JP5676586B2 - 耐衝撃性プロピレンポリマー組成物の製造方法 - Google Patents
耐衝撃性プロピレンポリマー組成物の製造方法 Download PDFInfo
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- JP5676586B2 JP5676586B2 JP2012515473A JP2012515473A JP5676586B2 JP 5676586 B2 JP5676586 B2 JP 5676586B2 JP 2012515473 A JP2012515473 A JP 2012515473A JP 2012515473 A JP2012515473 A JP 2012515473A JP 5676586 B2 JP5676586 B2 JP 5676586B2
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- 125000000217 alkyl group Chemical group 0.000 description 7
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- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
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- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
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- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
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- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 2
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- 238000004817 gas chromatography Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
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- 230000007704 transition Effects 0.000 description 2
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- BEDHCUAJOBASSZ-UHFFFAOYSA-N (2-cyclopentyl-1,3-dimethoxypropan-2-yl)cyclopentane Chemical compound C1CCCC1C(COC)(COC)C1CCCC1 BEDHCUAJOBASSZ-UHFFFAOYSA-N 0.000 description 1
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
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- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
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- BTJCEVZMRIJBSM-UHFFFAOYSA-N dimethoxy-methyl-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CO[Si](C)(OC)C(C)C(F)(F)F BTJCEVZMRIJBSM-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
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- 239000005457 ice water Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
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- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- 230000003287 optical effect Effects 0.000 description 1
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- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000000843 powder Substances 0.000 description 1
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- 230000000284 resting effect Effects 0.000 description 1
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- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
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| EP09163192 | 2009-06-19 | ||
| EP09163192.9 | 2009-06-19 | ||
| US26963509P | 2009-06-26 | 2009-06-26 | |
| US61/269,635 | 2009-06-26 | ||
| PCT/EP2010/058437 WO2010146074A1 (en) | 2009-06-19 | 2010-06-16 | Process for the preparation of impact resistant propylene polymer compositions |
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| JP2012530170A JP2012530170A (ja) | 2012-11-29 |
| JP2012530170A5 JP2012530170A5 (https=) | 2013-07-04 |
| JP5676586B2 true JP5676586B2 (ja) | 2015-02-25 |
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| EP (1) | EP2443159B1 (https=) |
| JP (1) | JP5676586B2 (https=) |
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| BR (1) | BRPI1014019B1 (https=) |
| ES (1) | ES2672731T3 (https=) |
| RU (1) | RU2536682C2 (https=) |
| WO (1) | WO2010146074A1 (https=) |
Families Citing this family (24)
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| BR112012006532B1 (pt) | 2009-09-22 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | Composições de polímero de propileno |
| EP2480605B1 (en) | 2009-09-22 | 2014-05-28 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| EP2501727B1 (en) | 2009-11-19 | 2014-05-14 | Basell Poliolefine Italia S.r.l. | Process for the preparation of impact resistant propylene polymer compositions |
| US9376513B2 (en) * | 2011-01-19 | 2016-06-28 | China Petroleum & Chemical Corporation | Solid catalyst component and catalyst for olefin polymerization |
| KR101912965B1 (ko) * | 2011-04-12 | 2019-01-14 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 |
| KR101884495B1 (ko) * | 2011-05-11 | 2018-08-01 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 연성 폴리올레핀 조성물 및 이의 고충전 화합물 |
| US9969820B2 (en) | 2011-07-01 | 2018-05-15 | Basell Poliolefine Italia S.R.L. | Polypropylene films and sheets |
| WO2013050384A2 (en) * | 2011-10-07 | 2013-04-11 | Total Research & Technology Feluy | High-fluidity heterophasic propylene copolymer with improved rigidity |
| EP2594593A1 (en) | 2011-11-17 | 2013-05-22 | Basell Poliolefine Italia S.r.l. | Process for the preparation of heterophasic propylene polymer compositions |
| EP2682505A1 (en) * | 2012-07-06 | 2014-01-08 | Basell Poliolefine Italia S.r.l. | Polypropylene fiber |
| EP2722348A1 (en) * | 2012-10-16 | 2014-04-23 | Basell Poliolefine Italia S.r.l. | Process for the preparation of propylene random copolymers |
