JP4306836B2 - オレフィン性不飽和化合物の水素化用の方法および触媒 - Google Patents
オレフィン性不飽和化合物の水素化用の方法および触媒 Download PDFInfo
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- JP4306836B2 JP4306836B2 JP28271598A JP28271598A JP4306836B2 JP 4306836 B2 JP4306836 B2 JP 4306836B2 JP 28271598 A JP28271598 A JP 28271598A JP 28271598 A JP28271598 A JP 28271598A JP 4306836 B2 JP4306836 B2 JP 4306836B2
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- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims description 40
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 11
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- 239000007788 liquid Substances 0.000 claims abstract description 8
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- 229910052736 halogen Inorganic materials 0.000 claims abstract description 6
- 150000002367 halogens Chemical class 0.000 claims abstract description 6
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims abstract description 4
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- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 6
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- 230000015572 biosynthetic process Effects 0.000 description 4
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- 239000013065 commercial product Substances 0.000 description 4
- QOXHZZQZTIGPEV-UHFFFAOYSA-K cyclopenta-1,3-diene;titanium(4+);trichloride Chemical compound Cl[Ti+](Cl)Cl.C=1C=C[CH-]C=1 QOXHZZQZTIGPEV-UHFFFAOYSA-K 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
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Classifications
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT97A002249 | 1997-10-03 | ||
| IT97MI002249A IT1295266B1 (it) | 1997-10-03 | 1997-10-03 | Procedimento e catalizzatore per l'idrogenazione di composti olefinicamente insaturi |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11192433A JPH11192433A (ja) | 1999-07-21 |
| JPH11192433A5 JPH11192433A5 (enExample) | 2005-11-10 |
| JP4306836B2 true JP4306836B2 (ja) | 2009-08-05 |
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| JP28271598A Expired - Lifetime JP4306836B2 (ja) | 1997-10-03 | 1998-10-05 | オレフィン性不飽和化合物の水素化用の方法および触媒 |
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| Country | Link |
|---|---|
| US (1) | US6180553B1 (enExample) |
| EP (1) | EP0908234B1 (enExample) |
| JP (1) | JP4306836B2 (enExample) |
| AT (1) | ATE217806T1 (enExample) |
| DE (1) | DE69805482T2 (enExample) |
| DK (1) | DK0908234T3 (enExample) |
| ES (1) | ES2176876T3 (enExample) |
| IT (1) | IT1295266B1 (enExample) |
| PT (1) | PT908234E (enExample) |
| RU (1) | RU2162472C2 (enExample) |
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| TW583027B (en) * | 1998-10-30 | 2004-04-11 | Shell Int Research | A method for preparing a hydrogenation catalyst system |
| MXPA02000311A (es) * | 1999-07-09 | 2002-06-21 | Dow Chemical Co | Hidrogenacion de polimeros insaturados usando catalizador de bis-ciclopentadienilo - metal de grupo iv divalente que contienen dieno. |
| ES2185467B2 (es) * | 2000-12-20 | 2004-10-01 | Chi Mei Corporation | Composicion catalizadora para hidrogenacion de cauchos sinteticos a base de dieno conjugado. |
| ITMI20011688A1 (it) * | 2001-08-02 | 2003-02-02 | Enichem Spa | Catalizzatore e suo impiego nella sintesi di acqua ossigenata |
| ITMI20050860A1 (it) * | 2005-05-13 | 2006-11-14 | Polimeri Europa Spa | Procedimento per la idrogenazione selettiva di copolimeri stirene-butadiene |
| PL2898949T3 (pl) * | 2012-09-21 | 2018-08-31 | Asahi Kasei Kabushiki Kaisha | Kompozycja katalizatora do uwodorniania i sposób uwodorniania z zastosowaniem wspomnianej kompozycji katalizatora do uwodorniania |
| TWI586693B (zh) | 2013-07-23 | 2017-06-11 | 財團法人工業技術研究院 | 選擇性氫化共聚物的方法 |
Family Cites Families (9)
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| GB2134909B (en) * | 1983-01-20 | 1986-08-20 | Asahi Chemical Ind | Catalytic hydrogenation of conjugated diene polymer |
| JP2969771B2 (ja) * | 1989-12-22 | 1999-11-02 | ジェイエスアール株式会社 | オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物 |
| WO1992001723A1 (fr) * | 1990-07-24 | 1992-02-06 | Mitsui Toatsu Chemicals, Incorporated | CATALYSEUR POUR POLYMERISATION α-OLEFINIQUE ET PRODUCTION D'UNE POLY-α-OLEFINE A L'AIDE DE CE CATALYSEUR |
| IT1244550B (it) * | 1991-02-06 | 1994-07-15 | Enichem Elastomers | Copolimeri a blocchi idrogenati contenenti gruppi epossidici e loro metodo di preparazione |
| ES2050620B1 (es) * | 1992-11-03 | 1994-12-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido. |
| US5583185A (en) | 1992-11-03 | 1996-12-10 | Repsol Quimica S.A. | Process for hydrogenation in solution of the double bonds of conjugated dienes, and hydrogenated block copolymer produced |
| WO1996018655A1 (en) * | 1994-12-12 | 1996-06-20 | The Dow Chemical Company | Hydrogenation of unsaturated polymers using monocyclopentadienyl group iv metal catalysts |
| IT1275777B1 (it) | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| US5739220A (en) * | 1997-02-06 | 1998-04-14 | Fina Technology, Inc. | Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation |
-
1997
- 1997-10-03 IT IT97MI002249A patent/IT1295266B1/it active IP Right Grant
-
1998
- 1998-09-17 PT PT98117654T patent/PT908234E/pt unknown
- 1998-09-17 DE DE69805482T patent/DE69805482T2/de not_active Expired - Lifetime
- 1998-09-17 ES ES98117654T patent/ES2176876T3/es not_active Expired - Lifetime
- 1998-09-17 EP EP98117654A patent/EP0908234B1/en not_active Expired - Lifetime
- 1998-09-17 AT AT98117654T patent/ATE217806T1/de active
- 1998-09-17 DK DK98117654T patent/DK0908234T3/da active
- 1998-09-23 US US09/158,770 patent/US6180553B1/en not_active Expired - Lifetime
- 1998-10-02 RU RU98118139/04A patent/RU2162472C2/ru active
- 1998-10-05 JP JP28271598A patent/JP4306836B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11192433A (ja) | 1999-07-21 |
| ES2176876T3 (es) | 2002-12-01 |
| EP0908234A1 (en) | 1999-04-14 |
| ATE217806T1 (de) | 2002-06-15 |
| DE69805482T2 (de) | 2003-01-16 |
| PT908234E (pt) | 2002-10-31 |
| EP0908234B1 (en) | 2002-05-22 |
| DE69805482D1 (de) | 2002-06-27 |
| US6180553B1 (en) | 2001-01-30 |
| ITMI972249A1 (it) | 1999-04-03 |
| DK0908234T3 (da) | 2002-09-09 |
| RU2162472C2 (ru) | 2001-01-27 |
| IT1295266B1 (it) | 1999-05-04 |
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