JP4238161B2 - インクジェット用記録材料及びその製造方法 - Google Patents
インクジェット用記録材料及びその製造方法 Download PDFInfo
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- JP4238161B2 JP4238161B2 JP2004068630A JP2004068630A JP4238161B2 JP 4238161 B2 JP4238161 B2 JP 4238161B2 JP 2004068630 A JP2004068630 A JP 2004068630A JP 2004068630 A JP2004068630 A JP 2004068630A JP 4238161 B2 JP4238161 B2 JP 4238161B2
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- 239000004593 Epoxy Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
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- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
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- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
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- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- TZMACLAARXHRRZ-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarbohydrazide Chemical compound NNC(=O)CC(O)(C(=O)NN)CC(=O)NN TZMACLAARXHRRZ-UHFFFAOYSA-N 0.000 description 1
- LYPJRFIBDHNQLY-UHFFFAOYSA-J 2-hydroxypropanoate;zirconium(4+) Chemical compound [Zr+4].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O LYPJRFIBDHNQLY-UHFFFAOYSA-J 0.000 description 1
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- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- BCTWNMTZAXVEJL-UHFFFAOYSA-N phosphane;tungsten;tetracontahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.P.[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W] BCTWNMTZAXVEJL-UHFFFAOYSA-N 0.000 description 1
- PDDXOPNEMCREGN-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum;hydrate Chemical compound O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O PDDXOPNEMCREGN-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- IYQJAGXFXWIEJE-UHFFFAOYSA-H trimagnesium;2-hydroxypropane-1,2,3-tricarboxylate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O IYQJAGXFXWIEJE-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
- 238000010947 wet-dispersion method Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- ZNVKGUVDRSSWHV-UHFFFAOYSA-L zinc;4-hydroxybenzenesulfonate Chemical compound [Zn+2].OC1=CC=C(S([O-])(=O)=O)C=C1.OC1=CC=C(S([O-])(=O)=O)C=C1 ZNVKGUVDRSSWHV-UHFFFAOYSA-L 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical class F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Description
1.耐水性支持体上にインク受容層を設けた記録材料において、該インク受容層の少なくとも1層が平均二次粒子径500nm以下の無機微粒子と樹脂バインダーとしてケト基を有する変性ポリビニルアルコール、及びその架橋剤としてヒドラジド基を分子内に2個以上有する化合物を含有することを特徴とするインクジェット用記録材料。
2.耐水性支持体上に平均二次粒子径500nm以下の無機微粒子とケト基を有する変性ポリビニルアルコール、及びヒドラジド基を分子内に2個以上含有する化合物を含有する塗工液を塗布し、30〜100℃の加熱温度で加熱することによって塗工液をゲル化させた後、乾燥することを特徴とするインクジェット用記録材料の製造方法。
