JP5662007B2 - Standing fabric and standing fabric product - Google Patents

Standing fabric and standing fabric product Download PDF

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JP5662007B2
JP5662007B2 JP2009076411A JP2009076411A JP5662007B2 JP 5662007 B2 JP5662007 B2 JP 5662007B2 JP 2009076411 A JP2009076411 A JP 2009076411A JP 2009076411 A JP2009076411 A JP 2009076411A JP 5662007 B2 JP5662007 B2 JP 5662007B2
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polyester
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raised
fabric
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謙吾 田中
謙吾 田中
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Teijin Ltd
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Description

本発明は、立毛部がソフトな風合いと適度な反発性とを兼ね備えた立毛布帛、および該立毛布帛を用いてなる立毛布帛製品に関する。   The present invention relates to a napped fabric in which the napped portion has a soft texture and appropriate resilience, and a napped fabric product using the napped fabric.

従来、立毛部と地組織部とで構成される立毛布帛は、外観、触感、風合いなどに優れるため、衣料用途を始め、家具用椅子張材、自動車、電車などの車輌内装材、スキンケア用具、塗装用ペイントローラーなど、多用途に用いられている。特に立毛糸に極細繊維を用いたものはソフト性な風合いに優れるという特徴を有している(例えば特許文献1参照)。
しかしながら、立毛糸に極細繊維を用いた立毛布帛では、反発性に劣るため使用や着用により立毛糸がへたってしまい、外観品位が損われるという問題があった。
Conventionally, a raised fabric composed of a raised portion and a ground tissue portion is excellent in appearance, touch, texture, etc., so it is used for clothing, chair interior materials for furniture, automobile interior materials such as automobiles, trains, skin care tools, Used for many purposes such as paint rollers for painting. In particular, those using ultrafine fibers for napped yarn have a feature of excellent soft texture (see, for example, Patent Document 1).
However, the raised fabric using ultrafine fibers for the raised yarn is inferior in resilience, so that the raised yarn is sagged by use or wearing, and the appearance quality is impaired.

特開2007−84989号公報JP 2007-84789 A 特開2007−291567号公報JP 2007-291567 A

本発明は上記の背景に鑑みなされたものであり、その目的は、立毛部がソフトな風合いと適度な反発性とを兼ね備えた立毛布帛、および該立毛布帛を用いてなる立毛布帛製品を提供することにある。   The present invention has been made in view of the above-mentioned background, and an object thereof is to provide a napped fabric having a soft texture and a moderate resilience in a napped portion, and a napped fabric product using the napped fabric. There is.

本発明者は上記の課題を達成するため鋭意検討した結果、立毛部と地組織部とで構成される立毛布帛において、前記立毛部に、特定の単繊維径を有する超極細繊維からなる立毛糸を配すと、立毛部がソフトな風合いと適度な反発性とを兼ね備えた立毛布帛が得られることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。   As a result of intensive studies to achieve the above-mentioned problems, the present inventor has found that a napped fabric comprising a napped portion and a ground tissue portion, and in the napped portion, a napped yarn comprising a superfine fiber having a specific single fiber diameter is provided. It has been found that a napped fabric having a soft texture and an appropriate resilience can be obtained, and the present invention has been completed by further intensive studies.

かくして、本発明によれば「立毛部と地組織部とで構成される立毛布帛であって、前記立毛部に、単繊維径が50〜1500nmのポリエステル立毛糸Aと単繊維径が5〜40μmのポリエステル立毛糸Bが含まれることを特徴とする立毛布帛を用いてなる、化粧用パフ、塗装用ペイントローラーからなる群より選択されるいずれかの用途に使用される立毛布帛製品。」が提供される。 Thus, according to the present invention, “a raised fabric composed of a raised portion and a ground tissue portion, wherein the raised portion has a polyester raised yarn A having a single fiber diameter of 50 to 1500 nm and a single fiber diameter of 5 to 40 μm. A napped fabric product for use in any application selected from the group consisting of a cosmetic puff and a paint roller for painting, using the napped fabric characterized in that the polyester napped yarn B is included. Is done.

その際、前記立毛部に含まれる、ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比が(ポリエステル立毛糸A:ポリエステル立毛糸B)15:85〜85:15の範囲内であることが好ましい。また、前記立毛糸の立毛糸高さが0.5〜20mmの範囲内のカットパイル糸であることが好ましい。また、前記ポリエステル立毛糸Aが、海成分とポリエステルからなりその径が50〜1500nmである島成分とで形成される海島型複合繊維の海成分をアルカリ水溶液で溶解除去してなる立毛糸であることが好ましい。また、前記ポリエステル立毛糸Aとポリエステル立毛糸Bとが、ポリエステル立毛糸A用糸条とポリエステル立毛糸B用糸条とで構成される複合糸から製造されたものであることが好ましい。また、前記地組織部がポリエステル繊維で構成されることが好ましい。

In that case, it is preferable that the weight ratio of the polyester raised yarn A and the polyester raised yarn B contained in the raised portion is within the range of (polyester raised yarn A: polyester raised yarn B) 15:85 to 85:15. . Moreover, it is preferable that the raised yarn height of the said raised yarn is a cut pile yarn in the range of 0.5-20 mm. The polyester napped yarn A is a napped yarn obtained by dissolving and removing a sea component of a sea-island type composite fiber formed from a sea component and an island component having a diameter of 50 to 1500 nm. It is preferable. Moreover, it is preferable that the said polyester raised yarn A and the polyester raised yarn B are manufactured from the composite yarn comprised by the yarn for polyester raised yarn A and the yarn for polyester raised yarn B. Moreover, it is preferable that the said ground organization part is comprised with a polyester fiber.

本発明によれば、立毛部がソフトな風合いと適度な反発性とを兼ね備えた立毛布帛、および該立毛布帛を用いてなる立毛布帛製品が得られる。   ADVANTAGE OF THE INVENTION According to this invention, the napped fabric which the napped part had both the soft texture and moderate resilience, and the napped fabric product using this napped fabric are obtained.

本発明において、立毛糸の立毛長を説明するための説明図である。In this invention, it is explanatory drawing for demonstrating the napping length of a napping yarn. KES風合い計測器による圧縮特性曲線を例示する図である。It is a figure which illustrates the compression characteristic curve by a KES texture measuring device.

