JP4121097B2 - 乳化重合を開始するためのレドックス触媒系 - Google Patents

乳化重合を開始するためのレドックス触媒系 Download PDF

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Publication number
JP4121097B2
JP4121097B2 JP32720696A JP32720696A JP4121097B2 JP 4121097 B2 JP4121097 B2 JP 4121097B2 JP 32720696 A JP32720696 A JP 32720696A JP 32720696 A JP32720696 A JP 32720696A JP 4121097 B2 JP4121097 B2 JP 4121097B2
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JP
Japan
Prior art keywords
catalyst system
bis
redox catalyst
hydrogen sulfite
sodium hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP32720696A
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English (en)
Japanese (ja)
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JPH09176217A5 (enExample
JPH09176217A (ja
Inventor
マルテイン・ヤコブ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Nippon Synthetic Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Synthetic Chemical Industry Co Ltd filed Critical Nippon Synthetic Chemical Industry Co Ltd
Publication of JPH09176217A publication Critical patent/JPH09176217A/ja
Publication of JPH09176217A5 publication Critical patent/JPH09176217A5/ja
Application granted granted Critical
Publication of JP4121097B2 publication Critical patent/JP4121097B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP32720696A 1995-12-07 1996-12-06 乳化重合を開始するためのレドックス触媒系 Expired - Lifetime JP4121097B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19545609A DE19545609A1 (de) 1995-12-07 1995-12-07 Redoxkatalysatorsystem zur Initiierung von Emulsionspolymerisationen
DE19545609:2 1995-12-07

Publications (3)

Publication Number Publication Date
JPH09176217A JPH09176217A (ja) 1997-07-08
JPH09176217A5 JPH09176217A5 (enExample) 2004-11-04
JP4121097B2 true JP4121097B2 (ja) 2008-07-16

Family

ID=7779409

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32720696A Expired - Lifetime JP4121097B2 (ja) 1995-12-07 1996-12-06 乳化重合を開始するためのレドックス触媒系

Country Status (7)

Country Link
US (2) US5744418A (enExample)
EP (1) EP0778290B1 (enExample)
JP (1) JP4121097B2 (enExample)
AT (1) ATE182155T1 (enExample)
DE (2) DE19545609A1 (enExample)
ES (1) ES2135154T3 (enExample)
GR (1) GR3031395T3 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1276816B1 (it) * 1995-10-04 1997-11-03 Atochem Elf Italia Emulsione a basso voc
DE19636510A1 (de) 1996-09-09 1998-03-12 Clariant Gmbh Polyvinylalkohol-Kompositionen
DE19851024A1 (de) * 1998-11-05 2000-05-11 Basf Ag Wäßrige Dispersionen von wasserlöslichen Polymerisaten von N-Vinylcarbonsäureamiden, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19857897A1 (de) * 1998-12-15 2000-06-21 Basf Ag Verfahren zur Herstellung wäßriger Polymerdispersionen
JP2000212533A (ja) * 1999-01-20 2000-08-02 Sumitomo Chem Co Ltd 接着剤組成物
DE19927278C1 (de) * 1999-06-15 2000-12-14 Siemens Audiologische Technik Verfahren zum Anpassen eines Hörhilfegeräts sowie Hörhilfegerät
US6379499B1 (en) 1999-09-28 2002-04-30 University Of Georgia Research Foundation, Inc. Polymer-aldehyde additives to improve paper properties
JP4379998B2 (ja) * 1999-09-30 2009-12-09 住友化学株式会社 エチレン−酢酸ビニル系共重合体水性エマルジョンの製造方法
DE10064085A1 (de) 2000-12-21 2002-07-04 Consortium Elektrochem Ind Verfahren zur Entfernung von freien Aldehyden
DE10163586A1 (de) * 2001-12-21 2003-07-03 Clariant Gmbh Verwendung von weichmacherfreien, wässrigen copolymeren Poly(vinylester)- Dispersionen in Lebensmittelbeschichtungsmassen
DE10241481B4 (de) * 2002-09-07 2006-07-06 Celanese Emulsions Gmbh Verfahren zum Herstellen von wässrigen Polymerdispersionen mit sehr niedrigen Restmonomergehalten und deren Verwendung
DE10320904A1 (de) * 2003-05-09 2004-11-25 Cognis Deutschland Gmbh & Co. Kg Startersysteme II
DE10333623A1 (de) * 2003-07-24 2005-02-24 Celanese Emulsions Gmbh Beschichtungszusammensetzung und Verfahren zu deren Herstellung
DE102005032194B4 (de) 2005-07-09 2008-11-27 Celanese Emulsions Gmbh Wässrige Kunststoff-Dispersionen, Verfahren zu deren Herstellung sowie deren Verwendung
DE102006030557A1 (de) * 2006-07-03 2008-01-10 Celanese Emulsions Gmbh Verfahren zur Herstellung wässriger Vinylester-Dispersionen
EP2125903B1 (en) * 2006-07-18 2014-01-15 Celanese International Corporation Emulsion polymerisation process
DE102007033595A1 (de) 2007-07-19 2009-01-22 Celanese Emulsions Gmbh Polyvinylesterdispersionen, Verfahren zu deren Herstellung und deren Verwendung
DE102007033596A1 (de) 2007-07-19 2009-01-22 Celanese Emulsions Gmbh Beschichtungsmittel mit hoher Bewitterungsbeständigkeit, Verfahren zu deren Herstellung und deren Verwendung
US20100167611A1 (en) * 2008-12-29 2010-07-01 Mclennan Alistair John Vinyl acetate / aromatic vinyl ester copolymer binder resins
KR101656542B1 (ko) * 2009-01-14 2016-09-09 트린세오 유럽 게엠베하 에멀젼 중합에서의 단량체 전환율 증가
US8440766B2 (en) 2010-07-28 2013-05-14 Celanese Emulsions Gmbh Heterogeneous vinyl acetate based copolymers as binder for paints
EP2431396B1 (en) 2010-09-15 2016-07-27 Celanese Sales Germany GmbH Vinyl acetate based alkaline resistant scrim binder

