JP4890702B2 - Decorative sheet and method for producing the same - Google Patents

Decorative sheet and method for producing the same Download PDF

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Publication number
JP4890702B2
JP4890702B2 JP2001287609A JP2001287609A JP4890702B2 JP 4890702 B2 JP4890702 B2 JP 4890702B2 JP 2001287609 A JP2001287609 A JP 2001287609A JP 2001287609 A JP2001287609 A JP 2001287609A JP 4890702 B2 JP4890702 B2 JP 4890702B2
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JP
Japan
Prior art keywords
pattern
layer
resin
coating layer
decorative sheet
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JP2001287609A
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Japanese (ja)
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JP2003094592A (en
Inventor
武 村田
由佳 鳥山
昇 寺沢
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DIC Decor Inc
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DIC Decor Inc
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Priority to JP2001287609A priority Critical patent/JP4890702B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、建築物の内装・外装、家具・建具の表面化粧、車両の内装等のための化粧シート及びその製造方法に関する。
【0002】
【従来の技術】
従来、特開平3−21342号公報に示されているように、基材に艶消しのコート層を設け、該コート層上に高固型分インキを使用してグラビヤ版の模様を印刷することによってベルベット調又はスウエード調の化粧シートを製造する方法が知られているが、この化粧シートの場合、多数の盛上部が梨地又は砂目の模様を形成するものの、この盛上部は表面層に均一に配置されたものであり、絵柄を構成するものではない。
【0003】
【発明が解決しようとする課題】
この発明は、基材上の印刷層に印刷による絵柄を形成すると共に、表面層に盛上部によって絵柄を形成することによって、さらに表面層に光沢差を現出することによって化粧シートの装飾的効果を高めることを目的とする。
【0004】
【課題を解決するための手段】
したがって、本発明に係る化粧シートは、基材と、該基材上の印刷層と、該印刷層上に設けられた熱硬化性樹脂又はラジカル重合型樹脂からなる透明又は半透明のコート層と、該コート層上に設けられ、前記コート層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂による透明又は半透明の間隔を置いて設けられた多数の盛上部によって絵柄の輪郭が表された表面層とを含み、各盛上部の高さが20〜150μ、その直径が200〜1000μ、その直径と盛上部の間隔との比が3:7〜9:1であることを特徴とする。また、本発明に係る化粧シートの製造方法は、基材に印刷層を形成し、該印刷層上に熱硬化性樹脂又はラジカル重合型樹脂で透明又は半透明のコート層を形成し、多数のセルを有するネガ版を用いて前記コート層上に該コート層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂により透明又は半透明の間隔を置いて設けられた多数の盛上部によって絵柄の輪郭が表された表面層を形成することを含み、各セルの深さが40〜300μ、その直径が200〜1000μ、その直径と盛上部の間隔との比が3:7〜9:1であることを特徴とする。前記絵柄の輪郭は、前記盛上部を部分的に設けないことによって表すことができ、前記盛上部によって表すこともできる。前記印刷層にはベタ刷り又は絵柄の印刷がされ、その絵柄は木目柄、大理石・砂岩のような石目柄、抽象柄を含む。また、各盛上部は円形、多角形又はそれらの組合せ形の平面形状を有する。
【0005】
【発明の効果】
本発明によれば、印刷層に絵柄、例えば木目柄を印刷し、表面層にネガ版を用いて透明又は半透明の盛上部によって印刷層の絵柄に見合った絵柄、例えば導管の輪郭を表すことによって豊かな絵柄表現が可能となることから、また表面層上の絵柄が形成された部分とこれが形成されていない部分との間に光沢差及び高低差が生じることから、光沢差による立体感と高低差による立体感との複合により、化粧シートの装飾効果を高めることができる。
【0006】
【実施の形態】
化粧シート10は、図1に示すように、基材12と、該基材上の印刷層14と、該印刷層上に設けられた熱硬化性樹脂又はラジカル重合型樹脂からなる透明又は半透明のコート層16と、該コート層上に設けられ、コート層16の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂による間隔を置かれた透明又は半透明の多数の盛上部18によって絵柄の輪郭(図2,3)が表された表面層20とを含む。