以下、本発明の実施の形態について詳細に説明する。
まず、本発明の立毛布帛は、有機繊維で構成される地組織部と、該地組織部に織り込まれるか、または編み込まれてなる立毛糸から構成される立毛部とで構成される。ここで、立毛糸はループパイル糸でもよいが、適度な反発性を得る上でカットパイル糸であることが好ましい。また、立毛糸の立毛糸高さLとしては、立毛部のソフトな風合いと適度な反発性とを両立させる上で、0.5〜20mm(より好ましくは1.0〜10mm)の範囲内であることが好ましい。該立毛糸高さLが0.5mmよりも小さいと、立毛部のソフトな風合いが損われるおそれがある。逆に、該立毛糸高さLが20mmよりも大きいと、適度な反発性が損われるおそれがある。
Hereinafter, embodiments of the present invention will be described in detail.
First, the raised fabric of the present invention is composed of a ground tissue portion composed of organic fibers and a raised portion composed of raised yarns woven or knitted into the ground tissue portion. Here, the napped yarn may be a loop pile yarn, but is preferably a cut pile yarn in order to obtain an appropriate resilience. Further, the napped yarn height L of the napped yarn is within the range of 0.5 to 20 mm (more preferably 1.0 to 10 mm) in order to achieve both the soft texture of the napped portion and appropriate resilience. Preferably there is. When the napped yarn height L is smaller than 0.5 mm, the soft texture of the napped portion may be impaired. On the other hand, if the raised yarn height L is greater than 20 mm, the appropriate resilience may be impaired.

前記立毛部には、単繊維径が50〜1500nmのポリエステル立毛糸Aが含まれる。該ポリエステル立毛糸Aにおいて、その単繊維径(単繊維の直径)が50〜1500nm(好ましくは100〜800nm、特に好ましくは550〜800nm)の範囲内であることが肝要である。該単繊維径が10nmよりも小さい場合は繊維強度が低下するため実用上好ましくない。逆に、該単繊維径が1500nmよりも大きい場合は、立毛部が超極細繊維特有のソフトな風合いを呈さないおそれがあり好ましくない。ここで、単繊維の断面形状は特に限定されず、丸、三角、扁平、中空など公知の断面形状でよく、単繊維の断面形状が丸断面以外の異型断面である場合には、外接円の直径を単繊維径とする。なお、単繊維径は、透過型電子顕微鏡で繊維の横断面を撮影することにより測定が可能である。   The raised portion includes a polyester raised yarn A having a single fiber diameter of 50 to 1500 nm. In the polyester napped yarn A, it is important that the single fiber diameter (single fiber diameter) is in the range of 50 to 1500 nm (preferably 100 to 800 nm, particularly preferably 550 to 800 nm). When the single fiber diameter is smaller than 10 nm, the fiber strength is lowered, which is not preferable for practical use. On the contrary, when the single fiber diameter is larger than 1500 nm, the napped portion may not exhibit a soft texture peculiar to the ultrafine fiber, which is not preferable. Here, the cross-sectional shape of the single fiber is not particularly limited, and may be a known cross-sectional shape such as a circle, a triangle, a flat shape, and a hollow, and when the cross-sectional shape of the single fiber is an atypical cross-section other than the round cross-section, Let the diameter be the single fiber diameter. The single fiber diameter can be measured by photographing the cross section of the fiber with a transmission electron microscope.

前記ポリエステル立毛糸Aを形成するポリマーの種類としては、ポリエステル系ポリマーであれば特に限定されず、ポリエチレンテレフタレートやポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸、ステレオコンプレックスポリ乳酸、第3成分を共重合させたポリエステルなどが好ましく例示される。かかるポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルであってもよい。さらには、特開2004−270097号公報や特開2004−211268号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよい。該ポリマー中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が1種または2種以上含まれていてもよい。なお、ポリエステル以外のポリアミドなどのポリマーでは、布帛の耐光性や耐摩耗性が損われるため好ましくない。   The type of polymer forming the polyester napping yarn A is not particularly limited as long as it is a polyester polymer, and includes polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, stereocomplex polylactic acid, and the third component. Preferred examples include polymerized polyester. Such polyester may be material recycled or chemically recycled polyester. Furthermore, the polyester obtained using the catalyst containing the specific phosphorus compound and titanium compound which are described in Unexamined-Japanese-Patent No. 2004-270097 and 2004-21268 may be sufficient. In the polymer, a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention. 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained. Polymers such as polyamide other than polyester are not preferable because the light resistance and wear resistance of the fabric are impaired.

前記ポリエステル立毛糸Aは、後記のように、海成分とポリエステルからなりその径が50〜1500nmである島成分とで形成される海島型複合繊維の海成分をアルカリ水溶液で溶解除去してなる立毛糸であることが好ましい。   As will be described later, the polyester napping yarn A is formed by dissolving and removing a sea component of a sea-island type composite fiber formed by a sea component and an island component having a diameter of 50 to 1500 nm with an alkaline aqueous solution. Yarn is preferred.

本発明において、立毛部は前記ポリエステル立毛糸Aのみで構成されていてもよいが、前記ポリエステル立毛糸Aと他の立毛糸とで構成されていてもよい。例えば、かかる他の立毛糸としては、単繊維径が5〜40μm(好ましくは6〜25μm)のポリエステル立毛糸Bが好ましい。ポリエステル立毛糸Bの単繊維径が5μm以下であると、立毛部が前記ポリエステル立毛糸Aのみからなる場合と同様、立毛部の反発性が損われるおそれがある。逆に該単繊維径が40μmよりも大きいと、超極細繊維が有するピーチタッチ状の独特の風合いが損われるおそれがある。ここで、単繊維の断面形状が丸断面以外の異型断面である場合には、外接円の直径を単繊維径とする。なお、単繊維径は、前記と同様、透過型電子顕微鏡で繊維の横断面を撮影することにより測定が可能である。また、該ポリエステル立毛糸Bは、通常の仮撚捲縮加工が施されていてもさしつかえない。   In the present invention, the napped portion may be composed only of the polyester napped yarn A, but may be composed of the polyester napped yarn A and another napped yarn. For example, as the other napped yarn, a polyester napped yarn B having a single fiber diameter of 5 to 40 μm (preferably 6 to 25 μm) is preferable. If the single fiber diameter of the polyester napped yarn B is 5 μm or less, the resilience of the napped portion may be impaired as in the case where the napped portion is made of only the polyester napped yarn A. On the other hand, if the single fiber diameter is larger than 40 μm, the peach touch-like unique texture of the ultrafine fibers may be impaired. Here, when the cross-sectional shape of the single fiber is an atypical cross section other than the round cross section, the diameter of the circumscribed circle is defined as the single fiber diameter. The single fiber diameter can be measured by photographing the cross section of the fiber with a transmission electron microscope, as described above. Further, the polyester napped yarn B may be subjected to normal false twist crimping.

