JP5720325B2

JP5720325B2 - 非水系電解液及びそれを用いた非水系電解液二次電池

非水系電解液及びそれを用いた非水系電解液二次電池 Download PDF

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Publication number: JP5720325B2
Authority: JP; Japan
Prior art keywords: carbonate; aqueous electrolyte; group; less; general formula
Prior art date: 2011-03-11
Legal status : Active

Application number

JP2011054242A

Other languages

English (en)

Japanese (ja)

Other versions

JP2012190699A (ja

JP2012190699A5 (enrdf_load_stackoverflow

Inventor

篤渡會

大貫　正道

正道大貫

古田土　稔

稔古田土

Current Assignee

Mitsubishi Chemical Corp

Original Assignee

Mitsubishi Chemical Corp

Priority date

2011-03-11

Filing date

2011-03-11

Publication date

2015-05-20

2011-03-11 Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp

2011-03-11 Priority to JP2011054242A priority Critical patent/JP5720325B2/ja

2012-10-04 Publication of JP2012190699A publication Critical patent/JP2012190699A/ja

2014-04-17 Publication of JP2012190699A5 publication Critical patent/JP2012190699A5/ja

2015-05-20 Application granted granted Critical

2015-05-20 Publication of JP5720325B2 publication Critical patent/JP5720325B2/ja

Status Active legal-status Critical Current

2031-03-11 Anticipated expiration legal-status Critical

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239000011255 nonaqueous electrolyte Substances 0.000 title claims description 184
150000001875 compounds Chemical class 0.000 claims description 125
-1 fluorosulfonyl Chemical group 0.000 claims description 111
150000003839 salts Chemical class 0.000 claims description 58
229910003002 lithium salt Inorganic materials 0.000 claims description 42
159000000002 lithium salts Chemical class 0.000 claims description 39
125000004432 carbon atom Chemical group C* 0.000 claims description 32
239000008151 electrolyte solution Substances 0.000 claims description 31
239000003125 aqueous solvent Substances 0.000 claims description 27
125000000129 anionic group Chemical group 0.000 claims description 24
239000003792 electrolyte Substances 0.000 claims description 21
229910052782 aluminium Inorganic materials 0.000 claims description 20
229910052723 transition metal Inorganic materials 0.000 claims description 17
125000005843 halogen group Chemical group 0.000 claims description 15
125000005842 heteroatom Chemical group 0.000 claims description 14
150000003624 transition metals Chemical class 0.000 claims description 14
125000000217 alkyl group Chemical group 0.000 claims description 13
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 12
229910001416 lithium ion Inorganic materials 0.000 claims description 12
125000003118 aryl group Chemical group 0.000 claims description 11
230000000737 periodic effect Effects 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 10
229910052739 hydrogen Inorganic materials 0.000 claims description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
229910052698 phosphorus Inorganic materials 0.000 claims description 6
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 claims description 5
229910052796 boron Inorganic materials 0.000 claims description 5
229910052795 boron group element Inorganic materials 0.000 claims description 5
229910052800 carbon group element Inorganic materials 0.000 claims description 5
125000004093 cyano group Chemical group *C#N 0.000 claims description 5
125000000524 functional group Chemical group 0.000 claims description 5
125000001261 isocyanato group Chemical group *N=C=O 0.000 claims description 5
239000011574 phosphorus Substances 0.000 claims description 5
229910052696 pnictogen Inorganic materials 0.000 claims description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims 7
235000002639 sodium chloride Nutrition 0.000 description 75
238000003860 storage Methods 0.000 description 67
239000007774 positive electrode material Substances 0.000 description 58
229910052751 metal Inorganic materials 0.000 description 56
239000002245 particle Substances 0.000 description 52
239000002184 metal Substances 0.000 description 48
239000007773 negative electrode material Substances 0.000 description 45
238000000034 method Methods 0.000 description 44
229910052744 lithium Inorganic materials 0.000 description 43
239000003575 carbonaceous material Substances 0.000 description 39
239000002131 composite material Substances 0.000 description 39
239000010410 layer Substances 0.000 description 38
230000000694 effects Effects 0.000 description 36