【0007】
盛上部18は隣接する盛上部から一定の間隔b(図4,5,6,8)を置かれているが、部分的に、すなわち図2に示すように木目の導管19のような絵柄の輪郭を盛上部を設けないことにより表すために、間隔bより一層大きな間隔が置かれている。同様に、図3に示すように石目柄21のような絵柄の輪郭を盛上部18により表す際には、すなわち周囲に盛上部を設けないことにより石目柄21を表す際には、隣接する柄との間隔は間隔bより大きくされる。
【0008】
表面層20に盛上部18によって導管の輪郭が表される図2の例の場合、印刷層14には木目柄が印刷されている。また、表面層20に盛上部18によって石目の輪郭が表される図3の例の場合、印刷層14には石目柄が印刷されている。印刷層14と表面層20との間に上記のような絵柄の整合性はなくても良く、印刷層に抽象柄を印刷し、表面層に石目柄の輪郭を表しても良い。
【0009】
基材12は、ポリエステル系フィルム、熱可塑性飽和ポリエステル系フィルム、ポリアクリロニトリル系フィルム、ポリイミド系フィルム、ポリエステルイミドフィルム、ポリエーテルケトン系フィルム、ポリサルホンフィルム、ポリカーボネートフィルム、ポリエーテルサルホン系フィルム、ポリフェニレンサルファイドフィルム、フッ素系フィルム、熱可塑性ポリウレタンフィルム、ナイロンフィルム、アクリルフィルム、ポリビニルアルコールフィルム、ポリプロピレン系フィルム、生分解性フィルム、合成紙、金属泊、不織布、紙又は塩化ビニルフィルムである。
【0010】
また、印刷層12には、着色物のベタ刷り印刷又は木目、石目、抽象柄のような絵柄模様の印刷がされている。
【0011】
さらに、前記高固型分樹脂は揮発分が40〜100%の熱硬化性樹脂、ラジカル重合型樹脂である。前記熱硬化性樹脂として、フェノール系樹脂、尿素系樹脂、メラミン系樹脂、エポキシ系樹脂、ポリエステル系樹脂、ポリウレタン系樹脂があり、前記ラジカル重合型樹脂として、紫外線硬化型樹脂、電子線硬化型樹脂、放射線硬化型樹脂がある。
【0012】
絵柄表面層20の盛上部18の平面形状は、多角形(図4)、円形(図5)又はそれらの組合せ形である。図示の例では、盛上部18の平面形状はそれぞれ亀甲形及び円形(図4,5)であり、その縦断面形状はそれぞれ台形及び半球形(図6,7)である。各盛上部18の高さ(h)は20〜150μ、好ましくは40〜90μであり、その直径(a)は200〜1000μ、好ましくは300〜700μであり、その直径(a)と盛上部間の間隔(b)との比が3:7〜9:1であり、好ましくは6:4〜7:3である。ここにいう直径(a)は、盛上部18の形状にかかわらず、その輪郭の内接円の最大直径である。
【0013】
次に、図1に示した化粧シート10の製造方法について説明する。まず、基材12にベタ刷り又は絵柄模様の印刷層14を設ける。次に、この印刷層14上に熱硬化性樹脂又はラジカル重合型樹脂で透明又は半透明のコート層16を設ける。次に、印刷技術を用いて、すなわち多数のセル22(図9,8)を有するネガ版24を用いてコート層16上にこのコート層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂により間隔を置いて形成された透明又は半透明の多数の盛上部18によって絵柄の輪郭が表された表面層20を設ける。ネガ版24のセル22は、これにより形成される盛上部18が例えば図2に示す木目の導管19のような絵柄を表すように、適宜に配置されている。
【0014】
盛上部18を形成するために必要なセル22の形状は、円形、多角形又はそれらの組合せ形で、その深さ(D)は、40〜300μ、好ましくは80〜180μであり、その直径(A)は200〜1000μ、好ましくは300〜700μであり、その直径(A)と盛上部間の間隔(B)との比は3:7〜9:1であり、好ましくは6:4〜7:3である。ここにいう直径(A)は、セル22の形状にかかわらず、その輪郭の内接円(図4)の最大直径である。
【0015】
印刷層14には絵柄が印刷され、表面層には透明又は半透明の盛上部により絵柄の輪郭が表される。盛上部18は艶又は光沢に富むグロスで、盛上部の間はそれの乏しいマットであり、両者間に光沢差が生じる。また、基材12上の印刷層14における色の明暗に従って透明又は半透明のコート層を通して観者の目に入る光量に差が生じる。これらが、化粧シート表面の装飾効果を高める。
【図面の簡単な説明】
【図1】本発明に係る化粧シートの部分断面図。
【図2】部分的に盛上部を設けないことにより導管の輪郭を表した化粧シート表面層の部分平面図。
【図3】盛上部により石目柄の輪郭を表した化粧シート表面層の部分平面図。
【図4】 亀甲形である盛上部の平面図。
【図5】円形である盛り上がり部の平面図。
【図6】図4に示した盛上部の断面図。
【図7】図5に示した盛上部の断面図。
【図8】図4,6に示した亀甲形盛上部を形成するための多数のセルを有するネガ版の部分断面図。
【図9】図5,7に示した円形盛上部を形成するための多数のセルを有するネガ版の部分断面図。
【符号の説明】
10 化粧シート
12 基材
14 印刷層
16 透明又は半透明のコート層
18 盛上部
19 木目の導管の輪郭
20 表面層
21 石目の輪郭
22 セル
24 ネガ版
[0001]
BACKGROUND OF THE INVENTION
The present invention, interior and exterior of a building, surface decorative furniture, fittings, relates粧sheet and a manufacturing method thereof of for interior of the vehicle.
[0002]
[Prior art]