前記ポリエステル立毛糸Bを形成するポリマーの種類としては、ポリエステル系ポリマーであれば特に限定されず、ポリエチレンテレフタレートやポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸、ステレオコンプレックスポリ乳酸、第3成分を共重合させたポリエステルなどが好ましく例示される。かかるポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルであってもよい。さらには、特開2004−270097号公報や特開2004−211268号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよい。該ポリマー中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が1種または2種以上含まれていてもよい。なお、ポリエステル以外のポリアミドなどのポリマーでは、布帛の耐光性や耐摩耗性が損われるため好ましくない。   The type of polymer that forms the polyester napped yarn B is not particularly limited as long as it is a polyester polymer, and includes polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, stereocomplex polylactic acid, and the third component. Preferred examples include polymerized polyester. Such polyester may be material recycled or chemically recycled polyester. Furthermore, the polyester obtained using the catalyst containing the specific phosphorus compound and titanium compound which are described in Unexamined-Japanese-Patent No. 2004-270097 and 2004-21268 may be sufficient. In the polymer, a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention. 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained. Polymers such as polyamide other than polyester are not preferable because the light resistance and wear resistance of the fabric are impaired.

本発明の立毛布帛において、前記ポリエステル立毛糸Aとポリエステル立毛糸Bとが立毛部に含まれる場合、前記ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比が(ポリエステル立毛糸A:ポリエステル立毛糸B)15:85〜85:15の範囲内であることが好ましい。前記ポリエステル立毛糸Aの重量比が該範囲よりも小さいと立毛部のソフトな風合いが損なわれるおそれがある。また、ポリエステル立毛糸Bの重量比が該範囲よりも小さいと立毛部の適度な反発性が損なわれるおそれがある。   In the raised fabric of the present invention, when the polyester raised yarn A and the polyester raised yarn B are included in the raised portion, the weight ratio of the polyester raised yarn A and the polyester raised yarn B is (polyester raised yarn A: polyester raised yarn). B) It is preferable to be within the range of 15:85 to 85:15. If the weight ratio of the polyester napped yarn A is smaller than the above range, the soft texture of the napped portion may be impaired. Further, if the weight ratio of the polyester napped yarn B is smaller than the above range, the appropriate resilience of the napped portion may be impaired.

なお、前記立毛部は、前記ポリエステル立毛糸Aのみ、あるいは前記ポリエステル立毛糸Aとポリエステル立毛糸Bだけで構成されることが好ましいが、立毛部の全重量に対して30重量%以下であれば、前記ポリエステル立毛糸Aとポリエステル立毛糸B以外の他の立毛糸が含まれていてもさしつかえない。   The raised portion is preferably composed of only the polyester raised yarn A or only the polyester raised yarn A and the polyester raised yarn B, and if it is 30% by weight or less based on the total weight of the raised portion. The napped yarn other than the polyester napped yarn A and the polyester napped yarn B may be included.

本発明の立毛布帛は例えば以下の製造方法により製造することができる。まず、海成分とポリエステルからなりその径が50〜1500nmである島成分とで形成される海島型複合繊維(ポリエステル立毛糸A用繊維)を用意する。かかる海島型複合繊維としては、特開2007−2364号公報に開示された海島型複合繊維マルチフィラメント(島数100〜1500)が好ましく用いられる。   The raised fabric of the present invention can be produced, for example, by the following production method. First, a sea-island type composite fiber (a fiber for polyester napped yarn A) formed of a sea component and an island component composed of polyester and having a diameter of 50 to 1500 nm is prepared. As such a sea-island type composite fiber, a sea-island type composite fiber multifilament (100 to 1500 islands) disclosed in Japanese Patent Application Laid-Open No. 2007-2364 is preferably used.

すなわち、海成分ポリマーとしては、繊維形成性の良好なポリエステル、ポリアミド、ポリスチレン、ポリエチレンなどが好ましい。例えば、アルカリ水溶液易溶解性ポリマーとしては、ポリ乳酸、超高分子量ポリアルキレンオキサイド縮合系ポリマー、ポリエチレングルコール系化合物共重合ポリエステル、ポリエチレングリコール系化合物と5−ナトリウムスルホン酸イソフタル酸の共重合ポリエステルが好適である。なかでも、5−ナトリウムスルホイソフタル酸6〜12モル%と分子量4000〜12000のポリエチレングルコールを3〜10重量%共重合させた固有粘度が0.4〜0.6のポリエチレンテレフタレート系共重合ポリエステルが好ましい。   That is, as the sea component polymer, polyester, polyamide, polystyrene, polyethylene and the like having good fiber forming properties are preferable. For example, as an easily soluble polymer in an alkaline aqueous solution, polylactic acid, an ultra-high molecular weight polyalkylene oxide condensation polymer, a polyethylene glycol compound copolymer polyester, a copolymer polyester of polyethylene glycol compound and 5-sodium sulfonic acid isophthalic acid may be used. Is preferred. Among them, a polyethylene terephthalate copolymer polyester having an intrinsic viscosity of 0.4 to 0.6 obtained by copolymerizing 6 to 12 mol% of 5-sodium sulfoisophthalic acid and 3 to 10% by weight of polyethylene glycol having a molecular weight of 4000 to 12000. Is preferred.

一方、島成分ポリマーは、繊維形成性のポリエチレンテレフタレートやポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸、第3成分を共重合させたポリエステルなどのポリエステルが好ましい。該ポリマー中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が1種または2種以上含まれていてもよい。   On the other hand, the island component polymer is preferably a polyester such as a fiber-forming polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, or a polyester obtained by copolymerizing a third component. In the polymer, a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention. 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained.

上記の海成分ポリマーと島成分ポリマーからなる海島型複合繊維は、溶融紡糸時における海成分の溶融粘度が島成分ポリマーの溶融粘度よりも大きいことが好ましい。また、島成分の径は、10〜1000nmの範囲とする必要がある。その際、該径が真円でない場合は外接円の直径を求める。前記の海島型複合繊維において、その海島複合重量比率(海:島)は、40:60〜5:95の範囲が好ましく、特に30:70〜10:90の範囲が好ましい。   The sea-island composite fiber composed of the sea component polymer and the island component polymer preferably has a sea component melt viscosity higher than that of the island component polymer during melt spinning. Further, the diameter of the island component needs to be in the range of 10 to 1000 nm. At this time, if the diameter is not a perfect circle, the diameter of the circumscribed circle is obtained. In the sea-island composite fiber, the sea-island composite weight ratio (sea: island) is preferably in the range of 40:60 to 5:95, and particularly preferably in the range of 30:70 to 10:90.

