JP4240011B2 - 排ガス浄化触媒 - Google Patents

排ガス浄化触媒 Download PDF

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Publication number
JP4240011B2
JP4240011B2 JP2005179884A JP2005179884A JP4240011B2 JP 4240011 B2 JP4240011 B2 JP 4240011B2 JP 2005179884 A JP2005179884 A JP 2005179884A JP 2005179884 A JP2005179884 A JP 2005179884A JP 4240011 B2 JP4240011 B2 JP 4240011B2
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JP
Japan
Prior art keywords
catalyst
layer
exhaust gas
zirconia
gas purification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2005179884A
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English (en)
Japanese (ja)
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JP2006346661A5 (enExample
JP2006346661A (ja
Inventor
真秀 三浦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2005179884A priority Critical patent/JP4240011B2/ja
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Priority to CNA2006800220113A priority patent/CN101203301A/zh
Priority to PCT/JP2006/312675 priority patent/WO2006137552A1/en
Priority to US11/922,456 priority patent/US20090099011A1/en
Priority to RU2008100938/04A priority patent/RU2372141C2/ru
Priority to EP06767292A priority patent/EP1907117A1/en
Priority to KR1020087001548A priority patent/KR20080028947A/ko
Publication of JP2006346661A publication Critical patent/JP2006346661A/ja
Publication of JP2006346661A5 publication Critical patent/JP2006346661A5/ja
Application granted granted Critical
Publication of JP4240011B2 publication Critical patent/JP4240011B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/395—Thickness of the active catalytic layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106—Auxiliary oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/902—Multilayered catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
JP2005179884A 2005-06-20 2005-06-20 排ガス浄化触媒 Expired - Fee Related JP4240011B2 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2005179884A JP4240011B2 (ja) 2005-06-20 2005-06-20 排ガス浄化触媒
PCT/JP2006/312675 WO2006137552A1 (en) 2005-06-20 2006-06-20 Catalyst for emission gas purification
US11/922,456 US20090099011A1 (en) 2005-06-20 2006-06-20 Catalyst for Emission Gas Purification
RU2008100938/04A RU2372141C2 (ru) 2005-06-20 2006-06-20 Катализатор для очистки выхлопного газа
CNA2006800220113A CN101203301A (zh) 2005-06-20 2006-06-20 用于废气净化的催化剂
EP06767292A EP1907117A1 (en) 2005-06-20 2006-06-20 Catalyst for emission gas purification
KR1020087001548A KR20080028947A (ko) 2005-06-20 2006-06-20 배기 가스 정화 촉매

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005179884A JP4240011B2 (ja) 2005-06-20 2005-06-20 排ガス浄化触媒

Publications (3)

Publication Number Publication Date
JP2006346661A JP2006346661A (ja) 2006-12-28
JP2006346661A5 JP2006346661A5 (enExample) 2007-06-14
JP4240011B2 true JP4240011B2 (ja) 2009-03-18

Family

ID=36988314

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005179884A Expired - Fee Related JP4240011B2 (ja) 2005-06-20 2005-06-20 排ガス浄化触媒

Country Status (7)

Country Link
US (1) US20090099011A1 (enExample)
EP (1) EP1907117A1 (enExample)
JP (1) JP4240011B2 (enExample)
KR (1) KR20080028947A (enExample)
CN (1) CN101203301A (enExample)
RU (1) RU2372141C2 (enExample)
WO (1) WO2006137552A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1974810B1 (de) * 2007-03-19 2010-08-18 Umicore AG & Co. KG Palladium-Rhodium Einfachschicht Katalysator
JP5218092B2 (ja) * 2009-01-23 2013-06-26 トヨタ自動車株式会社 排ガス浄化用触媒
US8568675B2 (en) * 2009-02-20 2013-10-29 Basf Corporation Palladium-supported catalyst composites
JP5807782B2 (ja) * 2011-12-28 2015-11-10 トヨタ自動車株式会社 排ガス浄化用触媒
KR101483651B1 (ko) * 2012-12-13 2015-01-16 현대자동차 주식회사 내연 기관용 가스 정화 촉매
US9266092B2 (en) * 2013-01-24 2016-02-23 Basf Corporation Automotive catalyst composites having a two-metal layer
GB201303396D0 (en) * 2013-02-26 2013-04-10 Johnson Matthey Plc Oxidation catalyst for a combustion engine
CN103191734B (zh) * 2013-03-15 2015-02-18 无锡威孚环保催化剂有限公司 用于汽车尾气处理的三元催化剂
JPWO2015076403A1 (ja) * 2013-11-22 2017-03-16 株式会社キャタラー 排気ガス浄化用触媒
US10864502B2 (en) 2013-12-16 2020-12-15 Basf Corporation Manganese-containing diesel oxidation catalyst
US10252217B2 (en) * 2014-06-05 2019-04-09 Basf Corporation Catalytic articles containing platinum group metals and non-platinum group metals and methods of making and using same
US9827562B2 (en) * 2015-10-05 2017-11-28 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US11179701B2 (en) 2016-03-25 2021-11-23 Cataler Corporation Exhaust gas purifying catalyst and production method therefor, and exhaust gas purification device using same
EP3468711A4 (en) * 2016-06-13 2020-02-26 BASF Corporation CATALYTIC ITEM WITH COMBINATION OF PGM AND OSC
GB2560940A (en) * 2017-03-29 2018-10-03 Johnson Matthey Plc Three layer NOx Adsorber catalyst
CN112138658B (zh) * 2020-09-30 2023-09-15 南京工程学院 一种用于坦克尾气净化整体式催化剂的制备方法
JP7600910B2 (ja) * 2021-07-06 2024-12-17 トヨタ自動車株式会社 排ガス浄化用触媒
CN116809061B (zh) * 2023-06-16 2025-10-03 昆明贵研催化剂有限责任公司 一种表面负载氧化钇的铂钯铈锆铝催化剂及其制备方法和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6388040A (ja) * 1986-09-30 1988-04-19 Nippon Engeruharudo Kk 車輌用排気ガス浄化用触媒及びその製造方法
JP2948232B2 (ja) * 1989-04-04 1999-09-13 日産自動車株式会社 排気ガス浄化用触媒
JP3591667B2 (ja) * 1995-06-23 2004-11-24 日野自動車株式会社 排ガス浄化用ＮＯｘ触媒及びその製造方法
RU2123881C1 (ru) * 1996-12-20 1998-12-27 Борис Николаевич Перевозчиков Каталитический нейтрализатор отработавших газов двигателя внутреннего сгорания
TWI290484B (en) * 2000-03-28 2007-12-01 Dmc2 Degussa Metals Catalysts Single layer high performance catalyst
JP4329432B2 (ja) * 2003-07-15 2009-09-09 トヨタ自動車株式会社 排ガス浄化用触媒
US7374729B2 (en) * 2004-03-30 2008-05-20 Basf Catalysts Llc Exhaust gas treatment catalyst
US20060217263A1 (en) * 2005-03-24 2006-09-28 Tokyo Roki Co., Ltd Exhaust gas purification catalyst
US7638459B2 (en) * 2005-05-25 2009-12-29 Uop Llc Layered composition and processes for preparing and using the composition

Also Published As

Publication number Publication date
RU2372141C2 (ru) 2009-11-10
KR20080028947A (ko) 2008-04-02
EP1907117A1 (en) 2008-04-09
WO2006137552A1 (en) 2006-12-28
JP2006346661A (ja) 2006-12-28
US20090099011A1 (en) 2009-04-16
CN101203301A (zh) 2008-06-18
RU2008100938A (ru) 2009-07-27

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