Conventionally, as shown in JP-A-3-2 8 1342 discloses a coating layer of matte formed on the substrate, printing a pattern of gravure plate using a high solids ink on the coating layer A method for producing a velvet-like or suede-like decorative sheet is known. In the case of this decorative sheet, a large number of raised portions form a textured or grainy pattern, but the raised portion is a surface layer. Are arranged uniformly and do not constitute a picture.
[0003]
[Problems to be solved by the invention]
The present invention provides a decorative effect of a decorative sheet by forming a printed pattern on a printed layer on a substrate, forming a pattern with a raised portion on the surface layer, and further revealing a gloss difference on the surface layer. The purpose is to increase.
[0004]
[Means for Solving the Problems]
Therefore, the decorative sheet according to the present invention includes a base material, a printed layer on the base material, and a transparent or translucent coating layer made of a thermosetting resin or a radical polymerization resin provided on the printed layer. A large number of raised portions provided on the coating layer at a transparent or translucent interval by a thermosetting resin having a higher gloss than the resin of the coating layer or a radical polymerization type high solid content resin. The height of each peak is 20 to 150 μ, the diameter is 200 to 1000 μ, and the ratio of the diameter to the pitch is 3: 7 to 9: 1. It is characterized by being. Further, the method for producing a decorative sheet according to the present invention includes forming a printed layer on a substrate, forming a transparent or translucent coat layer with a thermosetting resin or a radical polymerization type resin on the printed layer, Using a negative plate having a cell, a transparent or translucent space was provided on the coating layer with a thermosetting resin having a higher gloss than the resin of the coating layer or a radical polymerization type high solid content resin. Forming a surface layer in which the outline of the pattern is represented by a large number of raised portions, each cell having a depth of 40 to 300 μ, a diameter of 200 to 1000 μ, and a ratio of the diameter to the interval between the raised portions is 3 : 7 to 9: 1. The outline of the pattern can be expressed by not providing the raised portion partially, and can also be expressed by the raised portion. The printed layer is solid or printed with a pattern, and the pattern includes a grain pattern, a stone pattern such as marble / sandstone, and an abstract pattern. Each raised portion has a planar shape of a circle, a polygon, or a combination thereof.
