JP4480173B2 - Oat granule with high concentration of β-glucan - Google Patents
Oat granule with high concentration of β-glucan Download PDFInfo
- Publication number
- JP4480173B2 JP4480173B2 JP2006307785A JP2006307785A JP4480173B2 JP 4480173 B2 JP4480173 B2 JP 4480173B2 JP 2006307785 A JP2006307785 A JP 2006307785A JP 2006307785 A JP2006307785 A JP 2006307785A JP 4480173 B2 JP4480173 B2 JP 4480173B2
- Authority
- JP
- Japan
- Prior art keywords
- product
- glucan
- wheat
- classified
- barley
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920002498 Beta-glucan Polymers 0.000 title claims description 56
- FYGDTMLNYKFZSV-URKRLVJHSA-N (2s,3r,4s,5s,6r)-2-[(2r,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5r,6s)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1[C@@H](CO)O[C@@H](OC2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-URKRLVJHSA-N 0.000 title claims description 55
- 239000008187 granular material Substances 0.000 title claims description 31
- 240000005979 Hordeum vulgare Species 0.000 claims description 44
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 43
- 241000209140 Triticum Species 0.000 claims description 42
- 235000021307 Triticum Nutrition 0.000 claims description 42
- 235000013305 food Nutrition 0.000 claims description 35
- 238000010298 pulverizing process Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- 235000007319 Avena orientalis Nutrition 0.000 claims description 9
- 244000075850 Avena orientalis Species 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 2
- 239000000047 product Substances 0.000 description 141
- 235000013325 dietary fiber Nutrition 0.000 description 40
- 239000000203 mixture Substances 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 229940098396 barley grain Drugs 0.000 description 18
- 235000008429 bread Nutrition 0.000 description 14
- 235000015067 sauces Nutrition 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 235000009508 confectionery Nutrition 0.000 description 12
- 235000012149 noodles Nutrition 0.000 description 12
- 240000007594 Oryza sativa Species 0.000 description 10
- 235000007164 Oryza sativa Nutrition 0.000 description 10
- 235000013312 flour Nutrition 0.000 description 10
- 235000009566 rice Nutrition 0.000 description 10
- 235000013339 cereals Nutrition 0.000 description 8
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 8
- 235000014347 soups Nutrition 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- 239000008280 blood Substances 0.000 description 6
- 210000004369 blood Anatomy 0.000 description 6
- 235000012489 doughnuts Nutrition 0.000 description 6
- 230000008719 thickening Effects 0.000 description 6
- 229920002907 Guar gum Polymers 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 229920001503 Glucan Polymers 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 244000294411 Mirabilis expansa Species 0.000 description 4
- 235000015429 Mirabilis expansa Nutrition 0.000 description 4
- 240000003768 Solanum lycopersicum Species 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000001164 bioregulatory effect Effects 0.000 description 4
- 229940088598 enzyme Drugs 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 235000003132 food thickener Nutrition 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 235000013372 meat Nutrition 0.000 description 4
- 235000013336 milk Nutrition 0.000 description 4
- 239000008267 milk Substances 0.000 description 4
- 210000004080 milk Anatomy 0.000 description 4
- 235000013536 miso Nutrition 0.000 description 4
- 235000013550 pizza Nutrition 0.000 description 4
- 235000011888 snacks Nutrition 0.000 description 4
- 235000015113 tomato pastes and purées Nutrition 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 230000003266 anti-allergic effect Effects 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 235000015071 dressings Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 3
- 239000002778 food additive Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 230000000968 intestinal effect Effects 0.000 description 3
- 235000012054 meals Nutrition 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 235000021067 refined food Nutrition 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 235000013547 stew Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 2
- 235000002568 Capsicum frutescens Nutrition 0.000 description 2
- 240000006766 Cornus mas Species 0.000 description 2
- 235000003363 Cornus mas Nutrition 0.000 description 2
- 208000006558 Dental Calculus Diseases 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 2
- 240000008620 Fagopyrum esculentum Species 0.000 description 2
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 2
- 235000011201 Ginkgo Nutrition 0.000 description 2
- 244000194101 Ginkgo biloba Species 0.000 description 2
- 235000008100 Ginkgo biloba Nutrition 0.000 description 2
- 241000519695 Ilex integra Species 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 235000021536 Sugar beet Nutrition 0.000 description 2
- 239000005862 Whey Substances 0.000 description 2
- 102000007544 Whey Proteins Human genes 0.000 description 2
- 108010046377 Whey Proteins Proteins 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000008351 acetate buffer Substances 0.000 description 2
- 235000015173 baked goods and baking mixes Nutrition 0.000 description 2
- 235000015895 biscuits Nutrition 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000019219 chocolate Nutrition 0.000 description 2
- 235000012495 crackers Nutrition 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 235000021438 curry Nutrition 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 235000013611 frozen food Nutrition 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 235000015220 hamburgers Nutrition 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 235000015243 ice cream Nutrition 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 235000015094 jam Nutrition 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- 235000008960 ketchup Nutrition 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000010746 mayonnaise Nutrition 0.000 description 2
- 239000008268 mayonnaise Substances 0.000 description 2
- 235000015927 pasta Nutrition 0.000 description 2
- 239000008363 phosphate buffer Substances 0.000 description 2
- 235000015108 pies Nutrition 0.000 description 2
- 235000012830 plain croissants Nutrition 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000011962 puddings Nutrition 0.000 description 2
- 235000013580 sausages Nutrition 0.000 description 2
- 235000014214 soft drink Nutrition 0.000 description 2
- 235000013322 soy milk Nutrition 0.000 description 2
- 235000011496 sports drink Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000015193 tomato juice Nutrition 0.000 description 2
- 235000015192 vegetable juice Nutrition 0.000 description 2
- 235000012773 waffles Nutrition 0.000 description 2
- 229940100445 wheat starch Drugs 0.000 description 2
- 235000013618 yogurt Nutrition 0.000 description 2
- FYGDTMLNYKFZSV-WFYNLLPOSA-N (2s,3r,4s,5s,6r)-2-[(2r,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,3s,4r,5r,6s)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-WFYNLLPOSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000007558 Avena sp Nutrition 0.000 description 1
- OWNRRUFOJXFKCU-UHFFFAOYSA-N Bromadiolone Chemical compound C=1C=C(C=2C=CC(Br)=CC=2)C=CC=1C(O)CC(C=1C(OC2=CC=CC=C2C=1O)=O)C1=CC=CC=C1 OWNRRUFOJXFKCU-UHFFFAOYSA-N 0.000 description 1
- 244000205754 Colocasia esculenta Species 0.000 description 1
- 235000006481 Colocasia esculenta Nutrition 0.000 description 1
- 108010015776 Glucose oxidase Proteins 0.000 description 1
- 239000004366 Glucose oxidase Substances 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 241000482268 Zea mays subsp. mays Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003149 assay kit Methods 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 235000008452 baby food Nutrition 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 102000006995 beta-Glucosidase Human genes 0.000 description 1
- 108010047754 beta-Glucosidase Proteins 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000007661 gastrointestinal function Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229940116332 glucose oxidase Drugs 0.000 description 1
- 235000019420 glucose oxidase Nutrition 0.000 description 1
- 108010046301 glucose peroxidase Proteins 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 238000011899 heat drying method Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 108010076363 licheninase Proteins 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000013622 meat product Nutrition 0.000 description 1
- 238000003032 molecular docking Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000013606 potato chips Nutrition 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000020991 processed meat Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000019685 rice crackers Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Cereal-Derived Products (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Description
本発明は、麦に含まれるβグルカンを高濃度に含有する麦顆粒に関する。 The present invention relates to a wheat granule containing a high concentration of β-glucan contained in wheat.
