JP4769294B2 - 紡績ヤーン中のポリ燐酸に熱表面上で加水分解を受けさせる方法 - Google Patents
紡績ヤーン中のポリ燐酸に熱表面上で加水分解を受けさせる方法 Download PDFInfo
- Publication number
- JP4769294B2 JP4769294B2 JP2008504372A JP2008504372A JP4769294B2 JP 4769294 B2 JP4769294 B2 JP 4769294B2 JP 2008504372 A JP2008504372 A JP 2008504372A JP 2008504372 A JP2008504372 A JP 2008504372A JP 4769294 B2 JP4769294 B2 JP 4769294B2
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- filaments
- polyphosphoric acid
- filament
- polyareneazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 86
- 229920000137 polyphosphoric acid Polymers 0.000 title claims abstract description 82
- 230000007062 hydrolysis Effects 0.000 title claims description 36
- 238000006460 hydrolysis reaction Methods 0.000 title claims description 36
- 239000007788 liquid Substances 0.000 claims description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 56
- 229920000642 polymer Polymers 0.000 claims description 55
- 230000015271 coagulation Effects 0.000 claims description 24
- 238000005345 coagulation Methods 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 23
- 239000012530 fluid Substances 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 16
- 238000009987 spinning Methods 0.000 claims description 16
- 230000003301 hydrolyzing effect Effects 0.000 abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 39
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 35
- 229910052698 phosphorus Inorganic materials 0.000 description 35
- 239000011574 phosphorus Substances 0.000 description 35
- 239000000835 fiber Substances 0.000 description 34
- 239000000243 solution Substances 0.000 description 29
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 24
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 24
- 239000002585 base Substances 0.000 description 23
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 20
- 238000011282 treatment Methods 0.000 description 18
- 239000003570 air Substances 0.000 description 17
- 125000003118 aryl group Chemical group 0.000 description 16
- 239000007921 spray Substances 0.000 description 15
- 229910052786 argon Inorganic materials 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
- 229920000388 Polyphosphate Polymers 0.000 description 11
- 239000001205 polyphosphate Substances 0.000 description 11
- 235000011176 polyphosphates Nutrition 0.000 description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- 235000011054 acetic acid Nutrition 0.000 description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
- 230000004927 fusion Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 238000009941 weaving Methods 0.000 description 8
- 125000001072 heteroaryl group Chemical group 0.000 description 7
- 229920002577 polybenzoxazole Polymers 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 description 5
- 125000005551 pyridylene group Chemical group 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- 229920012306 M5 Rigid-Rod Polymer Fiber Polymers 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000019260 propionic acid Nutrition 0.000 description 4
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 238000001291 vacuum drying Methods 0.000 description 4
- 238000002166 wet spinning Methods 0.000 description 4
- 239000004693 Polybenzimidazole Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000005605 benzo group Chemical group 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920002480 polybenzimidazole Polymers 0.000 description 3
- 229920005594 polymer fiber Polymers 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- -1 2,5- Dihydroxy-para-phenylene Chemical group 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000011260 aqueous acid Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000005270 trialkylamine group Chemical group 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- OYFRNYNHAZOYNF-UHFFFAOYSA-N 2,5-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC(O)=C(C(O)=O)C=C1O OYFRNYNHAZOYNF-UHFFFAOYSA-N 0.000 description 1
- AZUHIVLOSAPWDM-UHFFFAOYSA-N 2-(1h-imidazol-2-yl)-1h-imidazole Chemical compound C1=CNC(C=2NC=CN=2)=N1 AZUHIVLOSAPWDM-UHFFFAOYSA-N 0.000 description 1
- 125000004008 6 membered carbocyclic group Chemical group 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000009967 Erodium cicutarium Nutrition 0.000 description 1
- 240000003759 Erodium cicutarium Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical group C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229920003252 rigid-rod polymer Polymers 0.000 description 1