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3438941A (en) * 1967-10-16 1969-04-15 Nalco Chemical Co Homopolymerization of acrolein in aqueous monomer emulsion via redox catalyst
JPS6010138B2 (ja) 1975-10-31 1985-03-15 住友化学工業株式会社 不織布
JPS588410B2 (ja) * 1975-11-04 1983-02-16 住友化学工業株式会社 スイセイブンサンエキノ セイゾウホウホウ
DE2620738C2 (de) 1976-05-11 1983-04-28 Wacker-Chemie GmbH, 8000 München Verfahren zur Herstellung wäßriger Copolymerdispersionen und deren Verwendung in Vermischung mit sauren, wasserlöslichen Härtezusätzen für Klebemittel
US4360632A (en) 1981-10-23 1982-11-23 Air Products And Chemicals, Inc. Ketone bisulfites as reducing agent for free radical polymerization
JPS6099096A (ja) 1984-10-12 1985-06-01 住友化学工業株式会社 含浸紙
DE3521618A1 (de) * 1985-06-15 1986-12-18 Bayer Ag, 5090 Leverkusen In wasser dispergierbare polyisocyanat-zubereitung und ihre verwendung als zusatzmittel fuer waessrige klebstoffe
DK0394774T3 (da) 1989-04-26 1996-02-19 Nat Starch Chem Invest Forbedrede klæbestoffer til træarbejde baseret på multitrinsemulitionspolymer
DE3942628A1 (de) * 1989-12-22 1991-06-27 Wacker Chemie Gmbh Verwendung waessriger copolymerdispersionen unter zusatz von sauren metallsalzen oder freien saeuren als klebemittel
US5434216A (en) 1993-05-07 1995-07-18 National Starch And Chemical Investment Holding Corporation Woodworking latex adhesives with improved water, heat and creep resistance
DE4420484C2 (de) 1994-06-11 1999-02-04 Clariant Gmbh Wäßriger Dispersionsklebstoff auf Polyvinylester-Basis, Verfahren zur Herstellung sowie dessen Verwendung

Also Published As

Publication number Publication date
EP0778290B1 (de) 1999-07-14
US5969065A (en) 1999-10-19
EP0778290A3 (de) 1997-09-10
JPH09176217A (ja) 1997-07-08
GR3031395T3 (en) 2000-01-31
EP0778290A2 (de) 1997-06-11
DE19545609A1 (de) 1997-06-12
ATE182155T1 (de) 1999-07-15
DE59602433D1 (de) 1999-08-19
US5744418A (en) 1998-04-28
ES2135154T3 (es) 1999-10-16

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