かかる海島型複合繊維は、例えば以下の方法により容易に製造することができる。すなわち、前記の海成分ポリマーと島成分ポリマーとを用い溶融紡糸する。溶融紡糸に用いられる紡糸口金としては、島成分を形成するための中空ピン群や微細孔群を有するものなど任意のものを用いることができる。吐出された海島型断面複合繊維マルチフィラメント糸は、冷却風によって固化され、好ましくは400〜6000m/分で溶融紡糸された後に巻き取られる。得られた未延伸糸は、別途延伸工程をとおして所望の強度・伸度・熱収縮特性を有する複合繊維とするか、あるいは、一旦巻き取ることなく一定速度でローラーに引き取り、引き続いて延伸工程をとおした後に巻き取る方法のいずれでも構わない。そして、必要に応じて撚糸を施す。かかる海島型複合繊維マルチフィラメント糸において、単糸繊維繊度、フィラメント数、総繊度としてはそれぞれ単糸繊維繊度0.5〜10.0dtex、フィラメント数5〜75本、総繊度30〜170dtexの範囲内であることが好ましい。   Such sea-island type composite fibers can be easily produced, for example, by the following method. That is, melt spinning is performed using the sea component polymer and the island component polymer. As the spinneret used for melt spinning, any one such as a hollow pin group for forming an island component or a group having a fine hole group can be used. The discharged sea-island type cross-section composite fiber multifilament yarn is solidified by cooling air, and is preferably wound after being melt spun at 400 to 6000 m / min. The obtained undrawn yarn is made into a composite fiber having desired strength, elongation, and heat shrinkage properties through a separate drawing process, or is taken up by a roller at a constant speed without being wound once, and subsequently drawn. Any of the methods of winding after passing through may be used. Then, twisted yarn is applied as necessary. In such a sea-island type composite fiber multifilament yarn, the single yarn fiber fineness, the number of filaments, and the total fineness are within the range of the single yarn fiber fineness of 0.5 to 10.0 dtex, the number of filaments of 5 to 75, and the total fineness of 30 to 170 dtex, respectively. It is preferable that

一方、必要に応じて、単繊維径が5〜40μmのポリエステル立毛糸B用繊維を用意する。該ポリエステル立毛糸B用繊維において、単繊維繊度が0.1dtexより大(好ましくは0.2〜6dtex)であることが好ましい。また、フィラメント数は特に限定されないが、1〜300本(好ましくは40〜200本)の範囲内であることが好ましい。   On the other hand, if necessary, a fiber for polyester napped yarn B having a single fiber diameter of 5 to 40 μm is prepared. In the fiber for polyester napping yarn B, the single fiber fineness is preferably larger than 0.1 dtex (preferably 0.2 to 6 dtex). The number of filaments is not particularly limited, but is preferably in the range of 1 to 300 (preferably 40 to 200).

次いで、立毛部用繊維として、前記ポリエステル立毛糸A用海島型複合繊維のみ、あるいは前記ポリエステル立毛糸A用海島型複合繊維とポリエステル立毛糸B用繊維とを用い、地組織部用繊維として例えばポリエステル繊維を用いて常法によりループパイル織編物を製編織する。   Next, only the sea-island type composite fiber for the polyester napping yarn A or the sea-island type composite fiber for the polyester napping yarn A and the fiber for the polyester napping yarn B is used as the fiber for the napping portion. A loop pile knitted fabric is knitted and woven using fibers in a conventional manner.

織編組織としては特に限定されないが、例えば経パイル織物、緯パイル織物、シンカーパイル編物、ラッセルパイル編物、トリコットパイル編物などが好ましい。そして、必要に応じてループパイルをカットする。この際、立毛糸高さが0.5〜20mmの範囲内になるようにカットすることが好ましい。   The knitted and knitted structure is not particularly limited, and for example, warp pile fabric, weft pile fabric, sinker pile knitted fabric, Russell pile knitted fabric, tricot pile knitted fabric and the like are preferable. Then, the loop pile is cut as necessary. At this time, it is preferable to cut the napped yarn so that the height of the napped yarn is within a range of 0.5 to 20 mm.

その際、前記ポリエステル立毛糸A用海島型複合繊維とポリエステル立毛糸B用繊維とを用いる場合、前記ポリエステル立毛糸A用海島型複合繊維とポリエステル立毛糸B用繊維が複合糸として製編織されていると、最終的に得られる立毛布帛の立毛部において、ポリエステル立毛糸Aとポリエステル立毛糸Bとがランダムに混在し、その結果、立毛部がソフトな風合いと適度な反発性とを兼ね備えることになり好ましい。かかる複合糸の複合方法としては、インターレース空気加工、カバリング加工、引き揃え仮撚捲縮加工などが例示される。   At this time, when the sea-island type composite fiber for polyester napping yarn A and the fiber for polyester napping yarn B are used, the sea-island type composite fiber for polyester napping yarn A and the fiber for polyester napping yarn B are knitted and woven as a composite yarn. In the napped portion of the finally obtained napped fabric, the polyester napped yarn A and the polyester napped yarn B are randomly mixed, and as a result, the napped portion has both a soft texture and appropriate resilience. It is preferable. Examples of the composite method of the composite yarn include interlaced air processing, covering processing, and even false false twist crimp processing.

次いで、該布帛にアルカリ水溶液処理を施し、前記海島型複合繊維の海成分をアルカリ水溶液で溶解除去することにより、海島型複合繊維を単繊維径が50〜1500nmのポリエステル立毛糸Aとする。その際、アルカリ水溶液処理の条件としては、濃度3〜5%のNaOH水溶液を使用し55〜80℃の温度で処理するとよい。かかるアルカリ水溶液処理は前記カットの前の工程で行ってもよいが、前記カットの後の工程で行うことが好ましい。   Next, the fabric is subjected to an alkaline aqueous solution treatment, and the sea component of the sea-island type composite fiber is dissolved and removed with an alkaline aqueous solution, whereby the sea-island type composite fiber is made into polyester raised yarn A having a single fiber diameter of 50 to 1500 nm. At that time, as a condition for the alkaline aqueous solution treatment, a NaOH aqueous solution having a concentration of 3 to 5% is used, and the treatment is preferably performed at a temperature of 55 to 80 ° C. Such alkaline aqueous solution treatment may be performed in a step before the cut, but is preferably performed in a step after the cut.

