JP5046626B2 - Mold tube for continuous casting of metal - Google Patents

Mold tube for continuous casting of metal Download PDF

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JP5046626B2
JP5046626B2 JP2006323430A JP2006323430A JP5046626B2 JP 5046626 B2 JP5046626 B2 JP 5046626B2 JP 2006323430 A JP2006323430 A JP 2006323430A JP 2006323430 A JP2006323430 A JP 2006323430A JP 5046626 B2 JP5046626 B2 JP 5046626B2
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cooling
mold tube
groove
mold
cooling groove
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JP2007152432A (en
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ハンス−ギュンター・ヴォーバー
ゲルハルト・フーゲンシュット
ディートマー・コルベック
ライムント・ボルト
フランク・マイヴァルト
ダニエル・ライネルト
ハンス−ディルク・ピヴォヴァール
ディルク・ローデ
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ケイエムイー・ジャーマニー・アクチエンゲゼルシャフト・ウント・コンパニー・コマンディトゲゼルシャフト
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/041Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for vertical casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/055Cooling the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/124Accessories for subsequent treating or working cast stock in situ for cooling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)

Abstract

The die has cooling grooves (2, 2c) over at least part of the outside surface and the depth and/or width of the grooves is greatest in the centre of a side wall of the die and decreases towards the corner areas of the side wall. There are preferably no cooling grooves in the area of 10 to 15 mm from the radius of the corner areas. The width/depth ratio for the cooling grooves is between 1 and 4.

Description

この発明は、特許請求項1の上位概念の特徴事項をもつ金属を連続鋳造する金型に関する。 The present invention relates to a mold pipe for continuously casting a metal having the features of the superordinate concept of claim 1.

高い溶融点を備える鋼或いは他の金属から形状を鋳造する銅或いは銅合金製の管状金型は先行技術において数倍に記載されていた。金型管は通常には水平横断面において金型管の内部円錐形状に基づいて連続成形方向に増大する均一な壁厚を有する。この内部円錐形状はストランドの凝固状態やストランドパラメータに適合している。連続鋳造材料の始まる凝固の直後に、つまりメニスカスの直接下部に、それは横断面にわたり三次元に鋳造された熱流出に基づいて鋳造ストランドの強く異なって鋳造された冷却状態を生じる。金型管の隅において幾何学的関係に基づいて特に大きい熱量が流出されるから、そこに特に強いストランド凝固殻成長とそれに伴う特に強い収縮が生じる。金型管の側壁には、熱流出は、ここで同時により高い熱流が現れるにもかかわらず、通常には僅かである。局部的に異なる冷却の結果は、不均一なストランド凝固殻成長であり、それはストランド凝固殻に材料応力と亀裂を生じて、それによってストランド湯漏れの危険が高まる。   Tubular molds made of copper or copper alloys that cast shapes from steel or other metals with high melting points have been described several times in the prior art. The mold tube usually has a uniform wall thickness that increases in the continuous molding direction on the horizontal cross section based on the internal cone shape of the mold tube. This internal cone shape is adapted to the solidification state of the strand and the strand parameters. Immediately after the initial solidification of the continuous casting material, ie directly below the meniscus, it results in a strongly differently cast cooling state of the cast strands based on the heat flow cast in three dimensions across the cross section. A particularly large amount of heat flows out at the corners of the mold tube based on the geometric relationship, which results in particularly strong strand solidification shell growth and associated strong contraction. On the side wall of the mold tube, the heat outflow is usually slight, although a higher heat flow appears at the same time here. The result of locally different cooling is non-uniform strand solidification shell growth, which creates material stresses and cracks in the strand solidification shell, thereby increasing the risk of strand leakage.

