JP4938021B2 - Ag/Al2O3HC−SCR触媒上でのコーキングの低減 - Google Patents
Ag/Al2O3HC−SCR触媒上でのコーキングの低減 Download PDFInfo
- Publication number
- JP4938021B2 JP4938021B2 JP2008540702A JP2008540702A JP4938021B2 JP 4938021 B2 JP4938021 B2 JP 4938021B2 JP 2008540702 A JP2008540702 A JP 2008540702A JP 2008540702 A JP2008540702 A JP 2008540702A JP 4938021 B2 JP4938021 B2 JP 4938021B2
- Authority
- JP
- Japan
- Prior art keywords
- exhaust gas
- gas stream
- hydrocarbon
- present
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/90—Injecting reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9495—Controlling the catalytic process
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/208—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/104—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Toxicology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0523135.2A GB0523135D0 (en) | 2005-11-14 | 2005-11-14 | Reducing coking over Ag/A1203 HC-SCR catalyst |
| GB0523135.2 | 2005-11-14 | ||
| PCT/GB2006/050376 WO2007054740A1 (en) | 2005-11-14 | 2006-11-09 | Reducing coking over ag/al203 hc-scr catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009516125A JP2009516125A (ja) | 2009-04-16 |
| JP2009516125A5 JP2009516125A5 (enExample) | 2009-12-24 |
| JP4938021B2 true JP4938021B2 (ja) | 2012-05-23 |
Family
ID=35516852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008540702A Expired - Fee Related JP4938021B2 (ja) | 2005-11-14 | 2006-11-09 | Ag/Al2O3HC−SCR触媒上でのコーキングの低減 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8387367B2 (enExample) |
| EP (1) | EP1948351A1 (enExample) |
| JP (1) | JP4938021B2 (enExample) |
| KR (1) | KR20080077112A (enExample) |
| CN (1) | CN101309742A (enExample) |
| AU (1) | AU2006313538A1 (enExample) |
| GB (1) | GB0523135D0 (enExample) |
| WO (1) | WO2007054740A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0318776D0 (en) | 2003-08-09 | 2003-09-10 | Johnson Matthey Plc | Lean NOx catalyst |
| KR101158816B1 (ko) * | 2009-08-21 | 2012-06-26 | 기아자동차주식회사 | 디젤 차량의 배기 장치 |
| KR20110024598A (ko) * | 2009-09-02 | 2011-03-09 | 현대자동차주식회사 | 디젤 자동차의 질소산화물 저감 장치 |
| US8813690B2 (en) * | 2009-10-30 | 2014-08-26 | Cummins Inc. | Engine control techniques to account for fuel effects |
| DE102009047067A1 (de) * | 2009-11-24 | 2011-05-26 | Robert Bosch Gmbh | Verfahren zum Betreiben einer Dosiervorrichtung und Vorrichtung zur Durchführung des Verfahrens |
| GB2485530A (en) * | 2010-11-11 | 2012-05-23 | Johnson Matthey Plc | Catalyst system |
| US9188041B2 (en) | 2011-10-31 | 2015-11-17 | General Electric Company | System and method for reducing mono-nitrogen oxide emissions |
| EP3511073A4 (en) * | 2016-09-12 | 2019-09-25 | Cataler Corporation | EXHAUST GAS CLEANING CATALYST AND METHOD FOR PRODUCING AN EXHAUST GAS CLEANING CATALYST |
| JP2019148232A (ja) * | 2018-02-27 | 2019-09-05 | 東京濾器株式会社 | 排気ガス処理システム、排気ガス浄化方法 |
| US11339745B1 (en) * | 2020-02-07 | 2022-05-24 | Rolls-Royce North American Technologies Inc. | Dual flowpath exhaust for fuel cooling in a hypersonic propulsion system |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5534237A (en) * | 1991-07-23 | 1996-07-09 | Kubushiki Kaisha Riken | Method of cleaning an exhaust gas and exhaust gas cleaner therefor |
