JP4953324B2 - 電気化学センサ - Google Patents
電気化学センサ Download PDFInfo
- Publication number
- JP4953324B2 JP4953324B2 JP2008510629A JP2008510629A JP4953324B2 JP 4953324 B2 JP4953324 B2 JP 4953324B2 JP 2008510629 A JP2008510629 A JP 2008510629A JP 2008510629 A JP2008510629 A JP 2008510629A JP 4953324 B2 JP4953324 B2 JP 4953324B2
- Authority
- JP
- Japan
- Prior art keywords
- matrix
- electrochemical sensor
- electrolyte
- acid
- sensor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003792 electrolyte Substances 0.000 claims abstract description 40
- 239000002253 acid Substances 0.000 claims abstract description 18
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims abstract description 7
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011159 matrix material Substances 0.000 claims description 41
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 32
- 239000003054 catalyst Substances 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 235000011007 phosphoric acid Nutrition 0.000 claims description 6
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- 229910010293 ceramic material Inorganic materials 0.000 claims description 3
- 230000009969 flowable effect Effects 0.000 claims 1
- 229910000510 noble metal Inorganic materials 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 14
- 238000009792 diffusion process Methods 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 239000010411 electrocatalyst Substances 0.000 description 3
- 206010006326 Breath odour Diseases 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000004135 Bone phosphate Substances 0.000 description 1
- 208000001408 Carbon monoxide poisoning Diseases 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000011214 refractory ceramic Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/004—CO or CO2
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/48—Biological material, e.g. blood, urine; Haemocytometers
- G01N33/483—Physical analysis of biological material
- G01N33/497—Physical analysis of biological material of gaseous biological material, e.g. breath
- G01N33/4972—Determining alcohol content
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Pathology (AREA)
- Immunology (AREA)
- General Physics & Mathematics (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Biophysics (AREA)
- Urology & Nephrology (AREA)
- Hematology (AREA)
- Combustion & Propulsion (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Hybrid Cells (AREA)
- Catalysts (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0509632.6 | 2005-05-11 | ||
| GBGB0509632.6A GB0509632D0 (en) | 2005-05-11 | 2005-05-11 | Electrochemical sensors |
| PCT/GB2006/001662 WO2006120409A2 (en) | 2005-05-11 | 2006-05-05 | Electrochemical sensors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008541082A JP2008541082A (ja) | 2008-11-20 |
| JP2008541082A5 JP2008541082A5 (enExample) | 2012-03-08 |
| JP4953324B2 true JP4953324B2 (ja) | 2012-06-13 |
Family
ID=34685455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008510629A Active JP4953324B2 (ja) | 2005-05-11 | 2006-05-05 | 電気化学センサ |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20090194417A1 (enExample) |
| EP (2) | EP1886128B1 (enExample) |
| JP (1) | JP4953324B2 (enExample) |
| CN (1) | CN101203749B (enExample) |
| AT (1) | ATE501434T1 (enExample) |
| DE (1) | DE602006020561D1 (enExample) |
| GB (1) | GB0509632D0 (enExample) |
| WO (1) | WO2006120409A2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2010000139A (es) | 2007-07-05 | 2010-06-01 | Alcotek Inc | Detector de alcohol para la boca. |
| US20120241319A1 (en) * | 2011-03-25 | 2012-09-27 | Life Safety Distribution Ag | Gas Detector Having Bipolar Counter/Reference Electrode |
| DE102012108997A1 (de) * | 2012-09-24 | 2014-03-27 | Heinrich-Heine-Universität Düsseldorf | Sensoranordnung und Verfahren zum Herstellen einer Sensoranordnung |
| AU2014292882A1 (en) | 2013-07-26 | 2016-01-21 | Alcotek, Inc. | Method of compressing fuel cell electrodes, resultant fuel cell, and a housing for the fuel cell which utilizes electrolyte reservoirs |
| US10468697B2 (en) | 2013-07-26 | 2019-11-05 | Alcotek, Inc. | Alcohol detecting fuel cell |
| JP6429193B2 (ja) * | 2015-02-10 | 2018-11-28 | 光明理化学工業株式会社 | アルコールセンサ |