出来るだけ均質熱搬出を得て、それにより高い鋳造出力の前提条件を作り出すために、既に一連の提案が成されていた。例えば、独逸特許出願公開第3621073号明細書(特許文献1)から、弓状側面のみが冷却溝を備えて、これに対して隅領域は冷却溝を備えていない金型が公知である。冷却は特にメニスカスの領域において高められた、それは独逸特許出願公開第3411359号明細書(特許文献2)と日本特開2003−311377公報(特許文献5)にも記載されている。欧州特許第1468760号明細書(特許文献3)も、冷却出力の改善と鋳造速度の上昇とを取り扱っていて、冷却通路は銅管の外表面の65%〜95%を必要とし、この場合に銅管は同時に全周辺にわたり且つ実質的に全長にわたり支持外被を備えている。垂直に振動する連続鋳造型では、逸特許第19581547号明細書(特許文献3)が内面に窪み或いは下降部を備えることを提案し、その窪み或いは下降部は安定な運転状態で把握されたメニスカスの下部の15mmから200mmまでの距離に配置されている。それによって同様に安定な鋳造がより早い速度で可能とされる。すべてのこれらの初めは理想的熱流分布の十分な算出を受けられない。
独逸特許出願公開第3621073号明細書 独逸特許出願公開第3411359号明細書 欧州特許第1468760号明細書 逸特許第19581547号明細書 日本特開2003−311377公報 日本特開平03−000453号公報
A series of proposals have already been made in order to obtain as much heat output as possible and thereby create the preconditions for high casting power. For example, from German Patent Application Publication No. 3621073 (Patent Document 1), a mold is known in which only the arcuate side surface is provided with cooling grooves, whereas the corner region is not provided with cooling grooves. Cooling was enhanced particularly in the area of the meniscus, which is also described in German Patent Application Publication No. 3411359 (Patent Document 2) and Japanese Patent Application Laid-Open No. 2003-311377 (Patent Document 5) . EP 1468760 (Patent Document 3) also deals with improving cooling output and increasing casting speed, and the cooling passage requires 65% to 95% of the outer surface of the copper tube, in this case The copper tube is simultaneously provided with a support jacket over the entire periphery and substantially over the entire length. In a continuous casting mold that vibrates vertically, Hei Patent No. 19581547 (Patent Document 3) proposes that the inner surface is provided with a depression or a descending part, and the depression or the descending part is grasped in a stable operating state. It is arranged at a distance of 15 mm to 200 mm at the lower part of. This likewise allows stable casting at a faster speed. All these beginnings do not receive a sufficient calculation of the ideal heat flow distribution.
German Patent Application Publication No. 3621073 German Patent Application No. 3411359 Specification European Patent No. 1468760 No. 19581547 specification Japanese Patent Laid-Open No. 2003-311377 Japanese Unexamined Patent Publication No. 03-000453

この発明の課題は、先行技術から出発して、ストランド冷却の均質性が、成果において高い鋳造出力と良いストランド品質を実現するために、さらに上昇されて、そのうえ、金型壁内部の応力を減少させるのに役立つ金型を用意することである。 The object of the present invention is that, starting from the prior art, the homogeneity of the strand cooling is further increased in order to achieve a high casting power and good strand quality in the results, as well as the stress inside the mold tube wall. It is to prepare a mold tube that helps to reduce.

この課題は、特許請求項1の特徴部分を備える金型により解決される。 This problem is solved by a die tube with the characterizing part of patent claim 1.

この発明の好ましい構成は、従属請求項の対象である。   Preferred configurations of the invention are the subject matter of the dependent claims.

