JP5339713B2 - 芳香族アミンからフェノール性ヒドロキシ基を含む化合物を除去する方法 - Google Patents
芳香族アミンからフェノール性ヒドロキシ基を含む化合物を除去する方法 Download PDFInfo
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- JP5339713B2 JP5339713B2 JP2007289856A JP2007289856A JP5339713B2 JP 5339713 B2 JP5339713 B2 JP 5339713B2 JP 2007289856 A JP2007289856 A JP 2007289856A JP 2007289856 A JP2007289856 A JP 2007289856A JP 5339713 B2 JP5339713 B2 JP 5339713B2
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- Prior art keywords
- group
- basic solid
- phenolic hydroxy
- basic
- solid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000000034 method Methods 0.000 title claims description 37
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims description 37
- 150000001875 compounds Chemical class 0.000 title claims description 25
- 150000004982 aromatic amines Chemical class 0.000 title claims description 14
- 239000007787 solid Substances 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 19
- 238000005984 hydrogenation reaction Methods 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 37
- 238000001179 sorption measurement Methods 0.000 description 19
- 239000000463 material Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000004821 distillation Methods 0.000 description 12
- 239000003463 adsorbent Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 238000004817 gas chromatography Methods 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000002828 nitro derivatives Chemical class 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009904 heterogeneous catalytic hydrogenation reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229940031826 phenolate Drugs 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/84—Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Description
Rep,M.;Palomares,A.E.;Eder−Mirth,G.;van Ommen,J.G.;Roesch,N;Lercher,J.A.著の"Interaction of Methanol with Alkali Metal Exchanged Molecular Sieves.1.IR Spectroscopic Study",Journal of Physical Chemistry B(2000),104(35),8624−8630と、
Tsyganenko,A.A.;Kondratieva,E.V.;Yanko,V.S.;Storozhev,P.Yu.著の"FTIR study of CO adsorption on basic zeolites",Journal of Materials Chemistry(2006),16(24),2358−2363と、
Plant,David F.;Simperler,Alexandra;Bell,Robert G.著の"Adsorption of methanol on zeolites X and Y.An atomistic and quantum chemical study",Journal of Physical Chemistry B(2006),110(12),6170−6178と
に記載されている。
B = 塩基性固体1kg当たりに吸着される、フェノール性ヒドロキシ基を含む化合物のモル数
C = 塩基性固体1kg当たりに吸着される芳香族アミンのモル数
χB/χC = 高いアミン過剰率を考慮に入れた重み係数
χB = 使用される混合物における、フェノール性ヒドロキシ基を含む化合物の含分と、フェノール性ヒドロキシ基を含む化合物及びアミンの合計含分とのモル比(モル分率)
χC = 使用される混合物における、アミンの含分と、フェノール性ヒドロキシ基を含む化合物及びアミンの合計含分とのモル比(モル分率)]。
アニリン(500ppmのフェノールでドープされている)49.12g/hと、水20.1g/hと、水素24.5l/hの気流を、周囲圧力において、長さ60cm及び直径2.5cmを有する吸着管であって240℃に外部加熱されかつガラスビーズと吸着体14gの充填物で満たされたものに通過させた。前記吸着器を出たガス流を、3℃で回収容器中で凝縮させ、そしてそのフェノール含有率をガスクロマトグラフィーによって測定した。吸着時間は6時間であった。第1表は、実測された吸着能と選択性を含んでいる。
アニリン(500ppmのフェノールでドープされている)8g/hと、水3.2g/hと、水素5.76l/hの気流を、周囲圧力及び240℃において、実施例1に挙げた吸着管であってガラスビーズと吸着体10gの充填物で満たされたものに通過させた。前記吸着器を出たガス流を、3℃で回収容器中で凝縮させ、そしてそのフェノール含有率をガスクロマトグラフィーによって測定した。第2表は、実測されたフェノール含有率に従うものである。
実施例1からの負荷された吸着体を、全ての吸着された有機化合物を340℃及び周囲圧力で窒素中空気流において焼却することによって再生させた。実施例1からの吸着体をそれぞれ再生させることができ、そして如何なる大きな活性損失を伴うことなく再び5回負荷させることができる。
Claims (7)
- フェノール性ヒドロキシ基を含む化合物を、少なくとも1種の芳香族アミンであってニトロ芳香族化合物の水素での気相水素化の過程において生成した芳香族アミンを含有するガス流から分離するための方法において、フェノール性ヒドロキシ基を含む化合物を塩基性固体上に吸着させる工程を含む方法。
- 請求項1に記載の方法であって、
前記塩基性固体上を通過するガス流は、入口温度が150〜500℃であり、かつ、絶対圧力が1〜50バールである、
方法。 - 請求項1又は2に記載の方法であって、
前記塩基性固体が、元素の周期律表の第1族、第2族、第12族、第13族、並びに第14族から選択される少なくとも1種の元素の酸化物及び/又は水酸化物を含む、
方法。 - 請求項1から3までのいずれか1項に記載の方法であって、
前記塩基性固体がゼオライトを含む、
方法。 - 請求項1から4までのいずれか1項に記載の方法であって、
前記塩基性固体が、酸化触媒を、当該酸化触媒を含む前記塩基性固体の全質量に対して、0.1〜10質量%の量で含む、
