JP4500059B2 - 水洗トイレ用固形洗浄剤 - Google Patents
水洗トイレ用固形洗浄剤 Download PDFInfo
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- JP4500059B2 JP4500059B2 JP2004009760A JP2004009760A JP4500059B2 JP 4500059 B2 JP4500059 B2 JP 4500059B2 JP 2004009760 A JP2004009760 A JP 2004009760A JP 2004009760 A JP2004009760 A JP 2004009760A JP 4500059 B2 JP4500059 B2 JP 4500059B2
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- Prior art keywords
- cleaning agent
- solid
- surfactant
- liquid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229940111630 tea tree oil Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
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- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
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Description
〔1〕 (A)25℃で固体である水溶性の界面活性剤、並びに(B)デキストリン及び/又はα化デンプンを含有してなる水洗トイレ用固形洗浄剤であって、該洗浄剤中、前記界面活性剤が陰イオン性界面活性剤であり、非イオン性界面活性剤を含まないか、含む場合でも1重量%未満である、水洗トイレ用固形洗浄剤、
〔2〕 (A)25℃で固体である水溶性の界面活性剤、(B)デキストリン及び/又はα化デンプン、(C)吸液量が1g/g以上の吸液性固体、並びに(D)25℃で液体である油性及び/又は水性の液体を含有してなる水洗トイレ用固形洗浄剤であって、該洗浄剤中、前記界面活性剤が陰イオン性界面活性剤であり、非イオン性界面活性剤を含まないか、含む場合でも1重量%未満である、水洗トイレ用固形洗浄剤、
〔3〕 (E)25℃で固体である水溶性の無機又は有機ビルダーをさらに含有してなるものである前記〔2〕記載の洗浄剤、
〔4〕 (C)の吸液性固体の含有量が5重量%未満である前記〔2〕又は〔3〕記載の洗浄剤、
〔5〕 (A)の界面活性剤と(B)のデキストリン及び/又はα化デンプンとの含有量比〔(A)/(B)〕が重量比で100/5〜100/60である前記〔1〕〜〔4〕いずれか記載の洗浄剤、
〔6〕 押出し成形、プレス成形又は打錠成形により成形してなる前記〔1〕〜〔5〕いずれか記載の洗浄剤、並びに
〔7〕 (B)のデキストリン及び/又はα化デンプンの含有量が5〜40重量%である前記〔1〕〜〔6〕いずれか記載の洗浄剤、
に関する。
該界面活性剤は、本発明の洗浄剤の主たる洗浄成分として使用される。該界面活性剤としては25℃で固体であって水溶性のものであればよく、特に限定はないが、好ましくは融点が55℃以上である水溶性の界面活性剤が挙げられる。なお、本明細書において「水溶性」とは、25℃の水100gに0.1g以上溶解しうる特性をいう。
本発明のデキストリン及び/又は処理デンプンとしては、水と混合することによりペースト状となり接着力を発揮する性質を有するものであれば、特に限定はない。デキストリン及び/又は処理デンプンは、本発明の洗浄剤の成形性の発現、並びに徐溶性及び/又は持続性の調整に寄与する。