[0005]
【The invention's effect】
According to the present invention, a pattern such as a wood grain pattern is printed on the print layer, and a pattern corresponding to the pattern on the print layer is expressed by a transparent or translucent embossed portion using a negative plate on the surface layer, for example, the outline of the conduit. since the gloss difference and elevation difference is generated between the rich since pattern representation is possible and not this and the picture is formed partially on the surface layer is formed partially by a stereoscopic effect by glossiness difference The decorative effect of the decorative sheet can be enhanced by the combination with the three-dimensional effect due to the height difference .
[0006]
Embodiment
As shown in FIG. 1, the decorative sheet 10 is a transparent or translucent material comprising a substrate 12, a printed layer 14 on the substrate, and a thermosetting resin or a radical polymerization resin provided on the printed layer. Coating layer 16 and a number of transparent or translucent layers provided on the coating layer and spaced by a thermosetting resin having a higher gloss than the resin of the coating layer 16 or a radical-polymerized high-solids resin. And the surface layer 20 in which the outline of the pattern (FIGS. 2 and 3) is represented by the raised portion 18.
[0007]
The upper portion 18 is spaced a certain distance b (FIGS. 4, 5, 6 and 8) from the adjacent upper portion, but is partially, that is, has a pattern such as a wood conduit 19 as shown in FIG. In order to express the contour by not providing a raised portion, an interval larger than the interval b is set. Similarly, when the contour of the pattern such as the stone pattern 21 is represented by the raised portion 18 as shown in FIG. 3, that is, when the stone pattern 21 is represented by not providing the raised portion around, The distance between the handle and the handle is larger than the distance b.
[0008]
In the case of the example of FIG. 2 in which the contour of the conduit is represented by the raised portion 18 on the surface layer 20, a wood grain pattern is printed on the printed layer 14. In the case of the example of FIG. 3 in which the contour of the stone is represented by the raised portion 18 on the surface layer 20, a stone pattern is printed on the printing layer 14. There is no need to match the pattern as described above between the print layer 14 and the surface layer 20, and an abstract pattern may be printed on the print layer and a contour of a stone pattern may be displayed on the surface layer.
[0009]
The substrate 12 is a polyester film, a thermoplastic saturated polyester film, a polyacrylonitrile film, a polyimide film, a polyester imide film, a polyether ketone film, a polysulfone film, a polycarbonate film, a polyether sulfone film, or a polyphenylene sulfide. A film, a fluorine film, a thermoplastic polyurethane film, a nylon film, an acrylic film, a polyvinyl alcohol film, a polypropylene film, a biodegradable film, a synthetic paper, a metal stay, a nonwoven fabric, paper, or a vinyl chloride film.
[0010]
Further, the printed layer 12 is printed with a solid color printing or a pattern such as a wood pattern, a stone pattern, or an abstract pattern.
[0011]
Further, the high solid content resin is a thermosetting resin or radical polymerization resin having a volatile content of 40 to 100%. Examples of the thermosetting resin include phenol resins, urea resins, melamine resins, epoxy resins, polyester resins, and polyurethane resins, and the radical polymerization resins include ultraviolet curable resins and electron beam curable resins. There are radiation curable resins.
[0012]
The planar shape of the raised portion 18 of the pattern surface layer 20 is a polygon (FIG. 4), a circle (FIG. 5), or a combination thereof. In the illustrated example, the planar shape of the raised portion 18 is a tortoiseshell shape and a circular shape (FIGS. 4 and 5), respectively, and the vertical cross-sectional shapes thereof are a trapezoidal shape and a hemispherical shape (FIGS. 6 and 7), respectively. The height (h) of each raised portion 18 is 20 to 150 μ, preferably 40 to 90 μ, and its diameter (a) is 200 to 1000 μ, preferably 300 to 700 μ, between the diameter (a) and the raised portion. The ratio with the interval (b) is 3: 7 to 9: 1, preferably 6: 4 to 7: 3. The diameter (a) here is the maximum diameter of the inscribed circle of the contour regardless of the shape of the raised portion 18.