この発明による金型では、金型の冷却作用がストランドの熱提供に一致して、それにより均一な冷却を生じるように最適化されることが、本質である。これは、冷却溝の深さと幅が金型の側壁の中心で最大であり、側壁の隅領域の方向に減少されることによって達成される。冷却溝の横断面が側壁の中心領域では側壁の縁領域より大きいことが重大である。この発明による技術や形式において冷却溝を設けることによって側壁に生じる最高比較応力が明らかに減少され得ることがわかった。理想的弾性剛性算定は比較応力が504MPaから348MPaまでの30%以上だけ減少され得ることを確認した。この主張は、130×130mmの金型横断面に関連し、金型管は溝なしにこの発明により構成された溝を備える金型管に対向配置されている。金型管内のこの技術で達成された応力の減少は好ましくは耐用期間に影響を与えて、金型管の熱条件付きゆがみを減少させる。この発明による金型管はこの算出において各側壁には8個の溝を鋳造方向に延びる200mmの長さをもつ5mmの間隔に有する。中間溝は5mmの深さを有し、それに対して外側溝は12mm或いは8mmの幅にて4mmの深さを有する。側壁の隅領域には、溝が配置されていない。 In the mold tube according to the invention, it is essential that the cooling action of the mold tube is optimized to match the heat provision of the strands and thereby produce a uniform cooling. This is achieved by the cooling groove depth and width being greatest at the center of the mold tube sidewall and being reduced in the direction of the corner area of the sidewall. It is important that the cross-section of the cooling groove is larger in the central region of the side wall than in the edge region of the side wall. It has been found that by providing cooling grooves in the technique and type according to the present invention, the maximum comparative stress produced on the side walls can be clearly reduced. Ideal elastic stiffness calculations confirmed that the comparative stress can be reduced by more than 30% from 504 MPa to 348 MPa. This allegation relates to a mold cross section of 130 × 130 mm, the mold tube being placed opposite the mold tube with a groove constructed according to the invention without a groove. The stress reduction achieved with this technique in the mold tube preferably affects the service life and reduces the thermal conditional distortion of the mold tube. In this calculation, the mold tube according to the present invention has 8 grooves on each side wall at a distance of 5 mm with a length of 200 mm extending in the casting direction. The intermediate groove has a depth of 5 mm, whereas the outer groove has a depth of 4 mm with a width of 12 mm or 8 mm. No groove is disposed in the corner region of the side wall.

冷却溝の具体的実施例にとってその深さと幅に関して、冷却幾何学形状はそれにより形成された熱流に出来るだけ良く一致させて、それによってさらに均質な温度区域が達成され得て、それがこれまでは不十分にしか達成されないことが、重大である。冷却溝が熱提供が最高である側壁の中心に深く且つ幅広く又はそのいずれか一方に形成され、つまりs隅半径付近領域よりも大きな横断面を有することが重要である。   For a specific embodiment of the cooling groove, with respect to its depth and width, the cooling geometry is matched as closely as possible to the heat flow formed thereby, so that a more homogeneous temperature zone can be achieved, It is crucial that is only achieved poorly. It is important that the cooling groove be formed deep and / or broadly in the center of the side wall where heat delivery is highest, i.e. having a larger cross section than the region near the s corner radius.

特に半径隅領域から10mmから15mmまでの間隔には、側壁に冷却溝が設けられていなく、冷却をここで高めなく且つ金型の剛性を不必要に弱めない。冷却溝が3mm〜6mmの深さを有するときに、最善の成果が達成され得る。この場合には、冷却溝最高深さと金型管内面の間の6mmの残存壁厚さが下回らない。   Especially in the interval from 10 mm to 15 mm from the radius corner region, no cooling groove is provided on the side wall, so that the cooling is not increased here and the rigidity of the mold is not unnecessarily reduced. Best results can be achieved when the cooling groove has a depth of 3 mm to 6 mm. In this case, the remaining wall thickness of 6 mm between the maximum depth of the cooling groove and the inner surface of the mold tube does not fall below.

冷却溝の幅は特に5mm〜20mmの間で選択すべきである。   The width of the cooling groove should be chosen in particular between 5 mm and 20 mm.

冷却溝の数を金型管の異なるフォーマット/寸法に適合するために、形成された溝寸法にとって、金型管の100mm側面当たり4〜10個の冷却溝の数が好ましいものと解った。   In order to adapt the number of cooling grooves to the different formats / dimensions of the mold tube, 4-10 cooling grooves per 100 mm side of the mold tube were found to be preferred for the groove size formed.

流体力学的に1と4の間の冷却溝の幅/深さの比が特に有利なものとみなされる。それから偏差する関係は流れ関係に不利な影響を有し、それによって溶湯面範囲における金型管の冷却出力並びに剛性に不利な影響を有する。冷却溝は、そこで応力ピークを回避するために、溝壁に対して小さいトランスミッション半径を備えている。   Hydrodynamic groove width / depth ratios between 1 and 4 are considered particularly advantageous. Deviations from it have a detrimental effect on the flow relationship, and thereby have a detrimental effect on the cooling power and stiffness of the mold tube in the melt surface area. The cooling groove has a small transmission radius relative to the groove wall to avoid stress peaks there.