国民1人あたりの食物繊維摂取量は年々減少しており、食物繊維を積極的に摂取することが推奨されている。一方、大麦には水溶性食物繊維であるβグルカンが豊富に含まれている。大麦由来のβグルカンはβ(1,3、1,4)グルカンであり、様々な生体調節機能を有する機能性食物繊維として広く知られ、該βグルカンは血中コレステロール低下、血糖値上昇抑制、抗アレルギー作用、整腸作用、免疫増強作用、皮膚の保湿作用など、多くの機能を有する食品素材として注目されている。 Dietary fiber intake per capita is decreasing year by year, and it is recommended to take dietary fiber actively. On the other hand, barley is rich in β-glucan, which is a water-soluble dietary fiber. Β-glucan derived from barley is β (1,3,1,4) glucan, and is widely known as a functional dietary fiber having various bioregulatory functions. This β-glucan lowers blood cholesterol, suppresses blood sugar level increase, It attracts attention as a food material having many functions such as antiallergic action, intestinal regulation action, immunity enhancement action, and skin moisturizing action.
一方、大麦やオーツ麦由来の水溶性食物繊維であるβグルカンは、穀類に由来するものであり、でんぷん・脂質・蛋白質との親和性がきわめてよく、加工食品に対する添加剤として優れている。大麦やオーツ麦由来の水溶性食物繊維や不溶性食物繊維は、吸水性が高く、液体の粘性を高める効果があることが知られている。 On the other hand, β-glucan, which is a water-soluble dietary fiber derived from barley and oats, is derived from cereals, has extremely good affinity with starch, lipids and proteins, and is excellent as an additive for processed foods. It is known that water-soluble dietary fibers and insoluble dietary fibers derived from barley and oats have high water absorption and are effective in increasing the viscosity of the liquid.
たれ、ソース、ドレッシング、バッターミックス、シチュー類等において粘性を高めるために使用される増粘剤としては、グアーガム、キサンタンガム、タマリンドガム等が使用されているが、それらは本来の飲食物ではなく、食品に特定の機能を付与する目的で使用されることから食品添加物として扱われており、表示義務が必要となる。また食品業界では、食品添加物を使用しない、安心、安全な無添加加工食品の開発が推進されている。そのため食品添加物の代替品となるような、表示義務の不要な食品素材が望まれており、増粘剤等を水溶性食物繊維や不溶性食物繊維に置き換えることにより、無添加加工食品を開発することができる。 As a thickener used to increase viscosity in sauce, dressing, batter mix, stew, etc., guar gum, xanthan gum, tamarind gum, etc. are used, but they are not original foods and drinks, It is used as a food additive because it is used for the purpose of imparting a specific function to food, and requires labeling. In the food industry, development of safe and safe additive-free processed foods that do not use food additives is being promoted. Therefore, there is a demand for food materials that do not require labeling, which can be used as substitutes for food additives, and develop additive-free processed foods by replacing thickeners with water-soluble or insoluble dietary fibers. be able to.
食品中の食物繊維を増強する方法としては、従来の食物繊維の少ない食品に大麦粒、あるいは大麦粉を添加する方法が提案されている。米飯用に米粒の形に削った大麦粒が精製大麦として市販され、また大麦粉を小麦粉に添加した大麦麺も開発されているが、比較的大量の大麦の食品への添加は、食品の食感を損ねる。更に、大麦糠を篩等で粒度分けして、60M篩通過分を消化管機能改善剤あるいはコレステロール上昇抑制剤として用いることが提案されている(特許文献1を参照。)。この方法によると、期待される効果を得るために食品中に該大麦糠を13%以上添加する必要があり、このように比較的大量の大麦糠の食品への添加は、食品の食感を損ね、あるいは、小麦加工食品においては、製パン性等の加工適性を損ねる。 As a method for enhancing dietary fiber in foods, a method of adding barley grains or barley flour to conventional foods with low dietary fiber has been proposed. Barley grains shaved into rice grains for rice are commercially available as refined barley, and barley noodles in which barley flour is added to wheat flour have also been developed. Detract from the feeling. Furthermore, it has been proposed to classify barley meal with a sieve or the like and use the 60M sieve passage as a gastrointestinal function improving agent or a cholesterol elevation inhibitor (see Patent Document 1). According to this method, it is necessary to add 13% or more of the barley koji to the food in order to obtain the expected effect. Thus, the addition of a relatively large amount of barley koji to the food does not improve the food texture. Or, in processed wheat foods, processing ability such as bread-making property is impaired.
そこで、大麦に含まれる食物繊維を濃縮あるいは単離して利用する方法が検討され、大麦あるいはオーツ麦に含まれる食物繊維であるβグルカンを、抽出して利用する方法が提案されている。大麦より水溶性食物繊維であるβグルカンを抽出する方法としては、大麦を原料とし、水抽出により製造する方法(特許文献2を参照。)、あるいは、大麦を原料としてアルカリ抽出、中和、アルコール沈殿により重量平均分子量10万〜100万のグルカンを得る方法(特許文献3を参照。)、とう精歩留まり82%以下の大麦糠を原料として、80〜90℃の熱水にてβグルカンを抽出する方法(特許文献4を参照。)、更には大麦糠、オーツ麦糠、未精麦大麦粒粉砕物又は未精麦オーツ麦粒粉砕物を、温水抽出する方法(特許文献5を参照。)等が報告されている。 Then, the method of concentrating or isolating and using the dietary fiber contained in barley has been studied, and a method of extracting and using β-glucan, which is a dietary fiber contained in barley or oats, has been proposed. As a method for extracting β-glucan, which is a water-soluble dietary fiber from barley, a method using barley as a raw material and manufacturing by water extraction (see Patent Document 2), or alkali extraction, neutralization, alcohol using barley as a raw material A method of obtaining glucan having a weight average molecular weight of 100,000 to 1,000,000 by precipitation (refer to Patent Document 3), and extracting barley straw with a fine yield of 82% or less as raw material, extracting β-glucan with hot water at 80 to 90 ° C. And a method of extracting barley meal, oat meal, unmilled barley grain pulverized product, or unmilled oat grain crushed product with hot water (see Patent Document 5) and the like. It has been reported.
これらの抽出方法は、温水、熱水、アルカリ、アルコール、酵素といった溶媒を使用しており、βグルカンの抽出に際し、化学的な処理が施され、特にアルカリやアルコールといった溶媒での抽出方法は、大麦粉砕物に含まれるβグルカンを天然のまま抽出する方法であるとは言い難い。また、温水、熱水、アルカリ、アルコールといった溶媒を使用することによるコスト高や、廃水の処理、処理装置などが必要になり、抽出に時間を要する等の問題があった。 These extraction methods use a solvent such as warm water, hot water, alkali, alcohol, and enzyme, and are subjected to chemical treatment during the extraction of β-glucan. It is difficult to say that this is a method for extracting β-glucan contained in the barley pulverized product as it is. In addition, there are problems such as high costs due to the use of solvents such as hot water, hot water, alkali, and alcohol, treatment of waste water, treatment equipment, and the like, and extraction takes time.
本発明は、麦に含まれるβグルカンを高濃度に含有する麦の顆粒を提供することを課題とする。 This invention makes it a subject to provide the granule of the wheat which contains the beta glucan contained in wheat at high concentration.
<1> 本発明は、麦に由来する顆粒において、麦を粉砕することにより得た粉砕物を分級することにより得られる、粒サイズが40μ以上600μ以下の範囲であることを特徴とする顆粒である。
<2> 前記麦の粉砕の前処理として、麦に加熱蒸気処理をして、麦厚が1.5mm以下に圧扁した後に、乾燥処理をすることが好ましく、更に前記麦が、外皮を含む外周部が、麦の重量に対し15〜50重量%研削された麦であることが好ましい。
<3> 前記麦は、大麦、及び/又はオーツ麦であることが好ましい。
<4> 更に本発明は前記の何れかに記載の顆粒を使用した食品である。
<1> The present invention is a granule obtained by classifying a pulverized product obtained by pulverizing wheat in a granule derived from wheat, wherein the particle size is in the range of 40 μm to 600 μm. is there.
<2> As a pretreatment for pulverization of the wheat, it is preferable to subject the wheat to a steam treatment, and after pressing the wheat to a thickness of 1.5 mm or less, a drying treatment is performed, and the wheat further includes a hull. It is preferable that the outer peripheral portion is wheat ground by 15 to 50% by weight with respect to the weight of wheat.
<3> The barley is preferably barley and / or oats.
<4> Further, the present invention is a food using the granule according to any one of the above.
