JP5242572B2 - フルオロポリマー分散体の調製及び安定化 - Google Patents
フルオロポリマー分散体の調製及び安定化 Download PDFInfo
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- JP5242572B2 JP5242572B2 JP2009528403A JP2009528403A JP5242572B2 JP 5242572 B2 JP5242572 B2 JP 5242572B2 JP 2009528403 A JP2009528403 A JP 2009528403A JP 2009528403 A JP2009528403 A JP 2009528403A JP 5242572 B2 JP5242572 B2 JP 5242572B2
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- Prior art keywords
- carbon atoms
- carbosilane
- surfactant
- group
- fluorinated
- Prior art date
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 53
- 125000002947 alkylene group Chemical group 0.000 claims description 17
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- 125000001931 aliphatic group Chemical group 0.000 claims description 7
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- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
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- 239000011734 sodium Substances 0.000 description 3
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- 239000005977 Ethylene Substances 0.000 description 2
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- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
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- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
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- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- KOPQZJAYZFAPBC-UHFFFAOYSA-N propanoyl propaneperoxoate Chemical compound CCC(=O)OOC(=O)CC KOPQZJAYZFAPBC-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/531,745 | 2006-09-14 | ||
| US11/531,745 US7678859B2 (en) | 2006-09-14 | 2006-09-14 | Preparation and stabilization of fluoropolymer dispersions |
| PCT/US2007/077851 WO2008033721A1 (en) | 2006-09-14 | 2007-09-07 | Preparation and stabilization of fluoropolymer dispersions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010503755A JP2010503755A (ja) | 2010-02-04 |
| JP2010503755A5 JP2010503755A5 (enExample) | 2010-10-14 |
| JP5242572B2 true JP5242572B2 (ja) | 2013-07-24 |
Family
ID=39184116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009528403A Expired - Fee Related JP5242572B2 (ja) | 2006-09-14 | 2007-09-07 | フルオロポリマー分散体の調製及び安定化 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7678859B2 (enExample) |
| EP (1) | EP2069407B1 (enExample) |
| JP (1) | JP5242572B2 (enExample) |
| CN (1) | CN101516919B (enExample) |
| AT (1) | ATE487743T1 (enExample) |
| DE (1) | DE602007010491D1 (enExample) |
| WO (1) | WO2008033721A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8080621B2 (en) * | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| EP3059265B1 (en) | 2015-02-23 | 2020-10-07 | 3M Innovative Properties Company | Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers |
| CN107849200B (zh) * | 2015-07-13 | 2020-07-28 | 3M创新有限公司 | 氟化嵌段共聚物 |
| JP7353267B2 (ja) | 2017-08-11 | 2023-09-29 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ素ポリマーの水性分散液を安定化させる方法 |
| CN118146601A (zh) * | 2019-07-23 | 2024-06-07 | 大金工业株式会社 | 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3642742A (en) * | 1969-04-22 | 1972-02-15 | Du Pont | Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers |
| US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
| US3855191A (en) * | 1973-04-04 | 1974-12-17 | Du Pont | Polytetrafluoroethylene molding powders of tetrafluoroethylene and perfluoro (alkyl vinyl ether) copolymer |
| US3879302A (en) * | 1973-07-10 | 1975-04-22 | Ebert Michael | Fluorocarbon-based sealing compound |
| GB1520421A (en) * | 1975-10-09 | 1978-08-09 | Dow Corning Ltd | Organosilicon compounds |
| DE2639109A1 (de) * | 1976-08-31 | 1978-03-09 | Hoechst Ag | Copolymerisate des tetrafluoraethylens und verfahren zu deren herstellung |
| DE3135598A1 (de) * | 1981-09-09 | 1983-03-17 | Hoechst Ag, 6000 Frankfurt | "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver" |