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 35
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 34
SWAIALBIBWIKKQ-UHFFFAOYSA-N lithium titanium Chemical compound [Li].[Ti] SWAIALBIBWIKKQ-UHFFFAOYSA-N 0.000 description 33
238000004519 manufacturing process Methods 0.000 description 30
239000000463 material Substances 0.000 description 30
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 29
239000002904 solvent Substances 0.000 description 28
150000004649 carbonic acid derivatives Chemical class 0.000 description 27
125000004122 cyclic group Chemical group 0.000 description 27
239000011230 binding agent Substances 0.000 description 26
JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 25
150000002430 hydrocarbons Chemical group 0.000 description 25
238000005259 measurement Methods 0.000 description 25
239000010936 titanium Substances 0.000 description 25
150000005678 chain carbonates Chemical class 0.000 description 24
230000007423 decrease Effects 0.000 description 23
SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 22
IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 22
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 21
229910052719 titanium Inorganic materials 0.000 description 21
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 20
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IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 18
239000011149 active material Substances 0.000 description 18
229910052731 fluorine Inorganic materials 0.000 description 18
239000011164 primary particle Substances 0.000 description 18
239000002562 thickening agent Substances 0.000 description 18
229920005989 resin Polymers 0.000 description 17
239000011347 resin Substances 0.000 description 17
150000005676 cyclic carbonates Chemical class 0.000 description 16
229910052718 tin Inorganic materials 0.000 description 16
239000010949 copper Substances 0.000 description 15
230000001771 impaired effect Effects 0.000 description 15
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 14
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 14
239000000654 additive Substances 0.000 description 14
229910052802 copper Inorganic materials 0.000 description 14
229910052710 silicon Inorganic materials 0.000 description 14
229910013063 LiBF 4 Inorganic materials 0.000 description 13
229910045601 alloy Inorganic materials 0.000 description 13
239000000956 alloy Substances 0.000 description 13
230000000052 comparative effect Effects 0.000 description 13
230000006866 deterioration Effects 0.000 description 13
239000007789 gas Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 13
229910052759 nickel Inorganic materials 0.000 description 13
239000011163 secondary particle Substances 0.000 description 13
239000002002 slurry Substances 0.000 description 13
229910013870 LiPF 6 Inorganic materials 0.000 description 12
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 12
150000001450 anions Chemical class 0.000 description 12
229910052799 carbon Inorganic materials 0.000 description 12
125000001153 fluoro group Chemical group F* 0.000 description 12
239000000126 substance Substances 0.000 description 12
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
229910013188 LiBOB Inorganic materials 0.000 description 11
239000004020 conductor Substances 0.000 description 11
238000011156 evaluation Methods 0.000 description 11
239000011737 fluorine Substances 0.000 description 11
230000000670 limiting effect Effects 0.000 description 11
239000011572 manganese Substances 0.000 description 11
238000002156 mixing Methods 0.000 description 11
239000003960 organic solvent Substances 0.000 description 11
229920000642 polymer Polymers 0.000 description 11
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 11
230000002829 reductive effect Effects 0.000 description 11
VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical group O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 10
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
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150000002739 metals Chemical class 0.000 description 10
239000000843 powder Substances 0.000 description 10
239000002243 precursor Substances 0.000 description 10
239000010703 silicon Substances 0.000 description 10
239000010409 thin film Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
229910052804 chromium Inorganic materials 0.000 description 9
239000011651 chromium Substances 0.000 description 9