本発明は、水、アルカリ、アルコール、酵素等の溶媒や化学的な処理を施さずに得られる、高濃度のβグルカン、及び食物繊維を含有する麦の顆粒であり、βグルカンの生体調節機能を発揮する食品素材として使用することができる。又本発明の顆粒は、βグルカンを高濃度に含有するために、食品に由来する食品増粘剤としても用いることができる。 The present invention is a granule of wheat containing a high concentration of β-glucan and dietary fiber obtained without subjecting to a solvent or chemical treatment such as water, alkali, alcohol, enzyme, etc., and the bioregulatory function of β-glucan It can be used as a food material that demonstrates Moreover, since the granule of the present invention contains β-glucan at a high concentration, it can also be used as a food thickener derived from food.
本発明は、麦に由来する顆粒において、麦を粉砕することにより得た粉砕物を分級することにより得られる粒サイズが40μ以上600μ以下の範囲であることを特徴とする顆粒である。以下に本発明の実施の形態について詳説する。 The present invention is a granule derived from wheat, wherein the particle size obtained by classifying a pulverized product obtained by pulverizing wheat is in the range of 40 μm to 600 μm. Hereinafter, embodiments of the present invention will be described in detail.
本発明に用いられる麦は、いずれの種類の麦をも用いることができるが、目的とするβグルカンを多く含むものが望ましい。具体的には、大麦が好ましく、中でも、二条や六条等の皮付麦、及び裸麦がより好ましく、でん粉がもち性の性質を持ったもち性大麦、あるいはもち性裸大麦等が特に好ましい。又オーツ麦も大麦と同様に好ましく用いることができる。 As the wheat used in the present invention, any type of wheat can be used, but it is preferable that the wheat contains a large amount of the desired β-glucan. Specifically, barley is preferable, among which barley barley such as Nijo or 6 and barley are more preferable, and glutinous barley in which starch has a sticky property or glutinous naked barley is particularly preferable. Oats can also be preferably used in the same manner as barley.
前記麦を、イクシードミル等の粉砕機により粉砕する。該粉砕は、目開き600μmのシフターをスルーするように、より好ましくは500μmのシフターをスルーするように粉砕する。又該粉砕は、粉砕機の粉砕回転数が大きい方が、より細かい粉砕品を調整でき、でん粉質等の食物繊維以外の成分と食物繊維を分離し、食物繊維をより高濃度で得ることができることから好ましい。前記粉砕は、イクシードミルの使用においては粉砕回転数が11800rpm以上、より好ましくは15800rpm以上、さらに好ましくは19800rpm以上で粉砕することが好ましい。 The wheat is pulverized by a pulverizer such as an Exceed Mill. The pulverization is performed so as to pass through a shifter having an opening of 600 μm, more preferably through a shifter having a size of 500 μm. In addition, the pulverization of the pulverizer having a larger pulverization speed can adjust a finer pulverized product, and can separate the dietary fiber from components other than dietary fiber such as starch and obtain a higher concentration of dietary fiber. It is preferable because it is possible. The pulverization is preferably performed at an pulverization speed of 11800 rpm or more, more preferably 15800 rpm or more, and further preferably 19800 rpm or more when using an seed mill.
本発明は、前記粉砕をすることにより、麦に含有されるデンプンが微小な粉末となる一方で、βグルカンを含む繊維質が比較的大きな顆粒となることから、粉砕物を分級することにより、麦中のβグルカンを高濃度に含有する顆粒を得ることができるものである。 In the present invention, the starch contained in the wheat becomes a fine powder by the pulverization, while the fibrous material containing β-glucan becomes relatively large granules. Granules containing a high concentration of β-glucan in wheat can be obtained.
前記粉砕物について、シフター等の分級器を用いて篩い、40〜600μm以上の顆粒、より好ましくは60〜400μmの顆粒を得る。前記40〜600μm以上の顆粒には、麦の平均βグルカン含量である4〜5重量%に対し、4〜6倍の20〜25重量%のβグルカンが含まれ、高濃度のβグルカンを得ることができる。 The pulverized product is sieved using a classifier such as a shifter to obtain granules of 40 to 600 μm or more, more preferably 60 to 400 μm. The granules of 40 to 600 μm or more contain 4 to 6 times 20 to 25% by weight of β-glucan with respect to 4 to 5% by weight of the average β-glucan content of wheat, thereby obtaining a high concentration of β-glucan. be able to.
又、前記40〜600μmの範囲の顆粒には、麦の平均不溶性食物繊維含量である2〜4重量%に対し、3〜5倍の高濃度の不溶性食物繊維が含有され、総食物繊維としては、麦の平均総食物繊維の3〜5倍の高濃度の総食物繊維が含有される。 The granules in the range of 40 to 600 μm contain 3 to 5 times higher concentration of insoluble dietary fiber relative to 2 to 4% by weight of the average insoluble dietary fiber content of wheat. It contains 3 to 5 times higher total dietary fiber than the average total dietary fiber of wheat.
前記麦を粉砕するにあたっては、以下の前処理を行うことが好ましい。先ずは麦に含まれる異物、夾雑物を除去し、外皮を含む外周部を研削することにより精白する。該研削は、麦の外周部を麦の重量に対し15〜50重量%、より好ましくは30〜40重量%まで研削することが好ましい。該外周部は、βグルカンが多量には含まれていないためである。 In crushing the wheat, the following pretreatment is preferably performed. First, foreign matters and impurities contained in the wheat are removed, and whitening is performed by grinding the outer peripheral portion including the outer skin. In the grinding, it is preferable to grind the outer peripheral part of the wheat to 15 to 50% by weight, more preferably 30 to 40% by weight with respect to the weight of the wheat. This is because the outer periphery does not contain a large amount of β-glucan.
前記精白した麦について、加水し、加熱蒸気処理を行う。該加水、加熱蒸気処理は、麦に加水して水分値を調整した後に、大麦を蒸して水蒸気で加熱することにより行うことが好ましい。該加水は、大麦の水分値が10〜20%、より好ましくは13〜17%に調整されることが好ましい。又前記加熱蒸気処理は、水蒸気により70〜90℃、より好ましくは75〜85℃に加熱されることが好ましい。 The refined wheat is hydrated and heated with steam. The hydration and heating steam treatment is preferably carried out by adding water to the wheat and adjusting the moisture value, and then steaming the barley and heating it with steam. The water content of barley is preferably adjusted to 10 to 20%, more preferably 13 to 17%. Moreover, it is preferable that the said heating steam process is heated at 70-90 degreeC with water vapor | steam, More preferably, it is 75-85 degreeC.
前記大麦は粉砕前に圧扁されて、該圧扁大麦とした上で、粉砕することが、製粉しやすく、より細かい粉砕品を調整でき、でん粉質等の他の成分と食物繊維を分離し、食物繊維をより高濃度で得ることができる上から好ましい。前記圧扁は、麦厚が1.5mm以下、より好ましくは1.2mm以下、さらに好ましくは0.9mm以下の圧扁大麦とすることが好ましい。 The barley is crushed before pulverization to form the crushed barley, and pulverization is easy to mill, finer pulverized products can be prepared, and dietary fiber can be separated from other ingredients such as starch. From the viewpoint that dietary fiber can be obtained at a higher concentration. It is preferable that the pressed barley has an oat thickness of 1.5 mm or less, more preferably 1.2 mm or less, and still more preferably 0.9 mm or less.
前記加水、加熱蒸気処理後の圧扁大麦を、水分値が16〜10%、より好ましくは15〜13%になるよう冷却、乾燥する。該冷却は室内において放冷することにより行うことが好ましい。該乾燥は、加熱乾燥法等の乾燥方法として知られる任意の方法を用いることができる。 The pressed barley after the hydration and heating steam treatment is cooled and dried so that the moisture value is 16 to 10%, more preferably 15 to 13%. The cooling is preferably performed by allowing to cool in the room. For the drying, any method known as a drying method such as a heat drying method can be used.
