JP4147553B2 - N−(シクロヘキシルチオ)−フタルイミド組成物、および、その固結防止方法 - Google Patents
N−(シクロヘキシルチオ)−フタルイミド組成物、および、その固結防止方法 Download PDFInfo
- Publication number
- JP4147553B2 JP4147553B2 JP2003384639A JP2003384639A JP4147553B2 JP 4147553 B2 JP4147553 B2 JP 4147553B2 JP 2003384639 A JP2003384639 A JP 2003384639A JP 2003384639 A JP2003384639 A JP 2003384639A JP 4147553 B2 JP4147553 B2 JP 4147553B2
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- JP
- Japan
- Prior art keywords
- cyclohexylthio
- phthalimide
- stearate
- oleate
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical compound O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 title claims description 22
- 239000000203 mixture Substances 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 7
- 150000002148 esters Chemical class 0.000 claims description 15
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 claims description 14
- MVLVMROFTAUDAG-UHFFFAOYSA-N ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 claims description 14
- 229940057995 liquid paraffin Drugs 0.000 claims description 12
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 7
- FDVCQFAKOKLXGE-UHFFFAOYSA-N 216978-79-9 Chemical compound C1CC(C)(C)C2=CC(C=O)=CC3=C2N1CCC3(C)C FDVCQFAKOKLXGE-UHFFFAOYSA-N 0.000 claims description 7
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 7
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 claims description 7
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 7
- 229940093471 ethyl oleate Drugs 0.000 claims description 7
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims description 7
- BTAXGNQLYFDKEF-UHFFFAOYSA-N propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC BTAXGNQLYFDKEF-UHFFFAOYSA-N 0.000 claims description 7
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 6
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 6
- 229940073769 methyl oleate Drugs 0.000 claims description 6
- -1 cyclohexylthio Chemical group 0.000 description 9
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- PVXPPJIGRGXGCY-TZLCEDOOSA-N 6-O-alpha-D-glucopyranosyl-D-fructofuranose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)C(O)(CO)O1 PVXPPJIGRGXGCY-TZLCEDOOSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- XRFDWTWFFLOKAV-UHFFFAOYSA-N cyclohexyl thiohypochlorite Chemical compound ClSC1CCCCC1 XRFDWTWFFLOKAV-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Indole Compounds (AREA)
Description
N−(シクロヘキシルチオ)−フタルイミド30gを500mlのナスフラスコに秤量する。表1に記載した添加剤を所定量シクロヘキサン20mlに溶かした溶液をN−(シクロヘキシルチオ)−フタルイミドの入ったナスフラスコに注ぎ込み、ロータリーエバポレーターで充分混合した。その後60〜70℃の温水浴下、減圧条件でシクロヘキサンを充分留去して乾燥し、サンプルを得た。
得られたサンプルを内径4cm、高さ8cmのポリテトラフルオロエチレン樹脂製円筒容器に入れ、これに上部から2.5kgの荷重をかけ50℃の恒温槽内で5日間放置した。その後、被検サンプル(ケーク状)を容器から取り出して上皿化学天秤の上に載せて、荷重を掛けてケークの崩れた時点での荷重数値を記録した。結果を表1に示す。崩壊荷重の小さいものが固結度の少ないことを示している。
Claims (2)
- N−(シクロヘキシルチオ)−フタルイミドに対して、オレイン酸メチル、オレイン酸エチル、オレイン酸プロピル、オレイン酸ブチル、ステアリン酸メチル、ステアリン酸エチル、ステアリン酸プロピル、ステアリン酸ブチルから選ばれる少なくとも1種のエステルまたは流動パラフィンを0.01〜5重量%含有することを特徴とするN−(シクロヘキシルチオ)−フタルイミド組成物。
- N−(シクロヘキシルチオ)−フタルイミドに、オレイン酸メチル、オレイン酸エチル、オレイン酸プロピル、オレイン酸ブチル、ステアリン酸メチル、ステアリン酸エチル、ステアリン酸プロピル、ステアリン酸ブチルから選ばれる少なくとも1種のエステルまたは流動パラフィンを0.01〜5重量%配合し混合することを特徴とするN−(シクロヘキシルチオ)−フタルイミド組成物の固結防止方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003384639A JP4147553B2 (ja) | 2003-11-14 | 2003-11-14 | N−(シクロヘキシルチオ)−フタルイミド組成物、および、その固結防止方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003384639A JP4147553B2 (ja) | 2003-11-14 | 2003-11-14 | N−(シクロヘキシルチオ)−フタルイミド組成物、および、その固結防止方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005145867A JP2005145867A (ja) | 2005-06-09 |
JP4147553B2 true JP4147553B2 (ja) | 2008-09-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2003384639A Expired - Lifetime JP4147553B2 (ja) | 2003-11-14 | 2003-11-14 | N−(シクロヘキシルチオ)−フタルイミド組成物、および、その固結防止方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4147553B2 (ja) |
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2003
- 2003-11-14 JP JP2003384639A patent/JP4147553B2/ja not_active Expired - Lifetime
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Publication number | Publication date |
---|---|
JP2005145867A (ja) | 2005-06-09 |
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