JP5006783B2 - メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー - Google Patents

メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー Download PDF

Info

Publication number
JP5006783B2
JP5006783B2 JP2007520792A JP2007520792A JP5006783B2 JP 5006783 B2 JP5006783 B2 JP 5006783B2 JP 2007520792 A JP2007520792 A JP 2007520792A JP 2007520792 A JP2007520792 A JP 2007520792A JP 5006783 B2 JP5006783 B2 JP 5006783B2
Authority
JP
Japan
Prior art keywords
group
butene
alkyl
formula
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2007520792A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008506663A (ja
JP2008506663A5 (enExample
Inventor
レスコーニ，ルイジ
モルハルト，フリーデリケ
Original Assignee
バーゼル・ポリオレフィン・ゲーエムベーハー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by バーゼル・ポリオレフィン・ゲーエムベーハー filed Critical バーゼル・ポリオレフィン・ゲーエムベーハー
Publication of JP2008506663A publication Critical patent/JP2008506663A/ja
Publication of JP2008506663A5 publication Critical patent/JP2008506663A5/ja
Application granted granted Critical
Publication of JP5006783B2 publication Critical patent/JP5006783B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2007520792A 2004-07-13 2005-05-31 メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー Expired - Lifetime JP5006783B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04103351 2004-07-13
EP04103351.5 2004-07-13
US59066004P 2004-07-23 2004-07-23
US60/590,660 2004-07-23
PCT/EP2005/052486 WO2006005648A1 (en) 2004-07-13 2005-05-31 Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom

Publications (3)

Publication Number Publication Date
JP2008506663A JP2008506663A (ja) 2008-03-06
JP2008506663A5 JP2008506663A5 (enExample) 2008-07-10
JP5006783B2 true JP5006783B2 (ja) 2012-08-22

Family

ID=35115855

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007520792A Expired - Lifetime JP5006783B2 (ja) 2004-07-13 2005-05-31 メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー

Country Status (5)

Country Link
US (1) US8003743B2 (enExample)
EP (1) EP1765886A1 (enExample)
JP (1) JP5006783B2 (enExample)
CN (1) CN101023105A (enExample)
WO (1) WO2006005648A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1492825A1 (en) 2002-02-25 2005-01-05 Basell Polyolefine GmbH Process for the copolymerization of ethylene
JP2011515518A (ja) * 2008-03-20 2011-05-19 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ １−ブテン系ポリマー類の組成物類
JP5346075B2 (ja) * 2008-04-22 2013-11-20 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ １−ブテンターポリマー
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
WO2017150731A1 (ja) * 2016-03-04 2017-09-08 日本ポリエチレン株式会社 メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
PL3266825T3 (pl) 2016-07-07 2022-05-09 Basell Poliolefine Italia S.R.L. Kompozycja polimerowa butenu-1 o wysokim wskaźniku szybkości płynięcia
ES2909824T3 (es) 2016-07-07 2022-05-10 Basell Poliolefine Italia Srl Composición de polímero de 1-buteno que tiene un alto índice de fluidez en estado fundido
JP7700241B2 (ja) * 2020-12-16 2025-06-30 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ パイプ用軟質ブテン－１コポリマー
IL301347B1 (en) 2023-03-13 2025-12-01 Tadiran Consumer And Tech Products Ltd Apparatus and method for treating air