前記により得られた、40〜600μmの範囲の顆粒、より好ましくは60〜400μmの顆粒は、麦由来のβ(1,3、1,4)グルカン及び食物繊維を高濃度に含有するために、血中コレステロール低下、血糖値上昇抑制、抗アレルギー作用、整腸作用、免疫増強作用、皮膚の保湿作用等の様々な生体調節機能を有する食品素材として用いられることができる。又本発明の顆粒は、βグルカンを高濃度に含有するために、食品に由来する食品増粘剤としても用いることができる。 Granules in the range of 40 to 600 μm, more preferably 60 to 400 μm, obtained as described above, contain β (1,3,1,4) glucan derived from wheat and dietary fiber in a high concentration. It can be used as a food material having various bioregulatory functions, such as blood cholesterol lowering, blood sugar level increase inhibition, antiallergic action, intestinal regulation action, immune enhancement action, and skin moisturizing action. Moreover, since the granule of the present invention contains β-glucan at a high concentration, it can also be used as a food thickener derived from food.
前記顆粒を用いた生体調節機能を有する食品素材として具体的には、食パン、菓子パン、惣菜パン、フランスパン、クロワッサン、パイ、カステラ、スポンジケーキ、バターケーキ、シュー、ワッフル、蒸しパン、ピザ等のベーカリー製品、ドーナツ、ビスケット、クラッカー、饅頭、和菓子、ようかん、最中、ういろう、団子、大福もち、キャンデー、ガム、チョコレート、飴、アイスクリーム、ソフトクリーム、シャーベット、アイスキャンデー、ラクトアイス、氷菓、ゼリー、プリン等の製菓類、 Specifically, the food material having a bioregulatory function using the granule, such as bread, confectionery bread, sugar beet bread, French bread, croissant, pie, castella, sponge cake, butter cake, shoe, waffle, steamed bread, pizza, etc. Bakery products, donuts, biscuits, crackers, buns, Japanese sweets, yokan, in the middle, Uiro, dumplings, Daifuku mochi, candy, gum, chocolate, rice cake, ice cream, soft cream, sorbet, popsicles, lact ice, ice confectionery, jelly, Confectionery such as pudding,
うどん、パスタ、ほうとう、中華そば、焼きそば、ちゃんぽん、そば、ひやむぎ、そうめん等のめん類、味噌、ジャム、たれ、ソース、ウスターソース、トマトソース、トマトケチャップ、トマトペースト、トマトピューレ、チリソース、ドレッシング、マヨネーズ、タルタルソース等の調味料類、シチュー、ポタージュスープ、コンソメスープ、味噌汁、雑煮、カレー等のスープ類、清涼飲料水、炭酸飲料水、ジュース、果汁、野菜ジュース、トマトジュース、シェーク、コーヒー、カフェオレ、スポーツドリンク等の飲料、牛乳、加工乳、ヨーグルト、乳清飲料、乳酸菌飲料等の乳製品、 Udon, pasta, hoto, Chinese noodles, fried noodles, champon, soba noodles, noodles such as noodles, miso, jam, sauce, sauce, Worcester sauce, tomato sauce, tomato ketchup, tomato paste, tomato puree, chili sauce, dressing, mayonnaise, Seasonings such as tartar sauce, stew, potage soup, consommé soup, miso soup, simmered, curry soup, soft drink, carbonated drink, juice, fruit juice, vegetable juice, tomato juice, shake, coffee, cafe au lait Dairy products such as sports drinks, milk, processed milk, yogurt, whey drinks, lactic acid bacteria drinks,
ホットケーキミックス、ケーキミックス、スナックロールミックス、ドーナツミックス、イーストドーナツミックス、菓子パンミックス、蒸しパンミックス、ピザミックス、お好み焼きミックス、たこ焼きミックス、餃子ミックス、バッターミックス、フリッターミックス、天ぷら粉、唐揚げ粉、ブレッダーミックス等のプレミックス、米飯類、おにぎり、にぎり寿司、まき寿司、ちらし寿司、餅、炒飯、ピラフ、お茶漬け、ドリア、ビーフン、あられ、せんべい等の米加工品、 Hot cake mix, cake mix, snack roll mix, donut mix, yeast donut mix, confectionery bread mix, steamed bread mix, pizza mix, okonomiyaki mix, takoyaki mix, dumpling mix, batter mix, fritter mix, tempura flour, deep-fried flour, Premixes such as blender mixes, cooked rice, rice balls, nigiri sushi, maki sushi, chirashi sushi, rice cakes, fried rice, pilaf, ochazuke, doria, rice noodles, taro, rice crackers and other processed rice products
シリアル、ピロシキ、コーンフレーク、コーンスナック、ポップコーン、ポテトスナック、ポテトチップ、スイートポテト、ポテトフライ等の穀物加工品、豆腐、豆乳、豆乳飲料、湯葉、油揚げ、厚揚げ、がんもどき、あん等の大豆加工品、ハンバーグ、ソーセージ、ハム、ミートボール、肉団子、肉まん、シュウマイ等の畜肉加工品、かまぼこ、さつま揚げ、つみれ、練り製品等の水産加工品、サプリメント、錠剤、ドリンク剤等の健康食品、アレルギー患者用食品、乳児用食品、老人用食品、美容食品、レトルト食品、低カロリー食品、冷凍食品、インスタント食品等を挙げることができる。 Cereals, piroshki, cornflakes, corn snacks, popcorn, potato snacks, potato chips, sweet potatoes, fried potatoes and other processed grains, tofu, soy milk, soy milk drinks, yuba, deep-fried, deep-fried, soy beans Processed products, hamburgers, sausages, ham, meatballs, meat dumplings, meat buns, meat products such as shumai, fishery products such as kamaboko, sweet potato fried, tsumire, kneaded products, health foods such as supplements, tablets, and drinks, allergic patients Food, baby food, food for the elderly, beauty food, retort food, low calorie food, frozen food, instant food and the like.
又本発明の顆粒は、βグルカンを高濃度に含有するために、食品に由来する食品増粘剤としても用いることができる。前記顆粒を増粘剤として用いることができる食品として具体的には、食パン、菓子パン、惣菜パン、フランスパン、クロワッサン、パイ、カステラ、スポンジケーキ、バターケーキ、シュー、ワッフル、蒸しパン、ピザ等のベーカリー製品、ドーナツ、ビスケット、クラッカー、饅頭、和菓子、ようかん、最中、ういろう、団子、大福もち、キャンデー、ガム、チョコレート、飴、アイスクリーム、ソフトクリーム、シャーベット、アイスキャンデー、ラクトアイス、氷菓、ゼリー、プリン等の製菓類、 Moreover, since the granule of the present invention contains β-glucan at a high concentration, it can also be used as a food thickener derived from food. Specifically, foods that can be used as a thickener, such as bread, confectionery bread, sugar beet bread, French bread, croissant, pie, castella, sponge cake, butter cake, shoe, waffle, steamed bread, pizza, etc. Bakery products, donuts, biscuits, crackers, buns, Japanese sweets, yokan, in the middle, Uiro, dumplings, Daifuku mochi, candy, gum, chocolate, rice cake, ice cream, soft cream, sorbet, popsicles, lact ice, ice confectionery, jelly, Confectionery such as pudding,
うどん、パスタ、ほうとう、中華そば、焼きそば、ちゃんぽん、そば、ひやむぎ、そうめん等のめん類、味噌、ジャム、たれ、ソース、ウスターソース、トマトソース、トマトケチャップ、トマトペースト、トマトピューレ、チリソース、ドレッシング、マヨネーズ、タルタルソース等の調味料類、シチュー、ポタージュスープ、コンソメスープ、味噌汁、雑煮、カレー等のスープ類、清涼飲料水、炭酸飲料水、ジュース、果汁、野菜ジュース、トマトジュース、シェーク、コーヒー、カフェオレ、スポーツドリンク等の飲料、牛乳、加工乳、ヨーグルト、乳清飲料、乳酸菌飲料等の乳製品、 Udon, pasta, hoto, Chinese noodles, fried noodles, champon, soba noodles, noodles such as noodles, miso, jam, sauce, sauce, Worcester sauce, tomato sauce, tomato ketchup, tomato paste, tomato puree, chili sauce, dressing, mayonnaise, Seasonings such as tartar sauce, stew, potage soup, consommé soup, miso soup, simmered, curry soup, soft drink, carbonated drink, juice, fruit juice, vegetable juice, tomato juice, shake, coffee, cafe au lait Dairy products such as sports drinks, milk, processed milk, yogurt, whey drinks, lactic acid bacteria drinks,
ホットケーキミックス、ケーキミックス、スナックロールミックス、ドーナツミックス、イーストドーナツミックス、菓子パンミックス、蒸しパンミックス、ピザミックス、お好み焼きミックス、たこ焼きミックス、餃子ミックス、バッターミックス、フリッターミックス、天ぷら粉、唐揚げ粉、ブレッダーミックス等のプレミックス、ハンバーグ、ソーセージ、ハム、ミートボール、肉団子、肉まん、シュウマイ等の畜肉加工品、かまぼこ、さつま揚げ、つみれ、練り製品等の水産加工品、及びレトルト食品、低カロリー食品、冷凍食品、インスタント食品等を挙げることができる。 Hot cake mix, cake mix, snack roll mix, donut mix, yeast donut mix, confectionery bread mix, steamed bread mix, pizza mix, okonomiyaki mix, takoyaki mix, dumpling mix, batter mix, fritter mix, tempura flour, deep-fried flour, Premixes such as bleeder mixes, processed meat products such as hamburger, sausage, ham, meatballs, meat dumplings, meat balls, shumai, fishery products such as kamaboko, fried fish, tsumi, kneaded products, retort foods, low calorie foods, Examples include frozen foods and instant foods.
