JP5284085B2 - 低ホルムアルデヒド放出量の熱成形性メラミン／ホルムアルデヒドフォーム材 - Google Patents
低ホルムアルデヒド放出量の熱成形性メラミン／ホルムアルデヒドフォーム材 Download PDFInfo
- Publication number
- JP5284085B2 JP5284085B2 JP2008516292A JP2008516292A JP5284085B2 JP 5284085 B2 JP5284085 B2 JP 5284085B2 JP 2008516292 A JP2008516292 A JP 2008516292A JP 2008516292 A JP2008516292 A JP 2008516292A JP 5284085 B2 JP5284085 B2 JP 5284085B2
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- JP
- Japan
- Prior art keywords
- formaldehyde
- melamine
- foam material
- precondensate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims description 84
- 239000006261 foam material Substances 0.000 title claims description 33
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 title claims description 29
- 238000000034 method Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000004604 Blowing Agent Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- 238000005187 foaming Methods 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 claims description 4
- 239000002516 radical scavenger Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 2
- -1 dicyandiamides Chemical class 0.000 description 18
- 229920000877 Melamine resin Polymers 0.000 description 12
- 239000006260 foam Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 230000005855 radiation Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000004640 Melamine resin Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 235000013877 carbamide Nutrition 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical group OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000010695 polyglycol Substances 0.000 description 4
- 229920000151 polyglycol Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003856 thermoforming Methods 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QECVIPBZOPUTRD-UHFFFAOYSA-N N=S(=O)=O Chemical class N=S(=O)=O QECVIPBZOPUTRD-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 150000003857 carboxamides Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000002666 chemical blowing agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- JCQKQWAONVEFJC-UHFFFAOYSA-N 3-hydroxy-2,2-bis(hydroxymethyl)propanal Chemical compound OCC(CO)(CO)C=O JCQKQWAONVEFJC-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 125000004395 glucoside group Chemical group 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- ZWLUXSQADUDCSB-UHFFFAOYSA-N phthalaldehyde Chemical compound O=CC1=CC=CC=C1C=O ZWLUXSQADUDCSB-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 239000003646 toxicity reducer Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0028—Use of organic additives containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/21—Urea; Derivatives thereof, e.g. biuret
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08J2361/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005027552A DE102005027552A1 (de) | 2005-06-14 | 2005-06-14 | Thermoformbare Melamin/Formaldehyd-Schaumstoffe mit geringer Formaldehydemission |
| DE102005027552.4 | 2005-06-14 | ||
| PCT/EP2006/063082 WO2006134083A1 (de) | 2005-06-14 | 2006-06-12 | Thermoformbare melamin/formaldehyd-schaumstoffe mit geringer formaldehydemission |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008544005A JP2008544005A (ja) | 2008-12-04 |
| JP5284085B2 true JP5284085B2 (ja) | 2013-09-11 |
Family
ID=36911354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008516292A Active JP5284085B2 (ja) | 2005-06-14 | 2006-06-12 | 低ホルムアルデヒド放出量の熱成形性メラミン／ホルムアルデヒドフォーム材 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20080197524A1 (zh) |
| EP (1) | EP1893674B1 (zh) |
| JP (1) | JP5284085B2 (zh) |
| KR (1) | KR101328822B1 (zh) |
| CN (1) | CN101198646B (zh) |
| DE (1) | DE102005027552A1 (zh) |
| ES (1) | ES2426344T3 (zh) |
| PL (1) | PL1893674T3 (zh) |
| WO (1) | WO2006134083A1 (zh) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9347004B2 (en) * | 2009-06-16 | 2016-05-24 | The Boeing Company | Flame propagation resistant foam and method |
| EP2371891A3 (en) | 2010-03-09 | 2012-04-25 | Borealis Agrolinz Melamine GmbH | Use of modified inorganic particles as aldehyde scavenger and curing agent, in particular in wood based panels |
| WO2012035457A1 (de) * | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur herstellung von melamin/formaldehyd-schaumstoffen |
| EP2630173B1 (en) | 2010-10-19 | 2015-01-07 | Borealis Agrolinz Melamine GmbH | Colloidal aminotriazine-aldehyde condensates and their use as aldehyde scavenger |
| DE102011009397A1 (de) | 2011-01-25 | 2012-07-26 | Basf Se | Verbundschaumstoff zur Schalldämmung |
| DE102012015128B4 (de) | 2012-07-30 | 2014-11-20 | Püschner GmbH + Co. KG | Verfahren und Vorrichtung zur Herstellung von harzbasierten Schaumstoffen |