229910052742 iron Inorganic materials 0.000 description 9
229910052748 manganese Inorganic materials 0.000 description 9
229910052757 nitrogen Inorganic materials 0.000 description 9
239000002994 raw material Substances 0.000 description 9
241000894007 species Species 0.000 description 9
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RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
239000002033 PVDF binder Substances 0.000 description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 8
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 8
230000000996 additive effect Effects 0.000 description 8
239000011203 carbon fibre reinforced carbon Substances 0.000 description 8
239000010408 film Substances 0.000 description 8
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 8
239000003112 inhibitor Substances 0.000 description 8
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 8
229920002981 polyvinylidene fluoride Polymers 0.000 description 8
IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 description 8
229910013553 LiNO Inorganic materials 0.000 description 7
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 7
238000001069 Raman spectroscopy Methods 0.000 description 7
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238000012360 testing method Methods 0.000 description 7
229910052720 vanadium Inorganic materials 0.000 description 7
229910052725 zinc Inorganic materials 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
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229910013075 LiBF Inorganic materials 0.000 description 6
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 6
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 6
150000001733 carboxylic acid esters Chemical class 0.000 description 6
238000000576 coating method Methods 0.000 description 6
238000001035 drying Methods 0.000 description 6
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FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 6
238000002847 impedance measurement Methods 0.000 description 6
VDVLPSWVDYJFRW-UHFFFAOYSA-N lithium;bis(fluorosulfonyl)azanide Chemical compound [Li+].FS(=O)(=O)[N-]S(F)(=O)=O VDVLPSWVDYJFRW-UHFFFAOYSA-N 0.000 description 6
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HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 5
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238000002441 X-ray diffraction Methods 0.000 description 5
230000009471 action Effects 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
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229920001343 polytetrafluoroethylene Polymers 0.000 description 5
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238000002360 preparation method Methods 0.000 description 5
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XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 description 4
OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 4
QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 4
238000004438 BET method Methods 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 4
229910013872 LiPF Inorganic materials 0.000 description 4
101150058243 Lipf gene Proteins 0.000 description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
229920001213 Polysorbate 20 Polymers 0.000 description 4
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
238000001237 Raman spectrum Methods 0.000 description 4
239000002174 Styrene-butadiene Substances 0.000 description 4
BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
150000001491 aromatic compounds Chemical class 0.000 description 4
239000012752 auxiliary agent Substances 0.000 description 4
WLLOZRDOFANZMZ-UHFFFAOYSA-N bis(2,2,2-trifluoroethyl) carbonate Chemical compound FC(F)(F)COC(=O)OCC(F)(F)F WLLOZRDOFANZMZ-UHFFFAOYSA-N 0.000 description 4
PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 4
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JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
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KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 4
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 4
125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 4
229910052733 gallium Inorganic materials 0.000 description 4
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ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 4
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HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
