sulfidation treatment in Example 1 was 1.5 μm.

The laser welding conditions are as follows.
(1) Laser welding apparatus: Furukawa Electric Co., Ltd. single mode fiber laser ASF1J221 (trade name)
Laser light source: Yb-doped glass fiber laser oscillator Laser light oscillation wavelength: 1084 ± 5 nm
Maximum laser beam output: 500W (continuous oscillation)

(2) Laser light irradiation conditions Laser light output: 400 W (continuous oscillation)
Laser light sweep speed: adjusted at 90 to 300 mm / sec Laser light sweep distance: 10 mm
All conditions Just focus laser irradiation (spot diameter size: 20μm)

  The state of the welded part after laser welding was measured and evaluated for “weldability” and “joint strength” as follows.

The “weldability” was evaluated based on the speed at which penetration welding with a laser beam was possible.
From the relationship between the laser beam sweep speed and the laser beam sweep time, it can be judged that the laser beam sweep rate is high, that is, that the laser beam sweep time is short, that is, it is desirable from the industrial viewpoint because it requires less energy for laser welding. Specifically, the case where penetration welding can be performed at a laser beam sweep speed of 500 mm / sec or more is “A (good)”, and the case where penetration welding is possible at less than 500 mm / sec and 300 mm / sec or more is “B (possible)”. The cases where through welding could be performed at a speed slower than 300 mm / sec, or through welding could not be performed, were determined as “C (poor)”.

  In addition, the “joining strength” is evaluated by conducting a tensile test on the crimped portion of the terminal after welding (that is, the welded portion, but not being crimped to the wire conductor). It was. The tensile breaking strength broken at the weld was measured and evaluated. Specifically, “A (good)” when the tensile strength at break is 200 MPa or more, “B (good)” when the tensile break strength is less than 200 MPa and 100 MPa or more, and “C (poor)” when it is lower than 100 MPa. Judged each. If the breaking strength is lower than 100 MPa, it cannot withstand the molding process for forming a terminal shape.

  Table 1 shows the various test conditions and the evaluation results.

As is clear from Table 1, in each of the examples, laser welding was possible at a high laser light sweep speed, and weldability was good. Further, the bonding strength was high, and a good bonding state was obtained.
On the other hand, in each comparative example, laser welding could be performed only at a slow laser beam sweep speed, and the weldability was poor. Furthermore, in Comparative Example 1 and Comparative Example 2, the bonding strength is low, and cracking occurs in the molding process for forming the terminal shape.

DESCRIPTION OF SYMBOLS 1 Terminal 10 Termination connection structure 20 Box part 30 Tube caulking part 31 Electric wire insertion port 32 Base material 33 Inner wall surface of a tube caulking part 34a, 34b Electric wire latching groove 35 1st crimping | compression-reducing diameter part 36 2nd crimping | compression-bonding Reduced diameter portion 37 Butting portion 40 Transition portion 50 Welding portion 60 Electric wire 61 Insulation coating FL Fiber laser welding apparatus L Fiber laser beam 100 End portion 101 of pipe material of terminal material 101 Pipe development portion 102 of terminal material Ag subjected to sulfidation treatment layer

Claims (3)

  A terminal material having a developed view shape of a terminal having a tubular caulking portion for crimping and joining a wire conductor to be inserted into the internal space of the tubular body, wherein the terminal material forms a tubular caulking portion. And a terminal material having an Ag layer having a thickness of 1 μm or less subjected to sulfidation treatment at each end of the tube development portion. From the copper or copper alloy plate material, by pressing the terminal material into a developed view shape of the terminal having a crimped portion of the tube body for crimping and joining the wire conductor to be inserted into the internal space of the tube body, the terminal material, A step of providing a pipe unfolding portion for forming a tubular caulking portion;
A method for producing a terminal material, comprising the steps of providing an Ag layer having a thickness of 1 μm or less at each end of the tube development portion and then subjecting the Ag layer to a sulfiding treatment in this order. The step of bending the tube expanding portion of the terminal material according to claim 1 and forming the tube shape by abutting the ends of the tube expanding portion,
The manufacturing method of a terminal which has the process of joining this butted part by laser welding and forming the said pipe | tube crimping part in this order.

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