[Al(OH)3]nAlCl3 一般式2
Aln(OH)mCl(3n-m) 0<m<3n 一般式3
広葉樹晒クラフトパルプ(LBKP)と針葉樹晒サルファイトパルプ(NBSP)の1:1混合物をカナディアン スタンダード フリーネスで300mlになるまで叩解し、パルプスラリーを調製した。これにサイズ剤としてアルキルケテンダイマーを対パルプ0.5%、強度剤としてポリアクリルアミドを対パルプ1.0%、カチオン化澱粉を対パルプ2.0%、ポリアミドエピクロロヒドリン樹脂を対パルプ0.5%添加し、水で希釈して1%スラリーとした。このスラリーを長網抄紙機で坪量170g/m2になるように抄造し、乾燥調湿してポリオレフィン樹脂被覆紙の原紙とした。抄造した原紙に、密度0.918g/cm3の低密度ポリエチレン100部の樹脂に対して、10部のアナターゼ型チタンを均一に分散したポリエチレン樹脂組成物を320℃で溶融し、200m/分で厚さ35μmになるように押出コーティングし、微粗面加工されたクーリングロールを用いて押出被覆し表面とした。もう一方の面には密度0.962g/cm3の高密度ポリエチレン樹脂70部と密度0.918g/cm3の低密度ポリエチレン樹脂30部のブレンド樹脂組成物を同様に320℃で溶融し、厚さ30μmになるように押出コーティングし、粗面加工されたクーリングロールを用いて押出被覆し裏面とした。
石灰処理ゼラチン 100部
スルフォコハク酸−2−エチルヘキシルエステル塩 2部
クロム明ばん 10部
水にジメチルジアリルアンモニウムクロライドホモポリマー(分子量9,000)4部と気相法シリカ(平均一次粒子径7nm、比表面積300m2/g)100部を添加し予備分散液を作製した後、高圧ホモジナイザーで処理して、固形分濃度20%のシリカ分散液1を製造した。このシリカ分散液1と水に溶解した他の薬品を30℃で混合して下記組成を含有するインク受容層用1用塗工液を調整した。この塗工液を、シリカ粒子の塗布量が20g/m2になるように、上記支持体上にワイヤーバーで塗布し、先ず80℃で15秒間加熱して塗工液をゲル化させ、次いで80℃、55℃の空気を順次吹き付けて乾燥した。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
<インク受容層1組成>
シリカ分散液1 (シリカ固形分として)100部
アセトアセチル変性ポリビニルアルコール 22部
(アセトアセチル化度3%、ケン化度98%、平均重合度2500)
アジピン酸ジヒドラジド 2部
水にジメチルジアリルアンモニウムクロライドホモポリマー(分子量9,000)4部と沈降法シリカ(吸油量200ml/100g、平均一次粒子径16nm、平均凝集粒子径9μm)100部を添加し、のこぎり歯状ブレード型分散機(ブレード周速30m/秒)を使用して予備分散液を作製した。次に得られた予備分散液をビーズミルで処理して、固形分濃度30%のシリカ分散液2を得た。このシリカ分散液2と水に溶解した他の薬品を30℃で混合して下記組成を含有するインク受容層2用塗工液を調整した。この塗工液を、シリカ粒子の塗布量が20g/m2になるように、上記支持体上にワイヤーバーで塗布し、記録シート1と同様に乾燥して記録シート2を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は100nmであった。
<インク受容層2組成>
シリカ分散液2 (シリカ固形分として)100部
アセトアセチル変性ポリビニルアルコール 16部
(アセトアセチル化度3%、ケン化度98%、平均重合度2500)
アジピン酸ジヒドラジド 1.5部
水に硝酸(2部)と擬ベーマイト(平均一次粒子径14nm)を添加し、のこぎり歯状ブレード型分散機を使用して、固形分濃度20%のアルミナ水和物分散液を作製した。このアルミナ水和物分散液と水に溶解した他の薬品を30℃で混合して下記組成を含有するインク受容層3用塗工液を調整した。この塗工液を、アルミナ水和物粒子の塗布量が20g/m2になるように、上記支持体上にワイヤーバーで塗布し、記録シート1と同様に乾燥して記録シート3を得た。なお、電子顕微鏡観察よりアルミナ水和物粒子の平均二次粒子径は80nmであった。
<インク受容層3組成>
アルミナ水和物分散液 (アルミナ水和物固形分として)100部
アセトアセチル変性ポリビニルアルコール 12部
(アセトアセチル化度3%、ケン化度98%、平均重合度2500)
アジピン酸ジヒドラジド 1.2部
上記インク受容層1組成のバインダー成分を、ジアセトンアクリルアミド変性ポリビニルアルコール(ジアセトンアクリルアミド変性度5モル%、鹸化度98モル%、重合度1700)25部に変更した以外は記録シート1と同様にして記録シート4を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のアジピン酸ジヒドラジドをコハク酸ジヒドラジド1.7部に変更した以外は記録シート1と同様にして記録シート5を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のバインダー成分を、部分鹸化ポリビニルアルコール(鹸化度88モル%、重合度3500)22部に変更した以外は記録シート1と同様にして記録シート6を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のアジピン酸ジヒドラジドを抜いて、ほう酸2部を添加した以外は記録シート1と同様にして記録シート7を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のアジピン酸ジヒドラジドを抜いて、ホルムアルデヒド2部を添加した以外は記録シート1と同様にして記録シート8を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のバインダー成分を、部分鹸化ポリビニルアルコール(鹸化度88モル%、重合度3500)22部に変更し、アジピン酸ジヒドラジドをほう酸2部に変更した以外は記録シート1と同様にして記録シート9を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
