JP4976607B2 - コンタクトレンズ用ゲル状洗浄剤 - Google Patents
コンタクトレンズ用ゲル状洗浄剤 Download PDFInfo
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- JP4976607B2 JP4976607B2 JP2012510051A JP2012510051A JP4976607B2 JP 4976607 B2 JP4976607 B2 JP 4976607B2 JP 2012510051 A JP2012510051 A JP 2012510051A JP 2012510051 A JP2012510051 A JP 2012510051A JP 4976607 B2 JP4976607 B2 JP 4976607B2
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- Prior art keywords
- cleaning agent
- cleaning
- modified silicone
- agent
- alcohol
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- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0078—Compositions for cleaning contact lenses, spectacles or lenses
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C13/00—Assembling; Repairing; Cleaning
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Physics & Mathematics (AREA)
- Ophthalmology & Optometry (AREA)
- Optics & Photonics (AREA)
- Eyeglasses (AREA)
- Detergent Compositions (AREA)
Description
適量の精製水に緩衝剤、EDTA・2Na、適宜選択した浸透圧調整剤を溶解させた水溶液に、ゲル化剤としてカルボキシビニルポリマーを加えて均一に分散させた後、可溶化剤、界面活性剤、ポリシリコーン−13の順に加えた。これに中和剤として水酸化ナトリウム水溶液を加えてゲル化させた後、精製水にて全量を100gとした。
(1)人工汚垢コンタクトレンズの作製
公知の涙液成分(蛋白質、脂質)からなる人工汚垢液に、あらかじめ化粧品(ファンデーション、マスカラ、アイシャドー(ウオータープルーフ))を付着させた試験用コンタクトレンズを浸漬して55℃で5時間加温し、次いでそのコンタクトレンズを70℃の純水中で16時間浸漬後、50℃で6時間乾燥させて人工汚垢コンタクトレンズを得た。
RGPCL:シード社製/シードUV−1
RGPCL(表面処理):シード社製/シードS−1
SCL:ジョンソンエンドジョンソン社製/アキュビュー2(グループIV)
SHCL(表面処理):チバビジョン社製/O2オプティクス(グループI)
人工汚垢コンタクトレンズの洗浄前のヘーズ値を測定(スガ試験機株式会社製:HGM−2DP)した後、表1に示した各洗浄剤で約30秒間(片面約15秒間)手指での擦り洗いを行った。擦り洗い後のコンタクトレンズのすすぎは、RGPCLでは流水(水道水)、SCL、SHCLではソフトコンタクトレンズ用保存剤(シード社製/ソフリンス)にて、各洗浄剤の残留感(ヌルヌル感)がなくなるまで(10〜20秒間)行ない自然乾燥させた。
*2.1,3−ブチレングリコール
*3.カルボキシビニルポリマー
*4.(メタ)アクリル酸アルキル共重合体
*5.α−オレフィンスルホン酸ナトリウム:株式会社ライオン リポランLB−440
(純分37%:純分換算後の配合量)
*6.アルキルグルコシド:コグニスジャパン株式会社 プランタケア2000UP
(純分50%:純分換算後の配合量)
*7. ポリオキシエチレンポリオキシプロピレンブロックポリマー
:旭電化工業株式会社 プルロニックF108
*8.プロピレングリコール
*9.トリメチルグリシン
◎;90%以上 ○;80〜90%未満 △;60〜80%未満 ▲;40〜60%未満 ×;40%未満
官能評価による触感・取扱い性を以下に示す3段階で評価した。
◎;洗浄しやすく取扱い性は良好
△;普通 ×;洗浄しにくく取扱い性は不良
*2)比較例1〜3の場合、浸透圧が2500mmol/kgと高いため、高含水率のSCLでは洗浄時にレンズ径が膨潤/収縮し、すすぎ時のレンズに著しい変形が生じた。
表面処理コンタクトレンズへの影響の評価として、レンズ表面を有機化合物で処理し、親水化した機能性表面を有するRGPCL(シード社製/シードS−1)、およびSHCL(チバビジョン社製/O2オプティクス)を用いた。
Claims (5)
- ABn型ブロック共重合体であるポリエーテル変性シリコーンオイル、可溶化剤およびゲル化剤を含むことを特徴とするコンタクトレンズ用ゲル状洗浄剤。
- 前記ABn型ブロック共重合体であるポリエーテル変性シリコーンオイルが、ABn型ブロック共重合体であるポリアルキレンオキシド変性シリコーンであることを特徴とする請求項1に記載のコンタクトレンズ用ゲル状洗浄剤。
- 前記ABn型ブロック共重合体であるポリエーテル変性シリコーンオイルがポリジメチルシロキサン−ポリアルキレンオキシドのABn型ブロック共重合体であり、かつ、前記可溶化剤が低級アルコールおよび/または液状多価アルコールであることを特徴とする請求項1に記載のコンタクトレンズ用ゲル状洗浄剤。
- 前記ポリジメチルシロキサン−ポリアルキレンオキシドのABn型ブロック共重合体におけるポリアルキレンオキシドがポリオキシエチレンまたはポリ(オキシエチレン−オキシプロピレン)共重合体であり、前記低級アルコールがエチルアルコール、プロピルアルコール、イソプロピルアルコールまたはベンジルアルコールであり、かつ、前記液状多価アルコールがエチレングリコール、プロピレングリコール、ジプロピレングリコール、1,3−ブタンジオールおよびグリセリンからなる群より選択された少なくとも1種類のアルコールであることを特徴とする請求項3に記載のコンタクトレンズ用ゲル状洗浄剤。
