JP4864902B2 - 石油ベースの液体炭化水素を改良する熱中性法 - Google Patents
石油ベースの液体炭化水素を改良する熱中性法 Download PDFInfo
- Publication number
- JP4864902B2 JP4864902B2 JP2007548593A JP2007548593A JP4864902B2 JP 4864902 B2 JP4864902 B2 JP 4864902B2 JP 2007548593 A JP2007548593 A JP 2007548593A JP 2007548593 A JP2007548593 A JP 2007548593A JP 4864902 B2 JP4864902 B2 JP 4864902B2
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen
- reforming
- fuel
- reaction
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C01B2203/107—Platinum catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Description
ここで、前記液体炭化水素燃料として、石油ベースの燃料を用いることができる。前記石油ベースの燃料としては、iso−オクタン、軽質ナフサ、重ナフサ、灯油及びディーゼルからなる群より選択することができる。
クス形成から検出可能な触媒非活性化がないという利点を有している。
善する斬新な高ガスの1時間あたりの空間速度(GHSV=25,000 h−1 to40,000 h−1)、つまり、熱中性改質(TNR)プロセスを包含している。本発明は、コークス生成なしで、液体炭化水素の改良という困難な課題を解決する。
を明確にすることができる。
ち少なくとも一方は、触媒温度の過度の上昇を抑制するために瞬間的に増加する。
によって、コークス形成の有害な影響の無い従来技術の方法と比べて、液体燃料を採用し
ているとき、合成ガスの大幅な生産増加が得られる。
(実施例1)
本発明の方法を明らかにするために固定床流通反応装置で実験を行った。その反応装置システムは、ガス及び液体の供給部と、予熱部と、反応炉部と、生成回収部とからなる。
送液される。反応炉チューブは、直径12.6mmであり、人口のハイネス(Haynes)2
30合金材料からなる。
不活性な炭化ケイ素からなる層間の該反応炉チューブの中央に配置されている。炭化ケイ素層の先端部は、予熱ゾーンとして機能し、前記混合物をその予熱ゾーンにおいて350℃で加熱した。
10℃であった。1時間あたりのガス空間速度は34,129h−1、圧力が2バール、炭
素に対する蒸気の比率が2.1、酸素/炭素(比率)が0.507である。その結果を表
1に示した。ここで、表1はIso−オクタン装入物の結果を要約したものである。
この実施例は、合成ガス中に200ppmの硫黄を含むナフサ装入物の触媒変換のための方法を示しており、詳細には実施例1に記載されている。
本実施例は、合成ガスに対する、硫黄の含有量が1ppmに満たない軽質ナフサ装入物の触媒変換のための方法を示しており、詳細には実施例1に記載されている。
表3は、軽質ナフサ装入物についての実験結果の概要である。
Claims (13)
- 燃焼改質触媒と蒸気及び/又はCO2改質触媒とを混合したNi-Ce2O3-Pt-Rhからなる触媒床を含む内側ゾーンを有する反応炉を用いて、1%に満たない芳香族化合物および200ppm未満の硫黄を含む液体炭化水素燃料から水素富化合成ガスを生成する熱中性改質方法であって、
反応炉の内側ゾーンに炭化水素燃料と、酸素富化ガス及び蒸気との混合物を供給するステップと、
前記炭化水素燃料と、前記酸素富化ガス及び蒸気とを380〜450℃の温度で予熱するステップと、
前記予熱された混合物を、25000h‐1又はそれ以上のガス空間速度で前記触媒床に接触させ、反応温度を800〜900℃に昇温する発熱燃焼反応を引き起こし、水素富化合成ガスを生成するための前記液体炭化水素燃料を改質するのに十分な時間をかけて吸熱蒸気改質反応を引き起こすステップと、
を有することを特徴とする熱中性改質方法。 - 前記液体炭化水素燃料は、石油ベースの燃料であることを特徴とする請求項1に記載の熱中性改質方法。
- 前記石油ベースの燃料は、iso−オクタン、軽質ナフサ、重ナフサ、灯油及びディーゼルからなる群より選択されることを特徴とする請求項2に記載の熱中性改質方法。
- 前記ガス空間速度は、25000〜40000h−1であることを特徴とする請求項1に記載の熱中性改質方法。
- 前記予熱温度は、410〜420℃であることを特徴とする請求項1に記載の熱中性改質方法。
- 前記発熱燃焼反応で得られた熱は、同じ前記触媒床上での吸熱反応で中和して、前記吸熱蒸気改質反応に必要な熱を補完することを特徴とする請求項1に記載の熱中性改質方法。
- 前記吸熱蒸気改質反応は、外熱供給無しで、行われることを特徴とする請求項1に記載の熱中性改質方法。
- 前記iso−オクタン及び前記軽質ナフサの96.5%以上が前記水素富化合成ガスに変換されることを特徴とする請求項3に記載の熱中性改質方法。
- 前記重ナフサの99%以上が前記水素富化合成ガスに変換されることを特徴とする請求項3に記載の熱中性改質方法。
- 請求項1に記載された改質方法から得られた合成ガスは、高純粋水素を生成するために精製したことを特徴とする熱中性改質方法。
- 前記水素富化合成ガスは、高温燃料電池又は低温燃料電池を組み込んだ乗物内のオンボード改質装置の燃料として使用されることを特徴とする請求項1に記載の熱中性改質方法。
- 前記水素富化合成ガスは、内燃機関内の水素富化のための燃料として使用されることを特徴とする請求項1に記載の熱中性改質方法。
- 前記水素富化合成ガスは、固定アプリケーションで用いられることを特徴とする請求項1に記載の熱中性改質方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63853304P | 2004-12-23 | 2004-12-23 | |
US60/638,533 | 2004-12-23 | ||
PCT/US2005/047220 WO2006071927A1 (en) | 2004-12-23 | 2005-12-23 | Thermo-neutral reforming of petroleum-based liquid hydrocarbons |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008525303A JP2008525303A (ja) | 2008-07-17 |
JP4864902B2 true JP4864902B2 (ja) | 2012-02-01 |
Family
ID=36615264