以下に本発明の更に具体的内容を実施例により説明するが、本発明は以下の実施例に限定されるものではない。
<実施例1>
本実施例に使用した大麦は、新潟県産ファイバースノーを用いた。該大麦をドッケージにて異物、夾雑物を除去して精選し、外周部から37%(搗精歩留まり63%)まで研削式搗精機((株)佐竹製作所社製、商品名:小型研削精米機RME25A)を用いて精白した後、水分値が15±1%になるように加水し、75℃以上に加熱されるよう蒸し器を用いて加熱蒸気処理した後、麦厚が0.9mm以下になるようドラムドライヤー(ジョンソンボイラ(株)社製、商品名:ドラムドライヤーJM-T)を用い圧扁して、圧扁大麦を得た。該圧扁大麦を放冷して冷却し、水分値が14.5%以下になるように加熱乾燥機(ヤマト科学(株)社製、商品名:ヤマト精密恒温器Fine Oven DF62)で乾燥した後、イクシードミル(槇野産業社製、商品名:イクシードミルEM-1A)を用いて、粉砕回転数19800rpmで粉砕して、大麦粒粉砕物を得た。該大麦粒粉砕物の目開き600μmのシフタースルー品を、本実施例1の大麦粒粉砕品の供用物とした。
Hereinafter, more specific contents of the present invention will be described by way of examples. However, the present invention is not limited to the following examples.
<Example 1>
The barley used in this example was Niigata fiber snow. The barley is carefully selected by removing foreign substances and impurities with a docking machine, and grinding type milling machine (manufactured by Satake Manufacturing Co., Ltd., trade name: RME25A) from the outer circumference to 37% (63% yield of milling yield). ) And then watered so that the moisture value becomes 15 ± 1%, and after steaming using a steamer to be heated to 75 ° C. or higher, the wheat thickness is 0.9 mm or less. Pressed barley was obtained by pressing using a drum dryer (trade name: Drum dryer JM-T, manufactured by Johnson Boiler Co., Ltd.). The pressure barley is allowed to cool and cooled, and dried with a heat dryer (Yamato Scientific Co., Ltd., trade name: Yamato Precision Incubator Fine Oven DF62) so that the moisture value is 14.5% or less. A barley grain pulverized product was obtained by pulverizing at an pulverization speed of 19800 rpm using an ixed mill (manufactured by Hadano Sangyo Co., Ltd., trade name: IXED Mill EM-1A). The shifter-through product having an aperture of 600 μm of the barley grain pulverized product was used as the service product of the barley grain pulverized product of Example 1.
前記大麦粒粉砕物を、空気分級機(ALPINE社製)を用い、シフター(IIDA MANUFACTURING社製、商品名THE IIDA TESTING SIEVE)の目開き150μで空気分級し、オーバー品を分級1の粉砕品(以下単に分級品1ということがある。又以下の他のサイズの分級も同等である。)とした。目開き150μのシフタースルー品を目開き106μのシフターで空気分級し、オーバー品を分級品2とした。目開き106μのシフタースルー品を目開き75μのシフターで空気分級し、オーバー品を分級品3とした。目開き75μのシフタースルー品を目開き53μのシフターで空気分級し、オーバー品を分級品4とした。目開き53μのシフタースルー品を分級品5とした。各分級品の構成割合を表1に示す。なお比較例として、前記実施例1の大麦粒粉砕品の供用物について空気分級を行わなかった粉砕品を用いた。 Using an air classifier (manufactured by ALPINE), the barley grain pulverized product is air-classified with an aperture of 150 μm of a shifter (manufactured by IIDA MANUFACTURING, trade name THE IIDA TESTING SIEVE), and the over product is pulverized product of class 1 Hereinafter, it may be simply referred to as a classified product 1. The following other sizes are also equivalent): A shifter-through product having a mesh opening of 150 μm was air-classified with a shifter having a mesh opening of 106 μm, and an over-product was classified as classification product 2. A shifter-through product having a mesh opening of 106 μm was air-classified with a shifter having a mesh opening of 75 μm. A shifter-through product having a mesh opening of 75 μm was air-classified with a shifter having a mesh opening of 53 μm. A shifter-through product with a mesh opening of 53 μm was designated as a classified product 5. Table 1 shows the composition ratio of each classified product. As a comparative example, a pulverized product that was not subjected to air classification was used for the service product of the barley grain pulverized product of Example 1.
前記により得た大麦分級品1〜5、及び比較例について、各分級品のβグルカン含有量を測定した。βグルカンの分析は、メガザイム社のβグルカン測定キット(商品名:(1-3)(1-4)BETA-D-GLUCAN ASSAY KIT(McCLEARY METHOD))を用いて、酵素法により、以下の通りに行った。 About the barley classification products 1-5 obtained by the above, and the comparative example, beta glucan content of each classification product was measured. Analysis of β-glucan was carried out by the enzyme method using β-glucan measurement kit (trade name: (1-3) (1-4) BETA-D-GLUCAN ASSAY KIT (McCLEARY METHOD)) of Megazyme as follows. Went to.
まず、各分級品の水分含量を測定した後に、各分級品の100mgを50mlの遠沈管に入れ、50%エタノール溶液を1mL加え、各分級品の分散物を得た。前記分散物に5mLの20mMリン酸緩衝液(pH6.5)を加えて混合した後、煮沸した湯浴中によくかき混ぜながら入れ、ゲルの塊が出来ないように注意し、2分間加熱した。該遠沈管を40℃に冷却後、リケナーゼ酵素溶液(キットに付属するバイアルを20mMリン酸緩衝液で20倍に希釈)の0.2mL(10U)を加え、40℃で1時間反応させた。1時間後、蒸留水を24mL加えて混合し、3000rpmで10分間遠心分離した。 First, after measuring the water content of each classified product, 100 mg of each classified product was placed in a 50 ml centrifuge tube, and 1 mL of 50% ethanol solution was added to obtain a dispersion of each classified product. After adding 5 mL of 20 mM phosphate buffer (pH 6.5) to the dispersion and mixing, the mixture was placed in a boiled water bath while stirring well, and heated for 2 minutes, taking care not to form a gel lump. After the centrifuge tube was cooled to 40 ° C., 0.2 mL (10 U) of a lichenase enzyme solution (a vial attached to the kit was diluted 20-fold with 20 mM phosphate buffer) was added and reacted at 40 ° C. for 1 hour. After 1 hour, 24 mL of distilled water was added and mixed, and centrifuged at 3000 rpm for 10 minutes.