- 前記ABn型ブロック共重合であるポリエーテル変性シリコーンオイルの含有量が0.05〜0.50w/w%であることを特徴とする請求項1〜4のいずれか1項に記載のコンタクトレンズ用ゲル状洗浄剤。
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JP2010223356 | 2010-10-01 | ||
JP2010223356 | 2010-10-01 | ||
PCT/JP2011/065370 WO2012043004A1 (ja) | 2010-10-01 | 2011-07-05 | コンタクトレンズ用ゲル状洗浄剤 |
JP2012510051A JP4976607B2 (ja) | 2010-10-01 | 2011-07-05 | コンタクトレンズ用ゲル状洗浄剤 |
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JP (1) | JP4976607B2 (ja) |
KR (1) | KR101245997B1 (ja) |
CN (1) | CN102822725B (ja) |
HK (1) | HK1173230A1 (ja) |
MY (1) | MY159143A (ja) |
SG (1) | SG183211A1 (ja) |
WO (1) | WO2012043004A1 (ja) |
Families Citing this family (6)
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US9701927B2 (en) | 2013-01-31 | 2017-07-11 | Sharp Kabushiki Kaisha | Cleaning solution, cleaning tool, and cleaning kit |
KR101926226B1 (ko) * | 2016-05-31 | 2019-02-26 | 한국화학연구원 | 알코올을 함유하지 않는 항균성이 우수한 안경용 세정제 조성물 |
CN106381241A (zh) * | 2016-08-30 | 2017-02-08 | 东兴华鸿光学科技有限公司 | 用于眼镜镜片的清洁除菌膏 |
CN107929790A (zh) * | 2017-11-08 | 2018-04-20 | 常州武城服饰有限公司 | 一种多功能隐形眼镜护理液 |
JP7314947B2 (ja) * | 2018-09-18 | 2023-07-26 | 日油株式会社 | コンタクトレンズ用処理溶液 |
KR102368898B1 (ko) * | 2020-05-18 | 2022-03-02 | 주식회사 태경코엠 | 알칸디올 또는 에틸헥실글리세린을 포함하는 세정제 조성물 |
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JPH05179293A (ja) * | 1991-12-26 | 1993-07-20 | Kao Corp | 洗浄剤組成物 |
JP2006011418A (ja) * | 2004-05-26 | 2006-01-12 | Seed Co Ltd | コンタクトレンズ用ゲル状洗浄剤 |
JP2006052319A (ja) * | 2004-08-11 | 2006-02-23 | P & P F:Kk | 透明ゲル状洗浄料 |
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CN1081669C (zh) * | 1993-06-18 | 2002-03-27 | 聚合物技术公司 | 清洗和湿润隐形眼镜的组合物 |
US6872695B1 (en) * | 2000-10-06 | 2005-03-29 | Bausch & Lomb Incorporated | Method for in-eye cleaning of contact lens comprising polymeric beads |
JP5179293B2 (ja) * | 2008-08-25 | 2013-04-10 | 京楽産業.株式会社 | 遊技機 |
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JPS58100119A (ja) * | 1981-08-13 | 1983-06-14 | バ−ンズ−ハインド・フア−マシユ−テイカルズ・インコ−ポレ−テツド | 洗浄用組成物 |
JPH05179293A (ja) * | 1991-12-26 | 1993-07-20 | Kao Corp | 洗浄剤組成物 |
JP2006011418A (ja) * | 2004-05-26 | 2006-01-12 | Seed Co Ltd | コンタクトレンズ用ゲル状洗浄剤 |
JP2006052319A (ja) * | 2004-08-11 | 2006-02-23 | P & P F:Kk | 透明ゲル状洗浄料 |
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CN102822725A (zh) | 2012-12-12 |
KR20120099289A (ko) | 2012-09-07 |
MY159143A (en) | 2016-12-15 |
CN102822725B (zh) | 2013-10-30 |
SG183211A1 (en) | 2012-09-27 |
JPWO2012043004A1 (ja) | 2014-02-06 |
HK1173230A1 (en) | 2013-05-10 |
WO2012043004A1 (ja) | 2012-04-05 |
KR101245997B1 (ko) | 2013-03-20 |
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