238000003466 welding Methods 0.000 description 4
239000008096 xylene Substances 0.000 description 4
239000011701 zinc Substances 0.000 description 4
229910052726 zirconium Inorganic materials 0.000 description 4
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YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 3
DFPJRUKWEPYFJT-UHFFFAOYSA-N 1,5-diisocyanatopentane Chemical compound O=C=NCCCCCN=C=O DFPJRUKWEPYFJT-UHFFFAOYSA-N 0.000 description 3
VUYOLIKWIVQHBC-UHFFFAOYSA-N 1-methylpiperidine-2,6-dione Chemical compound CN1C(=O)CCCC1=O VUYOLIKWIVQHBC-UHFFFAOYSA-N 0.000 description 3
ZXLYYQUMYFHCLQ-UHFFFAOYSA-N 2-methylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(C)C(=O)C2=C1 ZXLYYQUMYFHCLQ-UHFFFAOYSA-N 0.000 description 3
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AZGRTNZGVCFGJN-UHFFFAOYSA-L FS(=O)(=O)[O-].FS(=O)(=O)[O-].[Li+].[Li+] Chemical compound FS(=O)(=O)[O-].FS(=O)(=O)[O-].[Li+].[Li+] AZGRTNZGVCFGJN-UHFFFAOYSA-L 0.000 description 1
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229910012851 LiCoO 2 Inorganic materials 0.000 description 1
229910011281 LiCoPO 4 Inorganic materials 0.000 description 1
229910010701 LiFeP Inorganic materials 0.000 description 1
229910010707 LiFePO 4 Inorganic materials 0.000 description 1
229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
229910016118 LiMn1.5Ni0.5O4 Inorganic materials 0.000 description 1
229910014297 LiMn1.8Al0.2O4 Inorganic materials 0.000 description 1
229910014689 LiMnO Inorganic materials 0.000 description 1
229910013131 LiN Inorganic materials 0.000 description 1
229910013825 LiNi0.33Co0.33Mn0.33O2 Inorganic materials 0.000 description 1
229910012752 LiNi0.5Mn0.5O2 Inorganic materials 0.000 description 1
229910015701 LiNi0.85Co0.10Al0.05O2 Inorganic materials 0.000 description 1
229910013290 LiNiO 2 Inorganic materials 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229910000861 Mg alloy Inorganic materials 0.000 description 1
WITXFYCLPDFRNM-UHFFFAOYSA-N N-Benzylphthalimide Chemical compound O=C1C2=CC=CC=C2C(=O)N1CC1=CC=CC=C1 WITXFYCLPDFRNM-UHFFFAOYSA-N 0.000 description 1
240000007320 Pinus strobus Species 0.000 description 1
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150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
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239000002585 base Substances 0.000 description 1
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239000004305 biphenyl Substances 0.000 description 1
IEPBPSSCIZTJIF-UHFFFAOYSA-N bis(2,2,2-trichloroethyl) carbonate Chemical compound ClC(Cl)(Cl)COC(=O)OCC(Cl)(Cl)Cl IEPBPSSCIZTJIF-UHFFFAOYSA-N 0.000 description 1
RGTZUNKERJBBKQ-UHFFFAOYSA-N bis(2,2-dichloroethyl) carbonate Chemical compound ClC(Cl)COC(=O)OCC(Cl)Cl RGTZUNKERJBBKQ-UHFFFAOYSA-N 0.000 description 1
WQULVXNWEYLDJY-UHFFFAOYSA-N bis(2-chloroethyl) carbonate Chemical compound ClCCOC(=O)OCCCl WQULVXNWEYLDJY-UHFFFAOYSA-N 0.000 description 1
KVUDZUPUUSUAAJ-UHFFFAOYSA-N bis(chloromethyl) carbonate Chemical compound ClCOC(=O)OCCl KVUDZUPUUSUAAJ-UHFFFAOYSA-N 0.000 description 1
PACOTQGTEZMTOT-UHFFFAOYSA-N bis(ethenyl) carbonate Chemical compound C=COC(=O)OC=C PACOTQGTEZMTOT-UHFFFAOYSA-N 0.000 description 1
YRIJPMBUGWOQCC-UHFFFAOYSA-N bis(prop-2-ynyl) carbonate Chemical compound C#CCOC(=O)OCC#C YRIJPMBUGWOQCC-UHFFFAOYSA-N 0.000 description 1
LVYPNDZTRXRBNM-UHFFFAOYSA-N bis(trifluoromethyl) carbonate Chemical compound FC(F)(F)OC(=O)OC(F)(F)F LVYPNDZTRXRBNM-UHFFFAOYSA-N 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
238000009835 boiling Methods 0.000 description 1
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239000010974 bronze Substances 0.000 description 1
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RSYNHXZMASRGMC-UHFFFAOYSA-N butan-2-yl hydrogen carbonate Chemical compound CCC(C)OC(O)=O RSYNHXZMASRGMC-UHFFFAOYSA-N 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
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239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
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125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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239000006182 cathode active material Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
LZSJPZOQPVJLGJ-UHFFFAOYSA-N chloromethyl 2,2-dichloroethyl carbonate Chemical compound ClCOC(=O)OCC(Cl)Cl LZSJPZOQPVJLGJ-UHFFFAOYSA-N 0.000 description 1