冷却溝は理想的には入口出口領域には冷却水の流れ最適化と圧力損失の減少に貢献する半径を有する。   The cooling groove ideally has a radius in the inlet / outlet region that contributes to cooling water flow optimization and reduced pressure loss.

冷却溝の有効と見なされた配列では、その対向する溝中心から測定された間隔が10mmと25mmの間にある。冷却溝の幅に対する溝中間間隔の1.2〜3の比は驚くべき良い成果を提供する。   In an arrangement deemed effective for the cooling groove, the distance measured from its opposite groove center is between 10 mm and 25 mm. A ratio of the groove intermediate spacing to the cooling groove width of 1.2-3 provides surprisingly good results.

基本的には、冷却溝の幅が側壁の中心に対してより大きくなっていて、さらに深さが中心に対して増加することを得ようと努められている。異なる冷却溝幾何学形状は金型の機械加工によって或いは金型の変形における切り屑なし加工によっても製造され得る。 Basically, it is sought to obtain that the width of the cooling groove is larger with respect to the center of the sidewall and that the depth further increases with respect to the center. Different cooling groove geometries can also be prepared by no machining chips in machining or by deformation of the mold tube mold tube.

冷却溝がメニスカス目標位置の上部のおよそ50mmで開始して、メニスカス目標位置の下およそ300mmまで延びている範囲に配置されているときに、有効である、というのは、この領域では最大熱流密度が生じ、それにより金型の側壁における応力は最大であるからである。鋳造方向により深く位置する領域、即ちメニスカス目標位置の下部の300mmより大きい間隔の領域は確かに同様に冷却されなければならなく、無論、既に形成されたストランド殻に基づいて温度不均質性はこの発明による構成された溝が強制的にこの下領域に於いて必要であるより大きくない。この発明による構成された溝がメニスカス目標位置の上部のおよそ50mmで開始して、メニスカス目標位置の下およそ300mmまで延びているときに、卓越した成果が既に達成される。 It is effective when the cooling groove is arranged in a range starting about 50 mm above the meniscus target position and extending to about 300 mm below the meniscus target position, in this region the maximum heat flow density This is because the stress on the side wall of the mold tube is maximum. The region deeper in the casting direction, i.e. the region with a spacing of more than 300 mm below the meniscus target position, must certainly be cooled as well, and of course the temperature inhomogeneity is based on the already formed strand shell. The constructed groove according to the invention is not forced larger than necessary in this lower region. Excellent results are already achieved when the constructed groove according to the invention starts approximately 50 mm above the meniscus target position and extends to approximately 300 mm below the meniscus target position.