前記遠心分離した上清0.1mLを、それぞれ3本の10mL遠沈管に取り、1本には0.1mLの50mM酢酸緩衝液(pH4.0)を、他の2本には0.1mL(0.2U)のβグルコシダーゼ溶液(前記キットに付属するバイアルを、50mM酢酸緩衝溶液で20倍に希釈)を加え、40℃にて15分間反応させた。各遠沈管に4mLのグルコースオキシダーゼ/ペルオキシダーゼ溶液を加えて、40℃にて20分間反応させ、各サンプルの510nmにおける吸光度(ΔE)を測定した。βグルカン含量は、次式1により求めた。結果を表1に示す。 0.1 mL of the centrifuged supernatant is taken into three 10 mL centrifuge tubes, one with 0.1 mL of 50 mM acetate buffer (pH 4.0) and the other two with 0.1 mL ( 0.2 U) β-glucosidase solution (the vial attached to the kit was diluted 20-fold with a 50 mM acetate buffer solution) and reacted at 40 ° C. for 15 minutes. 4 mL of glucose oxidase / peroxidase solution was added to each centrifuge tube and reacted at 40 ° C. for 20 minutes, and the absorbance (ΔE) at 510 nm of each sample was measured. The β-glucan content was determined by the following formula 1. The results are shown in Table 1.
βグルカン含量(%)=ΔE×F/W×27 式1 β-glucan content (%) = ΔE × F / W × 27 Formula 1
前記式において、ΔEは各サンプルの510nmにおける吸光度、Fは100(μgのグルコース)/100μgグルコースの吸光度(吸光度からμgへの換算)、Wは測定に用いた大麦粉砕物の乾燥重量(mg)をそれぞれ示す。 In the above formula, ΔE is the absorbance at 510 nm of each sample, F is the absorbance of 100 (μg glucose) / 100 μg glucose (converted from absorbance to μg), W is the dry weight (mg) of the barley grind used in the measurement Respectively.
又前記各分級品について、不溶性食物繊維の含量を、酵素重量法により測定した。総食物繊維の含量は、水溶性食物繊維(βグルカン)含量と不溶性食物繊維含量をトータルして求めた。結果を表1に示す。 Further, the content of insoluble dietary fiber for each of the classified products was measured by an enzyme gravimetric method. The total dietary fiber content was determined by totaling the water-soluble dietary fiber (β-glucan) content and the insoluble dietary fiber content. The results are shown in Table 1.
前記表1より、大麦粒粉砕物の各分級品におけるβグルカン含有量は、分級品1は12.24、分級品2は16.89、分級品3は23.40、分級品4は20.33、分級品5は0.74となり、53μを境にしてβグルカンがきれいに分離されていることがわかった。また、106〜75μの分級品3においてβグルカン含量が最も多く含まれた。また不溶性食物繊維の含量は、分級品1は4.27、分級品2は13.48、分級品3は13.98、分級品4は8.68、分級品5は0.25となり、53μを境にして不溶性食物繊維がきれいに分離されていることがわかった。また、106〜75μの分級品3において、不溶性食物繊維含量が最も多く含まれた。 From Table 1, the β-glucan content in each classified product of the barley grain pulverized product is 12.24 for the classified product 1, 16.89 for the classified product 2, 23.40 for the classified product 3, and 20 for the classified product 4. 33, classified product 5 was 0.74, and it was found that β-glucan was clearly separated at 53 μ as a boundary. Further, the β-glucan content was the highest in the classified product 3 of 106 to 75 μm. The content of insoluble dietary fiber is 4.27 for classified product 1, 13.48 for classified product 2, 13.98 for classified product 3, 8.68 for classified product 4, 0.25 for classified product 5, and 53 μm. It was found that insoluble dietary fiber was separated cleanly at the boundary. In addition, the classified product 3 of 106 to 75 μm contained the most insoluble dietary fiber content.
<実施例2>
前記実施例1の結果、粒子の大きさによってβグルカンが存在する粒度区域がわかったため、次にβグルカンが存在する粒度区域を更に粉砕、空気分級し、βグルカン含量を高める試験を行った。
分級に使用した大麦粒粉砕物は、実施例1で調製したものと同様のものを使用した。実施例1の大麦粒粉砕物を、目開き100μのシフターで空気分級し、オーバー品を実施例2の大麦粒粉砕品の供用物とした。該実施例2の大麦粒粉砕品の供用物をイクシードミル(槇野産業製、商品名:イクシードミルEM-1A)を用い、粉砕回転数19800rpmの条件でさらに細かく粉砕した。
<Example 2>
As a result of Example 1, since the particle size area where β-glucan was present was found depending on the particle size, the particle size area where β-glucan was present was further pulverized and air-classified to increase the β-glucan content.
The barley grain pulverized product used for classification was the same as that prepared in Example 1. The barley grain pulverized product of Example 1 was air-classified with a shifter having an opening of 100 μm, and the over product was used as the service product of the barley grain pulverized product of Example 2. The product obtained by pulverizing the barley grains of Example 2 was further finely pulverized using an ix seed mill (trade name: XX seed mill EM-1A, manufactured by Hadano Sangyo Co., Ltd.) at a pulverization speed of 19800 rpm.
この粉砕品を目開き355μのシフターで空気分級し、オーバー品を分級品22とした。目開き355μのシフタースルー品を目開き250μのシフターで空気分級し、オーバー分を分級品23とした。目開き250μのシフタースルー品を目開き212μのシフターで空気分級し、オーバー品を分級品24とした。目開き212μのシフタースルー品を目開き149μのシフターで空気分級し、オーバー品を分級品25とした。目開き149μのシフタースルー品を目開き106μのシフターで空気分級し、オーバー品を分級品26とした。目開き106μのシフタースルー品を目開き63μのシフターで空気分級し、オーバー品を分級品27とした。目開き63μのシフタースルー品を分級品28とした。なお比較例として、前記実施例2の大麦粒粉砕品の供用物について、空気分級を行わなかった粉砕品を用いた。 This pulverized product was air-classified with a shifter having an opening of 355 μm, and the over product was designated as the classified product 22. A shifter-through product having a mesh opening of 355 μm was air-classified with a shifter having a mesh opening of 250 μm, and the over-mixing product was designated as a classified product 23. A shifter-through product having a mesh opening of 250 μm was air-classified with a shifter having a mesh opening of 212 μm, and an over-product was designated as a classified product 24. A shifter-through product having a mesh opening of 212 μm was air-classified with a shifter having a mesh opening of 149 μm. A shifter-through product having a mesh size of 149 μm was air-classified with a shifter having a mesh size of 106 μm, and the over product was classified as a classified product 26. A shifter-through product with a mesh opening of 106 μm was air-classified with a shifter with a mesh opening of 63 μm, and an over-product was classified into a classified product 27. A shifter-through product having a mesh opening of 63 μm was designated as a classified product 28. As a comparative example, a pulverized product that was not subjected to air classification was used for the service product of the barley grain pulverized product of Example 2.
前記分級品22〜28、及び比較例について、実施例1と同様に、βグルカン含有量を測定した。結果を表2に示す。 For the classified products 22 to 28 and the comparative example, the β-glucan content was measured in the same manner as in Example 1. The results are shown in Table 2.
表2の結果、大麦粒粉砕物の分級品におけるβグルカン含有量は、比較例は15.08、分級品22は19.71、分級品23は21.21、分級品24は18.72、分級品25は20.04、分級品26は20.97、分級品27は21.63、分級品28は6.34となり、63μを境にしてβグルカンが分離され、βグルカンの濃度を高めることが出来ることがわかった。また、106〜63μの分級品27においてβグルカン含量が最も多く含まれた。また不溶性食物繊維の含量は、分級品21は13.75、分級品22は11.07、分級品23は11.18、分級品24は16.91、分級品25は20.86、分級品26は22.15、分級品27は21.74、分級品28は7.94となり、63μを境にして不溶性食物繊維が分離され、不溶性食物繊維の濃度を高めることが出来ることがわかった。また、149〜106μの分級品26において不溶性食物繊維含量が最も多く含まれた。 As a result of Table 2, the content of β-glucan in the classified product of the barley grain pulverized product is 15.08 for the comparative example, 19.71 for the classified product 22, 21.21 for the classified product 23, 18.72 for the classified product 24, Classification product 25 is 20.04, classification product 26 is 20.97, classification product 27 is 21.63, classification product 28 is 6.34, and β-glucan is separated at 63 μ as a boundary to increase the concentration of β-glucan I understood that I could do it. In addition, the classified product 27 of 106 to 63 μm contained the most β-glucan content. The content of insoluble dietary fiber is 13.75 for the classified product 21, 11.07 for the classified product 22, 11.18 for the classified product 23, 16.91 for the classified product 24, 20.86 for the classified product 25, and the classified product. 26 was 22.15, classification 27 was 21.74, classification 28 was 7.94, and it was found that insoluble dietary fiber was separated at 63 μ and the concentration of insoluble dietary fiber could be increased. Further, the classified product 26 of 149 to 106 μm contained the most insoluble dietary fiber content.