上記インク受容層1組成のアジピン酸ジヒドラジドをプロピオン酸ヒドラジド2部に変更した以外は記録シート1と同様にして記録シート10を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
水にジメチルジアリルアンモニウムクロライドホモポリマー(分子量9,000)4部と沈降法シリカ(吸油量250ml/100g、平均一次粒子径30nm、平均凝集粒子径2μm)100部を添加し、のこぎり歯状ブレード型分散機(ブレード周速30m/秒)を使用してシリカ分散液3を作製した。このシリカ分散液3と水に溶解した他の薬品を30℃で混合して下記組成を含有するインク受容層用4用塗工液を調整し、シリカ粒子の塗布量が20g/m2になるように、上記支持体上にワイヤーバーで塗布した。この塗工液を、記録シート1と同様に乾燥して記録シート11を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は1.0μmであった。
<インク受容層4組成>
シリカ分散液3 (シリカ固形分として)100部
アセトアセチル変性ポリビニルアルコール 16部
(アセトアセチル化度3%、ケン化度98%、平均重合度2500)
アジピン酸ジヒドラジド 1.5部
記録シート9と同じインク受容層用塗工液を、シリカ粒子の塗布量が20g/m2になるように上記支持体上にワイヤーバーで塗布した後、10℃で30秒間冷却して塗工液の粘度を上昇させ、次に40℃の風を吹き付けて乾燥させて記録シート12を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
乾燥条件を、10℃で30秒間冷却して塗工液の粘度を上昇させた後、60℃の風を吹き付けて乾燥させるように変更した以外は記録シート12と同様にして記録シート13を得た。なお、電子顕微鏡観察よりシリカ微粒子の平均二次粒子径は80nmであった。
塗布・乾燥したインク受容層の塗布面を観察し、下記の基準で評価した。
○:ひび割れが全くなく、均一な塗布面である。
△:目視では判別し難いくらいの小さいひび割れが発生している。
×:目視で明らかに判別できる大きなひび割れが発生している。
記録シートの印字前の白紙部光沢感を斜光で観察し、下記の基準で評価した。
○:カラー写真並の高い光沢感が有る。
△:少し光沢感が有る。
×:光沢感が無い。
記録シートに、染料インクを用いた市販のインクジェットプリンター(エプソン社製、PM−950C)にてレッド、ブルー、グリーン、ブラックのベタ印字を行い、印字直後にPPC用紙を印字部に重ねて軽く圧着し、PPC用紙に転写したインク量の程度を目視で観察した。下記の基準で評価した。最も悪い評価結果を採用した。
○:転写しない。
△:印字部全体に薄い転写が観察される。
×:印字部全体に濃い転写が観察される。
記録シートに、市販の顔料インクを用いたインクジェットプリンターにてC、M、Y、K、R、G、Bをそれぞれ最大インク吐出量でベタ印字して、印字直後にPPC用紙を印字部に重ねて軽く圧着し、PPC用紙に転写したインク量の程度を目視で観察し、下記の基準で評価した。最も悪い評価結果を採用した。
○:全く転写しない。
△:やや転写する。
×:転写が大きく実使用不可。
上記の黒色顔料インクで印字した試料をアルバム保存し、30日経時後に印字部分の顔料インク皮膜を目視観察し、下記の基準で評価した。
○:割れが全く見えない。
△:許容限界であるが割れが見える。
×:割れが著しく見える。
記録シート表面に水滴を落とし、1分間放置後表面を擦り、表面状態を観察し、下記の基準で評価した。
○:変化なし
△:インク受容層の一部が削り取られ、光沢が低下した状態となる。
×:インク受容層の大部分が削り取られた状態となる。
未印字の記録シートを印字面を上にして曲げていったときに、表面に割れが生じるかどうかを観察し、下記の基準で評価した。なお、記録シート表面に元々ひび割れが発生しているものやマット調のため割れが確認できなかったものについては評価不能とした。(表には−で示す。)
○:割れが生じない。
×:割れが生じる。
Claims (2)
- 耐水性支持体上にインク受容層を設けた記録材料において、該インク受容層の少なくとも1層が平均二次粒子径500nm以下の無機微粒子と樹脂バインダーとしてケト基を有する変性ポリビニルアルコール、及びその架橋剤としてヒドラジド基を分子内に2個以上有する化合物を含有することを特徴とするインクジェット用記録材料。
- 耐水性支持体上に平均二次粒子径500nm以下の無機微粒子とケト基を有する変性ポリビニルアルコール、及びヒドラジド基を分子内に2個以上含有する化合物を含有する塗工液を塗布し、30〜100℃の加熱温度で加熱することによって塗工液をゲル化させた後、乾燥することを特徴とするインクジェット用記録材料の製造方法。
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JP4509939B2 (ja) * | 2006-01-06 | 2010-07-21 | ダイセル化学工業株式会社 | インク記録体用樹脂組成物及びインク記録体 |
JP5322625B2 (ja) * | 2008-12-24 | 2013-10-23 | 日本合成化学工業株式会社 | インクジェット記録用媒体、インク受容層形成用塗工液、およびインクジェット記録用媒体の製造方法 |
JP6324059B2 (ja) * | 2013-12-24 | 2018-05-16 | 日本合成化学工業株式会社 | 樹脂組成物、コート層、感熱記録媒体、及び水性塗工液 |
JP2017189927A (ja) * | 2016-04-14 | 2017-10-19 | 日本合成化学工業株式会社 | インクジェット記録媒体及びその製造方法 |
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