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007548593A Expired - Fee Related JP4864902B2 (ja) | 2004-12-23 | 2005-12-23 | 石油ベースの液体炭化水素を改良する熱中性法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US7820140B2 (ja) |
EP (1) | EP1828085B1 (ja) |
JP (1) | JP4864902B2 (ja) |
KR (1) | KR101301710B1 (ja) |
CN (1) | CN101460437B (ja) |
AU (1) | AU2005321933B2 (ja) |
BR (1) | BRPI0517600B1 (ja) |
CA (1) | CA2592441C (ja) |
EA (1) | EA011521B1 (ja) |
ES (1) | ES2450591T3 (ja) |
NO (1) | NO339383B1 (ja) |
WO (1) | WO2006071927A1 (ja) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7700005B2 (en) * | 2006-12-26 | 2010-04-20 | Saudi Arabian Oil Company | Oil-based thermo-neutral reforming with a multi-component catalyst |
US9162887B2 (en) | 2008-07-02 | 2015-10-20 | Powercell Sweden Ab | Reformer reactor and method for converting hydrocarbon fuels into hydrogen rich gas |
US8563186B2 (en) * | 2009-06-16 | 2013-10-22 | Shell Oil Company | Systems and processes of operating fuel cell systems |
US8632922B2 (en) * | 2009-06-16 | 2014-01-21 | Shell Oil Company | Systems and processes for operating fuel cell systems |
US8795912B2 (en) * | 2009-06-16 | 2014-08-05 | Shell Oil Company | Systems and processes for operating fuel cell systems |
RU2515326C1 (ru) * | 2012-10-04 | 2014-05-10 | Открытое акционерное общество "Центральное конструкторское бюро морской техники "Рубин" | Способ конверсии дизельного топлива и конвертор для его осуществления |
US9499403B2 (en) | 2013-07-10 | 2016-11-22 | Saudi Arabian Oil Company | Catalyst and process for thermo-neutral reforming of liquid hydrocarbons |
WO2017085626A2 (en) * | 2015-11-19 | 2017-05-26 | Sabic Global Technologies B.V. | Oxidative conversion of variable feed c1 - oil to olefins, aromatic hydrocarbons, low molecular weight paraffinic hydrocarbons & syngas mixture |
US11472700B2 (en) * | 2019-12-27 | 2022-10-18 | Saudi Arabian Oil Company | Catalyst and process for thermo-neutral reforming of petroleum-based liquid hydrocarbons |
US11358128B2 (en) | 2019-12-30 | 2022-06-14 | Saudi Arabian Oil Company | High activity reforming catalyst formulation and process for low temperature steam reforming of hydrocarbons to produce hydrogen |
US11322766B2 (en) | 2020-05-28 | 2022-05-03 | Saudi Arabian Oil Company | Direct hydrocarbon metal supported solid oxide fuel cell |
US11639290B2 (en) | 2020-06-04 | 2023-05-02 | Saudi Arabian Oil Company | Dry reforming of methane with carbon dioxide at elevated pressure |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08239201A (ja) * | 1994-07-05 | 1996-09-17 | Satoyuki Inui | メタンの改質による水素の製造法 |
JP2002220202A (ja) * | 2001-01-23 | 2002-08-09 | Kansai Coke & Chem Co Ltd | 水素の製造法 |
JP2003530664A (ja) * | 2000-04-05 | 2003-10-14 | ハイドロジェン、バーナー、テクノロジー、インコーポレーテッド | 一体形反応装置 |
JP2004507425A (ja) * | 2000-08-31 | 2004-03-11 | エンゲルハード・コーポレーシヨン | 水素に富んだガスを発生させる方法 |
JP2008207186A (ja) * | 2000-11-08 | 2008-09-11 | Idemitsu Kosan Co Ltd | 炭化水素の改質触媒及びそれを用いた炭化水素の改質方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4473543A (en) * | 1982-04-26 | 1984-09-25 | United Technologies Corporation | Autothermal reforming catalyst and process |
US4650651A (en) * | 1983-06-09 | 1987-03-17 | Union Carbide Corporation | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