[0013]
Next, a method for manufacturing the decorative sheet 10 shown in FIG. 1 will be described. First, a solid printing or pattern printing layer 14 is provided on the substrate 12. Next, a transparent or translucent coat layer 16 is provided on the printed layer 14 with a thermosetting resin or a radical polymerization type resin. Next, using a printing technique, that is, using a negative plate 24 having a large number of cells 22 (FIGS. 9 and 8), a thermosetting resin or radical polymerization having a higher gloss than the resin of this coating layer on the coating layer 16. A surface layer 20 in which the outline of the pattern is expressed by a large number of transparent or semi-transparent upper portions 18 formed at intervals by a highly solid resin of the mold is provided. The cells 22 of the negative plate 24 are appropriately arranged so that the raised portion 18 formed thereby represents, for example, a pattern such as a wood conduit 19 shown in FIG.
[0014]
The cell 22 necessary for forming the raised portion 18 is circular, polygonal or a combination thereof, and its depth (D) is 40 to 300 μm, preferably 80 to 180 μm, and its diameter ( A) is 200 to 1000 μm, preferably 300 to 700 μm, and the ratio of the diameter (A) to the interval (B) between the raised portions is 3: 7 to 9: 1, preferably 6: 4 to 7 : 3. The diameter (A) here is the maximum diameter of the inscribed circle (FIG. 4) of the contour regardless of the shape of the cell 22.
[0015]
A pattern is printed on the printing layer 14, and the outline of the pattern is expressed on the surface layer by a transparent or translucent embossed portion. The upper portion 18 is gloss which is rich in gloss or gloss, and the gap between the upper portions is a poor mat, resulting in a difference in gloss between the two. In addition, a difference occurs in the amount of light entering the viewer's eyes through the transparent or translucent coating layer according to the brightness of the color in the printed layer 14 on the substrate 12. These enhance the decorative effect on the decorative sheet surface.
[Brief description of the drawings]
FIG. 1 is a partial cross-sectional view of a decorative sheet according to the present invention.
FIG. 2 is a partial plan view of a decorative sheet surface layer that represents the outline of a conduit by not providing a raised portion partially.
FIG. 3 is a partial plan view of a decorative sheet surface layer in which a contour of a stone pattern is represented by a raised portion.
FIG. 4 is a plan view of the upper part of the turtle shell shape.
FIG. 5 is a plan view of a raised portion that is circular.
6 is a cross-sectional view of the upper portion shown in FIG.
FIG. 7 is a cross-sectional view of the upper portion shown in FIG.
8 is a partial cross-sectional view of a negative plate having a large number of cells for forming the upper part of the turtle shell as shown in FIGS. 4 and 6. FIG.
9 is a partial cross-sectional view of a negative plate having a large number of cells for forming the circular embankment shown in FIGS.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 10 Decorative sheet 12 Base material 14 Print layer 16 Transparent or translucent coat layer 18 Embossed portion 19 Contour of wood conduit 20 Surface layer 21 Contour of stone 22 Cell 24 Negative plate

Claims (7)

