JP5501769B2 - 架橋可能なポリエチレン組成物、その製造方法及びそれから製造された物品 - Google Patents
架橋可能なポリエチレン組成物、その製造方法及びそれから製造された物品 Download PDFInfo
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- JP5501769B2 JP5501769B2 JP2009548365A JP2009548365A JP5501769B2 JP 5501769 B2 JP5501769 B2 JP 5501769B2 JP 2009548365 A JP2009548365 A JP 2009548365A JP 2009548365 A JP2009548365 A JP 2009548365A JP 5501769 B2 JP5501769 B2 JP 5501769B2
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- polyethylene composition
- polyethylene
- crosslinkable
- temperature
- crosslinking
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- NCXJHEBVPMOSEM-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CC(C)(CO)CO Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CC(C)(CO)CO NCXJHEBVPMOSEM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- QYTDEUPAUMOIOP-UHFFFAOYSA-N TEMPO Chemical group CC1(C)CCCC(C)(C)N1[O] QYTDEUPAUMOIOP-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229920010346 Very Low Density Polyethylene (VLDPE) Polymers 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
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- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- SRIDKWFKROYRSX-UHFFFAOYSA-N bis[(2-methylpropan-2-yl)oxy]-phenylphosphane Chemical compound CC(C)(C)OP(OC(C)(C)C)C1=CC=CC=C1 SRIDKWFKROYRSX-UHFFFAOYSA-N 0.000 description 1
- QUZSUMLPWDHKCJ-UHFFFAOYSA-N bisphenol A dimethacrylate Chemical compound C1=CC(OC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C(C)=C)C=C1 QUZSUMLPWDHKCJ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- QZYRMODBFHTNHF-UHFFFAOYSA-N ditert-butyl benzene-1,2-dicarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)OOC(C)(C)C QZYRMODBFHTNHF-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000012156 elution solvent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOSUIKFOFHZNED-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,3,5-tricarboxylate Chemical compound C=CCOC(=O)C1=CC(C(=O)OCC=C)=CC(C(=O)OCC=C)=C1 VOSUIKFOFHZNED-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89948507P | 2007-02-05 | 2007-02-05 | |
| US60/899,485 | 2007-02-05 | ||
| PCT/US2008/051991 WO2008097732A1 (en) | 2007-02-05 | 2008-01-25 | A crosslinkable polyethylene composition, method of making the same, and articles made therefrom |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010518197A JP2010518197A (ja) | 2010-05-27 |
| JP2010518197A5 JP2010518197A5 (enExample) | 2011-03-10 |
| JP5501769B2 true JP5501769B2 (ja) | 2014-05-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009548365A Expired - Fee Related JP5501769B2 (ja) | 2007-02-05 | 2008-01-25 | 架橋可能なポリエチレン組成物、その製造方法及びそれから製造された物品 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8283420B2 (enExample) |
| EP (1) | EP2118195B1 (enExample) |
| JP (1) | JP5501769B2 (enExample) |
| CN (1) | CN101652417B (enExample) |
| AR (1) | AR065166A1 (enExample) |
| TW (1) | TWI426084B (enExample) |
| WO (1) | WO2008097732A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2256158B1 (en) * | 2009-05-26 | 2014-07-02 | Borealis AG | Polymer composition for crosslinked articles |
| EP2256159A1 (en) * | 2009-05-26 | 2010-12-01 | Borealis AG | Polymer composition for crosslinked pipes |
| CN102504113B (zh) * | 2011-10-24 | 2013-11-20 | 中国石油化工股份有限公司 | 一种长支链化聚乙烯树脂及其制备方法 |
| CN102543316A (zh) * | 2012-02-17 | 2012-07-04 | 杭州电缆股份有限公司 | 500kV交联电缆绝缘工序的加工方法 |
| KR101933255B1 (ko) * | 2012-05-10 | 2018-12-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리부타디엔 가교 조제를 사용하여 제조한 에틸렌 중합체 전도체 코팅 |
| WO2014040237A1 (en) * | 2012-09-12 | 2014-03-20 | Dow Global Technologies Llc | Cross-linkable polymeric compositions, methods for making the same, and articles made therefrom |
| WO2014089065A1 (en) * | 2012-12-04 | 2014-06-12 | Rutgers, The State University Of New Jersey | Apparatus for thermoforming polymer composite panels |
| US9422423B2 (en) | 2012-12-04 | 2016-08-23 | Rutgers, The State University Of New Jersey | Composite articles compression molded from recycled plastic |
| EP3116951B1 (en) * | 2014-03-11 | 2019-10-02 | SACO AEI Polymers, Inc. | Tin-free catalysts for cross-linked polyethylene pipe and wire |
| WO2015149223A1 (en) * | 2014-03-31 | 2015-10-08 | Dow Global Technologies Llc | Crosslinkable polymeric compositions with diallylamide crosslinking coagents, methods for making the same, and articles made therefrom |
| EP3298075B1 (en) * | 2015-05-22 | 2025-07-16 | Dow Global Technologies LLC | Processes for preparing cables with crosslinked insulation layer and cables for same |
| WO2016201659A1 (en) | 2015-06-18 | 2016-12-22 | Dow Global Technologies Llc | Thermally conductive elastomeric composites |
| US20190106557A1 (en) * | 2016-03-30 | 2019-04-11 | Dow Global Technologies Llc | Crosslinkable polymeric compositions with methyl-radical scavengers and articles made therefrom |
| CN106478887B (zh) * | 2016-10-18 | 2019-12-10 | 神华集团有限责任公司 | 一种可交联接枝聚乙烯组合物、交联接枝聚乙烯制品及制备方法和制品 |
| ES3047811T3 (en) * | 2020-08-21 | 2025-12-05 | Dow Global Technologies Llc | Meltblown nonwovens having high volume resistivity and articles thereof |
| CN114736443A (zh) * | 2021-01-07 | 2022-07-12 | 国家能源投资集团有限责任公司 | 可交联聚乙烯组合物及其应用、交联聚乙烯及其制备方法与应用 |
| CN115073834A (zh) * | 2021-03-11 | 2022-09-20 | 中国石油天然气股份有限公司 | 一种微交联高密度聚乙烯及其制备方法 |
| CN116625427B (zh) * | 2022-09-02 | 2025-10-31 | 南方电网科学研究院有限责任公司 | 高压交流电缆交联聚乙烯绝缘材料配方设计和优化方法 |
| WO2025168740A1 (en) * | 2024-02-07 | 2025-08-14 | Uponor Innovation Ab | Polymeric pipe |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| JP2704649B2 (ja) * | 1988-12-02 | 1998-01-26 | 日本ユニカー株式会社 | 成形可能な樹脂組成物 |
| CA2063478A1 (en) * | 1991-03-22 | 1992-09-23 | Michael F. Novits | Scorch extending curing/crosslinking compositions |
| US6103807A (en) | 1998-03-19 | 2000-08-15 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Ethylene-polymer-based composition, process for obtaining and using same |
| US6228917B1 (en) | 1998-06-16 | 2001-05-08 | Union Carbide Chemicals & Plastics Technology Corporation | Polyethylene crosslinkable composition |
| US6143822A (en) | 1999-03-18 | 2000-11-07 | Union Carbide Chemicals & Plastics Technology Corporation | Polyethylene crosslinkable composition |
| US6231978B1 (en) * | 1999-03-31 | 2001-05-15 | Union Carbide Chemicals & Plastics Technology Corporation | Crosslinkable polyethylene composition |
| US6187847B1 (en) | 1999-07-22 | 2001-02-13 | Union Carbide Chemicals & Plastics Technology Corporation | Polyethylene crosslinkable composition |
| FR2819517B1 (fr) * | 2000-10-03 | 2003-03-21 | Atofina | Composition comprenant un nitroxyde, un promoteur et eventuellement un initiateur de radicaux libres |
| US20040198920A1 (en) * | 2003-04-03 | 2004-10-07 | Atofina | Scorch-retardant composition |
| US6656986B2 (en) | 2001-03-01 | 2003-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Polyethylene crosslinkable composition |
| JP2007517119A (ja) * | 2003-12-24 | 2007-06-28 | ダウ グローバル テクノロジーズ インコーポレイティド | フリーラジカル架橋性ポリマー：架橋のための改良工程および組成物 |
| US7608668B2 (en) | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
| FR2875502B1 (fr) * | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| US7465769B2 (en) * | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
-
2008
- 2008-01-25 JP JP2009548365A patent/JP5501769B2/ja not_active Expired - Fee Related
- 2008-01-25 EP EP08728253.9A patent/EP2118195B1/en not_active Not-in-force
- 2008-01-25 CN CN2008800104094A patent/CN101652417B/zh not_active Expired - Fee Related
- 2008-01-25 WO PCT/US2008/051991 patent/WO2008097732A1/en not_active Ceased
- 2008-01-25 US US12/525,688 patent/US8283420B2/en not_active Expired - Fee Related
- 2008-02-04 AR ARP080100461A patent/AR065166A1/es not_active Application Discontinuation
- 2008-02-04 TW TW097104219A patent/TWI426084B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US8283420B2 (en) | 2012-10-09 |
| TWI426084B (zh) | 2014-02-11 |
| AR065166A1 (es) | 2009-05-20 |
| EP2118195B1 (en) | 2014-06-04 |
| CN101652417B (zh) | 2013-10-30 |
| JP2010518197A (ja) | 2010-05-27 |
| US20100016515A1 (en) | 2010-01-21 |
| TW200848437A (en) | 2008-12-16 |
| WO2008097732A1 (en) | 2008-08-14 |
| CN101652417A (zh) | 2010-02-17 |
| EP2118195A1 (en) | 2009-11-18 |
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