本発明において、吸液性固体とは、吸液量が1g/g以上のものをいう。ここで、吸液量とは吸液性固体1g当たりの吸液対象となる液体の吸液量を意味し、複数の液体を吸液する場合は、複数の液体の混合液の吸液量を意味する。吸液量は、後述の実施例に記載の方法で測定することができる。吸液量としては、後述の(D)の油性及び/又は水性の液体が充分効果を発揮する量を吸液させ、良好な成形性を得る観点から、1.5g/g以上であるのが望ましく、一方、吸液された液体成分を水中に溶出せしめ、充分にその機能を発揮させる観点から、10g/g以下が望ましい。すなわち、吸液性固体の吸液量としては、1〜10g/gが好ましく、1.5〜10g/gがより好ましい。
油性及び/又は水性の液体は、25℃で液体であるものであり、本発明において前記吸液性固体の吸液対象となる液体である。例えば、溶剤、香料、消臭剤、抗菌・除菌剤、防汚剤、界面活性剤、忌避剤、防虫剤、殺虫剤等が挙げられる。具体的には、以下のようなものが挙げられるが、25℃で液体であればこれら以外の成分でもよい。
本発明の無機又は有機ビルダーは、25℃で固体であり水溶性を有するものであり、本発明の洗浄剤の洗浄助剤として機能すると共に、成形性、保形性の維持に寄与する。従って、本発明の洗浄剤としては、かかるビルダーを含有してなるものが好ましい。無機又は有機ビルダーとしては、具体的には、以下のようなものが挙げられる。
洗浄剤の成形性は、成形時の状態及びタレ性により評価した。
洗浄剤を押出し成形及び打錠成形により製造し、成形時における原料混合物の状態をそれぞれ評価し、その結果に基づいて洗浄剤の成形時の状態を総合的に評価した。
〔評価基準〕
○: 原料混合物がキャラメル状に練られた状態で、40秒/m以上のスピードで棒状に
押出される
△: 原料混合物が練られた状態で押出されるがそのスピードが40秒/m未満である
×: 原料混合物が練られておらず、塊となって押出し口から出ないか、又は原料混合物
が液状化している
〔評価基準〕
○: 原料混合物の打錠が問題なく行える
△: キャッピングが起こる場合があるが、原料混合物をよく練ることで解消できる
×: 原料混合物の打錠を行うことができない
洗浄剤を押出し成形及び打錠成形により製造し、得られた洗浄剤をそれぞれ直径55mmのポリカップ中央に設置し、50mLの水(25℃)を加え、24時間経過後の洗浄剤の状態を以下の評価基準に従って評価した。それぞれの評価結果に基づき、洗浄剤のタレ性を総合的に評価した。
〔評価基準〕
○: 洗浄剤の液状化が認められない
×: 洗浄剤の液状化が認められる
洗浄剤の保形性は、その膨潤性により評価した。
洗浄剤を押出し成形及び打錠成形により製造し、得られた洗浄剤の体積を予めデジマチックキャリパ(MITUTOYO製)によりそれぞれ測定した〔M1(cm3)〕。次いで、該洗浄剤を直径33mmの円柱状容器に入れ、水(25℃)を加えていき、吸水限界(洗浄剤の形状が保持される限界)まで吸水させ、同様にして体積を測定した〔M2(cm3)〕。以下の式:
膨潤率(%)=(M2/M1)×100
にM1及びM2の値を代入してそれぞれ膨潤率(%)を求め、以下の評価基準に従って洗浄剤の膨潤性を総合的に評価した。
〔評価基準〕
◎: 膨潤率が100%以上106%未満
○: 膨潤率が106%以上111%未満
△: 膨潤率が111%以上116%未満
×: 膨潤率が116%以上
洗浄剤の溶解性は、徐溶性(溶解持続性)、水温安定性及び溶け残りの状態により評価した。
洗浄剤を押出し成形及び打錠成形により製造し、得られた洗浄剤をそれぞれ側面底部に10mm(幅)×1mm(高さ)のスリットを6箇所設けた円筒状の容器内に設置し、それをトイレタンク(東洋陶器株式会社製、商品名:TOTO S781B)内にそれぞれ投入した。30分ごとに自動フラッシュし、洗浄剤がなくなるまでのフラッシュ回数を求め、以下の評価基準に従って洗浄剤の徐溶性を総合的に評価した。なお、水温は10℃とした。
〔評価基準〕
○: フラッシュ回数が450〜549
△: フラッシュ回数が350〜449
×: フラッシュ回数が250〜349