次いで、必要に応じて、常法の染色加工、バフ加工、起毛加工、裏面バックコーテイング、撥水加工、さらには、紫外線遮蔽あるいは制電剤、抗菌剤、消臭剤、防虫剤、蓄光剤、再帰反射剤、マイナスイオン発生剤等の機能を付与する各種加工を付加適用してもよい。   Then, if necessary, conventional dyeing, buffing, raising, back-back coating, water-repellent processing, and further UV shielding or antistatic agent, antibacterial agent, deodorant, insect repellent, phosphorescent agent, Various processes that provide functions such as a retroreflective agent and a negative ion generator may be additionally applied.

かくして得られた立毛布帛の立毛部には、単繊維径が50〜1500nmのポリエステル立毛糸Aが含まれるので立毛部がソフトな風合いと適度な反発性とを兼ね備える。特に、立毛部に、単繊維径が50〜1500nmのポリエステル立毛糸Aと単繊維径が5〜40μmのポリエステル立毛糸Bとが含まれる場合は、立毛部がソフトな風合いとさらに適度な反発性とを兼ね備える。その際、反発性の指標として、KES風合い計測器による布帛の圧縮回復率(立毛布帛の厚さ方向の圧縮回復率)が30%以上(より好ましくは40〜80%)であることが好ましい。ただし、該圧縮回復率は、KES風合い計測器による圧縮特性(圧縮方向:立毛布帛の厚さ方向、圧縮面積:2cm、圧縮速度:50sec/mm、指定圧力:49cN/cm(50gf/cm))における曲線(図2に例示)から求める三角形ABCにおけるaの面積とbの面積から下記の式で圧縮回復率を計算する。
圧縮回復率=bの面積/(aの面積+bの面積)×100
The napped portion of the napped fabric thus obtained contains polyester napped yarn A having a single fiber diameter of 50 to 1500 nm, so that the napped portion has both a soft texture and appropriate resilience. In particular, when the napped portion includes a polyester napped yarn A having a single fiber diameter of 50 to 1500 nm and a polyester napped yarn B having a single fiber diameter of 5 to 40 μm, the napped portion has a soft texture and further moderate resilience. And combine. At that time, as an index of resilience, it is preferable that the compression recovery rate of the fabric (compression recovery rate in the thickness direction of the napped fabric) by the KES texture measuring instrument is 30% or more (more preferably 40 to 80%). However, the compression recovery rate was determined by the compression characteristics (compression direction: thickness direction of the raised fabric, compression area: 2 cm 2 , compression speed: 50 sec / mm, specified pressure: 49 cN / cm 2 (50 gf / cm 2 )) The compression recovery rate is calculated by the following formula from the area of a and the area of b in the triangle ABC obtained from the curve (illustrated in FIG. 2).
Compression recovery rate = b area / (a area + b area) × 100

次に、本発明の立毛布帛製品は、前記の立毛布帛を用いてなる、スキンケア用具、ヘルスケア用具、化粧用パフ、塗装用ペイントローラー(塗装に用いるローラー式の刷毛であり、例えば、外径が5〜15mmのポリエチレン製円筒の外面に立毛布帛を貼り付けたものが好ましい。)、カーシート、吸音シート、液晶素子製造用ラビング布帛、研磨布、ワイピング材からなる群より選択されるいずれかの用途に使用される立毛布帛製品である。かかる立毛布帛製品は前記の立毛布帛を用いているので、立毛部がソフトな風合いと適度な反発性とを兼ね備えており、立毛部がへたりにくいという効果を奏する。   Next, the raised fabric product of the present invention is a skin care device, a health care device, a cosmetic puff, a painting paint roller (a roller-type brush used for painting, for example, an outer diameter). In which a napped fabric is pasted on the outer surface of a polyethylene cylinder having a thickness of 5 to 15 mm.), Any one selected from the group consisting of a car sheet, a sound absorbing sheet, a rubbing fabric for manufacturing a liquid crystal element, a polishing cloth, and a wiping material. It is a napped fabric product used for Since this napped fabric product uses the above napped fabric, the napped portion has both a soft texture and an appropriate resilience, and the napped portion is less likely to sag.

次に本発明の実施例及び比較例を詳述するが、本発明はこれらによって限定されるものではない。なお、実施例中の各測定項目は下記の方法で測定した。
<風合い>
立毛布帛表面の風合いを試験者3人が官能評価し、3級:超極細繊維(ナノファイバー)特有の柔らかくヌメリ感のある風合いを呈する、2級:普通、1級:超極細繊維特有の風合いを呈さない、の3段階に評価した。
<単繊維径>
布帛を電子顕微鏡で写真撮影した後、n数5で単繊維径を測定しその平均値を求めた。
<圧縮回復率>
KES風合い計測器による圧縮特性(圧縮方向:立毛布帛の厚さ方向、圧縮面積:2cm、圧縮速度:50sec/mm、指定圧力:49cN/cm(50gf/cm))における曲線(図2に例示)から求める三角形ABCにおけるaの面積とbの面積から下記の式で圧縮回復率を計算した。
圧縮回復率=bの面積/(aの面積+bの面積)×100
<ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比>
1cm×1cmの正方形の試料を切り取り、該試料に含まれるポリエステル立毛糸Aとポリエステル立毛糸Bの重量を実測し、これの重量比を求めた。
<立毛糸高さ>
キーエンス(株)製マイクロスコープ(型式:VH−6300)を用いて、立毛布帛の断面を撮影(倍率50倍)し、全体厚みおよび地組織部の厚みを測定して、下記式により立毛糸高さを算出した。なお、全体厚みは地組織部の最底部から立毛部の最高部までの距離を測定した。n数は5でその平均値を求めた。
立毛糸高さL(mm)=全体厚み(mm)−地組織部厚み(mm)
Next, although the Example and comparative example of this invention are explained in full detail, this invention is not limited by these. In addition, each measurement item in an Example was measured with the following method.
<Texture>
Three testers have a sensory evaluation of the texture of the surface of the napped fabric, and grade 3: presents a soft and slimy texture peculiar to ultrafine fibers (nanofibers), grade 2: normal, grade 1: texture peculiar to superfine fibers It was evaluated in three grades.
<Single fiber diameter>
After the fabric was photographed with an electron microscope, the single fiber diameter was measured with an n number of 5, and the average value was obtained.
<Compression recovery rate>
Curves in compression characteristics (compression direction: thickness direction of napped fabric, compression area: 2 cm 2 , compression speed: 50 sec / mm, specified pressure: 49 cN / cm 2 (50 gf / cm 2 )) by the KES texture measuring instrument (FIG. 2) The compression recovery rate was calculated by the following formula from the area of a and the area of b in the triangle ABC obtained from FIG.
Compression recovery rate = b area / (a area + b area) × 100
<Weight ratio of polyester raised yarn A and polyester raised yarn B>
A 1 cm × 1 cm square sample was cut out, and the weights of the polyester raised yarn A and the polyester raised yarn B contained in the sample were measured, and the weight ratio thereof was determined.
<Raised yarn height>
Using a microscope (model: VH-6300) manufactured by Keyence Corporation, photograph a cross-section of the napped fabric (magnification 50 times), measure the overall thickness and the thickness of the ground tissue part, and determine the napped yarn height according to the following formula: Was calculated. In addition, the total thickness measured the distance from the lowest part of a ground tissue part to the highest part of a napped part. The number of n was 5, and the average value was obtained.
Napped yarn height L (mm) = total thickness (mm) −ground tissue thickness (mm)