この発明は、次に図面に図示された実施例に基づいて詳細に説明される。図1aと図1bは詳細に図示されていない形式で水槽に位置されている金型管1を一方では斜視図で示し且つ一方では斜視図の拡大で示す。この金型管1の特殊性は、金型管1の外面3に形成されている特殊に構成された冷却溝2である。この冷却溝2は金型管1の全長にわたり延びていなく、むしろ専ら金型管1の上鋳造側領域に存在する。この実施例では、冷却溝2は200mの長さを有する。この冷却溝2はメニスカス目標位置の領域に存在し、この場合にはこれは図示された冷却溝2の上四分の一に位置する。この金型管1の冷却溝2における特殊性は、これら金属管がすべて同じ幅と深さではなく、むしろ幅と深さにおいて異なっていることである。この実施例では隅領域4に向いた外部冷却溝2aと2bはそれぞれの側壁の中間領域に位置する冷却溝2cより狭い。 中間冷却溝2cが例えば12mmの幅を有する間に、四つの外部冷却溝2aと2bは例えば8mmの幅を有する。すべての冷却溝2a、2b、2cは同じ長さを有する。けれども、それは冷却溝2a、2b、2cの幅ばかりではなく、むしろその深さも同じである。それで、冷却溝2a、2b、2cが入口出口領域において、即ちそれぞれに端面に 1つの半径5を有する。個々の冷却溝2a、2b、2cの最高深さに対する半径2の移行が水平線によって認識される。中間冷却溝2cの場合には深さが最大に認識できる。外側に隣接した冷却溝2bの深さは多少より浅い。この深さは隅領域4に向いた外部冷却溝2aでは最小である。   The invention will now be described in detail on the basis of an embodiment illustrated in the drawings. FIGS. 1a and 1b show, on the one hand, a perspective view and, on the other hand, an enlarged perspective view, of a mold tube 1 which is located in a water tank in a manner not shown in detail. The peculiarity of this mold tube 1 is a specially configured cooling groove 2 formed on the outer surface 3 of the mold tube 1. The cooling groove 2 does not extend over the entire length of the mold tube 1 but rather exists exclusively in the upper casting side region of the mold tube 1. In this embodiment, the cooling groove 2 has a length of 200 m. This cooling groove 2 exists in the region of the meniscus target position, which in this case is located in the upper quarter of the cooling groove 2 shown. The peculiarity of the mold tube 1 in the cooling groove 2 is that these metal tubes are not all the same width and depth, but rather differ in width and depth. In this embodiment, the external cooling grooves 2a and 2b facing the corner region 4 are narrower than the cooling groove 2c located in the intermediate region of each side wall. The four external cooling grooves 2a and 2b have a width of, for example, 8 mm, while the intermediate cooling groove 2c has a width of, for example, 12 mm. All the cooling grooves 2a, 2b, 2c have the same length. However, it is not only the width of the cooling grooves 2a, 2b, 2c, but rather the depth. Thus, the cooling grooves 2a, 2b, 2c have one radius 5 in the inlet / outlet region, i.e. each end face. The transition of radius 2 with respect to the maximum depth of the individual cooling grooves 2a, 2b, 2c is recognized by the horizontal line. In the case of the intermediate cooling groove 2c, the depth can be recognized to the maximum. The depth of the cooling groove 2b adjacent to the outside is somewhat shallower. This depth is minimal in the external cooling groove 2 a facing the corner region 4.

隅領域4は冷却溝を備えていない。金型管1は詳細に図示されていない水案内薄板により水槽内に固定オされているので、冷却水は個々の冷却通路2a、2b、2cに押し込まれる。この水案内薄板は、金型管が水隙間内の中心に保持されているように配置されている。   The corner region 4 is not provided with a cooling groove. Since the mold tube 1 is fixed in the water tank by a water guide thin plate not shown in detail, the cooling water is pushed into the individual cooling passages 2a, 2b and 2c. The water guide thin plate is arranged so that the mold tube is held at the center in the water gap.

金型管1を斜視図で示す。A mold tube 1 is shown in a perspective view. 金型管1を拡大斜視図で示す。The mold tube 1 is shown in an enlarged perspective view.

符号の説明Explanation of symbols

1.....金型管
2.....溝、通路
3.....外面
4.....隅領域
5.....半径
1. . . . . Mold tube 2. . . . . Grooves, passages 3. . . . . External surface 4. . . . . Corner area 5. . . . . radius

Claims (8)