| JP2000093803A (ja) * | 1998-09-18 | 2000-04-04 | Nissan Motor Co Ltd | 排気ガス浄化用触媒及び排気ガス浄化方法 |
| JP2004506505A (ja) * | 2000-08-17 | 2004-03-04 | アクセンタス パブリック リミテッド カンパニー | エンジン排気ガスからのnoxの除去方法及び装置 |
| JP2004330191A (ja) * | 2003-05-07 | 2004-11-25 | Kocat Inc | 多段噴射を利用する窒素酸化物低減触媒及びその用途 |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3857921A (en) * | 1972-09-27 | 1974-12-31 | Asahi Chemical Ind | Method for eliminating nitrogen oxides and catalyst composition for use in practicing said method |
| JP2863567B2 (ja) | 1989-10-03 | 1999-03-03 | 株式会社リケン | 排ガス浄化材及び排ガス浄化方法 |
| JP2971081B2 (ja) | 1989-11-13 | 1999-11-02 | 株式会社日立製作所 | 脱臭触媒 |
| JP4087897B2 (ja) * | 1991-11-26 | 2008-05-21 | バスフ・カタリスツ・エルエルシー | 改良された酸化触媒および使用方法 |
| EP0577438B1 (en) | 1992-07-03 | 2001-05-16 | Kabushiki Kaisha Riken | Exhaust gas cleaner and method of cleaning exhaust gas |
| JP3447384B2 (ja) | 1993-09-29 | 2003-09-16 | 本田技研工業株式会社 | 排気ガス浄化用触媒 |
| CA2138333A1 (en) | 1993-12-17 | 1995-06-18 | Takashi Itoh | Nox removal catalyst and method of purifying exhaust gas by using the same |
| DE4404617C2 (de) * | 1994-02-14 | 1998-11-05 | Daimler Benz Ag | Vorrichtung zur selektiven katalysierten NO¶x¶-Reduktion in sauerstoffhaltigen Abgasen von Brennkraftmaschinen |
| US5714130A (en) | 1994-11-28 | 1998-02-03 | Kabushiki Kaisha Riken | Exhaust gas cleaner and method for cleaning exhaust gas |
| US5593933A (en) * | 1995-08-30 | 1997-01-14 | Ford Motor Company | Refractory oxides based silver-tungsten lean-NOx catalyst |
| EP0761289A3 (en) | 1995-09-08 | 1997-05-02 | Riken Kk | Exhaust gas purifiers and exhaust gas purification methods |
| US6199372B1 (en) * | 1996-04-26 | 2001-03-13 | Komatsu Ltd. | Apparatus and method for regenerating NOx catalyst for diesel engine |
| JPH11342339A (ja) | 1998-03-31 | 1999-12-14 | Mazda Motor Corp | 排気ガス浄化用触媒 |
| JP3565035B2 (ja) | 1998-07-10 | 2004-09-15 | 三菱ふそうトラック・バス株式会社 | 燃焼排ガス用NOx還元システム |
| JP2000064827A (ja) | 1998-08-24 | 2000-02-29 | Mazda Motor Corp | 燃焼機関の排気ガス浄化装置 |
| US6176078B1 (en) | 1998-11-13 | 2001-01-23 | Engelhard Corporation | Plasma fuel processing for NOx control of lean burn engines |
| FR2787037B1 (fr) | 1998-12-09 | 2002-01-11 | Inst Francais Du Petrole | Procede et dispositif d'elimination des oxydes d'azote dans une ligne d'echappement de moteur a combustion interne |
| DE19908023A1 (de) | 1999-02-25 | 2000-08-31 | Dornier Gmbh | Verfahren und Element zur Speicherung von in einem Gas enthaltenen Stickoxiden |
| US6237326B1 (en) * | 1999-08-24 | 2001-05-29 | Ford Global Technolgies, Inc. | Engine control system and method with lean catalyst and particulate filter |
| US6314722B1 (en) * | 1999-10-06 | 2001-11-13 | Matros Technologies, Inc. | Method and apparatus for emission control |
| JP2001115825A (ja) | 1999-10-19 | 2001-04-24 | Yanmar Diesel Engine Co Ltd | 火花点火式エンジンの脱硝方法 |
| JP2001113134A (ja) * | 1999-10-20 | 2001-04-24 | Tokyo Gas Co Ltd | NOx含有排ガスの浄化方法 |
| US20010035006A1 (en) | 2000-02-01 | 2001-11-01 | Danan Dou | Sulfur trap in NOx adsorber systems for enhanced sulfur resistance |
| US6311484B1 (en) * | 2000-02-22 | 2001-11-06 | Engelhard Corporation | System for reducing NOx transient emission |
| GB2374559A (en) | 2001-04-20 | 2002-10-23 | Accentus Plc | Removal of nitrogen oxides from effluent gases |