[実施例1]
島成分としてポリエチレンテレフタレート、海成分として5−ナトリウムスルホイソフタル酸9モル%と数平均分子量4000のポリエチレングリコール3重量%を共重合したポリエチレンテレフタレートを用い、海:島=30:70、島数=836の海島型複合未延伸繊維を、紡糸温度280℃、紡糸速度1500m/分で溶融紡糸して一旦巻き取った。得られた未延伸糸を、延伸温度80℃、延伸倍率2.5倍でローラー延伸し、次いで150℃で熱セットして巻き取り、ポリエステル立毛糸A用糸条とした。得られた海島型複合延伸糸は56dtex/10filであり、透過型電子顕微鏡TEMによる繊維横断面を観察したところ、島の形状は丸形状でかつ島の径は700nmであった。その後、ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36fil(単繊維径14.8μm)をグランド糸に全量配し、前記ポリエステル立毛糸A用糸条をパイル糸に全量配し、24Gの丸編み機にて、通常の製編方法によりシンカーパイル編物生機を得た。次いで、ループ状に形成されたパイル糸の先端をカットした後、該編物を50℃にて湿熱処理した後、海島型複合延伸糸の海成分を除去するために、2.5%NaOH水溶液で、55℃にて24.7%減量(アルカリ減量)した。その後、常法の湿熱加工、乾熱加工を行った。
得られた編物において、ポリエステル立毛糸Aの平均繊維径は700nmであった。また、ポリエステル立毛糸Aの立毛糸高さは0.7mm、圧縮回復率は33.1%であり、風合いはソフト(3級)であった。
次いで、該立毛布帛を用いて、化粧用パフおよび塗装用ペイントローラーを作製した。化粧用パフおよび塗装用ペイントローラーともに、立毛部がソフトな風合いと適度な反発性とを兼ね備えており、長時間使用してもへたることがなかった。
[Example 1]
Using polyethylene terephthalate as the island component, polyethylene terephthalate copolymerized with 9% by mole of 5-sodium sulfoisophthalic acid and 3% by weight of polyethylene glycol having a number average molecular weight of 4000 as the sea component, sea: island = 30: 70, number of islands = 836 The sea-island type composite undrawn fiber was melt-spun at a spinning temperature of 280 ° C. and a spinning speed of 1500 m / min, and was wound up once. The obtained undrawn yarn was subjected to roller drawing at a drawing temperature of 80 ° C. and a draw ratio of 2.5 times, and then heat-set at 150 ° C. and wound up to obtain a yarn for polyester raised yarn A. The obtained sea-island type composite drawn yarn was 56 dtex / 10 fil and the cross section of the fiber was observed with a transmission electron microscope TEM. As a result, the shape of the island was round and the diameter of the island was 700 nm. Then, all the multifilament yarns 84dtex / 36fil (single fiber diameter 14.8μm) made of polyethylene terephthalate are arranged in the ground yarn, and all the polyester raised yarn A yarn is arranged in the pile yarn. Then, a sinker pile knitting raw machine was obtained by a normal knitting method. Next, after cutting the tip of the pile yarn formed in a loop shape, the knitted fabric was subjected to wet heat treatment at 50 ° C., and then with a 2.5% NaOH aqueous solution in order to remove the sea component of the sea-island type composite drawn yarn. , 24.7% weight loss (alkali weight loss) at 55 ° C. Thereafter, conventional wet heat processing and dry heat processing were performed.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn A was 700 nm. In addition, the height of the napped yarn of the polyester napped yarn A was 0.7 mm, the compression recovery rate was 33.1%, and the texture was soft (third grade).
Next, a cosmetic puff and a paint roller for painting were produced using the raised fabric. Both the makeup puff and the paint roller for painting had a soft texture and moderate resilience, and did not sag even when used for a long time.

[実施例2]
実施例1と同様にして海島型複合延伸糸56dtex/10fil(ポリエステル立毛糸A用糸条)を得た。また、ポリエステル立毛糸B用糸条として、ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36filを用意し、前記ポリエステル立毛糸A用糸条2本とポリエステル立毛糸B用糸条1本を引き揃えてインターレース加工により複合糸を得た。
その後、ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36fil(単繊維径14.8μm)をグランド糸に全量配し、前記複合糸条をパイル糸に全量配し、24Gの丸編み機にて、通常の製編方法によりシンカーパイル編物生機を得た。次いで、ループ状に形成されたパイル糸の先端をカットした後、該編物を50℃にて湿熱処理した後、海島型複合延伸糸の海成分を除去するために、2.5%NaOH水溶液で、55℃にて15.7%減量(アルカリ減量)した。その後、常法の湿熱加工、乾熱加工を行った。
得られた編物において、ポリエステル立毛糸Aの平均繊維径は700nmであった。また、ポリエステル立毛糸Bの平均繊維径は14.8μmであった。また、ポリエステル立毛糸Aおよびポリエステル立毛糸Bの立毛糸高さは2.2mm、圧縮回復率は35.2%であり、風合いはソフト(3級)であった。また、ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比は、(ポリエステル立毛糸A:ポリエステル立毛糸B)48:52であった。
次いで、該立毛布帛を用いて、化粧用パフおよび塗装用ペイントローラーを作製した。化粧用パフおよび塗装用ペイントローラーともに、立毛部がソフトな風合いと適度な反発性とを兼ね備えており、長時間使用してもへたることがなかった。
[Example 2]
In the same manner as in Example 1, a sea-island composite drawn yarn 56 dtex / 10 fil (polyester napped yarn A yarn) was obtained. Also, as filaments for polyester raised yarn B, multifilament yarns 84dtex / 36fil made of polyethylene terephthalate are prepared, and the two polyester raised yarn A yarns and one polyester raised yarn B yarn are aligned and interlaced. A composite yarn was obtained by processing.
After that, all the multifilament yarns 84dtex / 36fil (single fiber diameter 14.8μm) made of polyethylene terephthalate are arranged on the ground yarn, all the composite yarns are arranged on the pile yarn, and the 24G circular knitting machine is used for normal production. A sinker pile knitting raw machine was obtained by the knitting method. Next, after cutting the tip of the pile yarn formed in a loop shape, the knitted fabric was subjected to wet heat treatment at 50 ° C., and then with a 2.5% NaOH aqueous solution in order to remove the sea component of the sea-island type composite drawn yarn. 15.7% weight loss (alkali weight loss) at 55 ° C. Thereafter, conventional wet heat processing and dry heat processing were performed.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn A was 700 nm. The average fiber diameter of the polyester napped yarn B was 14.8 μm. The height of the napped yarns of the polyester napped yarn A and the polyester napped yarn B was 2.2 mm, the compression recovery rate was 35.2%, and the texture was soft (third grade). The weight ratio of the polyester napped yarn A to the polyester napped yarn B was (polyester napped yarn A: polyester napped yarn B) 48:52.
Next, a cosmetic puff and a paint roller for painting were produced using the raised fabric. Both the makeup puff and the paint roller for painting had a soft texture and moderate resilience, and did not sag even when used for a long time.

