JP3971835B2 - 無水マレイン酸で変性したポリマーを含有する直接塗布可能な熱可塑性オレフィン組成物 - Google Patents
無水マレイン酸で変性したポリマーを含有する直接塗布可能な熱可塑性オレフィン組成物 Download PDFInfo
- Publication number
- JP3971835B2 JP3971835B2 JP6382798A JP6382798A JP3971835B2 JP 3971835 B2 JP3971835 B2 JP 3971835B2 JP 6382798 A JP6382798 A JP 6382798A JP 6382798 A JP6382798 A JP 6382798A JP 3971835 B2 JP3971835 B2 JP 3971835B2
- Authority
- JP
- Japan
- Prior art keywords
- ethylene
- copolymer
- olefin
- propylene
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 title claims description 49
- 229920002397 thermoplastic olefin Polymers 0.000 title claims description 44
- 239000000203 mixture Substances 0.000 title claims description 39
- 229920000642 polymer Polymers 0.000 title claims description 22
- 229920001577 copolymer Polymers 0.000 claims description 77
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 59
- 239000005977 Ethylene Substances 0.000 claims description 59
- 239000004711 α-olefin Substances 0.000 claims description 54
- -1 propylene, ethylene Chemical group 0.000 claims description 41
- 229920000098 polyolefin Polymers 0.000 claims description 24
- 239000002861 polymer material Substances 0.000 claims description 23
- 229920001155 polypropylene Polymers 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 22
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 20
- 229920000573 polyethylene Polymers 0.000 claims description 17
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000008096 xylene Substances 0.000 claims description 16
- 150000001993 dienes Chemical class 0.000 claims description 14
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000005060 rubber Substances 0.000 claims description 13
- 229920001384 propylene homopolymer Polymers 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 11
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 8
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 7
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 229920001083 polybutene Polymers 0.000 claims description 5
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 4
- 229920005604 random copolymer Polymers 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 229920000578 graft copolymer Polymers 0.000 claims description 3
- 229920005684 linear copolymer Polymers 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
- 150000008064 anhydrides Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 239000003973 paint Substances 0.000 description 17
- 239000004743 Polypropylene Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004018 acid anhydride group Chemical group 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229920001910 maleic anhydride grafted polyolefin Polymers 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- WEHDCBONCFYXKK-UHFFFAOYSA-N tert-butyl 3-(4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)OC(=O)CCC1=CC=C(O)C=C1 WEHDCBONCFYXKK-UHFFFAOYSA-N 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6382798A JP3971835B2 (ja) | 1998-02-06 | 1998-02-06 | 無水マレイン酸で変性したポリマーを含有する直接塗布可能な熱可塑性オレフィン組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6382798A JP3971835B2 (ja) | 1998-02-06 | 1998-02-06 | 無水マレイン酸で変性したポリマーを含有する直接塗布可能な熱可塑性オレフィン組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11255985A JPH11255985A (ja) | 1999-09-21 |
| JPH11255985A5 JPH11255985A5 (enExample) | 2005-08-04 |
| JP3971835B2 true JP3971835B2 (ja) | 2007-09-05 |
Family
ID=13240593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6382798A Expired - Fee Related JP3971835B2 (ja) | 1998-02-06 | 1998-02-06 | 無水マレイン酸で変性したポリマーを含有する直接塗布可能な熱可塑性オレフィン組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3971835B2 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5962573A (en) * | 1998-02-13 | 1999-10-05 | Montell North America Inc. | Directly paintable thermoplastic olefin composition containing oxidized polyethylene waxes |
| US6433063B1 (en) * | 2000-06-30 | 2002-08-13 | Basell Technology Company Bv | Directly paintable thermoplastic olefin composition with improved conductivity |
| US6667367B1 (en) * | 2000-10-10 | 2003-12-23 | Basell Poliolefine Italia S.P.A. | Directly paintable polypropylene graft copolymers |
| US6743864B2 (en) * | 2002-03-12 | 2004-06-01 | Basell Poliolefine Italia S.P.A. | Polyolefin compositions having high tenacity |
| JP2004254403A (ja) * | 2003-02-19 | 2004-09-09 | Toshiba Corp | 永久磁石形モータ及びその製造方法 |
| JP4507606B2 (ja) * | 2004-01-19 | 2010-07-21 | 住友化学株式会社 | 熱可塑性エラストマー組成物 |
| ES2863574T3 (es) * | 2015-03-18 | 2021-10-11 | Dow Global Technologies Llc | Películas protectoras, mezclas y métodos de fabricación de las mismas |
| CN111040300A (zh) * | 2019-12-26 | 2020-04-21 | 上海涵点科技有限公司 | 一种能使pp材料免火焰处理的功能母粒及其制备方法和应用 |
| CN117511030A (zh) * | 2023-11-02 | 2024-02-06 | 中国神华煤制油化工有限公司 | 一种熔体增强聚乙烯组合物及其制备方法 |
-
1998
- 1998-02-06 JP JP6382798A patent/JP3971835B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11255985A (ja) | 1999-09-21 |
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