| US4588796A (en) * | 1984-04-23 | 1986-05-13 | E. I. Du Pont De Nemours And Company | Fluoroolefin polymerization process using fluoroxy compound solution as initiator |
| JPS6134032A (ja) * | 1984-07-25 | 1986-02-18 | Daikin Ind Ltd | フツ素樹脂被覆用組成物 |
| US4861845A (en) * | 1988-03-10 | 1989-08-29 | E. I. Du Pont De Nemours And Company | Polymerization of fluoroolefins |
| GB8819567D0 (en) * | 1988-08-17 | 1988-09-21 | Dow Corning Ltd | Carbosilane surfactants |
| US5453477A (en) * | 1992-05-01 | 1995-09-26 | Alliedsignal Inc. | Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite |
| DE4320920C1 (de) * | 1993-06-24 | 1994-06-16 | Goldschmidt Ag Th | Silane mit hydrophilen Gruppen, deren Herstellung und Verwendung als Tenside in wäßrigen Medien |
| DE4330059C1 (de) * | 1993-09-06 | 1994-10-20 | Goldschmidt Ag Th | Silane mit hydrophilen Gruppen, deren Herstellung und Verwendung als Tenside in wäßrigen Medien |
| DE4335705A1 (de) | 1993-10-20 | 1995-04-27 | Hoechst Ag | Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung |
| DE4433139A1 (de) * | 1994-09-16 | 1996-03-21 | Thera Ges Fuer Patente | Hydrophilierte Zahnabdruckmassen |
| DE4437886A1 (de) * | 1994-10-22 | 1996-07-04 | Max Planck Gesellschaft | Saccharidmodifizierte Silane und Carbosilane |
| US5623038A (en) * | 1994-12-14 | 1997-04-22 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation thereof |
| US5478905A (en) * | 1995-02-06 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene/hexafluoropropylene copolymers |
| WO1996024622A1 (en) | 1995-02-10 | 1996-08-15 | Alliedsignal Inc. | Production of fluoropolymers, fluoropolymer suspension and polymer formed therefrom |
| US5955556A (en) | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5704839A (en) | 1996-01-30 | 1998-01-06 | Lord Corporation | Elastomeric torsional drive coupling with secondary damping element |
| TW494125B (en) * | 1997-07-11 | 2002-07-11 | Rohm And Haas Compary | Preparation of fluorinated polymers |
| DE19824188A1 (de) * | 1998-05-29 | 1999-12-02 | Bayer Ag | Wäßrige Zubereitung zur Behandlung mineralischer Baustoffe |
| US6103844A (en) | 1998-06-08 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Polymerization of fluoromonomers in carbon dioxide |
| RU2158274C1 (ru) | 1999-08-24 | 2000-10-27 | ОАО "Кирово-Чепецкий химический комбинат имени Б.П.Константинова" | Способ получения эластичного сополимера винилиденфторида с 25-30 мол.% гексафторпропилена |
| US6512063B2 (en) * | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| CA2445998A1 (en) | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| JP4624646B2 (ja) * | 2001-05-02 | 2011-02-02 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロポリマーを製造するための連鎖移動剤としてのエーテルの存在下での水性乳化重合 |
| US6841616B2 (en) | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| ITMI20032377A1 (it) * | 2003-12-04 | 2005-06-05 | Solvay Solexis Spa | Copolimeri del tfe. |
-
2006
- 2006-09-14 US US11/531,745 patent/US7678859B2/en not_active Expired - Fee Related
-
2007
- 2007-09-07 AT AT07814742T patent/ATE487743T1/de not_active IP Right Cessation
- 2007-09-07 DE DE602007010491T patent/DE602007010491D1/de active Active
- 2007-09-07 JP JP2009528403A patent/JP5242572B2/ja not_active Expired - Fee Related
- 2007-09-07 EP EP07814742A patent/EP2069407B1/en not_active Not-in-force
- 2007-09-07 CN CN2007800338035A patent/CN101516919B/zh not_active Expired - Fee Related
- 2007-09-07 WO PCT/US2007/077851 patent/WO2008033721A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010503755A (ja) | 2010-02-04 |
| US20080097060A1 (en) | 2008-04-24 |
| EP2069407A1 (en) | 2009-06-17 |
| WO2008033721A1 (en) | 2008-03-20 |
| EP2069407A4 (en) | 2009-11-11 |
| CN101516919B (zh) | 2012-08-08 |
| DE602007010491D1 (de) | 2010-12-23 |
| CN101516919A (zh) | 2009-08-26 |
| EP2069407B1 (en) | 2010-11-10 |
| US7678859B2 (en) | 2010-03-16 |
| ATE487743T1 (de) | 2010-11-15 |
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