[実施例3]
実施例1において、ポリエステル立毛糸A用糸条1本とポリエステル立毛糸B用糸条2本を引き揃えてインターレース加工により混繊糸を得ること以外は実施例1と同様にした。
得られた編物において、ポリエステル立毛糸Aの平均繊維径は700nmであった。また、ポリエステル立毛糸Bの平均繊維径は14.8μmであった。また、ポリエステル立毛糸Aおよびポリエステル立毛糸Bの立毛糸高さは2.2mm、圧縮回復率は37.9%であり、風合いはソフト(3級)であった。また、ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比は、(ポリエステル立毛糸A:ポリエステル立毛糸B)19:81であった。
[Example 3]
In Example 1, the same procedure as in Example 1 was carried out except that one yarn for polyester raised yarn A and two yarns for polyester raised yarn B were aligned and a mixed yarn was obtained by interlacing.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn A was 700 nm. The average fiber diameter of the polyester napped yarn B was 14.8 μm. Further, the height of the napped yarns of the polyester napped yarn A and the polyester napped yarn B was 2.2 mm, the compression recovery rate was 37.9%, and the texture was soft (third grade). The weight ratio of the polyester napped yarn A to the polyester napped yarn B was 19:81 (polyester napped yarn A: polyester napped yarn B).

[実施例4]
実施例1と同様にして海島型複合延伸糸56dtex/10fil(ポリエステル立毛糸A用糸条)を得た。一方、ポリエステル立毛糸B用糸条として、ポリエチレンテレフタレートからなるマルチフィラメント半延伸糸(POY)130dtex/36filを用意し、前記ポリエステル立毛糸A用糸条とポリエステル立毛糸B用糸条とを1本ずつ引き揃えて複合仮撚捲縮加工により複合糸条を得た。
その後、ポリエチレンテレフタレートからなるマルチフィラメント仮撚捲縮加工糸167dtex/48fil(単繊維径18.1μm)をグランド糸に全量配し、前記複合糸条をパイル糸に全量配し、16Gの丸編み機にて、通常の製編方法によりシンカーパイル丸編生機を得た。次いで、ループ状に形成されたパイル糸の先端をカットした後、該編物を50℃にて湿熱処理した後、海島型複合延伸糸の海成分を除去するために、2.5%NaOH水溶液で、55℃にて7.2%減量(アルカリ減量)した。その後、常法の湿熱加工、乾熱加工を行った。
得られた編物において、ポリエステル立毛糸Aの平均繊維径は700nmであった。また、ポリエステル立毛糸Bの平均繊維径は18.3μmであった。また、ポリエステル立毛糸Aおよびポリエステル立毛糸Bの立毛糸高さは7.5mm、圧縮回復率は47.2%であり、風合いはソフト(3級)であった。また、ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比は、(ポリエステル立毛糸A:ポリエステル立毛糸B)23:77であった。
[Example 4]
In the same manner as in Example 1, a sea-island composite drawn yarn 56 dtex / 10 fil (polyester napped yarn A yarn) was obtained. On the other hand, a multifilament semi-drawn yarn (POY) 130 dtex / 36fil made of polyethylene terephthalate is prepared as a polyester raised yarn B yarn, and one of the polyester raised yarn A yarn and the polyester raised yarn B yarn is provided. They were drawn one by one and a composite yarn was obtained by a composite false twist crimping process.
Thereafter, 167 dtex / 48 fil (single fiber diameter: 18.1 μm) of multifilament false twist crimped yarn made of polyethylene terephthalate is distributed in the ground yarn, and the composite yarn is distributed in the pile yarn. Thus, a sinker pile circular knitting machine was obtained by a normal knitting method. Next, after cutting the tip of the pile yarn formed in a loop shape, the knitted fabric was subjected to wet heat treatment at 50 ° C. The weight was reduced by 7.2% (alkali weight loss) at 55 ° C. Thereafter, conventional wet heat processing and dry heat processing were performed.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn A was 700 nm. The average fiber diameter of the polyester napped yarn B was 18.3 μm. Further, the height of the napped yarns of the polyester napped yarn A and the polyester napped yarn B was 7.5 mm, the compression recovery rate was 47.2%, and the texture was soft (third grade). The weight ratio of the polyester napping yarn A to the polyester napping yarn B was (polyester napping yarn A: polyester napping yarn B) 23:77.