| EP2703074A1 (de) * | 2012-09-04 | 2014-03-05 | Basf Se | Verfahren zur Herstellung von Melamin/Formaldehyd-Schaumstoffen |
| CN102898778B (zh) * | 2012-09-07 | 2014-07-30 | 南通紫鑫实业有限公司 | 一种三聚氰胺甲醛树脂闭孔泡沫的制备方法 |
| EP2735584A1 (de) | 2012-11-26 | 2014-05-28 | Basf Se | Thermoverformbarer Melaminharzschaumstoff mit partikelförmigem Füllmaterial |
| DE102013217654B4 (de) | 2013-09-04 | 2017-02-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Formaldehydfreie Amino- oder Amidharze basierend auf einer reaktiven Schutzgruppe und einem Di- oder Trialdehyd als Netzwerkbildner |
| EP3080178B1 (de) | 2013-12-12 | 2018-11-21 | Fraunhofer Gesellschaft zur Förderung der Angewand | Formaldehyd-freie harze basierend auf hydroxyaldehyden |
| EP3080179A1 (de) | 2013-12-12 | 2016-10-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Formaldehyd-freie harze basierend auf glyoxylsäureestern |
| DE102015000393A1 (de) | 2014-01-21 | 2015-07-23 | Frank Becher | Verfahren zur Herstellung von geschlossen-porigen Erzeugnissen mit hohlen Zellen, mittels dessen der Druck in den Zellen kontrolliert während des Aufschäumens erhöht oder reduziert werden kann, sowie Erzeugnisse, die nach diesem Verfahren hergestellt werden |
| DE102014105093B4 (de) | 2014-04-10 | 2016-01-28 | Püschner Gmbh & Co. Kg | Verfahren und Mehrkammeranlage zur Herstellung von Keramikschäumen auf Basis von wässrigen Keramiksuspensionen und von harzbasierten Schaumstoffen |
| KR102176171B1 (ko) * | 2018-08-22 | 2020-11-09 | 주식회사 동성화학 | 내열성이 우수한 열성형성 멜라민 발포체 및 이의 제조방법 |
| JP2022530798A (ja) | 2019-05-02 | 2022-07-01 | ビーエーエスエフ ソシエタス・ヨーロピア | 低下したホルムアルデヒド放出を有するメラミンホルムアルデヒドフォーム |
| KR102295346B1 (ko) * | 2019-07-17 | 2021-08-31 | 주식회사 동성케미컬 | 열성형성 멜라민 발포체 및 이의 제조 방법 |
| CN111234291B (zh) * | 2020-03-06 | 2022-09-20 | 郑州峰泰纳米材料有限公司 | 一种三聚氰胺甲醛树脂阻燃泡沫的制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5580441A (en) * | 1978-12-14 | 1980-06-17 | Mitsui Toatsu Chem Inc | Production of urea resin foam |
| JPS5826370B2 (ja) * | 1979-04-03 | 1983-06-02 | 三井東圧化学株式会社 | 尿素−ホルムアルデヒド樹脂発泡体の製造方法 |
| JPS56166237A (en) * | 1980-05-23 | 1981-12-21 | Mitsui Toatsu Chem Inc | Foam of urea formaldehyde resin |
| JPS5840330A (ja) * | 1981-09-04 | 1983-03-09 | Mitsui Toatsu Chem Inc | 尿素樹脂発泡体の製造方法 |
| US4935149A (en) * | 1989-01-12 | 1990-06-19 | Calgon Corporation | Low free formaldehyde melamine-formaldehyde detackifier and method of using |
| DE4123050A1 (de) * | 1991-07-12 | 1993-01-14 | Basf Ag | Modifizierte melamin-formaldehyd-harze |
| US5914365A (en) * | 1997-02-06 | 1999-06-22 | Georgia-Pacific Resins, Inc. | Modified urea-formaldehyde binder for making fiber mats |
| DE19735809A1 (de) * | 1997-08-18 | 1999-02-25 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von Amino- und/oder Phenoplasten |
| US6497959B1 (en) * | 2000-03-30 | 2002-12-24 | General Electric Company | Use of dendrimers as a processing aid and surface modifier for thermoplastic resins |
| DE10047717A1 (de) * | 2000-09-27 | 2002-04-18 | Basf Ag | Hydrophile, offenzellige, elastische Schaumstoffe auf Basis von Melamin/Formaldehyd-Harzen, ihre Herstellung und ihre Verwendung in Hygieneartikeln |
| CN1216679C (zh) * | 2003-04-10 | 2005-08-31 | 上海化工研究院 | 微胶囊包覆聚磷酸铵的制备方法 |
| DE10335957A1 (de) * | 2003-08-04 | 2005-02-24 | Basf Ag | Formteile aus Melamin/Formaldehyd-Schaumstoffen mit geringer Formaldehyd-Emission |
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- 2006-06-12 US US11/917,481 patent/US20080197524A1/en not_active Abandoned
- 2006-06-12 CN CN2006800211171A patent/CN101198646B/zh active Active
- 2006-06-12 KR KR1020087000863A patent/KR101328822B1/ko active IP Right Grant
- 2006-06-12 EP EP06763637.3A patent/EP1893674B1/de active Active
- 2006-06-12 WO PCT/EP2006/063082 patent/WO2006134083A1/de active Application Filing
- 2006-06-12 ES ES06763637T patent/ES2426344T3/es active Active
- 2006-06-12 PL PL06763637T patent/PL1893674T3/pl unknown
- 2006-06-12 JP JP2008516292A patent/JP5284085B2/ja active Active
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| Publication number | Publication date |
|---|---|
| WO2006134083A1 (de) | 2006-12-21 |
| ES2426344T3 (es) | 2013-10-22 |
| PL1893674T3 (pl) | 2014-01-31 |
| DE102005027552A1 (de) | 2006-12-21 |
| CN101198646B (zh) | 2011-03-02 |
| EP1893674B1 (de) | 2013-08-14 |
| EP1893674A1 (de) | 2008-03-05 |
| CN101198646A (zh) | 2008-06-11 |
| KR101328822B1 (ko) | 2013-11-13 |
| US20080197524A1 (en) | 2008-08-21 |
| JP2008544005A (ja) | 2008-12-04 |
| KR20080026605A (ko) | 2008-03-25 |
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