- 125000006413 ring segment Chemical group 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000003260 vortexing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/74—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66574405P | 2005-03-28 | 2005-03-28 | |
| US60/665,744 | 2005-03-28 | ||
| PCT/US2006/011671 WO2006105310A1 (en) | 2005-03-28 | 2006-03-27 | Hot surface hydrolysis of polyphosphoric acid in spun yarns |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008534810A JP2008534810A (ja) | 2008-08-28 |
| JP2008534810A5 JP2008534810A5 (enExample) | 2009-05-14 |
| JP4769294B2 true JP4769294B2 (ja) | 2011-09-07 |
Family
ID=36716370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008504372A Expired - Fee Related JP4769294B2 (ja) | 2005-03-28 | 2006-03-27 | 紡績ヤーン中のポリ燐酸に熱表面上で加水分解を受けさせる方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7968030B2 (enExample) |
| EP (1) | EP1871932B1 (enExample) |
| JP (1) | JP4769294B2 (enExample) |
| KR (1) | KR101327706B1 (enExample) |
| CN (1) | CN101258272B (enExample) |
| AT (1) | ATE495289T1 (enExample) |
| DE (1) | DE602006019572D1 (enExample) |
| WO (1) | WO2006105310A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101287865B (zh) * | 2005-03-28 | 2012-06-13 | 纳幕尔杜邦公司 | 在纺成复丝纱线中不熔结地水解多磷酸 |
| CN104988623A (zh) * | 2015-06-23 | 2015-10-21 | 张家港市华阳针纺织品有限公司 | 一种低收缩率复合纱线的制备方法 |
| CN104988625A (zh) * | 2015-06-23 | 2015-10-21 | 张家港市华阳针纺织品有限公司 | 一种高强度复合纱线的制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0978350A (ja) * | 1995-09-13 | 1997-03-25 | Toyobo Co Ltd | ポリベンザゾール繊維の製造方法およびポリベンザゾール中間乾燥繊維 |
| JPH0978349A (ja) * | 1995-09-05 | 1997-03-25 | Toyobo Co Ltd | ポリベンザゾール繊維の製造方法 |
Family Cites Families (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3227793A (en) | 1961-01-23 | 1966-01-04 | Celanese Corp | Spinning of a poly(polymethylene) terephthalamide |
| US3424720A (en) | 1963-04-18 | 1969-01-28 | Koppers Co Inc | Polybenzothiazoles |
| US3414645A (en) | 1964-06-19 | 1968-12-03 | Monsanto Co | Process for spinning wholly aromatic polyamide fibers |
| US3804804A (en) | 1970-11-23 | 1974-04-16 | Horizons Inc | Preparation of heterocyclic polymers from heteroaromatic tetramines |
| CA973554A (en) | 1970-12-30 | 1975-08-26 | Arthur H. Gerber | 2,3,5,6-tetraaminopyridine and its acid salts and processes for its preparation |
| US3767756A (en) | 1972-06-30 | 1973-10-23 | Du Pont | Dry jet wet spinning process |
| US4079039A (en) | 1974-03-04 | 1978-03-14 | Horizons Research Incorporated | Polyheterocyclic polymers derived from substituted tetraamino pyridines |
| US4002679A (en) | 1974-08-07 | 1977-01-11 | The United States Of America As Represented By The Secretary Of The Air Force | Preparation of polybenzimidazoles |
| US3940955A (en) | 1974-11-26 | 1976-03-02 | E. I. Du Pont De Nemours And Co. | Yarn extraction and washing apparatus |
| US3996321A (en) | 1974-11-26 | 1976-12-07 | E. I. Du Pont De Nemours And Company | Level control of dry-jet wet spinning process |
| US4070431A (en) | 1976-12-21 | 1978-01-24 | E. I. Du Pont De Nemours And Company | Improved yarn extraction process |
| US4078034A (en) | 1976-12-21 | 1978-03-07 | E. I. Du Pont De Nemours And Company | Air gage spinning process |
| US4298565A (en) | 1980-02-12 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Spinning process |
| US4452971A (en) | 1982-07-19 | 1984-06-05 | Celanese Corporation | Production of improved high molecular weight polybenzimidazole with tin containing catalyst |
| US4533693A (en) | 1982-09-17 | 1985-08-06 | Sri International | Liquid crystalline polymer compositions, process, and products |
| US4772678A (en) * | 1983-09-15 | 1988-09-20 | Commtech International Management Corporation | Liquid crystalline polymer compositions, process, and products |
| US4703103A (en) | 1984-03-16 | 1987-10-27 | Commtech International | Liquid crystalline polymer compositions, process and products |
| DE3617248C2 (de) * | 1985-08-30 | 1995-05-24 | Barmag Barmer Maschf | Verfahren zum Herstellen eines Kompositfadens aus Chemiefasern |
| US5168011A (en) * | 1985-09-26 | 1992-12-01 | Foster Miller Inc. | Interpenetrated polymer fibers |
| US4973442A (en) | 1985-09-26 | 1990-11-27 | Foster Miller Inc. | Forming biaxially oriented ordered polymer films |
| US4845150A (en) | 1985-09-26 | 1989-07-04 | Foster-Miller Inc. | Interpenetrated polymer films |
