JP4551770B2 - 低下した変色傾向を示す部分的に適用された銀系仕上げ剤を有する布地 - Google Patents
低下した変色傾向を示す部分的に適用された銀系仕上げ剤を有する布地 Download PDFInfo
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- JP4551770B2 JP4551770B2 JP2004557144A JP2004557144A JP4551770B2 JP 4551770 B2 JP4551770 B2 JP 4551770B2 JP 2004557144 A JP2004557144 A JP 2004557144A JP 2004557144 A JP2004557144 A JP 2004557144A JP 4551770 B2 JP4551770 B2 JP 4551770B2
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- Prior art keywords
- silver
- fabric
- containing compound
- halide
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004332 silver Substances 0.000 title claims description 40
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- 239000003795 chemical substances by application Substances 0.000 claims description 8
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
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- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
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- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2475—Coating or impregnation is electrical insulation-providing, -improving, or -increasing, or conductivity-reducing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/273—Coating or impregnation provides wear or abrasion resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Detergent Compositions (AREA)
Description
以下において、本発明の布地処理(洗濯耐久性、非変色性、又は両方を有する)の好ましい態様を詳細に説明する。
この試験では、所望の機能(例えば、臭気制御又は低減の為の抗菌活性など)を発揮するために基材から自由に解離して、洗濯済み又は未洗濯試料上で機能する活性金属イオンの量を測定し、放出され得る活性成分、この場合は銀イオンの耐久性を観察する。試験は、試料(本件の場合、4インチ×4インチの寸法の布地試料)を、試料に所望の機能を発揮させる為に試料を暴露する液の代表例である溶液に接触させることを含む。即ち、この試験では、試料布地を、(最初に有効数字4桁で秤量した後)AATCC Test Method 15-1994の溶液に従った人体臭気コントロール標準物に暴露した。暴露は、本質的に、人工標準液を10倍に希釈した液に8時間浸漬して行った。暴露時間後、試料を乾燥し、再度秤量した。質量の減少は、標準液中の臭い発生微生物を殺菌するために銀イオン活性成分が放出されたことを表していた。計算結果は、試料布地の質量に対する活性成分量(ppm)で報告されている。実施例1及びある種の比較布地(Aは、繊維あたり180ppmのALPHASANTMと共押出しした繊維を含む布地;Bは、繊維あたり60ppmのZEOMICTMと共押出しした繊維を含む布地;Cは、8000ppmの銀をその上に有する導電性布地X-STATICTM)についての結果は以下の通りである:
布地の変色性に関し、実施例4−7について、試料を以下の式で評価する耐光性試験により分析した:
Claims (10)
- 一部が仕上げ剤で被覆された表面を有する布地であって、該仕上げ剤は、リン酸銀ジルコニウム、銀ゼオライト、銀ガラス及びこれらの混合物からなる群から選択される少なくとも1種の銀イオン含有化合物、少なくとも1種の結合剤、並びに少なくとも1種のハライド含有化合物を含んでおり、該ハライド含有化合物は、存在するハライドイオン量及び存在する銀イオン量のモル比として測定して5:1〜1:10の範囲で存在し、該仕上げ剤は実質的にアルカリ金属イオンを含まない布地。
- 該少なくとも1種のハライド含有化合物はクロライド含有化合物である請求項1に記載の布地。
- 該クロライド含有化合物は塩化マグネシウムである請求項2に記載の布地。
- 該銀イオン含有化合物はリン酸銀ジルコニウムである請求項1に記載の布地。
- (a)表面を有する布地を供給し、
(b)工程(a)の該布地の表面の少なくとも一部を、リン酸銀ジルコニウム、銀ゼオライト、銀ガラス及びこれらの混合物からなる群から選択される少なくとも1種の銀イオン含有化合物、少なくとも1種の結合剤、並びに少なくとも1種のハライド含有化合物を含み、実質的にアルカリ金属イオンを含まない仕上げ剤に接触させる
工程を含んでなり、該ハライド含有化合物は、存在するハライドイオン量及び存在する銀イオン量のモル比として測定して5:1〜1:10の範囲で存在する
請求項1に記載の布地の製造方法。 - 一部が仕上げ剤で被覆された表面を有する布地であって、該仕上げ剤は、リン酸銀ジルコニウム、銀ゼオライト、銀ガラス及びこれらの混合物からなる群から選択される少なくとも1種の銀イオン含有化合物、少なくとも1種の結合剤、並びに少なくとも1種のハライド含有化合物を含んでおり、該ハライド含有化合物は、存在するハライドイオン量及び存在する銀イオン量のモル比として測定して5:1〜1:10の範囲で存在し、該仕上げ剤は実質的にナトリムイオンを含まない布地。
- 該少なくとも1種のハライド含有化合物はクロライド含有化合物である請求項6に記載の布地。
- 該クロライド含有化合物は塩化マグネシウムである請求項7に記載の布地。
- 該銀イオン含有化合物はリン酸銀ジルコニウムである請求項6に記載の布地。
- (a)表面を有する布地を供給し、
(b)工程(a)の該布地の表面の少なくとも一部を、リン酸銀ジルコニウム、銀ゼオライト、銀ガラス及びこれらの混合物からなる群から選択される少なくとも1種の銀イオン含有化合物、少なくとも1種の結合剤、並びに少なくとも1種のハライド含有化合物を含み、実質的にナトリウムイオンを含まない仕上げ剤に接触させる
工程を含んでなり、該ハライド含有化合物は、存在するハライドイオン量及び存在する銀イオン量のモル比として測定して5:1〜1:10の範囲で存在する
請求項6に記載の布地の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/307,027 US20040106341A1 (en) | 2002-11-29 | 2002-11-29 | Fabrics having a topically applied silver-based finish exhibiting a reduced propensity for discoloration |
PCT/US2003/033258 WO2004050963A2 (en) | 2002-11-29 | 2003-10-20 | Fabrics having a topically applied silver-based finish exhibiting a reduced propensity for discoloration |
Publications (3)
Publication Number | Publication Date |
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JP2006508277A JP2006508277A (ja) | 2006-03-09 |
JP2006508277A5 JP2006508277A5 (ja) | 2006-12-07 |
JP4551770B2 true JP4551770B2 (ja) | 2010-09-29 |