| ES2597129B1 (es) * | 2015-07-13 | 2017-11-08 | Consejo Superior De Investigaciones Científicas (Csic) | Sensor de iones de medida diferencial |
| US10520465B2 (en) | 2016-02-17 | 2019-12-31 | Carrier Corporation | Gas detector utilizing an aqueous solution |
| DE102020114281A1 (de) | 2020-05-28 | 2021-12-02 | Dräger Safety AG & Co. KGaA | Ausgleichsmodul für einen Gassensor |
| DE102024101872A1 (de) * | 2024-01-23 | 2025-07-24 | Dräger Safety AG & Co. KGaA | Einrichtung und Verfahren zum Überprüfen eines elektrochemischen Sensors |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4036724A (en) * | 1973-04-02 | 1977-07-19 | Dragerwerk Aktiengesellschaft | Device for the continuous determination of carbon monoxide content of air |
| US3886058A (en) * | 1973-07-30 | 1975-05-27 | Texas Instruments Inc | Gas sensing electrode system employing hydrophilic wick |
| JPS5288282A (en) | 1976-01-19 | 1977-07-23 | Riken Keiki Kk | Reduction gas absorbentsand utilization and manufacture thereof |
| US4073698A (en) * | 1976-06-04 | 1978-02-14 | Energetics Science, Inc. | Method and device for the detection and measurement of carbon monoxide in the presence of hydrogen |
| US4346584A (en) * | 1980-10-20 | 1982-08-31 | Boehringer John R | Gas analyzer |
| US4563249A (en) * | 1983-05-10 | 1986-01-07 | Orbisphere Corporation Wilmington, Succursale De Collonge-Bellerive | Electroanalytical method and sensor for hydrogen determination |
| US4859305A (en) * | 1984-08-30 | 1989-08-22 | Mine Safety Appliances Company | Electrochemical cell |
| EP0221381B1 (en) * | 1985-11-06 | 1991-01-02 | Environmental Technologies Group, Inc. | Electrochemical gas sensor |
| US4692220A (en) * | 1986-01-24 | 1987-09-08 | Mine Safety Appliances Company | Electrochemical determination of formaldehyde |
| US5322602A (en) * | 1993-01-28 | 1994-06-21 | Teledyne Industries, Inc. | Gas sensors |
| US5338429A (en) * | 1993-03-05 | 1994-08-16 | Mine Safety Appliances Company | Electrochemical toxic gas sensor |
| JP3453954B2 (ja) | 1994-11-02 | 2003-10-06 | トヨタ自動車株式会社 | 一酸化炭素検出装置、有機化合物検出装置および低級アルコール検出装置 |
| US6967183B2 (en) * | 1998-08-27 | 2005-11-22 | Cabot Corporation | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
| US6319473B1 (en) * | 1998-06-16 | 2001-11-20 | Figaro Engineering, Inc. | Co sensor and its fabrication |
| CN1128353C (zh) * | 1999-04-16 | 2003-11-19 | 电子科技大学 | 掺杂态聚苯胺的氧化氮气体传感器的制备方法 |
| GB9913946D0 (en) * | 1999-06-15 | 1999-08-18 | Dart Sensors Ltd | Carbon monoxide sensor |
| JP3865114B2 (ja) * | 2000-08-01 | 2007-01-10 | 理研計器株式会社 | 電気化学式ガスセンサー |
| GB0027877D0 (en) * | 2000-11-15 | 2000-12-27 | Alphasense Ltd | Electrochemical gas sensor |
| GB2374419B (en) * | 2001-03-09 | 2004-12-29 | Zellweger Analytics Ltd | Electrochemical gas sensor |
| US6792793B2 (en) * | 2002-03-28 | 2004-09-21 | Ignition Lock International | Breath measurement instrument and breath alcohol interlock device incorporating same |
| JP4155562B2 (ja) * | 2003-02-03 | 2008-09-24 | 理研計器株式会社 | 電気化学式ガスセンサー |
-
2005
- 2005-05-11 GB GBGB0509632.6A patent/GB0509632D0/en not_active Ceased
-
2006
- 2006-05-05 EP EP06727030A patent/EP1886128B1/en active Active
- 2006-05-05 EP EP11150664A patent/EP2312305A1/en not_active Withdrawn
- 2006-05-05 DE DE602006020561T patent/DE602006020561D1/de active Active
- 2006-05-05 AT AT06727030T patent/ATE501434T1/de not_active IP Right Cessation
- 2006-05-05 WO PCT/GB2006/001662 patent/WO2006120409A2/en not_active Ceased
- 2006-05-05 JP JP2008510629A patent/JP4953324B2/ja active Active
- 2006-05-05 CN CN200680016266.9A patent/CN101203749B/zh active Active
- 2006-05-05 US US11/920,005 patent/US20090194417A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1886128B1 (en) | 2011-03-09 |
| JP2008541082A (ja) | 2008-11-20 |
| GB0509632D0 (en) | 2005-06-15 |
| EP2312305A1 (en) | 2011-04-20 |
| DE602006020561D1 (de) | 2011-04-21 |
| CN101203749A (zh) | 2008-06-18 |
| WO2006120409A3 (en) | 2007-01-11 |
| EP1886128A2 (en) | 2008-02-13 |
| CN101203749B (zh) | 2013-05-01 |
| ATE501434T1 (de) | 2011-03-15 |
| WO2006120409A2 (en) | 2006-11-16 |
| US20090194417A1 (en) | 2009-08-06 |
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