| JP6177938B2 (ja) * | 2013-03-15 | 2017-08-09 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレン三元重合体の製造工程、およびそれにより得たプロピレン三元重合体 |
| EP2829557A1 (en) * | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Sterilisable article made of propylene copolymer |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| JP6147925B2 (ja) | 2013-10-24 | 2017-06-14 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 多孔質プロピレン重合体の製造工程 |
| JP6841814B2 (ja) * | 2015-08-04 | 2021-03-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用予備重合触媒成分 |
| CN108350241B (zh) * | 2015-11-17 | 2020-12-04 | 博里利斯股份公司 | 具有优异的低温冲击的高流动性tpo组合物 |
| ES2704727T3 (es) * | 2015-11-17 | 2019-03-19 | Borealis Ag | Composición de TPO de flujo elevado con excelente balance de propiedades mecánicas para interiores de automóviles |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| JP6860326B2 (ja) * | 2016-11-07 | 2021-04-14 | サンアロマー株式会社 | ポリプロピレン組成物およびこれを成形してなるマット調フィルム |
| CN112969727B (zh) * | 2018-12-04 | 2022-11-11 | 巴塞尔聚烯烃意大利有限公司 | 制备彩色聚丙烯的方法 |
| CN114058113B (zh) * | 2020-08-10 | 2023-09-26 | 中国石油天然气股份有限公司 | 高抗冲透明聚丙烯树脂及其制备方法 |
| US20230383107A1 (en) * | 2020-10-19 | 2023-11-30 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| BR112023025122A2 (pt) | 2021-06-25 | 2024-02-20 | Braskem Sa | Processo para polimerização preliminar de propileno, composição de polímero preliminar, aparelho para alimentar um sistema de catalisadores, e, reator de polimerização preliminar |
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| SE363977B (https=) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| FI952175A7 (fi) | 1995-05-05 | 1996-11-06 | Borealis As | Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi |
| CA2334743C (en) * | 1999-04-15 | 2010-01-12 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| JP4644352B2 (ja) | 2000-10-19 | 2011-03-02 | 日本ポリプロ株式会社 | プロピレン−エチレンブロック共重合体の製造方法 |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| DE60317903T2 (de) | 2002-07-02 | 2008-11-13 | Basell Poliolefine Italia S.R.L. | Katalysatorsystem für die polymerisation von olefinen |
| US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| RU2325404C2 (ru) | 2002-08-01 | 2008-05-27 | Базелль Полиолефин Италия С.П.А. | Высокостереорегулярный полипропилен с улучшенными свойствами |
| TW200427763A (en) * | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| CN1274724C (zh) * | 2003-09-18 | 2006-09-13 | 中国石油化工股份有限公司 | 一种生产烯烃聚合物的方法及其聚合物 |
| AU2005291326A1 (en) * | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| EP1799725B1 (en) | 2004-10-14 | 2010-03-17 | Basell Poliolefine Italia S.r.l. | Process for the gas-phase polymerization of olefins |
| JP5394231B2 (ja) | 2006-04-24 | 2014-01-22 | トタル リサーチ アンド テクノロジー フエリユイ | 高い溶融流動性を有するプロピレンの単独重合体またはランダム共重合体の製造でのチーグラー‐ナッタ触媒の使用 |
| EP1849807A1 (en) | 2006-04-24 | 2007-10-31 | Total Petrochemicals Research Feluy | Catalyst composition for the copolymerization of propylene |
| ATE465184T1 (de) | 2006-06-21 | 2010-05-15 | Total Petrochemicals Res Feluy | Katalysatorzusammensetzung zur (co)polymerisierung von propylen |
| EP2094744A1 (en) * | 2006-12-20 | 2009-09-02 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| KR20090101192A (ko) | 2006-12-22 | 2009-09-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 그로부터 수득된 촉매 |
| WO2009050045A2 (en) | 2007-10-15 | 2009-04-23 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high fluidity propylene polymers |
| BRPI0821410A2 (pt) * | 2007-12-20 | 2015-06-16 | Basell Poliolefine Srl | Componentes catalisadores para a polimerização de olefinas |
| JP5740159B2 (ja) | 2007-12-21 | 2015-06-24 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 二座内部供与体を有する自己制限性触媒組成物 |
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2010
- 2010-06-16 KR KR1020117030298A patent/KR101769275B1/ko active Active
- 2010-06-16 ES ES10725462.5T patent/ES2672731T3/es active Active
- 2010-06-16 CN CN201710041292.7A patent/CN107043491A/zh active Pending
- 2010-06-16 US US13/376,893 patent/US9068028B2/en active Active
- 2010-06-16 JP JP2012515473A patent/JP5676586B2/ja active Active
- 2010-06-16 RU RU2012101804/04A patent/RU2536682C2/ru active
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20120042763A (ko) | 2012-05-03 |
| WO2010146074A1 (en) | 2010-12-23 |
| EP2443159B1 (en) | 2018-04-25 |
| ES2672731T3 (es) | 2018-06-15 |
| KR101769275B1 (ko) | 2017-08-18 |
| RU2012101804A (ru) | 2013-07-27 |
| JP2012530170A (ja) | 2012-11-29 |
| CN102803310A (zh) | 2012-11-28 |
| US20120083576A1 (en) | 2012-04-05 |
| EP2443159A1 (en) | 2012-04-25 |
| BRPI1014019B1 (pt) | 2019-10-22 |
| BRPI1014019A2 (pt) | 2016-04-12 |
| US9068028B2 (en) | 2015-06-30 |
| CN107043491A (zh) | 2017-08-15 |
| RU2536682C2 (ru) | 2014-12-27 |
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