US4666680A (en) * | 1984-01-30 | 1987-05-19 | Fluor Corporation | Autothermal production of synthesis gas |
CN85102194B (zh) * | 1985-04-01 | 1988-08-24 | 四川化工厂催化剂分厂 | 烃类蒸汽重整催化剂 |
US5122299A (en) * | 1989-12-11 | 1992-06-16 | The M. W. Kellogg Company | Autothermal steam reforming process |
US5248566A (en) * | 1991-11-25 | 1993-09-28 | The United States Of America As Represented By The United States Department Of Energy | Fuel cell system for transportation applications |
JPH05270803A (ja) | 1992-03-24 | 1993-10-19 | Toyo Eng Corp | メタンと二酸化炭素および水蒸気を原料とする合成ガスの製造方法 |
JP3225078B2 (ja) | 1992-03-24 | 2001-11-05 | 東洋エンジニアリング株式会社 | 合成ガス製造用触媒 |
GB9412786D0 (en) * | 1994-06-24 | 1994-08-17 | Johnson Matthey Plc | Improved reformer |
US6293979B1 (en) * | 1994-12-19 | 2001-09-25 | Council Of Scientific & Industrial Research | Process for the catalytic conversion of methane or natural gas to syngas or a mixture of carbon monoxide and hydrogen |
ATE274468T1 (de) * | 1997-04-11 | 2004-09-15 | Chiyoda Chem Eng Construct Co | Verfahren zur herstellung von synthesegas mittels outothermer reformierung |
US6303098B1 (en) * | 1997-06-02 | 2001-10-16 | University Of Chicago | Steam reforming catalyst |
AU740872B2 (en) | 1998-06-09 | 2001-11-15 | Idemitsu Kosan Co. Ltd | Catalyst and process for reforming hydrocarbon |
CA2282948A1 (en) * | 1998-09-16 | 2000-03-16 | University Technologies International, Inc. | Low temperature autothermal steam reformation of methane in a fluidized bed |
DK173897B1 (da) * | 1998-09-25 | 2002-02-04 | Topsoe Haldor As | Fremgangsmåde til autotermisk reforming af et carbonhydridfødemateriale indeholdende højere carbonhydrider |
AU7765200A (en) * | 1999-10-05 | 2001-05-10 | Ballard Power Systems Inc. | Autothermal reformer |
US6610196B1 (en) | 1999-11-24 | 2003-08-26 | Conocophillips Company | Catalytic reforming process |
US6713040B2 (en) * | 2001-03-23 | 2004-03-30 | Argonne National Laboratory | Method for generating hydrogen for fuel cells |
US6967063B2 (en) * | 2001-05-18 | 2005-11-22 | The University Of Chicago | Autothermal hydrodesulfurizing reforming method and catalyst |
US6884531B2 (en) * | 2001-05-21 | 2005-04-26 | Saudi Arabian Oil Company | Liquid hydrocarbon based fuels for fuel cell on-board reformers |
US7090826B2 (en) * | 2002-12-23 | 2006-08-15 | The Boc Group, Inc. | Monolith based catalytic partial oxidation process for syngas production |
-
2005
- 2005-12-23 JP JP2007548593A patent/JP4864902B2/ja not_active Expired - Fee Related
- 2005-12-23 WO PCT/US2005/047220 patent/WO2006071927A1/en active Application Filing
- 2005-12-23 AU AU2005321933A patent/AU2005321933B2/en not_active Ceased
- 2005-12-23 US US11/792,769 patent/US7820140B2/en not_active Expired - Fee Related
- 2005-12-23 KR KR1020077016736A patent/KR101301710B1/ko active IP Right Grant
- 2005-12-23 BR BRPI0517600A patent/BRPI0517600B1/pt not_active IP Right Cessation
- 2005-12-23 ES ES05855731.5T patent/ES2450591T3/es active Active
- 2005-12-23 CN CN2005800482234A patent/CN101460437B/zh not_active Expired - Fee Related
- 2005-12-23 CA CA2592441A patent/CA2592441C/en not_active Expired - Fee Related