ZKOFCURZLHKSBQ-UHFFFAOYSA-N chloromethyl ethenyl carbonate Chemical compound ClCOC(=O)OC=C ZKOFCURZLHKSBQ-UHFFFAOYSA-N 0.000 description 1
RTFGZMKXMSDULM-UHFFFAOYSA-N chloromethyl ethyl carbonate Chemical compound CCOC(=O)OCCl RTFGZMKXMSDULM-UHFFFAOYSA-N 0.000 description 1
UCSVAARRMAMTIF-UHFFFAOYSA-N chloromethyl phenyl carbonate Chemical compound ClCOC(=O)OC1=CC=CC=C1 UCSVAARRMAMTIF-UHFFFAOYSA-N 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
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CKFRRHLHAJZIIN-UHFFFAOYSA-N cobalt lithium Chemical compound [Li].[Co] CKFRRHLHAJZIIN-UHFFFAOYSA-N 0.000 description 1
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WEZJBAOYGIDDLB-UHFFFAOYSA-N cobalt(3+);borate Chemical class [Co+3].[O-]B([O-])[O-] WEZJBAOYGIDDLB-UHFFFAOYSA-N 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000002153 concerted effect Effects 0.000 description 1
239000006258 conductive agent Substances 0.000 description 1
238000007596 consolidation process Methods 0.000 description 1
150000004696 coordination complex Chemical group 0.000 description 1
KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
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PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
239000002180 crystalline carbon material Substances 0.000 description 1
125000005724 cycloalkenylene group Chemical group 0.000 description 1
VMUOSHREZKXCIV-UHFFFAOYSA-N cyclohexane-1,3,5-tricarbonitrile Chemical compound N#CC1CC(C#N)CC(C#N)C1 VMUOSHREZKXCIV-UHFFFAOYSA-N 0.000 description 1
HHNHBFLGXIUXCM-GFCCVEGCSA-N cyclohexylbenzene Chemical compound [CH]1CCCC[C@@H]1C1=CC=CC=C1 HHNHBFLGXIUXCM-GFCCVEGCSA-N 0.000 description 1
VDIHFNQRHGYISG-UHFFFAOYSA-N cyclopentylbenzene Chemical compound C1CCCC1C1=CC=CC=C1 VDIHFNQRHGYISG-UHFFFAOYSA-N 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
UREBDLICKHMUKA-CXSFZGCWSA-N dexamethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O UREBDLICKHMUKA-CXSFZGCWSA-N 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
JLTKRILASAPIGR-UHFFFAOYSA-N dichloromethyl ethyl carbonate Chemical compound CCOC(=O)OC(Cl)Cl JLTKRILASAPIGR-UHFFFAOYSA-N 0.000 description 1
VPCZSEHIVISGMC-UHFFFAOYSA-N dichloromethyl methyl carbonate Chemical compound COC(=O)OC(Cl)Cl VPCZSEHIVISGMC-UHFFFAOYSA-N 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
LRMLWYXJORUTBG-UHFFFAOYSA-N dimethylphosphorylmethane Chemical compound CP(C)(C)=O LRMLWYXJORUTBG-UHFFFAOYSA-N 0.000 description 1
VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
238000003411 electrode reaction Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
SVRGWPBWQJXEMG-UHFFFAOYSA-N ethenyl 2,2,2-trichloroethyl carbonate Chemical compound ClC(Cl)(Cl)COC(=O)OC=C SVRGWPBWQJXEMG-UHFFFAOYSA-N 0.000 description 1
DPGXGQNEWAAUKM-UHFFFAOYSA-N ethenyl 2,2,2-trifluoroethyl carbonate Chemical compound FC(F)(F)COC(=O)OC=C DPGXGQNEWAAUKM-UHFFFAOYSA-N 0.000 description 1
JCBADTLNWNTCNV-UHFFFAOYSA-N ethenyl 2-fluoroethyl carbonate Chemical compound FCCOC(=O)OC=C JCBADTLNWNTCNV-UHFFFAOYSA-N 0.000 description 1
BDNXATXQVYVLCI-UHFFFAOYSA-N ethenyl fluoromethyl carbonate Chemical compound FCOC(=O)OC=C BDNXATXQVYVLCI-UHFFFAOYSA-N 0.000 description 1
NCHRDVARPJUMRC-UHFFFAOYSA-N ethenyl methyl carbonate Chemical compound COC(=O)OC=C NCHRDVARPJUMRC-UHFFFAOYSA-N 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
HAPOVYFOVVWLRS-UHFFFAOYSA-N ethosuximide Chemical compound CCC1(C)CC(=O)NC1=O HAPOVYFOVVWLRS-UHFFFAOYSA-N 0.000 description 1
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NIQAXIMIQJNOKY-UHFFFAOYSA-N ethyl 2,2,2-trifluoroethyl carbonate Chemical compound CCOC(=O)OCC(F)(F)F NIQAXIMIQJNOKY-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
RGXYYFBTELSLFV-UHFFFAOYSA-N ethyl trichloromethyl carbonate Chemical compound CCOC(=O)OC(Cl)(Cl)Cl RGXYYFBTELSLFV-UHFFFAOYSA-N 0.000 description 1
239000004744 fabric Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
KUPHFFIERSZZDV-UHFFFAOYSA-N fluoromethyl phenyl carbonate Chemical compound FCOC(=O)OC1=CC=CC=C1 KUPHFFIERSZZDV-UHFFFAOYSA-N 0.000 description 1
229920002313 fluoropolymer Polymers 0.000 description 1
239000006232 furnace black Substances 0.000 description 1
GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical class CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 1
238000007429 general method Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
238000009499 grossing Methods 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