洗浄剤を押出し成形及び打錠成形により製造し、得られた洗浄剤を風袋に入れて10℃又は25℃に調整した水2000mL中に吊るした。攪拌機(井内製)で300rpmにて水を攪拌し、経時的に洗浄剤の減少を確認し、洗浄剤がなくなるまでの時間を測定した。得られた10℃及び25℃での測定時間の関係〔(10℃での測定時間)÷(25℃での測定時間)〕を求め、以下の評価基準に従って、洗浄剤の水温安定性を総合的に評価した。
〔評価基準〕
○: 測定時間の関係が1以上1.5未満である
×: 測定時間の関係が1.5以上である
洗浄剤を押出し成形及び打錠成形により製造し、得られた洗浄剤をそれぞれ側面底部に10mm(幅)×1mm(高さ)のスリットを6箇所設けた円筒状の容器内に設置し、水を流量500mL/分で該容器の蓋及び側面部に伝わせて流し込んだ。この操作を該容器から流出する水に色(青色)が確認できなくなるまで1時間毎に繰り返し、残渣を観察し、以下の評価基準に従って洗浄剤の溶け残りの状態を総合的に評価した。なお、水温は25℃とした。
〔評価基準〕
○: 塊がないか、又は0mmを超え2mm未満の塊
△: 2mm以上10mm未満の塊
×: 10mm以上の塊
表1に各洗浄剤の配合を示す。各洗浄剤を以下の方法で製造した。
表1記載の各成分のうち、A、A’、B、B’、D’、Eを混練機(高津製作所製)にて混練後、予め均一に混合したC、Dを添加し、再度混練し、混合粉を得た。
前記(1)押出し成形と同様にして得た混合粉を乳鉢で充分に混練した。原料混合物を直径30mmの打錠型を使用し、油圧式のプレス機(理研製)にてプレス成形し(10MPa)、1個当たりの重量が20gである錠剤状の洗浄剤を得た。
Claims (7)
- (A)25℃で固体である水溶性の界面活性剤、並びに(B)デキストリン及び/又はα化デンプンを含有してなる水洗トイレ用固形洗浄剤であって、該洗浄剤中、前記界面活性剤が陰イオン性界面活性剤であり、非イオン性界面活性剤を含まないか、含む場合でも1重量%未満である、水洗トイレ用固形洗浄剤。
- (A)25℃で固体である水溶性の界面活性剤、(B)デキストリン及び/又はα化デンプン、(C)吸液量が1g/g以上の吸液性固体、並びに(D)25℃で液体である油性及び/又は水性の液体を含有してなる水洗トイレ用固形洗浄剤であって、該洗浄剤中、前記界面活性剤が陰イオン性界面活性剤であり、非イオン性界面活性剤を含まないか、含む場合でも1重量%未満である、水洗トイレ用固形洗浄剤。
- (E)25℃で固体である水溶性の無機又は有機ビルダーをさらに含有してなるものである請求項2記載の洗浄剤。
- (C)の吸液性固体の含有量が5重量%未満である請求項2又は3記載の洗浄剤。
- (A)の界面活性剤と(B)のデキストリン及び/又はα化デンプンとの含有量比〔(A)/(B)〕が重量比で100/5〜100/60である請求項1〜4いずれか記載の洗浄剤。
- 押出し成形、プレス成形又は打錠成形により成形してなる請求項1〜5いずれか記載の洗浄剤。
- (B)のデキストリン及び/又はα化デンプンの含有量が5〜40重量%である請求項1〜6いずれか記載の洗浄剤。
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JPH08157896A (ja) * | 1994-12-02 | 1996-06-18 | Kobayashi Pharmaceut Co Ltd | トイレ用洗浄剤組成物及びその製造方法 |
JP2002226899A (ja) * | 2001-01-31 | 2002-08-14 | Fumakilla Ltd | 水洗トイレ用固形洗浄剤 |
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JPH08157896A (ja) * | 1994-12-02 | 1996-06-18 | Kobayashi Pharmaceut Co Ltd | トイレ用洗浄剤組成物及びその製造方法 |
JP2002226899A (ja) * | 2001-01-31 | 2002-08-14 | Fumakilla Ltd | 水洗トイレ用固形洗浄剤 |
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