<実施例3>
前記実施例2の結果、βグルカンが存在する粒度区域を更に粉砕することによってβグルカン含量を高めることが出来ることがわかったため、次にβグルカン含量の高い区域を量産する試験を行った。
分級に使用した大麦粒粉砕物は、実施例1の大麦粒粉砕物を目開き100μのシフターで空気分級し、オーバー品を実施例3の大麦粒粉砕品の供用物とした。実施例3の大麦粒粉砕品の供用物をイクシードミル(槇野産業社製、商品名:イクシードミルEM-1A)を用い、粉砕回転数19800rpmで粉砕してさらに細かく粉砕した。この粉砕品を目開き100μのシフターで空気分級し、オーバー品を分級品32とした。目開き100μのシフタースルー品を分級品33とした。なお比較例として、前記実施例3の大麦粒粉砕品の供用物について、空気分級を行わなかった粉砕品を用いた。
<Example 3>
As a result of Example 2, it was found that the β-glucan content can be increased by further pulverizing the particle size region where β-glucan is present, and therefore, a test for mass-producing a region having a high β-glucan content was conducted.
The barley grain pulverized product used in the classification was air-classified with a 100 μm shifter of the barley grain pulverized product of Example 1, and the over product was used as the service product of the barley grain pulverized product of Example 3. The product obtained by pulverizing the barley grain of Example 3 was pulverized more finely by pulverization at 19800 rpm using an ixseed mill (manufactured by Hadano Sangyo Co., Ltd., trade name: ixed mill EM-1A). This pulverized product was air-classified with a shifter having an opening of 100 μm, and the over product was classified as a classified product 32. A shifter-through product having an opening of 100 μm was designated as a classified product 33. As a comparative example, a pulverized product which was not subjected to air classification was used for the service product of the barley grain pulverized product of Example 3.
前記分級品32〜33、及び比較例について、実施例1と同様に、βグルカン含有量を測定した。結果を表3に示す。 About the said classified products 32-33 and the comparative example, it carried out similarly to Example 1, and measured beta glucan content. The results are shown in Table 3.
表3の結果、大麦粒粉砕物の分級品におけるβグルカン含有量は、比較例3は15.08、分級品32は20.18、分級品33は8.95となり、100μを境にしてβグルカンが分離され、100μ以上の分級品を採取すればβグルカン含量の高い区域を量産できることがわかった。また不溶性食物繊維の含量は、分級品31は13.75、分級品32は18.37、分級品33は10.30となり、100μを境にして不溶性食物繊維が分離され、100μ以上の分級品を採取すれば不溶性食物繊維含量の高い区域を量産できることがわかった。 As a result of Table 3, β-glucan content in the classified product of the barley grain pulverized product was 15.08 in Comparative Example 3, 20.18 in the classified product 32, and 8.95 in the classified product 33. It was found that glucan was separated and an area with high β-glucan content could be mass-produced by collecting 100 μm or more of classified product. The content of the insoluble dietary fiber is 13.75 for the classified product 31, 18.37 for the classified product 32, and 10.30 for the classified product 33. The insoluble dietary fiber is separated at 100μ, and the classified product is 100μ or more. It was found that the area with a high content of insoluble dietary fiber can be mass-produced by collecting.
<実施例4>
本発明の大麦粉砕品について、増粘剤としての効果を検討した。実施例1で得られた分級品1、分級品2、分級品3と分級品4の混合(分級品3と分級品4は収量が少なかったため混合した)、及び分級品5のそれぞれを、熊本製粉社製の小麦粉(商品名:赤銀杏)に20重量%添加し、ビニール袋内で均一になるよう1分間混合し、ミックスを調整した。又比較対照として、既存の増粘剤(グアーガム)(太陽化学社製、商品名:ネオソフトG)を1%添加したミックスを比較例とした。
<Example 4>
About the barley ground product of this invention, the effect as a thickener was examined. Mixing of the classified product 1, the classified product 2, the classified product 3 and the classified product 4 obtained in Example 1 (the mixed product 3 and the classified product 4 were mixed because the yield was low), and each of the classified product 5 20% by weight was added to flour (trade name: red ginkgo) manufactured by Flour Milling Co., Ltd. and mixed for 1 minute so as to be uniform in the plastic bag, thereby adjusting the mix. As a comparative control, a comparative example was prepared by adding 1% of an existing thickener (guar gum) (trade name: Neosoft G, manufactured by Taiyo Kagaku Co., Ltd.).
前記により調整した各ミックスの増粘効果を調べるために、粘度を経時的に測定した。粘度はブルックフィールド社製のB型粘度計を使用した。まず、ボールに冷水(15℃)を250g入れて、ミックス100gを加え、40秒間で120回攪拌し、バッター液を作成した。5分間室温で放置し、その後B型粘度計にて3号ローター、12rpmで測定し、30秒後の数値を、0hの粘度値とした。0h測定後、バッター液を室温で保存し、30分経過毎に粘度を測定し、2時間経過後まで測定した。結果を表4に示す。 In order to examine the thickening effect of each mix prepared as described above, the viscosity was measured over time. The viscosity used was a B-type viscometer manufactured by Brookfield. First, 250 g of cold water (15 ° C.) was added to the ball, 100 g of the mix was added, and the mixture was stirred 120 times for 40 seconds to prepare a batter solution. It was allowed to stand at room temperature for 5 minutes, then measured with a B-type viscometer at No. 3 rotor and 12 rpm, and the value after 30 seconds was taken as a viscosity value of 0 h. After the measurement for 0 h, the batter solution was stored at room temperature, the viscosity was measured every 30 minutes, and measured until after 2 hours. The results are shown in Table 4.
表4の結果、分級品3、4の混合品が最も増粘効果が高いことが分かった。各分級品を添加したものは、測定開始後から粘度が上昇し、30分程で粘度値のピークを迎え、その後の経時変化では粘度値が下がりにくく、粘度安定効果を持つことがわかった。分級品5には増粘効果は見られなかった。グアーガムについては、測定開始後から粘度が下降し、その後の経時変化でも粘度安定性は見られなかった。 As a result of Table 4, it was found that the mixed products of classified products 3 and 4 had the highest thickening effect. It was found that the products to which each classified product was added increased in viscosity after the start of measurement, reached a viscosity value peak in about 30 minutes, and did not easily decrease with time, and had a viscosity stabilizing effect. In the classified product 5, no thickening effect was observed. With respect to guar gum, the viscosity decreased after the start of measurement, and no viscosity stability was observed even with a change with time.
<実施例5>
実施例1で得られたβグルカン含量が最も多い分級品3を使用し、増粘効果とその粘度安定性について、添加量を変えて検討した。熊本製粉製の小麦粉(商品名:赤銀杏)に、実施例1の分級品3をそれぞれ、5%、6%、8%、及び10重量%添加し、ビニール袋内で均一になるよう1分間混合し、ミックスを調整した。比較対照として、既存の増粘剤(グアーガム)を1%添加したミックスを比較例とした。
<Example 5>
The classified product 3 having the highest β-glucan content obtained in Example 1 was used, and the thickening effect and the viscosity stability thereof were examined by changing the addition amount. 5%, 6%, 8%, and 10% by weight of the classified product 3 of Example 1 are added to wheat flour (trade name: red ginkgo) made by Kumamoto Milling for 1 minute so as to be uniform in the plastic bag. Mix and adjust the mix. As a comparative control, a mix to which 1% of an existing thickener (guar gum) was added was used as a comparative example.
前記により調整した各ミックスの増粘効果、粘度安定性の測定は実施例4と同様に行った。結果を表5に示す。 The thickening effect and viscosity stability of each mix prepared as described above were measured in the same manner as in Example 4. The results are shown in Table 5.