Family
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Application Number | Title | Priority Date | Filing Date |
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JP2004557144A Expired - Fee Related JP4551770B2 (ja) | 2002-11-29 | 2003-10-20 | 低下した変色傾向を示す部分的に適用された銀系仕上げ剤を有する布地 |
Country Status (8)
Country | Link |
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US (2) | US20040106341A1 (ja) |
EP (1) | EP1565311B1 (ja) |
JP (1) | JP4551770B2 (ja) |
CN (1) | CN100448665C (ja) |
AT (1) | ATE522349T1 (ja) |
AU (1) | AU2003284298A1 (ja) |
BR (1) | BR0316701A (ja) |
WO (1) | WO2004050963A2 (ja) |
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US7132378B2 (en) * | 2003-04-23 | 2006-11-07 | Milliken & Company | Fabrics having a topically applied silver-based finish with a cross-linked binder system for improved high-temperature wash durability |
US7842306B2 (en) * | 2003-08-14 | 2010-11-30 | Milliken & Company | Wound care device having fluid transfer properties |
US20050064020A1 (en) * | 2003-08-14 | 2005-03-24 | Schuette Robert L. | Method for producing silver-containing antimicrobial fabric |
US7335613B2 (en) * | 2004-04-08 | 2008-02-26 | Rohm And Haas Company | Fiber substrate with antibacterial finish and methods of making and using the same |
JP3761892B1 (ja) | 2004-10-19 | 2006-03-29 | シャープ株式会社 | 繊維構造体に制電性を付与する方法およびその方法によって制電性が付与された繊維構造体 |
US7671398B2 (en) * | 2005-02-23 | 2010-03-02 | Tran Bao Q | Nano memory, light, energy, antenna and strand-based systems and methods |
US20070220674A1 (en) * | 2006-03-22 | 2007-09-27 | Richard Haskins | Antibacterial-based system and method for prevention of separation anxiety |
US20070220675A1 (en) * | 2006-03-22 | 2007-09-27 | Richard Haskins | Filtration-based system and method for prevention of separation anxiety |
ATE530932T1 (de) * | 2007-01-31 | 2011-11-15 | Novartis Ag | Antimikrobielle medizinische vorrichtungen mit silbernanopartikeln |
US8178120B2 (en) * | 2008-06-20 | 2012-05-15 | Baxter International Inc. | Methods for processing substrates having an antimicrobial coating |
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US20100227052A1 (en) * | 2009-03-09 | 2010-09-09 | Baxter International Inc. | Methods for processing substrates having an antimicrobial coating |
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CN102888751B (zh) * | 2012-06-11 | 2015-03-25 | 浙江理工大学 | 亚铁离子感应变色织物的制备方法和使用法 |
CN104755669A (zh) * | 2012-10-26 | 2015-07-01 | As株式会社 | 凉感性纤维布及其制造方法 |
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-
2002
- 2002-11-29 US US10/307,027 patent/US20040106341A1/en not_active Abandoned
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2003
- 2003-10-20 JP JP2004557144A patent/JP4551770B2/ja not_active Expired - Fee Related
- 2003-10-20 WO PCT/US2003/033258 patent/WO2004050963A2/en active Application Filing
- 2003-10-20 BR BR0316701A patent/BR0316701A/pt not_active IP Right Cessation
- 2003-10-20 CN CNB2003801046248A patent/CN100448665C/zh not_active Expired - Fee Related
- 2003-10-20 AU AU2003284298A patent/AU2003284298A1/en not_active Abandoned
- 2003-10-20 AT AT03776478T patent/ATE522349T1/de not_active IP Right Cessation
- 2003-10-20 EP EP20030776478 patent/EP1565311B1/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
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US20040106341A1 (en) | 2004-06-03 |
JP2006508277A (ja) | 2006-03-09 |
BR0316701A (pt) | 2005-10-18 |
AU2003284298A8 (en) | 2004-06-23 |
ATE522349T1 (de) | 2011-09-15 |
CN1720137A (zh) | 2006-01-11 |
CN100448665C (zh) | 2009-01-07 |
EP1565311B1 (en) | 2011-08-31 |
US20100285711A1 (en) | 2010-11-11 |
AU2003284298A1 (en) | 2004-06-23 |
US7993415B2 (en) | 2011-08-09 |
EP1565311A4 (en) | 2008-03-12 |
EP1565311A2 (en) | 2005-08-24 |
WO2004050963A3 (en) | 2004-09-16 |
WO2004050963A2 (en) | 2004-06-17 |
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