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE38044T1 (de) 1984-08-30 1988-11-15 Mitsui Petrochemical Ind Buten-1-polymer und seine verwendung.
USH179H (en) * 1984-11-28 1986-12-02 Polybutylene
WO1991002012A1 (en) 1989-08-03 1991-02-21 Exxon Chemical Patents Inc. Very high molecular weight polyethylene
ATE147761T1 (de) 1990-06-22 1997-02-15 Exxon Chemical Patents Inc Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
PL334470A1 (en) * 1997-11-12 2000-02-28 Montell Technology Company Bv Metalocenes and olefins polymerisation catalysts
DE19804970A1 (de) 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
CA2289026C (en) 1998-03-05 2008-11-18 Montell Technology Company B.V. Polybutene-1 (co)polymers and process for their preparation
US7141527B1 (en) 1999-09-22 2006-11-28 Basell Polyolefine Gmbh Catalyst system and process for the polymerization of olefins
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
WO2001048039A2 (en) 1999-12-28 2001-07-05 Basell Technology Company B.V. Process for the preparation of ethylene polymers
AU3538601A (en) * 1999-12-28 2001-07-09 Basell Technology Company B.V. Process for the preparation of ethylene polymers
ATE508135T1 (de) * 1999-12-28 2011-05-15 Basell Polyolefine Gmbh Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren
JP2003524013A (ja) 2000-02-24 2003-08-12 バセル テクノロジー カンパニー ビー．ブイ． オレフィン重合用助触媒として有用な有機金属化合物
KR20020007419A (ko) 2000-03-22 2002-01-26 간디 지오프레이 에이치. 이소택틱 프로필렌 중합체 및 감소된 이소택틱성을 갖는유연성 프로필렌 중합체의 열가소성 조성물 및 그 제조방법
KR100733191B1 (ko) 2000-08-22 2007-06-27 이데미쓰 고산 가부시키가이샤 1-부텐계 중합체 및 상기 중합체로 이루어진 성형체
WO2002100909A1 (en) 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP4571798B2 (ja) 2001-06-12 2010-10-27 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンの重合方法
DE60210089T2 (de) 2001-06-22 2006-10-19 Basell Polyolefine Gmbh Metallocene, verwendung in katalysatoren für olefinpolymerisation
US6930190B2 (en) 2001-08-01 2005-08-16 Basell Polyolefine Gmbh Process for the preparation of heterocyclic pentalene derivatives
DE60218059T2 (de) 2001-11-12 2007-08-30 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1-buten polymeren
EP1492825A1 (en) 2002-02-25 2005-01-05 Basell Polyolefine GmbH Process for the copolymerization of ethylene
DE60309020T2 (de) 2002-05-29 2007-05-10 Basell Poliolefine Italia S.R.L. Buten-1-(co)polymere und verfahren zu ihrer herstellung
US7390862B2 (en) * 2003-05-12 2008-06-24 Basell Polyolefine Gmbh Process for polymerizing 1-butene
WO2005095474A1 (en) * 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
JP2008501659A (ja) * 2004-06-04 2008-01-24 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 遷移金属化合物、リガンド、触媒組成物及びポリオレフィンを製造する方法

Also Published As

Publication number Publication date
JP2008506663A (ja) 2008-03-06
EP1765886A1 (en) 2007-03-28
CN101023105A (zh) 2007-08-22
US20080139762A1 (en) 2008-06-12
WO2006005648A1 (en) 2006-01-19
US8003743B2 (en) 2011-08-23

Similar Documents

Publication Publication Date Title
JP5584639B2 (ja) １−ブテンの重合方法
JP4758650B2 (ja) １−ブテンポリマーの製造方法
US7981993B2 (en) 1-butene ethylene copolymers
US7964679B2 (en) Process for the polymerization of alpha olefins
US7589160B2 (en) Process for preparing 1-butene polymers
US7943716B2 (en) Process for polymerizing 1-hexene or higher alpha-olefins
JP2005509062A6 (ja) １−ブテンを重合する方法および１−ブテンポリマー
JP2005509062A (ja) １−ブテンを重合する方法および１−ブテンポリマー
US7799871B2 (en) 1-butene polymers composition
JP5006783B2 (ja) メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー
CA2573984A1 (en) Process for producing fractionable 1-butene polymers
KR20090043545A (ko) 1-부텐 프로필렌 공중합체 조성물
KR20090043546A (ko) 1-부텐 프로필렌 공중합체 조성물
US20090234084A1 (en) Metallocene Compounds
KR20070032012A (ko) 메탈로센 화합물, 그의 제조에 사용되는 리간드, 1-부텐중합체의 제조 및 이로부터 제조된 1-부텐 중합체

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080519

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080519

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110201

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110426

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110509

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110531

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110607

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110701

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110708

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110727

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20110905

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120427

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120525

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150601

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Ref document number: 5006783

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term