YDWPLCGCQQIMLM-UHFFFAOYSA-N heptane-1,3,5-tricarbonitrile Chemical compound CCC(C#N)CC(C#N)CCC#N YDWPLCGCQQIMLM-UHFFFAOYSA-N 0.000 description 1
150000002391 heterocyclic compounds Chemical class 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000005462 imide group Chemical group 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
239000010954 inorganic particle Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011229 interlayer Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical class [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
LAQPNDIUHRHNCV-UHFFFAOYSA-N isophthalonitrile Chemical compound N#CC1=CC=CC(C#N)=C1 LAQPNDIUHRHNCV-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
229910052808 lithium carbonate Inorganic materials 0.000 description 1
229910001947 lithium oxide Inorganic materials 0.000 description 1
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
230000015654 memory Effects 0.000 description 1
229910052752 metalloid Inorganic materials 0.000 description 1
CHCLGECDSSWNCP-UHFFFAOYSA-N methoxymethoxyethane Chemical compound CCOCOC CHCLGECDSSWNCP-UHFFFAOYSA-N 0.000 description 1
HYBCSYUDJOFGEO-UHFFFAOYSA-N methyl 2,2,2-trichloroethyl carbonate Chemical compound COC(=O)OCC(Cl)(Cl)Cl HYBCSYUDJOFGEO-UHFFFAOYSA-N 0.000 description 1
GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 description 1
CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
XTBFPVLHGVYOQH-UHFFFAOYSA-N methyl phenyl carbonate Chemical compound COC(=O)OC1=CC=CC=C1 XTBFPVLHGVYOQH-UHFFFAOYSA-N 0.000 description 1
YHLVIDQQTOMBGN-UHFFFAOYSA-N methyl prop-2-enyl carbonate Chemical compound COC(=O)OCC=C YHLVIDQQTOMBGN-UHFFFAOYSA-N 0.000 description 1
AUUBCQYRIBDKHO-UHFFFAOYSA-N methyl prop-2-ynyl carbonate Chemical compound COC(=O)OCC#C AUUBCQYRIBDKHO-UHFFFAOYSA-N 0.000 description 1
KYZWAJMFZBMJEN-UHFFFAOYSA-N methyl trichloromethyl carbonate Chemical compound COC(=O)OC(Cl)(Cl)Cl KYZWAJMFZBMJEN-UHFFFAOYSA-N 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
125000002560 nitrile group Chemical group 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000005486 organic electrolyte Substances 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
229930184652 p-Terphenyl Natural products 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
YYSONLHJONEUMT-UHFFFAOYSA-N pentan-3-yl hydrogen carbonate Chemical compound CCC(CC)OC(O)=O YYSONLHJONEUMT-UHFFFAOYSA-N 0.000 description 1
229950003332 perflubutane Drugs 0.000 description 1
229960004065 perflutren Drugs 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000011301 petroleum pitch Substances 0.000 description 1
DCJYJZZSUQZHIG-UHFFFAOYSA-N phenyl 2,2,2-trichloroethyl carbonate Chemical compound ClC(Cl)(Cl)COC(=O)OC1=CC=CC=C1 DCJYJZZSUQZHIG-UHFFFAOYSA-N 0.000 description 1
NGGUSKNBBASYGO-UHFFFAOYSA-N phenyl 2,2,2-trifluoroethyl carbonate Chemical compound FC(F)(F)COC(=O)OC1=CC=CC=C1 NGGUSKNBBASYGO-UHFFFAOYSA-N 0.000 description 1
125000005328 phosphinyl group Chemical group [PH2](=O)* 0.000 description 1
125000005499 phosphonyl group Chemical group 0.000 description 1
239000011295 pitch Substances 0.000 description 1
239000006253 pitch coke Substances 0.000 description 1
238000007747 plating Methods 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
229920006393 polyether sulfone Polymers 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
230000002265 prevention Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000003672 processing method Methods 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000010008 shearing Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
UXWVQHXKKOGTSY-UHFFFAOYSA-N tert-butyl phenyl carbonate Chemical compound CC(C)(C)OC(=O)OC1=CC=CC=C1 UXWVQHXKKOGTSY-UHFFFAOYSA-N 0.000 description 1
PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
238000009283 thermal hydrolysis Methods 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
150000003613 toluenes Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910000314 transition metal oxide Inorganic materials 0.000 description 1
229910000326 transition metal silicate Inorganic materials 0.000 description 1
229910000385 transition metal sulfate Inorganic materials 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
238000001132 ultrasonic dispersion Methods 0.000 description 1
239000011800 void material Substances 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1
238000004804 winding Methods 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1