基材と、該基材上の絵柄の印刷層と、該印刷層上に設けられた熱硬化性樹脂又はラジカル重合型樹脂からなる透明又は半透明のコート層と、該コート層上に設けられ、前記コート層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂による透明又は半透明の、間隔を置いて設けられた多数の盛上部によって絵柄の輪郭が表された表面層とを含み、各盛上部の高さが20〜150μ、その直径が200〜1000μ、その直径と盛上部の間隔との比が3:7〜9:1である、前記盛上部と該盛上部間の前記コート層との間の光沢差による立体感と前記盛上部と前記コート層との間の高低差による立体感とを複合させた、化粧シート。  A substrate, a printed layer of a pattern on the substrate, a transparent or translucent coating layer made of a thermosetting resin or a radical polymerization resin provided on the printing layer, and provided on the coating layer The outline of the pattern is expressed by a large number of spaced-apart, transparent or semi-transparent portions made of a thermosetting resin having a higher gloss than the resin of the coating layer or a high-polymer resin of radical polymerization type. The height of each peak is 20 to 150 μ, the diameter is 200 to 1000 μ, and the ratio of the diameter to the distance between the peaks is 3: 7 to 9: 1. A decorative sheet that combines a three-dimensional effect due to a difference in gloss between the upper layer and the coat layer and a three-dimensional effect due to a difference in height between the upper layer and the coat layer. 前記絵柄の輪郭は、前記盛上部を部分的に設けないことによって表されている、請求項1に記載の仮称シート。  The temporary name sheet according to claim 1, wherein the outline of the pattern is represented by not providing the raised portion partially. 前記絵柄の輪郭は、前記盛上部によって表されている、請求項1に記載の化粧シート。  The decorative sheet according to claim 1, wherein an outline of the pattern is represented by the raised portion. 前記絵柄は木目柄、石目柄又は抽象柄である、請求項1ないし3のいずれか1項に記載の化粧シート。  The decorative sheet according to any one of claims 1 to 3, wherein the pattern is a wood grain pattern, a stone pattern, or an abstract pattern. 前記印刷層にはベタ刷り又は絵柄の印刷がされている、請求項1に記載の化粧シート。  The decorative sheet according to claim 1, wherein the printing layer is solidly printed or printed with a pattern. 前記盛上部は円形、多角形又はそれらの組合せ形の平面形状を有する、請求項1に記載の化粧シート。  The decorative sheet according to claim 1, wherein the raised portion has a planar shape of a circle, a polygon, or a combination thereof. 基材に絵柄の印刷層を形成し、該印刷層上に熱硬化性樹脂又はラジカル重合型樹脂で透明又は半透明のコート層を形成し、多数のセルを有するネガ版を用いて前記コート層上に該コート層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重合型の高固型分樹脂により透明又は半透明の間隔を置いて設けられた多数の盛上部によって絵柄の輪郭が表された表面層を形成することを含み、各セルの深さが40〜300μ、その直径が200〜1000μ、その直径と盛上部の間隔との比が3:7〜9:1である、前記盛上部と該盛上部間の前記コート層との間の光沢差による立体感と前記盛上部と前記コート層との間の高低差による立体感とを複合させた化粧シートの製造方法。  A printed layer of a pattern is formed on a substrate, a transparent or translucent coating layer is formed on the printed layer with a thermosetting resin or a radical polymerization resin, and the coating layer is formed using a negative plate having a large number of cells. The outline of the pattern is represented by a large number of raised portions provided at a transparent or translucent interval on the thermosetting resin having a higher gloss than the resin of the coating layer or a radically-polymerized high-solid resin. Forming a surface layer, wherein each cell has a depth of 40 to 300 [mu], a diameter of 200 to 1000 [mu], and a ratio of the diameter to the interval between the tops is 3: 7 to 9: 1. The manufacturing method of the decorative sheet which combined the three-dimensional effect by the gloss difference between the said upper part and the said coating layer between this upper part, and the three-dimensional effect by the height difference between the said upper part and the said coating layer.
JP2001287609A 2001-09-20 2001-09-20 Decorative sheet and method for producing the same Expired - Lifetime JP4890702B2 (en)

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JP5119637B2 (en) * 2006-09-29 2013-01-16 大日本印刷株式会社 Decorative sheet
JP2008087158A (en) * 2006-09-29 2008-04-17 Dainippon Printing Co Ltd Decorative sheet
JP5028932B2 (en) * 2006-09-29 2012-09-19 大日本印刷株式会社 Decorative sheet
JP2009234159A (en) * 2008-03-28 2009-10-15 Dainippon Printing Co Ltd Decorative film for molding
JP5899889B2 (en) * 2011-12-15 2016-04-06 株式会社トッパン・コスモ Decorative sheet
JP5931789B2 (en) * 2013-03-29 2016-06-08 大建工業株式会社 Decorative plate manufacturing method

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