金型の外面(3)の少なくともある部分領域が冷却溝(2、2c)を備えている金属を連続鋳造する金型管において、冷却溝(2,2a,2b,2c)の深さと幅が金型(1)の側壁の中心で最大であり、側壁の隅領域の方向に減少されていて、一つの冷却溝(2,2a,2b,2c)の幅に対する溝中間間隔の比が1.2から3までの範囲に位置しており、冷却溝(2,2a,2b,2c)は3mmから8mmまでの深さを有し、冷却溝(2,2a,2b,2c)の範囲内の残壁厚さでは6mmより少なくないこと、100mm金型管側面当たり4〜10個の冷却溝(2,2a,2b,2c)が配置されていることを特徴とする金型The depth and width of the cooling groove (2, 2a, 2b, 2c) in a mold tube for continuously casting a metal in which at least a partial region of the outer surface (3) of the mold tube is provided with a cooling groove (2, 2c) Is the largest at the center of the side wall of the mold tube (1) and is reduced in the direction of the corner region of the side wall, and the ratio of the groove intermediate spacing to the width of one cooling groove (2, 2a, 2b, 2c) is Located in the range from 1.2 to 3, the cooling groove (2, 2a, 2b, 2c) has a depth from 3 mm to 8 mm, the range of the cooling groove (2, 2a, 2b, 2c) The mold tube is characterized in that the remaining wall thickness is not less than 6 mm, and 4 to 10 cooling grooves (2, 2a, 2b, 2c) are disposed per side surface of the 100 mm mold tube . 隅領域(4)の半径から10mmから15mmまでの間隔には冷却溝(2,2a,2b,2c)が側壁に配置されていないことを特徴とする請求項1に記載の金型2. The mold tube according to claim 1, wherein no cooling groove (2, 2 a, 2 b, 2 c) is arranged on the side wall at an interval of 10 mm to 15 mm from the radius of the corner region (4). 二つの冷却溝(2,2a,2b,2c)の溝中間間隔が10mmから25mmまでの範囲に位置することを特徴とする請求項1或いは請求項2に記載の金型3. The mold tube according to claim 1, wherein a groove intermediate distance between the two cooling grooves (2, 2 a, 2 b, 2 c) is located in a range from 10 mm to 25 mm . 一つの冷却溝(2,2a,2b,2c)の幅と深さの比が1から4までの範囲に位置することを特徴とする請求項1乃至のいずれか一項に記載の金型The mold according to any one of claims 1 to 3 , wherein the ratio of the width and the depth of one cooling groove (2, 2a, 2b, 2c) is located in the range of 1 to 4. Tube . 冷却溝(2,2a,2b,2c)は5mmから20mmまでの範囲の幅を有することを特徴とする請求項1乃至のいずれか一項に記載の金型The mold tube according to any one of claims 1 to 4 , characterized in that the cooling groove (2, 2a, 2b, 2c) has a width in the range of 5 mm to 20 mm. 冷却溝(2,2a,2b,2c)はメニスカス目標位置の上部の50mmで開始し、メニスカス目標位置の下に300mmまで延びている範囲に配置されていることを特徴とする請求項1乃至のいずれか一項に記載の金型Cooling channels (2, 2a, 2b, 2c) starts at the top of 50mm meniscus target location, claims 1 to 5, characterized by being disposed in a range extending up to 300mm below the meniscus target location The mold tube as described in any one of. 冷却溝(2,2a,2b,2c)は溝底において溝壁に対する移行半径を備えていることを特徴とする請求項1乃至のいずれか一項に記載の金型Cooling groove (2,2a, 2b, 2c) is a mold tube according to any one of claims 1 to 6, characterized in that it comprises a transition radius for groove wall at the groove bottom. 冷却溝(2,2a,2b,2c)はその入口と出口領域において半径(5)を有することを特徴とする請求項1乃至のいずれか一項に記載の金型Cooling channels (2, 2a, 2b, 2c) is a mold tube according to any one of claims 1 to 7, characterized in that it has a radius (5) in the region of its inlet and outlet.
JP2006323430A 2005-12-05 2006-11-30 Mold tube for continuous casting of metal Expired - Fee Related JP5046626B2 (en)

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DE502006005774D1 (en) 2010-02-11
CN1978091B (en) 2011-04-13
EP1792676A1 (en) 2007-06-06
BRPI0605174A (en) 2007-10-09
CN1978091A (en) 2007-06-13
CA2570085A1 (en) 2007-06-05
EP1792676B1 (en) 2009-12-30
KR20070058968A (en) 2007-06-11
ES2337281T3 (en) 2010-04-22
ATE453472T1 (en) 2010-01-15
RU2415731C2 (en) 2011-04-10
JP2007152432A (en) 2007-06-21
DE102006001812A1 (en) 2007-06-06
RU2006142826A (en) 2008-06-10
CA2570085C (en) 2012-07-10

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