方法。 - 請求項5に記載の方法であって、
前記酸化触媒が、元素の周期律表の第5族、第6族、第7族、第10族、及び第11族から選択される少なくとも1種の金属又は金属酸化物を含む、
方法。 - 請求項1から6までのいずれか1項に記載の方法であって、
前記塩基性固体が前記のフェノール性ヒドロキシ基を含む化合物で完全に又は部分的に負荷されたときに、当該塩基性固体を、250〜500℃の温度において、酸素もしくは酸素含有ガス混合物で処理することによって再生させる、
方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006052989.8 | 2006-11-10 | ||
DE102006052989A DE102006052989A1 (de) | 2006-11-10 | 2006-11-10 | Verfahren zur Entfernung von Verbindungen mit phenolischen Hydroxygruppen aus aromatischen Aminen |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008120803A JP2008120803A (ja) | 2008-05-29 |
JP5339713B2 true JP5339713B2 (ja) | 2013-11-13 |
Family
ID=38738833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007289856A Expired - Fee Related JP5339713B2 (ja) | 2006-11-10 | 2007-11-07 | 芳香族アミンからフェノール性ヒドロキシ基を含む化合物を除去する方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7488850B2 (ja) |
EP (1) | EP1921060B1 (ja) |
JP (1) | JP5339713B2 (ja) |
KR (1) | KR20080042739A (ja) |
CN (1) | CN101177401B (ja) |
AT (1) | ATE459596T1 (ja) |
DE (2) | DE102006052989A1 (ja) |
PT (1) | PT1921060E (ja) |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3136818A (en) | 1960-01-15 | 1964-06-09 | Basf Ag | Production of aniline |
BE793928A (fr) | 1972-01-13 | 1973-05-02 | Deggendorfer Werft Eisenbau | Appareil pour la mise en oeuvre de processus chimiques exothermiques et endothermiques |
JPS4935341A (ja) * | 1972-07-31 | 1974-04-01 | ||
SU592436A1 (ru) * | 1975-12-29 | 1978-02-15 | Всесоюзный Центральный Научно-Исследовательский Институт Охраны Труда Вцспс | Способ очистки газовоздушной смеси |
DE3414714C2 (de) | 1984-04-18 | 1986-06-19 | Friedrich 6720 Speyer Sperling | Vorrichtung zur Zubereitung von Dampfnudeln (von gebratenen bzw. gekochten Teigstücken) |
JPH06239813A (ja) * | 1993-02-05 | 1994-08-30 | Tokuyama Soda Co Ltd | ハロゲノアミノフェノールの精製方法 |
DE4428017A1 (de) | 1994-08-08 | 1996-02-15 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen |
DE4428018A1 (de) | 1994-08-08 | 1996-02-15 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen |
JP3804082B2 (ja) | 1995-04-27 | 2006-08-02 | 住友化学株式会社 | アニリンの精製方法 |
US5733788A (en) * | 1996-07-26 | 1998-03-31 | Gilead Sciences, Inc. | PMPA preparation |
US7049471B2 (en) * | 2003-10-10 | 2006-05-23 | E. I. Du Pont De Nemours And Company | Separation of amine from a phenolic compound |
DE102006007619A1 (de) * | 2006-02-18 | 2007-08-23 | Bayer Materialscience Ag | Verfahren zur Herstellung von Anilin |
-
2006
- 2006-11-10 DE DE102006052989A patent/DE102006052989A1/de not_active Withdrawn
-
2007
- 2007-11-02 PT PT07021397T patent/PT1921060E/pt unknown
- 2007-11-02 AT AT07021397T patent/ATE459596T1/de active
- 2007-11-02 EP EP07021397A patent/EP1921060B1/de not_active Not-in-force
- 2007-11-02 DE DE502007002986T patent/DE502007002986D1/de active Active
- 2007-11-06 US US11/982,959 patent/US7488850B2/en not_active Expired - Fee Related
- 2007-11-07 JP JP2007289856A patent/JP5339713B2/ja not_active Expired - Fee Related
- 2007-11-09 KR KR1020070114161A patent/KR20080042739A/ko not_active Application Discontinuation
- 2007-11-09 CN CN2007101860378A patent/CN101177401B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE102006052989A1 (de) | 2008-05-15 |
US7488850B2 (en) | 2009-02-10 |
CN101177401B (zh) | 2013-03-27 |
ATE459596T1 (de) | 2010-03-15 |
EP1921060B1 (de) | 2010-03-03 |
EP1921060A1 (de) | 2008-05-14 |
KR20080042739A (ko) | 2008-05-15 |
PT1921060E (pt) | 2010-04-27 |
JP2008120803A (ja) | 2008-05-29 |
CN101177401A (zh) | 2008-05-14 |
DE502007002986D1 (de) | 2010-04-15 |
US20080139850A1 (en) | 2008-06-12 |
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