| JP3659193B2 (ja) | 2001-06-08 | 2005-06-15 | 日産自動車株式会社 | 内燃機関の排気浄化システム |
| JP2002370031A (ja) | 2001-06-13 | 2002-12-24 | Sumitomo Metal Mining Co Ltd | 排ガス浄化用触媒、並びにそれを使用する触媒体、排ガス浄化用触媒被覆構造体及び排ガス浄化方法 |
| US6742328B2 (en) | 2001-10-11 | 2004-06-01 | Southwest Research Institute | Systems and methods for controlling diesel engine emissions |
| US20030073566A1 (en) * | 2001-10-11 | 2003-04-17 | Marshall Christopher L. | Novel catalyst for selective NOx reduction using hydrocarbons |
| WO2004022229A1 (en) | 2002-09-04 | 2004-03-18 | The University Of Chicago | Novel catalyst for selective nox reduction using hydrocarbons |
| WO2004025093A1 (en) * | 2002-09-13 | 2004-03-25 | Johnson Matthey Public Limited Company | Compression ignition engine and exhaust system therefor |
| DE10331393B4 (de) | 2003-07-11 | 2006-10-26 | Adam Opel Ag | Verfahren und Katalysator zur Reduzierung der Emissionen nicht-dieselgetriebener Motoren mit SCR-Katalysatoren |
| GB0318776D0 (en) | 2003-08-09 | 2003-09-10 | Johnson Matthey Plc | Lean NOx catalyst |
| US7490464B2 (en) * | 2003-11-04 | 2009-02-17 | Basf Catalysts Llc | Emissions treatment system with NSR and SCR catalysts |
| US6990854B2 (en) * | 2003-11-19 | 2006-01-31 | Ford Global Technologies, Llc | Active lean NOx catalyst diagnostics |
| JP4567968B2 (ja) | 2003-12-25 | 2010-10-27 | トヨタ自動車株式会社 | 排ガス浄化装置及び排ガス浄化方法 |
| US7481983B2 (en) * | 2004-08-23 | 2009-01-27 | Basf Catalysts Llc | Zone coated catalyst to simultaneously reduce NOx and unreacted ammonia |
| GB0514188D0 (en) | 2005-07-12 | 2005-08-17 | Johnson Matthey Plc | Desulphating Ag/A1203 hc-scr catalyst |
| US7396517B2 (en) * | 2005-08-05 | 2008-07-08 | Gm Global Technology Operations, Inc. | Reduction of NOx emissions using a staged silver/alumina catalyst system |
-
2005
- 2005-11-14 GB GBGB0523135.2A patent/GB0523135D0/en not_active Ceased
-
2006
- 2006-11-09 WO PCT/GB2006/050376 patent/WO2007054740A1/en not_active Ceased
- 2006-11-09 KR KR1020087011360A patent/KR20080077112A/ko not_active Withdrawn
- 2006-11-09 US US12/084,997 patent/US8387367B2/en not_active Expired - Fee Related
- 2006-11-09 EP EP06808740A patent/EP1948351A1/en not_active Withdrawn
- 2006-11-09 CN CNA2006800425005A patent/CN101309742A/zh active Pending
- 2006-11-09 AU AU2006313538A patent/AU2006313538A1/en not_active Abandoned
- 2006-11-09 JP JP2008540702A patent/JP4938021B2/ja not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5534237A (en) * | 1991-07-23 | 1996-07-09 | Kubushiki Kaisha Riken | Method of cleaning an exhaust gas and exhaust gas cleaner therefor |
| JP2000093803A (ja) * | 1998-09-18 | 2000-04-04 | Nissan Motor Co Ltd | 排気ガス浄化用触媒及び排気ガス浄化方法 |
| JP2004506505A (ja) * | 2000-08-17 | 2004-03-04 | アクセンタス パブリック リミテッド カンパニー | エンジン排気ガスからのnoxの除去方法及び装置 |
| JP2004330191A (ja) * | 2003-05-07 | 2004-11-25 | Kocat Inc | 多段噴射を利用する窒素酸化物低減触媒及びその用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20100205935A1 (en) | 2010-08-19 |
| KR20080077112A (ko) | 2008-08-21 |
| US8387367B2 (en) | 2013-03-05 |
| EP1948351A1 (en) | 2008-07-30 |
| GB0523135D0 (en) | 2005-12-21 |
| CN101309742A (zh) | 2008-11-19 |
| WO2007054740A1 (en) | 2007-05-18 |
| JP2009516125A (ja) | 2009-04-16 |
| AU2006313538A1 (en) | 2007-05-18 |
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