JP4694787B2 - 新規なホスオキソファイト配位子及びカルボニル化方法におけるそれらの使用 - Google Patents

新規なホスオキソファイト配位子及びカルボニル化方法におけるそれらの使用 Download PDF

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JP4694787B2
JP4694787B2 JP2003576449A JP2003576449A JP4694787B2 JP 4694787 B2 JP4694787 B2 JP 4694787B2 JP 2003576449 A JP2003576449 A JP 2003576449A JP 2003576449 A JP2003576449 A JP 2003576449A JP 4694787 B2 JP4694787 B2 JP 4694787B2
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phosoxophyte
carbonylation
group
transition metal
ligand
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JP2005519968A5 (enExample
JP2005519968A (ja
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ペン，ウェイ−ジュン
ロバート ブライアント，デイビッド
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ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2003576449A 2002-03-11 2003-03-04 新規なホスオキソファイト配位子及びカルボニル化方法におけるそれらの使用 Expired - Fee Related JP4694787B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US36372502P 2002-03-11 2002-03-11
US60/363,725 2002-03-11
PCT/US2003/006456 WO2003078444A2 (en) 2002-03-11 2003-03-04 Bisphosphite ligands for carbonylation processes

Publications (3)

Publication Number Publication Date
JP2005519968A JP2005519968A (ja) 2005-07-07
JP2005519968A5 JP2005519968A5 (enExample) 2006-03-30
JP4694787B2 true JP4694787B2 (ja) 2011-06-08

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JP2003576449A Expired - Fee Related JP4694787B2 (ja) 2002-03-11 2003-03-04 新規なホスオキソファイト配位子及びカルボニル化方法におけるそれらの使用

Country Status (8)

Country Link
US (1) US7196230B2 (enExample)
EP (1) EP1485392B1 (enExample)
JP (1) JP4694787B2 (enExample)
CN (1) CN1639177B (enExample)
AT (1) ATE320438T1 (enExample)
AU (1) AU2003230587A1 (enExample)
DE (1) DE60304034T2 (enExample)
WO (1) WO2003078444A2 (enExample)

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AU2003230587A1 (en) 2002-03-11 2003-09-29 Union Carbide Chemicals And Plastics Technology Corporation Bisphosphite ligands for carbonylation processes
AU2003270902A1 (en) * 2002-10-15 2004-05-04 Union Carbide Chemicals And Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
EP1646599B1 (en) 2003-07-03 2015-12-02 Dow Technology Investments LLC Minimization of ligand degradation products, or reversion of same to useful phosphine ligands
DE10360772A1 (de) 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
US7156098B2 (en) * 2004-03-19 2007-01-02 Dolezal Creative Innovations, Llc Breathing air filtration system
US8833369B2 (en) * 2004-03-19 2014-09-16 Airware, Inc. Breathing air filtration devices
US7671231B2 (en) 2006-01-18 2010-03-02 Lloyd Michael C Process for making amino acids
WO2007133379A1 (en) * 2006-05-15 2007-11-22 Dow Global Technologies Inc. Hydroformylation process and product separation with improved recovery of rhodium
DE102006058682A1 (de) 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
WO2009120529A1 (en) * 2008-03-28 2009-10-01 Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) Slurry process for phosphoromonochloridite synthesis
US8097749B2 (en) * 2008-03-28 2012-01-17 Union Carbide Chemical and Plastics Technology Technology Isothermal process for phosphoromonochloridite synthesis
EP2346887B1 (en) * 2008-10-08 2013-12-25 Dow Technology Investments LLC Slurry process for synthesis of bisphosphites
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
RU2601416C2 (ru) 2010-11-12 2016-11-10 Дау Текнолоджи Инвестментс Ллс Снижение загрязнения в процессах гидроформилирования посредством добавления воды
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
RU2634719C2 (ru) 2012-06-04 2017-11-03 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования
WO2014051975A1 (en) 2012-09-25 2014-04-03 Dow Technology Investments Llc Process for stabilizing a phosphite ligand against degradation
US9382180B2 (en) 2012-12-06 2016-07-05 Dow Technology Investments Llc Hydroformylation process
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
US9688598B2 (en) 2013-12-19 2017-06-27 Dow Technology Investments Llc Hydroformylation process
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
PL3126319T3 (pl) 2014-03-31 2020-01-31 Dow Technology Investments Llc Proces hydroformylowania
WO2017064064A1 (en) * 2015-10-12 2017-04-20 Basf Se Hydroformylation process for producing 1,6-disubstituted hexane derivatives
JP7547397B2 (ja) 2019-06-27 2024-09-09 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 貴金属回収のためのヒドロホルミル化プロセスから溶液を調製するプロセス
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
US11884614B2 (en) 2022-05-26 2024-01-30 Chevron Phillips Chemical Company Lp Normal alpha olefin synthesis using decarbonylative olefination
CN121039090A (zh) 2023-05-04 2025-11-28 陶氏技术投资有限责任公司 加氢甲酰化方法

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Also Published As

Publication number Publication date
EP1485392B1 (en) 2006-03-15
AU2003230587A1 (en) 2003-09-29
EP1485392A2 (en) 2004-12-15
US20060100453A1 (en) 2006-05-11
ATE320438T1 (de) 2006-04-15
DE60304034D1 (de) 2006-05-11
CN1639177A (zh) 2005-07-13
CN1639177B (zh) 2010-05-05
WO2003078444A3 (en) 2003-12-18
DE60304034T2 (de) 2006-10-12
JP2005519968A (ja) 2005-07-07
WO2003078444A2 (en) 2003-09-25
US7196230B2 (en) 2007-03-27
AU2003230587A8 (en) 2003-09-29

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