| US4939235A (en) | 1985-09-26 | 1990-07-03 | Foster-Miller, Inc. | Biaxially oriented ordered polybenzothiazole film |
| US4847350A (en) | 1986-05-27 | 1989-07-11 | The Dow Chemical Company | Preparation of aromatic heterocyclic polymers |
| US5227457A (en) | 1988-02-17 | 1993-07-13 | Maxdem Incorporated | Rigid-rod polymers |
| US4898924A (en) | 1989-01-11 | 1990-02-06 | Hoechst Celanese Corporation | Process for the production of biaxially oriented rigid rod heterocyclic liquid crystalline polymer films |
| US5041522A (en) | 1990-03-23 | 1991-08-20 | The United States Of America As Represented By The Secretary Of The Air Force | Dihydroxy-pendant rigid-rod benzobisazole polymer |
| US5089591A (en) | 1990-10-19 | 1992-02-18 | The Dow Chemical Company | Rapid advancement of molecular weight in polybenzazole oligomer dopes |
| US5276128A (en) | 1991-10-22 | 1994-01-04 | The Dow Chemical Company | Salts of polybenzazole monomers and their use |
| US5367042A (en) | 1992-08-27 | 1994-11-22 | The Dow Chemical Company | Process for fabricating oriented polybenzazole films |
| US5286833A (en) * | 1992-12-03 | 1994-02-15 | The Dow Chemical Company | Polybenzazole fiber with ultra-high physical properties |
| US5294390A (en) | 1992-12-03 | 1994-03-15 | The Dow Chemical Company | Method for rapid spinning of a polybenzazole fiber |
| TW257798B (enExample) * | 1992-12-03 | 1995-09-21 | Dow Chemical Co | |
| US5429787A (en) | 1992-12-03 | 1995-07-04 | The Dow Chemical Company | Method for rapid drying of a polybenzazole fiber |
| JP3246571B2 (ja) | 1993-02-15 | 2002-01-15 | 東洋紡績株式会社 | パルプ |
| KR100306676B1 (ko) * | 1993-04-28 | 2001-11-30 | 샬크비즈크 피이터 코르넬리스; 페트귄터 | 피리도비스이미다졸성분의강성막대형중합체 |
| US5393478A (en) | 1993-08-20 | 1995-02-28 | The Dow Chemical Company | Process for coagulation and washing of polybenzazole fibers |
| US5525638A (en) * | 1994-09-30 | 1996-06-11 | The Dow Chemical Company | Process for the preparation of polybenzazole filaments and fibers |
| EP0783603B1 (en) * | 1994-09-30 | 1999-12-08 | Toyobo Co., Ltd. | Process for the preparation of polybenzazole filaments and fibres |
| JP3613719B2 (ja) * | 1994-12-23 | 2005-01-26 | 東洋紡績株式会社 | ポリベンザゾール繊維の製造方法 |
| US5552221A (en) | 1994-12-29 | 1996-09-03 | The Dow Chemical Company | Polybenzazole fibers having improved tensile strength retention |
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| EP1553143B1 (en) | 2002-06-26 | 2007-05-02 | Toyo Boseki Kabushiki Kaisha | Highly durable polybenzazole composition, fiber and film |
| DE60336140D1 (de) | 2002-06-27 | 2011-04-07 | Teijin Aramid Bv | Verfahren zur herstellung von synthetisch-organischen fasern mit hoher festigkeit und/oder hohem modul aus aromatischen heterozyklischen steifen polymeren |
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| US7189346B2 (en) | 2004-07-22 | 2007-03-13 | E. I. Du Pont De Nemours And Company | Polybenzazole fibers and processes for their preparation |
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| CN101218384B (zh) | 2005-03-28 | 2010-12-08 | 纳幕尔杜邦公司 | 从纤维或纱线中去除磷的方法 |
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-
2006
- 2006-03-27 KR KR1020077024786A patent/KR101327706B1/ko not_active Expired - Fee Related
- 2006-03-27 CN CN2006800101379A patent/CN101258272B/zh not_active Expired - Fee Related
- 2006-03-27 AT AT06740063T patent/ATE495289T1/de not_active IP Right Cessation
- 2006-03-27 US US11/909,950 patent/US7968030B2/en active Active
- 2006-03-27 JP JP2008504372A patent/JP4769294B2/ja not_active Expired - Fee Related
- 2006-03-27 EP EP06740063A patent/EP1871932B1/en not_active Not-in-force
- 2006-03-27 DE DE602006019572T patent/DE602006019572D1/de active Active
- 2006-03-27 WO PCT/US2006/011671 patent/WO2006105310A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0978349A (ja) * | 1995-09-05 | 1997-03-25 | Toyobo Co Ltd | ポリベンザゾール繊維の製造方法 |
| JPH0978350A (ja) * | 1995-09-13 | 1997-03-25 | Toyobo Co Ltd | ポリベンザゾール繊維の製造方法およびポリベンザゾール中間乾燥繊維 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008534810A (ja) | 2008-08-28 |
| KR20080034833A (ko) | 2008-04-22 |
| WO2006105310A1 (en) | 2006-10-05 |
| KR101327706B1 (ko) | 2013-11-11 |
| DE602006019572D1 (de) | 2011-02-24 |
| EP1871932B1 (en) | 2011-01-12 |
| EP1871932A1 (en) | 2008-01-02 |
| US7968030B2 (en) | 2011-06-28 |
| ATE495289T1 (de) | 2011-01-15 |
| CN101258272B (zh) | 2010-12-29 |
| US20080203610A1 (en) | 2008-08-28 |
| CN101258272A (zh) | 2008-09-03 |
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