表5の結果、分級品3を8%添加すると、既存の増粘剤1%添加時と同等の増粘効果があることが分かった。分級品3を添加したものは測定開始後から急激に粘度が下がることはなく、その後の経時変化でも粘度値は下がりにくくなり、その粘度安定性は既存の増粘剤よりも安定することが分かった。グアーガムについては、測定開始後から粘度が下降し、その後の経時変化でも粘度安定性は見られず、粘度値は下がりやすかった。 As a result of Table 5, it was found that when 8% of the classified product 3 was added, there was a thickening effect equivalent to that when 1% of the existing thickener was added. It was found that the viscosity of the product with Class 3 added does not drop sharply from the start of measurement, and the viscosity value is less likely to decrease with time, and the viscosity stability is more stable than existing thickeners. It was. With respect to guar gum, the viscosity decreased after the start of the measurement, the viscosity stability was not seen even with a change with time, and the viscosity value was easy to decrease.
本発明の顆粒は、麦のβグルカン、及び食物繊維を多量に含有する一方で、麦のデンプン等の含量が少ない顆粒であり、食品に添加することにより、βグルカンが有する血中コレステロール低下、血糖値上昇抑制、抗アレルギー作用、整腸作用、免疫増強作用、皮膚の保湿作用などの機能を有する食品、及び食物繊維を高濃度に含有する食品を提供することができる。又本発明の顆粒は、βグルカンを高濃度に含有するために、食品に由来する食品増粘剤としても用いることができる。一方で本発明の顆粒は、麦のデンプン等の含量が少ない顆粒であることから、本発明の顆粒を添加しても、食品の食感を損ね、製パン性等の加工適性を損ねることが少ない食品を得ることができる。 The granule of the present invention is a granule containing a large amount of wheat β-glucan and dietary fiber, while containing a small amount of wheat starch and the like. By adding it to food, β-glucan has low blood cholesterol, It is possible to provide foods having functions such as suppression of increase in blood glucose level, antiallergic action, intestinal regulation action, immunity enhancement action, skin moisturizing action, and the like, and foods containing dietary fibers at high concentrations. Moreover, since the granule of the present invention contains β-glucan at a high concentration, it can also be used as a food thickener derived from food. On the other hand, since the granule of the present invention is a granule with a low content of wheat starch and the like, even if the granule of the present invention is added, the food texture is impaired, and the processing suitability such as bread-making property may be impaired. Less food can be obtained.
Claims (5)
A food using the granule according to claim 4 .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006307785A JP4480173B2 (en) | 2006-11-14 | 2006-11-14 | Oat granule with high concentration of β-glucan |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006307785A JP4480173B2 (en) | 2006-11-14 | 2006-11-14 | Oat granule with high concentration of β-glucan |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008118943A JP2008118943A (en) | 2008-05-29 |
JP4480173B2 true JP4480173B2 (en) | 2010-06-16 |
Family
ID=39504390
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006307785A Active JP4480173B2 (en) | 2006-11-14 | 2006-11-14 | Oat granule with high concentration of β-glucan |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4480173B2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010110296A (en) * | 2008-11-10 | 2010-05-20 | Hakubaku:Kk | METHOD FOR PRODUCING BARLEY POWDER ABUNDANTLY CONTAINING EDIBLE FIBER MAINLY COMPOSED OF beta-GLUCAN |
JP2011000055A (en) * | 2009-06-18 | 2011-01-06 | Kirin Holdings Co Ltd | Composition for lasting feeling of fullness, containing insoluble dietary fiber derived from grain plant seed |
JP5985146B2 (en) | 2010-10-27 | 2016-09-06 | 国立大学法人埼玉大学 | Cereal powder and applied food |
JP2014054205A (en) * | 2012-09-12 | 2014-03-27 | Unitec Foods Co Ltd | Premix powder |
JP6220190B2 (en) * | 2013-08-19 | 2017-10-25 | みたけ食品工業株式会社 | Process for producing β-glucan-rich powder |
JP6029217B2 (en) * | 2013-12-20 | 2016-11-24 | 株式会社サヌキフーズ | Bread crumbs with low oil absorption containing β-glucan |
JP2015228820A (en) * | 2014-06-04 | 2015-12-21 | 株式会社はくばく | Barley product and production method thereof |
CN112089002B (en) * | 2020-09-16 | 2022-09-06 | 江南大学 | Preparation method of whole highland barley rice ball |
JP7217555B2 (en) * | 2021-05-25 | 2023-02-03 | 国立研究開発法人農業・食品産業技術総合研究機構 | Method for disaggregating water-insoluble carbohydrates |
JP7454308B1 (en) | 2023-07-26 | 2024-03-22 | 株式会社はくばく | Rice-like food |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09505204A (en) * | 1993-09-15 | 1997-05-27 | レンナルト リンダール | Uniform and stable cereal suspension |
JP2002528062A (en) * | 1998-10-26 | 2002-09-03 | セバ エービー | Method for separating β-glucan composition from oats and product obtained therefrom |
JP2005058024A (en) * | 2003-08-19 | 2005-03-10 | Ajinomoto Co Inc | Mixed flour for sheet-like food |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ526829A (en) * | 2003-07-02 | 2006-03-31 | Granate Seed Ltd | Beta-glucan-containing products, methods of making same, and uses therefor |
-
2006
- 2006-11-14 JP JP2006307785A patent/JP4480173B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09505204A (en) * | 1993-09-15 | 1997-05-27 | レンナルト リンダール | Uniform and stable cereal suspension |
JP2002528062A (en) * | 1998-10-26 | 2002-09-03 | セバ エービー | Method for separating β-glucan composition from oats and product obtained therefrom |
JP2005058024A (en) * | 2003-08-19 | 2005-03-10 | Ajinomoto Co Inc | Mixed flour for sheet-like food |
Also Published As
Publication number | Publication date |
---|---|
JP2008118943A (en) | 2008-05-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4480173B2 (en) | Oat granule with high concentration of β-glucan | |
Twinomuhwezi et al. | Comparative study of the proximate composition and functional properties of composite flours of amaranth, rice, millet, and soybean | |
Anglani | Sorghum for human food–A review | |
JP5985146B2 (en) | Cereal powder and applied food | |
CN101095482B (en) | Method for preparing barley wheat bran or oat wheat bran for the preparation of fibre foodstuff | |
Mrabet et al. | Date palm fruits as a potential source of functional dietary fiber: A review | |
Niu et al. | Whole grain noodles | |
Di Cairano et al. | Functional cereal-based bakery products, breakfast cereals, and pasta products | |
JP4035308B2 (en) | Process for producing processed grain germs | |
JP6073581B2 (en) | Rice with rice flour-like flavor and rice flour | |
KR100782350B1 (en) | Processed food using undaria pinnatifida and laminaria japonica containing fucoidan | |
JP2547573B2 (en) | Beverage manufacturing method | |
JPH0424028B2 (en) | ||
JP2006109801A (en) | Processed bean and method for producing the same | |
JP3815882B2 (en) | Foods and drinks containing processed sesame seeds | |
JPS5939260A (en) | Preparation of food and drink | |
El-Habashy | Health benefits, extraction and utilization of dietary fibers: A review | |
JA et al. | Production and Quality Evaluation of Acha (D. exilis)-Cowpea (Phaseleous vulgaris)-Carrot (Daucus carota) Based Couscous | |
JP7508215B2 (en) | Wheat flour composition, dough and croutons, and methods for producing the same | |
JP7169558B2 (en) | Method for producing isolated vegetable protein | |
WO2023195538A1 (en) | Potato syrup powder formed from powder or granules of sweet potato syrup, supernatant thereof, or both | |
WO2024143552A1 (en) | Method for producing granular rice flour product, granular rice flour product, method for producing granular food product, granular food product, and food composition | |
Ghodke et al. | Development of Innovative Finger Millet-Watermelon Seed Powder Drink Mix | |
KR20070066475A (en) | Noodles composition comprising tangerine extracts and the process for preparing the same | |
Melgarejo-Cabello et al. | Latin-American Crops in Gluten-Free Applications |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20090513 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091022 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091215 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100312 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100315 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130326 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4480173 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130326 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160326 Year of fee payment: 6 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |