JP4026833B2 - 殺菌剤組成物 - Google Patents
殺菌剤組成物 Download PDFInfo
- Publication number
- JP4026833B2 JP4026833B2 JP2004089001A JP2004089001A JP4026833B2 JP 4026833 B2 JP4026833 B2 JP 4026833B2 JP 2004089001 A JP2004089001 A JP 2004089001A JP 2004089001 A JP2004089001 A JP 2004089001A JP 4026833 B2 JP4026833 B2 JP 4026833B2
- Authority
- JP
- Japan
- Prior art keywords
- isothiazolin
- composition
- fungicide
- ppm
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims description 49
- 239000000645 desinfectant Substances 0.000 title description 3
- 239000000417 fungicide Substances 0.000 claims description 39
- 230000000855 fungicidal effect Effects 0.000 claims description 36
- JEVCLNJEBFWVPD-UHFFFAOYSA-N n-methyl-2-[[2-(methylcarbamoyl)phenyl]disulfanyl]benzamide Chemical compound CNC(=O)C1=CC=CC=C1SSC1=CC=CC=C1C(=O)NC JEVCLNJEBFWVPD-UHFFFAOYSA-N 0.000 claims description 14
- 230000002195 synergetic effect Effects 0.000 claims description 13
- OKPNGJYDFAMSHL-UHFFFAOYSA-N 2-methyl-3h-1,2-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)N(C)CC2=C1 OKPNGJYDFAMSHL-UHFFFAOYSA-N 0.000 claims description 12
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 12
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 9
- 239000002537 cosmetic Substances 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 239000002453 shampoo Substances 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- 239000008199 coating composition Substances 0.000 claims description 3
- 244000005700 microbiome Species 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002904 solvent Substances 0.000 description 11
- 230000000844 anti-bacterial effect Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000003973 paint Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical class O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- -1 glycol ethers Chemical class 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 230000000813 microbial effect Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 241000222122 Candida albicans Species 0.000 description 3
- 229940126062 Compound A Drugs 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000011534 incubation Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000011885 synergistic combination Substances 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002455 scale inhibitor Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical group O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- OAAZUWWNSYWWHG-UHFFFAOYSA-N 1-phenoxypropan-1-ol Chemical compound CCC(O)OC1=CC=CC=C1 OAAZUWWNSYWWHG-UHFFFAOYSA-N 0.000 description 1
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 1
- PUSPAPGHKSLKKH-UHFFFAOYSA-N 2-methyl-1,2-thiazolidin-3-one Chemical compound CN1SCCC1=O PUSPAPGHKSLKKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 240000005428 Pistacia lentiscus Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229940041514 candida albicans extract Drugs 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000001965 potato dextrose agar Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- QCRXMFTZTSTGJM-UHFFFAOYSA-N triacetyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(=O)OC(=O)CC(O)(C(=O)OC(C)=O)CC(=O)OC(C)=O QCRXMFTZTSTGJM-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62M—RIDER PROPULSION OF WHEELED VEHICLES OR SLEDGES; POWERED PROPULSION OF SLEDGES OR SINGLE-TRACK CYCLES; TRANSMISSIONS SPECIALLY ADAPTED FOR SUCH VEHICLES
- B62M23/00—Transmissions characterised by use of other elements; Other transmissions
- B62M23/02—Transmissions characterised by use of other elements; Other transmissions characterised by the use of two or more dissimilar sources of power, e.g. transmissions for hybrid motorcycles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62M—RIDER PROPULSION OF WHEELED VEHICLES OR SLEDGES; POWERED PROPULSION OF SLEDGES OR SINGLE-TRACK CYCLES; TRANSMISSIONS SPECIALLY ADAPTED FOR SUCH VEHICLES
- B62M6/00—Rider propulsion of wheeled vehicles with additional source of power, e.g. combustion engine or electric motor
- B62M6/40—Rider propelled cycles with auxiliary electric motor
- B62M6/60—Rider propelled cycles with auxiliary electric motor power-driven at axle parts
- B62M6/65—Rider propelled cycles with auxiliary electric motor power-driven at axle parts with axle and driving shaft arranged coaxially
Description
(b)2,2’−ジチオビス(N−メチルベンズアミド)および2−メチルベンズイソチアゾロンの少なくとも一つを含む殺菌剤組成物に関する。
Qa/QA+Qb/QB=相乗指数(SI)
(式中、
QA=単独で作用する場合に終点を提供する化合物A(第一成分)の濃度(化合物AのMIC)(ppm)
Qa=混合物において終点を提供する化合物Aの濃度(ppm)
QA=単独で作用する場合に終点を提供する化合物B(第二成分)の濃度(化合物BのMIC)(ppm)
Qa=混合物において終点を提供する化合物Bの濃度(ppm))
により決定される比を用いて、相乗作用を確認した。
8.5〜8.8のpHを有する塗料配合物を、アクリル系バインダー、セルソース系増粘剤、カオリン、配合物ための添加剤、および水から調製した。50グラムの塗料サンプルに、汚染された塗料から単離された微生物を、接種物の濃度を上昇させながら繰り返し接種する。この処置を1週間に1回行う。各接種の6日後に、栄養培地上に適用することにより各サンプルにおいて生存する微生物を評価する。これらの縞状物(streak−out)を最高7日までのインキュベーション時間(27±2℃、85〜95%相対大気湿度)の後に評価する。試験されるシステムの保存されなかったサンプルを微生物の成長の感受性をチェックするために使用する。接種サイクルを5回行い、かくして6週間の試験期間に至る。微生物成長の評価のための評価尺度は次の通りである:
0=成長なし
1=若干成長
2=中程度の成長
3=著しい成長
Claims (11)
- (a)置換および非置換2−(C1−C4)アルキル−4−イソチアゾリン−3−オンから選択される少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オン;および
(b)2,2’−ジチオビス(N−メチルベンズアミド)および2−メチルベンズイソチアゾロンの少なくとも一つ
を含み、
前記の少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オンの、前記の2,2’−ジチオビス(N−メチルベンズアミド)および2−メチルベンズイソチアゾロンの少なくとも一つに対する重量比が750:1〜1:1である殺菌剤組成物。 - (a)置換および非置換2−(C 1 −C 4 )アルキル−4−イソチアゾリン−3−オンから選択される少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オン;および
(b)2,2’−ジチオビス(N−メチルベンズアミド)
を含み、
前記の少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オンの、前記の2,2’−ジチオビス(N−メチルベンズアミド)に対する重量比が375:1〜1:20である殺菌剤組成物。 - 前記の少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オンが2−メチル−4−イソチアゾリン−3−オンである請求項2記載の組成物。
- 前記重量比が100:1〜1:20である請求項3記載の組成物。
- 前記の2,2’−ジチオビス(N−メチルベンズアミド)および2−メチルベンズイソチアゾロンの少なくとも一つが2−メチルベンズイソチアゾロンであり、前記重量比が750:1〜2.5:1である請求項1記載の組成物。
- 前記の少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オンが2−メチル−4−イソチアゾリン−3−オンである請求項5記載の組成物。
- 前記重量比が125:1〜2.5:1である請求項6記載の組成物。
- 50ppmから500ppmの相乗殺菌剤組成物を含む塗料組成物であって;前記相乗殺菌剤組成物が:
(a)2−メチル−4−イソチアゾリン−3−オン;および
(b)2,2’−ジチオビス(N−メチルベンズアミド);を含み;
2−メチル−4−イソチアゾリン−3−オンの、2,2’−ジチオビス(N−メチルベンズアミド)に対する重量比が375:1〜1:6である塗料組成物。 - 前記の少なくとも一つの非ハロゲン化2−アルキル−4−イソチアゾリン−3−オンが2−メチル−4−イソチアゾリン−3−オンである請求項1記載の組成物。
- 請求項9に記載の殺菌剤組成物を含む、家庭用品、化粧品、洗面用化粧品、シャンプー、石けんまたは洗剤。
- 前記の2,2’−ジチオビス(N−メチルベンズアミド)および2−メチルベンズイソチアゾロンの少なくとも一つが2−メチルベンズイソチアゾロンであり、前記重量比が750:1〜2.5:1である請求項10記載の家庭用品、化粧品、洗面用化粧品、シャンプー、石けんまたは洗剤。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US45820303P | 2003-03-26 | 2003-03-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2004292449A JP2004292449A (ja) | 2004-10-21 |
JP4026833B2 true JP4026833B2 (ja) | 2007-12-26 |
Family
ID=32825477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004089001A Expired - Lifetime JP4026833B2 (ja) | 2003-03-26 | 2004-03-25 | 殺菌剤組成物 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7560476B2 (ja) |
EP (1) | EP1462003B1 (ja) |
JP (1) | JP4026833B2 (ja) |
KR (1) | KR101061402B1 (ja) |
CN (1) | CN1307876C (ja) |
AU (1) | AU2004201059B2 (ja) |
BR (1) | BRPI0400354B1 (ja) |
DE (1) | DE602004007564T2 (ja) |
ES (1) | ES2288664T3 (ja) |
TW (1) | TWI342749B (ja) |
ZA (1) | ZA200402085B (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA200508883B (en) * | 2004-11-16 | 2006-07-26 | Rohm & Haas | Microbicidal composition |
AU2012201220B2 (en) * | 2005-10-04 | 2013-09-05 | Rohm And Haas Company | Microbicidal composition |
EP1772055A1 (en) * | 2005-10-04 | 2007-04-11 | Rohm and Haas France SAS | Synergistic microbicidal compositions comprising a N-alkyl-1,2-benzoisothiazolin-3-one |
AU2012201209B2 (en) * | 2005-10-04 | 2013-09-05 | Rohm And Haas Company | Microbicidal composition |
AU2012201201B2 (en) * | 2005-10-04 | 2013-09-05 | Rohm And Haas Company | Microbicidal composition |
EP1849362B1 (en) * | 2006-04-07 | 2012-09-12 | Rohm and Haas Company | Water treatment method |
US8309231B2 (en) * | 2006-05-31 | 2012-11-13 | Usg Interiors, Llc | Acoustical tile |
CA2707743C (en) | 2007-06-21 | 2013-12-31 | Rohm And Haas Company | Microbicidal composition comprising n-methyl-1,2-benzisothiazolin-3-one and at least one of 2-n-octyl-4-isothiazolin-3-one and a mixture of chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one |
JP4944843B2 (ja) * | 2007-07-18 | 2012-06-06 | ローム アンド ハース カンパニー | 殺微生物組成物 |
JP4944844B2 (ja) * | 2007-07-18 | 2012-06-06 | ローム アンド ハース カンパニー | 殺微生物組成物 |
KR20100101589A (ko) * | 2007-11-30 | 2010-09-17 | 다우 글로벌 테크놀로지스 인크. | 살생제를 함유하는 라텍스 페인트의 제조 방법, 라텍스 페인트용 그라인드 및 분산 상 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1532984A (en) | 1975-04-10 | 1978-11-22 | Ici Ltd | Method for the control of micro-organisms |
JPS5657874A (en) * | 1979-10-18 | 1981-05-20 | Yoshitomi Pharmaceut Ind Ltd | Antiseptic agent of mud drilling process |
GB8715191D0 (en) * | 1987-06-29 | 1987-08-05 | Ici Plc | Composition |
EP0900525A1 (de) * | 1997-08-20 | 1999-03-10 | Thor Chemie Gmbh | Synergistische Biozidzusammensetzung |
JP4377521B2 (ja) * | 2000-04-28 | 2009-12-02 | 株式会社パーマケム・アジア | 工業用殺菌剤及び殺菌方法 |
DE10042894A1 (de) * | 2000-08-31 | 2002-03-14 | Thor Chemie Gmbh | Synergistische Biozidzusammensetzung mit 2-Methylisothiazolin-3-on |
DE10046265A1 (de) * | 2000-09-19 | 2002-03-28 | Bayer Ag | Wirkstoffkombination zum Schutz von tierischen Häuten |
-
2004
- 2004-03-12 AU AU2004201059A patent/AU2004201059B2/en not_active Ceased
- 2004-03-15 EP EP04251466A patent/EP1462003B1/en not_active Expired - Lifetime
- 2004-03-15 BR BRPI0400354A patent/BRPI0400354B1/pt active IP Right Grant
- 2004-03-15 ES ES04251466T patent/ES2288664T3/es not_active Expired - Lifetime
- 2004-03-15 DE DE602004007564T patent/DE602004007564T2/de not_active Expired - Lifetime
- 2004-03-15 TW TW093106856A patent/TWI342749B/zh not_active IP Right Cessation
- 2004-03-16 ZA ZA200402085A patent/ZA200402085B/xx unknown
- 2004-03-18 US US10/803,237 patent/US7560476B2/en active Active
- 2004-03-18 CN CNB2004100300801A patent/CN1307876C/zh not_active Expired - Lifetime
- 2004-03-22 KR KR1020040019403A patent/KR101061402B1/ko active IP Right Grant
- 2004-03-25 JP JP2004089001A patent/JP4026833B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
BRPI0400354A (pt) | 2004-12-28 |
CN1307876C (zh) | 2007-04-04 |
AU2004201059A1 (en) | 2004-10-14 |
AU2004201059B2 (en) | 2009-06-04 |
US20040198785A1 (en) | 2004-10-07 |
DE602004007564T2 (de) | 2008-04-17 |
US7560476B2 (en) | 2009-07-14 |
EP1462003A1 (en) | 2004-09-29 |
CN1531848A (zh) | 2004-09-29 |
DE602004007564D1 (de) | 2007-08-30 |
JP2004292449A (ja) | 2004-10-21 |
ES2288664T3 (es) | 2008-01-16 |
ZA200402085B (en) | 2004-09-16 |
TWI342749B (en) | 2011-06-01 |
KR20040084694A (ko) | 2004-10-06 |
KR101061402B1 (ko) | 2011-09-01 |
EP1462003B1 (en) | 2007-07-18 |
TW200423870A (en) | 2004-11-16 |
BRPI0400354B1 (pt) | 2016-10-25 |
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