JP5478063B2 - 担持型重合触媒 - Google Patents
担持型重合触媒 Download PDFInfo
- Publication number
- JP5478063B2 JP5478063B2 JP2008515277A JP2008515277A JP5478063B2 JP 5478063 B2 JP5478063 B2 JP 5478063B2 JP 2008515277 A JP2008515277 A JP 2008515277A JP 2008515277 A JP2008515277 A JP 2008515277A JP 5478063 B2 JP5478063 B2 JP 5478063B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- ratio
- cocatalyst
- ethylene
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05253551.5 | 2005-06-09 | ||
| EP05253551A EP1731536A1 (en) | 2005-06-09 | 2005-06-09 | Supported polymerisation catalysts |
| PCT/GB2006/002007 WO2006131704A1 (en) | 2005-06-09 | 2006-06-01 | Supported polymerisation catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008542516A JP2008542516A (ja) | 2008-11-27 |
| JP2008542516A5 JP2008542516A5 (https=) | 2012-10-25 |
| JP5478063B2 true JP5478063B2 (ja) | 2014-04-23 |
Family
ID=35124603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008515277A Expired - Fee Related JP5478063B2 (ja) | 2005-06-09 | 2006-06-01 | 担持型重合触媒 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20090131613A1 (https=) |
| EP (2) | EP1731536A1 (https=) |
| JP (1) | JP5478063B2 (https=) |
| WO (1) | WO2006131704A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1935909A1 (en) * | 2006-12-21 | 2008-06-25 | Ineos Europe Limited | Copolymers and films thereof |
| JP5613583B2 (ja) * | 2010-02-17 | 2014-10-29 | 日本ポリエチレン株式会社 | エチレン重合用触媒、それを用いたエチレン系重合体の製造方法、並びにそれによって得られるエチレン系重合体及びエチレン系重合体粒子 |
| EP2923756B1 (en) | 2012-11-26 | 2018-05-30 | Braskem S.A. | Metallocene catalyst supported by hybrid supporting means, process for producing same, polymerization process for producing an ethylene homopolymer or copolymer with broad or bimodal molar mass distribution, use of the supported metallocene catalyst and ethylene polymer with broad or bimodal molar mass distribution |
| DE102017201442B4 (de) | 2017-01-30 | 2026-03-05 | Volkswagen Aktiengesellschaft | Verfahren zum Betreiben einer elektromechanischen Parkbremse sowie Steuervorrichtung für eine Parkbremse, Parkbremse und Kraftfahrzeug |
| KR20220092932A (ko) | 2019-10-28 | 2022-07-04 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 비페놀 금속 착물, 및 이의 제조 방법 및 용도 |
| CN113185673B (zh) * | 2021-05-20 | 2022-09-27 | 长春三友智造科技发展有限公司 | 一种碳基催化剂及其制备方法以及用于双环戊二烯聚合的催化剂体系 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB305207A (en) | 1928-02-02 | 1929-05-09 | Siemens Ag | An arrangement for limited power transmission in networks |
| IT1037112B (it) | 1975-03-28 | 1979-11-10 | Montedison Spa | Catalizzatori per la polimerizzazione delle olfine |
| US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
| DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5801113A (en) * | 1990-06-22 | 1998-09-01 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
| RU2118203C1 (ru) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| ES2235285T3 (es) | 1993-05-13 | 2005-07-01 | Exxonmobil Chemical Patents Inc. | Copolimeros de etileno con una distribucion de la composicion relativamente estrecha, su produccion y uso. |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| JP2736938B2 (ja) | 1993-06-24 | 1998-04-08 | ザ ダウ ケミカル カンパニー | チタン(▲ii▼)またはジルコニウム(▲ii▼)錯体およびそれからなる付加重合触媒 |
| CA2171831A1 (en) | 1993-09-17 | 1995-03-23 | Moses Olukayode Jejelowo | Polymerization catalyst systems, their production and use |
| ES2165425T3 (es) | 1994-06-24 | 2002-03-16 | Exxonmobil Chem Patents Inc | Sistemas cataliticos de polimerizacion, su produccion y uso. |
| US5972822A (en) | 1994-08-02 | 1999-10-26 | The Dow Chemical Company | Biscyclopentadienyldiene complex containing addition polymerization catalysts |
| WO1996004318A1 (en) | 1994-08-05 | 1996-02-15 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| CA2223258A1 (en) | 1995-07-06 | 1997-01-23 | Exxon Chemical Patents, Inc. | Method for producing prepolymerized, supported metallocene catalyst systems |
| FI104825B (fi) * | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US5783512A (en) * | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| ID20751A (id) * | 1997-02-07 | 1999-02-25 | Mitsui Chemicals Inc | Katalis polimerisasi olefin dan proses pembuatan polimer olefin |
| CA2204803C (en) | 1997-05-08 | 2005-11-15 | Nova Chemicals Ltd. | Process to prepare bridged phosphole-cyclopentadienyl compounds |
| CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| JP3890761B2 (ja) * | 1997-08-21 | 2007-03-07 | 住友化学株式会社 | 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法 |
| CN1246341C (zh) | 1997-09-05 | 2006-03-22 | 英国石油化学品有限公司 | 聚合催化剂 |
| CA2228923A1 (en) | 1998-02-06 | 1999-08-06 | Nova Chemicals Ltd. | Process for preparing supported olefin polymerization catalyst |
| JPH11343308A (ja) * | 1998-06-02 | 1999-12-14 | Chisso Corp | オレフィン重合用予備活性化触媒 |
| CA2243783C (en) | 1998-07-21 | 2007-06-05 | Nova Chemicals Ltd. | Bis-phosphinimine catalyst |
| CA2243775C (en) | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
| CA2254841C (en) | 1998-11-26 | 2007-02-06 | Nova Chemicals Ltd. | Nitrogen substituted phosphinimine ligand |
| JP2001329006A (ja) * | 2000-03-17 | 2001-11-27 | Chisso Corp | ポリプロピレン組成物 |
| JP2001302716A (ja) * | 2000-04-25 | 2001-10-31 | Asahi Kasei Corp | オレフィン重合体の製造方法 |
| TWI300782B (en) | 2002-08-29 | 2008-09-11 | Ineos Europe Ltd | Supported polymerisation catalysts |
| US20060287449A1 (en) * | 2003-03-10 | 2006-12-21 | Koichi Miyamoto | Ultrahigh-molecular ethylene polymer |
| ES2391973T3 (es) | 2003-08-22 | 2012-12-03 | Ineos Commercial Services Uk Limited | Catalizadores de polimerización soportados |
-
2005
- 2005-06-09 EP EP05253551A patent/EP1731536A1/en not_active Withdrawn
-
2006
- 2006-06-01 JP JP2008515277A patent/JP5478063B2/ja not_active Expired - Fee Related
- 2006-06-01 US US11/921,268 patent/US20090131613A1/en not_active Abandoned
- 2006-06-01 EP EP06744063A patent/EP1888654A1/en not_active Withdrawn
- 2006-06-01 WO PCT/GB2006/002007 patent/WO2006131704A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP1731536A1 (en) | 2006-12-13 |
| JP2008542516A (ja) | 2008-11-27 |
| EP1888654A1 (en) | 2008-02-20 |
| US20090131613A1 (en) | 2009-05-21 |
| WO2006131704A1 (en) | 2006-12-14 |
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