[実施例5]
実施例1と同様に海島型複合延伸糸56dtex/10fil(ポリエステル立毛糸A用糸条)を得た。その後、ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36fil(単繊維径14.8μm)をグランド糸に全量配し、前記ポリエステル立毛糸A用糸条のみをパイル糸に全量配し、24Gの丸編み機にて、通常の製編方法によりシンカーパイル編物生機を得た。次いで、ループ状に形成されたパイル糸の先端をカットした後、該編物を50℃にて湿熱処理した後、海島型複合延伸糸の海成分を除去するために、2.5%NaOH水溶液で、55℃にて25.8%減量(アルカリ減量)した。その後、常法の湿熱加工、乾熱加工を行った。
得られた編物において、ポリエステル立毛糸Aの平均繊維径は700nmであった。また、ポリエステル立毛糸Aの立毛糸高さは20.5mm、圧縮回復率は19.4%であり、風合いはソフト(3級)であった。
次いで、該立毛布帛を用いて、化粧用パフおよびペイントローラーを作製した。化粧用パフおよびペイントローラーともに、立毛部はソフトな風合いは有していたが、反発性がやや劣り、使用により少しへたりが生じた。
[Example 5]
In the same manner as in Example 1, a sea-island type composite drawn yarn 56 dtex / 10 fil (polyester napped yarn A yarn) was obtained. After that, all the multifilament yarns 84dtex / 36fil (single fiber diameter 14.8μm) made of polyethylene terephthalate are allotted to the ground yarn, and only all the polyester raised yarn A yarns are allotted to the pile yarn. Thus, a sinker pile knitting raw machine was obtained by a normal knitting method. Next, after cutting the tip of the pile yarn formed in a loop shape, the knitted fabric was subjected to wet heat treatment at 50 ° C., and then with a 2.5% NaOH aqueous solution in order to remove the sea component of the sea-island type composite drawn yarn. The weight was reduced by 25.8% (alkali weight loss) at 55 ° C. Thereafter, conventional wet heat processing and dry heat processing were performed.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn A was 700 nm. Further, the height of the napped yarn of the polyester napped yarn A was 20.5 mm, the compression recovery rate was 19.4%, and the texture was soft (third grade).
Next, a cosmetic puff and a paint roller were produced using the raised fabric. Both the cosmetic puff and the paint roller had a soft texture at the raised portion, but the resilience was slightly inferior and a little sag was caused by use.

[比較例1]
ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36fil(単繊維径14.8μm)をグランド糸に全量配し、一方、ポリエステル立毛糸B用糸条として、ポリエチレンテレフタレートからなるマルチフィラメント糸84dtex/36filのみをパイル糸に全量配し、24Gの丸編み機にて、通常の製編方法によりシンカーパイル編物生機を得た。次いで、ループ状に形成されたパイル糸の先端をカットした後、該編物を50℃にて湿熱処理した後、常法の湿熱加工、乾熱加工を行った。
得られた編物において、ポリエステル立毛糸Bの平均繊維径は14.8μmであった。また、ポリエステル立毛糸Bの立毛糸高さは2.2mm、圧縮回復率は69.3%であり、ソフト感は低く硬い風合い(1級)であった。
[Comparative Example 1]
Multifilament yarn 84dtex / 36fil (single fiber diameter: 14.8μm) made of polyethylene terephthalate is all arranged on the ground yarn. On the other hand, as yarn for polyester raised yarn B, only multifilament yarn 84dtex / 36fil made of polyethylene terephthalate is piled. The entire amount was arranged on the yarn, and a sinker pile knitting raw machine was obtained by a normal knitting method using a 24G circular knitting machine. Next, after cutting the tip of the pile yarn formed in a loop shape, the knitted fabric was subjected to wet heat treatment at 50 ° C., and then subjected to conventional wet heat processing and dry heat processing.
In the obtained knitted fabric, the average fiber diameter of the polyester napped yarn B was 14.8 μm. Further, the height of the napped yarn of the polyester napped yarn B was 2.2 mm, the compression recovery rate was 69.3%, and the soft feeling was low and the texture was hard (first grade).

本発明によれば、立毛部がソフトな風合いと適度な反発性とを兼ね備えた立毛布帛、および該立毛布帛を用いてなる立毛布帛製品が提供され、その工業的価値は極めて大である。   ADVANTAGE OF THE INVENTION According to this invention, the napped fabric which the napped part had a soft texture and moderate resilience, and the napped fabric product using this napped fabric are provided, The industrial value is very large.

1 地組織部
2 ポリエステル立毛糸A
3 立毛部
4 ポリエステル立毛糸B
L 立毛糸高さ
1 Ground tissue part 2 Polyester napping yarn A
3 Napped parts 4 Polyester napped threads B
L Standing yarn height

Claims (6)

立毛部と地組織部とで構成される立毛布帛であって、前記立毛部に、単繊維径が50〜1500nmのポリエステル立毛糸Aと単繊維径が5〜40μmのポリエステル立毛糸Bが含まれることを特徴とする立毛布帛を用いてなる、化粧用パフ、塗装用ペイントローラーからなる群より選択されるいずれかの用途に使用される立毛布帛製品。 A raised fabric comprising a raised portion and a ground tissue portion, wherein the raised portion includes a polyester raised yarn A having a single fiber diameter of 50 to 1500 nm and a polyester raised yarn B having a single fiber diameter of 5 to 40 μm. A napped fabric product used for any application selected from the group consisting of a cosmetic puff and a paint roller for painting, comprising the napped fabric characterized by the above. 前記立毛部に含まれる、ポリエステル立毛糸Aとポリエステル立毛糸Bとの重量比が(ポリエステル立毛糸A:ポリエステル立毛糸B)15:85〜85:15の範囲内である、請求項1に記載の立毛布帛製品。The weight ratio of the polyester napping yarn A and the polyester napping yarn B contained in the napped portion is in the range of (polyester napping yarn A: polyester napping yarn B) 15:85 to 85:15. Napping fabric products. 前記立毛部の立毛糸高さが0.5〜20mmの範囲内のカットパイル糸である、請求項1または請求項2に記載の立毛布帛製品。The raised fabric product according to claim 1 or 2, wherein the raised yarn height of the raised portion is a cut pile yarn within a range of 0.5 to 20 mm. 前記ポリエステル立毛糸Aが、海成分とポリエステルからなりその径が50〜1500nmである島成分とで形成される海島型複合繊維の海成分をアルカリ水溶液で溶解除去してなる立毛糸である、請求項1〜3のいずれかに記載の立毛布帛製品。The polyester napped yarn A is a napped yarn formed by dissolving and removing a sea component of a sea-island type composite fiber formed of a sea component and an island component having a diameter of 50 to 1500 nm, with an alkaline aqueous solution. Item 4. The napped fabric product according to any one of Items 1 to 3. 前記ポリエステル立毛糸Aとポリエステル立毛糸Bとが、ポリエステル立毛糸A用糸条とポリエステル立毛糸B用糸条とで構成される複合糸から製造されたものである、請求項1〜4のいずれかに記載の立毛布帛製品。The polyester napped yarn A and the polyester napped yarn B are produced from a composite yarn composed of a polyester napped yarn A yarn and a polyester napped yarn B yarn. A raised fabric product according to any one of the above. 前記地組織部がポリエステル繊維で構成される、請求項1〜5のいずれかに記載の立毛布帛製品。The raised fabric product according to any one of claims 1 to 5, wherein the ground tissue portion is made of polyester fiber.
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