- 2005-12-23 EA EA200701343A patent/EA011521B1/ru not_active IP Right Cessation
- 2005-12-23 EP EP05855731.5A patent/EP1828085B1/en not_active Not-in-force
-
2007
- 2007-07-06 NO NO20073515A patent/NO339383B1/no not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08239201A (ja) * | 1994-07-05 | 1996-09-17 | Satoyuki Inui | メタンの改質による水素の製造法 |
JP2003530664A (ja) * | 2000-04-05 | 2003-10-14 | ハイドロジェン、バーナー、テクノロジー、インコーポレーテッド | 一体形反応装置 |
JP2004507425A (ja) * | 2000-08-31 | 2004-03-11 | エンゲルハード・コーポレーシヨン | 水素に富んだガスを発生させる方法 |
JP2008207186A (ja) * | 2000-11-08 | 2008-09-11 | Idemitsu Kosan Co Ltd | 炭化水素の改質触媒及びそれを用いた炭化水素の改質方法 |
JP2002220202A (ja) * | 2001-01-23 | 2002-08-09 | Kansai Coke & Chem Co Ltd | 水素の製造法 |
Also Published As
Publication number | Publication date |
---|---|
NO339383B1 (no) | 2016-12-05 |
CA2592441A1 (en) | 2006-07-26 |
BRPI0517600B1 (pt) | 2018-11-21 |
EP1828085A1 (en) | 2007-09-05 |
US20080081018A1 (en) | 2008-04-03 |
US7820140B2 (en) | 2010-10-26 |
KR20080015773A (ko) | 2008-02-20 |
BRPI0517600A (pt) | 2008-10-14 |
AU2005321933B2 (en) | 2011-09-08 |
NO20073515L (no) | 2007-09-21 |
KR101301710B1 (ko) | 2013-08-30 |
EP1828085A4 (en) | 2010-09-15 |
EA011521B1 (ru) | 2009-04-28 |
EA200701343A1 (ru) | 2007-10-26 |
AU2005321933A1 (en) | 2006-07-06 |
JP2008525303A (ja) | 2008-07-17 |
CN101460437A (zh) | 2009-06-17 |
ES2450591T3 (es) | 2014-03-25 |
WO2006071927A1 (en) | 2006-07-06 |
CN101460437B (zh) | 2013-05-29 |
EP1828085B1 (en) | 2013-12-11 |
CA2592441C (en) | 2013-05-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4864902B2 (ja) | 石油ベースの液体炭化水素を改良する熱中性法 | |
KR101419567B1 (ko) | 다성분 촉매를 사용한 유성 열-중화 개질 방법 | |
Rostrup-Nielsen | Conversion of hydrocarbons and alcohols for fuel cells | |
Krumpelt et al. | Fuel processing for fuel cell systems in transportation and portable power applications | |
US6887455B2 (en) | Catalytic generation of hydrogen | |
US20040047799A1 (en) | Dynamic sulfur tolerant process and system with inline acid gas-selective removal for generating hydrogen for fuel cells | |
JP2011507214A (ja) | 燃料電池による電力発生方法 | |
KR20140103141A (ko) | 연료 전지용의 조절가능한 기체 조성물의 제조방법 | |
US20040209131A1 (en) | Process and apparatus for producing hydrogen | |
Kang et al. | The operating characteristics of solid oxide fuel cells driven by diesel autothermal reformate | |
US6669923B2 (en) | Gas generator | |
US8100994B2 (en) | Process for generating electricity and hydrogen that comprises a hybrid reformer | |
JP2001080906A (ja) | 水素ガス生成装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101102 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110127 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110816 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111012 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111101 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111109 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141118 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4864902 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313114 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313114 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |