JP3716088B2 - Wiring board - Google Patents

Wiring board Download PDF

Info

Publication number
JP3716088B2
JP3716088B2 JP33730297A JP33730297A JP3716088B2 JP 3716088 B2 JP3716088 B2 JP 3716088B2 JP 33730297 A JP33730297 A JP 33730297A JP 33730297 A JP33730297 A JP 33730297A JP 3716088 B2 JP3716088 B2 JP 3716088B2
Authority
JP
Japan
Prior art keywords
zno
mgo
sio
over
insulating substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP33730297A
Other languages
Japanese (ja)
Other versions
JPH11176998A (en
Inventor
邦英 四方
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP33730297A priority Critical patent/JP3716088B2/en
Publication of JPH11176998A publication Critical patent/JPH11176998A/en
Application granted granted Critical
Publication of JP3716088B2 publication Critical patent/JP3716088B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/151Die mounting substrate
    • H01L2924/153Connection portion
    • H01L2924/1531Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
    • H01L2924/15311Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA

Landscapes

  • Compositions Of Oxide Ceramics (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、LSI(大規模集積回路素子)等の半導体素子が搭載接続される配線基板に関するものである。
【0002】
【従来の技術】
従来、半導体素子が搭載接続される外部電気回路基板は酸化アルミニウム質焼結体等の電気絶縁材料から成る絶縁基体と、該絶縁基体の表面及び内部に形成され、タングステン、モリブデン、マンガン等の金属材料から成る複数個の配線導体とで構成されている。
【0003】
かかる外部電気回路基板は一般にMoーMn法等の厚膜形成技術を採用することによって形成され、具体的には、タングステン、モリブデン、マンガン等の高融点金属から成る金属粉末に有機バインダー、溶剤等を添加し、ペースト状となした金属ペーストを生もしくは焼結セラミック体の外表面にスクリーン印刷法により配線導体となる所定パターンに印刷塗布し、次にこれを還元雰囲気中で焼成し、高融点金属とセラミック体とを焼結一体化させることによって形成されている。
【0004】
また近時、電子機器の小型化に対応して外部電気回路基板も小型にして、かつ配線導体を高密度に形成することが要求されるようになってきており、これに対応するために配線導体を厚膜形成技術で形成するのに変えて微細配線が可能な薄膜形成技術で形成した外部電気回路基板も使用されるようになってきた。
【0005】
この配線導体を薄膜形成技術で形成した外部電気回路基板は、絶縁基体上に、例えば、窒化タンタルやニッケル・クロム合金等から成る接着層と、ニッケル・クロム合金やチタン・タングステン合金、ニッケル、パラジウム等から成る中間層と、金や銅等から成る主導体層をイオンプレーティング法やスパッタリング法、蒸着法、メッキ法等の薄膜形成技術を採用することによって順次被着させ、次に、これらの各層をフォトリソグラフィー技術で所定パターンに加工し、配線導体とすることによって形成されている。
【0006】
かかる外部電気回路基板は、絶縁基体の上面に、下面に電極を有する半導体素子が載置され、絶縁基体上面の配線導体と半導体素子の下面の電極とを半田等を介し接合させることによって半導体素子が搭載接続されることとなり、配線導体を介して半導体素子に所定の電気信号を出し入れすることによって半導体素子が駆動する。
【0007】
【発明が解決しようとする課題】
しかしながら、近年、情報処理装置は高性能化が急激に進展し、これに伴って半導体素子も高速駆動が行われ、ノイズの影響を極めて受け易いものになってきたこと、従来の外部電気回路基板はタングステン、モリブデン等から成る配線導体が高調波のノイズを伝搬させ易いこと等から配線基板の配線導体に高調波のノイズが入り込んだ場合、このノイズがそのまま配線導体を介して半導体素子に入り込み、半導体素子を誤動作させるという欠点を有していた。
【0008】
本発明は、上記欠点に鑑み案出されたもので、その目的は、半導体素子と従来の外部電気回路基板との間に配され、外部電気回路基板の配線導体に入り込んだノイズがそのまま半導体素子に入り込むのを有効に防止し、半導体素子を長期間にわたり正常に作動させることができる配線基板を提供することにある。
【0009】
【課題を解決するための手段】
本発明は、厚み方向に複数個の貫通孔を有する絶縁基体と、前記貫通孔内に充填され、一端が絶縁基体の上面に導出されて半導体素子の電極が接続される上部接続パッドを形成し、他端が絶縁基体の下面に導出されて外部電気回路基板の配線導体が接続される下部接続パッドを形成する複数個の配線層とから成る配線基板であって、前記絶縁基体はSiOーAlーMgOーZnOーB系結晶性ガラスから成り、かつZnFe、MnFe、FeFe、CoFe、NiFe、CuFeの少なくとも1種から成る磁性材料が含有されていることを特徴とするものである。
【0010】
また本発明は前記磁性材料の含有量が50〜90重量%であることを特徴とするものである。
【0011】
更に本発明は、前記絶縁基体に、外添加で10〜40重量部の無機物フィラーを含有させたことを特徴とするものである。
【0012】
本発明の配線基板によれば、絶縁基体をSiOーAlーMgOーZnOーB系結晶性ガラスで形成するとともにZnFe、MnFe、FeFe、CoFe、NiFe、CuFeの少なくとも1種から成る磁性材料を含有させたことから絶縁基体に設けた配線層にノイズが伝搬した場合、そのノイズは磁性材料で熱エネルギーに変換されて吸収され、その結果、ノイズが半導体素子に入り込むことはなく、半導体素子を常に正常に作動させることが可能となる。
【0013】
また本発明の配線基板によれば、絶縁基体を形成するSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が800〜1050℃であり、低いことからこの結晶性ガラス中に磁性材料を含有させて焼成しても磁性材料は磁性を失うことはなく、ノイズを良好に吸収することが可能となる。
【0014】
同時にガラスセラミック焼結体の焼成温度が低いことから銅、銀、金等の融点が低くく、導通抵抗の低い材料から成る配線層を同時焼成によって形成することが可能となり、配線層を電気信号が伝搬した際、電気信号に減衰等が生じるのを有効に防止して半導体素子を正確に作動させることもできる。
【0015】
更に絶縁基体に無機物フィラーを外添加で10〜40重量部の範囲で含有させると絶縁基体の機械的強度が強くなり、外力印加によって破損等が招来するのを有効に防止することもできる。
【0016】
【発明の実施の形態】
次に本発明を添付図面に基づき詳細に説明する。
図1は本発明の配線基板の一実施例を示し、1は絶縁基体、2は配線層である。
【0017】
前記絶縁基体1はSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスから成り、その厚み方向に貫通する複数個の貫通孔3が形成されており、該貫通孔3内には銅、銀、金等から成る導通抵抗の小さい金属材料から成る配線層2が形成されている。
【0018】
前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスから成る絶縁基体1は、例えば、SiO2 、Al2 3 、MgO、ZnO、B2 3 から成るガラス成分粉末に適当な有機バインダー、溶剤、可塑剤等を添加混合して泥漿状となすとともにこれを従来周知のドクターブレード法やカレンダーロール法等を採用しシート状に成形することによって複数枚のグリーンシート(生シート)を得、次に、前記グリーンシートに適当な打ち抜き加工を施すとともに所定の順に上下に積層して生成形体となすとともに該生成形体を800〜1050℃の温度で焼成することによって製作される。
【0019】
また前記絶縁基体1に形成されている貫通孔3は、焼成によって絶縁基体1となるグリーンシート(生シート)に従来周知の金型によるパンチング孔開け加工法を採用することによって、例えば、直径80μm〜250μmに形成される。
【0020】
前記絶縁基体1に形成した貫通孔3内には配線層2が形成されており、該配線層2は外部電気回路基板5の配線導体5aと半導体素子4の電極4aとを電気的に接続する作用をなし、配線層2の一端を絶縁基体1の上面に導出させて上部接続パッド2aを形成するとともに、他端を絶縁基体1の下面に導出されて下部接続パッド2bを形成し、上部接続パッド2aに半導体素子4の電極4aを半田等から成る導電性接合材6を介して接合させ、下部接続パッド2bに外部電気回路基板5の配線導体5aを半田等から成る導電性接合材7を介して接合させれば半導体素子4の電極4aは配線層2を介して外部電気回路基板5の配線導体5aに接続されることとなり、これによって外部電気回路より半導体素子4に電気信号が出し入れし、半導体素子4を作動させることができる。
【0021】
前記配線層2は銅、銀、金等の融点が低く、導通抵抗の小さい金属材料によって形成されており、銅、銀、金等の金属粉末に有機バインダー、溶剤、可塑材等を添加混合して金属ペーストを作成し、この金属ペーストを焼成によって絶縁基体1となるグリーンシート(生シート)に設けた貫通孔内に充填しておき、グリーンシートの焼成と同時焼成によって絶縁基体1の貫通孔3内に形成される。この場合、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスはその焼成温度が800〜1050℃と低いため、絶縁基体1の焼成時に金属ペーストの金属粉末が気散してしまうことはなく、絶縁基体1と同時焼成によって絶縁基体1の貫通孔3内に形成することができる。
【0022】
なお、前記配線層2は銅、銀、金等の導通抵抗が低い金属材料で形成されていることから配線層2を電気信号が伝搬しても電気信号に減衰等が生じるのを有効に防止することができ、その結果、半導体素子4を正確に作動させることができる。
【0023】
また前記貫通孔3内に配線層2を有する絶縁基体1は、その内部にZnFe2 4 、MnFe2 4 、FeFe2 4 、CoFe2 4 、NiFe2 4 、CuFe2 4 の少なくとも1種から成る磁性材料が含有されており、該磁性材料は配線層2に外部電気回路から入り込んだ高調波ノイズが伝搬した場合、そのノイズを熱エネルギーに変換して吸収し、ノイズが半導体素子に入り込むのを有効に防止する作用をなし、これによって半導体素子は常に正常に作動させることが可能となる。
【0024】
前記磁性材料は、例えば、焼成によって絶縁基体1となるグリーンシートに、ZnFe2 4 、MnFe2 4 、FeFe2 4 、CoFe2 4 、NiFe2 4 、CuFe2 4 の少なくとも1種から成る磁性粉末を添加含有させておくことによって絶縁基体1内に含有される。
【0025】
前記磁性材料を含有する絶縁基体1、即ち、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスと、磁性材料とより成る絶縁基体1はSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの量が10重量%未満、言い換えると磁性材料が90重量%を超えたものとなるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となり、またSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの量が50重量%を超え、言い換えると磁性材料が50重量%未満となると、絶縁基体1に設けた配線層2に外部電気回路基板5の配線導体5aよりノイズが入り込んだ場合、ノイズを良好に吸収することができず、半導体素子4に誤動作を起こさせてしまう。従って、前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスに磁性材料を含有させた絶縁基体1は、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの量を10〜50重量%の範囲に、磁性材料の量を50〜90重量%の範囲にしておくことが好ましい。
【0026】
前記磁性材料はまたその粒径が0.5μm未満となると、焼成によって絶縁基体1を製作する際、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスとの反応が進行し、磁性材料の残存率が低下してノイズを効果的に吸収することができなくなり、また10μmを超えるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となる。従って、前記磁性材料はその粒径を0.5μm〜10μmの範囲としておくことが好ましい。
【0027】
本発明の配線基板においては絶縁基体1をSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスで形成することが重要である。
【0028】
このSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスは、例えば、SiO2 :40〜46重量%、Al2 3 :25〜30重量%、MgO:8〜13重量%、ZnO:6〜9重量%、B2 3 :8〜11重量%で形成されている。
【0029】
前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスは、焼成時にガーナイト(ZnO・Al2 3 )、コージェライト(2MgO・2Al2 3 )、スピネル型結晶相(MgO・Al2 3 、ZnO・Al2 3 )等の結晶相を生成するが、これらの結晶相の生成により絶縁基体1の強度が向上するという性質を持っている。
【0030】
また前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスはその焼成温度が800〜1050℃と低いことから、配線層2を銅、銀、金等の融点が低くく、導通抵抗の低い材料としても絶縁基体1と同時焼成によって形成することが可能となり、配線層2を電気信号が伝搬した際、電気信号に減衰等が生じるのを有効に防止して半導体素子4を正確に作動させることができる。
【0031】
更に前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が800〜1050℃と低いことから焼成時に磁性材料を含有させておいても磁性材料の磁性が失われることはなく、これによって配線層2に入り込んだノイズを良好に吸収することが可能となる。
【0032】
前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスはまたその比誘電率が約5(室温1MHz)と低くく、そのため絶縁基体1の貫通孔3内に配されている配線層2に電気信号を伝搬させても伝搬遅延を招来することはなく、これによって配線層2に高速で電気信号を伝搬させることが可能となる。
【0033】
なお、前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスは、SiO2 の量が40重量%未満、或いは46重量%を超えるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となる。従って、SiO2 の量は40〜46重量%の範囲としておくことが好ましい。
【0034】
またAl2 3 の量が25重量%未満、或いは30重量%を超えるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となる。従って、Al2 3 の量は25〜30重量%の範囲としておくことが好ましい。
【0035】
またMgOの量が8重量%未満となると焼成によってSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスから成る絶縁基体1を製作する際、生成するコージェライト(2MgO・2Al2 3 )の量が少なくなって絶縁基体1の強度を大きく向上させることができず、また13重量%を超えるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となる。従って、MgOの量は8〜13重量%の範囲としておくことが好ましい。
【0036】
またZnOの量が6重量%未満となると焼成によってSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスから成る絶縁基体1を製作する際、生成するガーナイト(ZnO・Al2 3 )の量が少なくなって絶縁基体1の強度を大きく向上させることができず、また9重量%を超えるとSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が高いものとなって銅等の金属材料から成る配線層2と同時に焼成するのが困難となる。従って、ZnOの量は6〜9重量%の範囲としておくことが好ましい。
【0037】
またB2 3 の量が8重量%未満となると焼成によってSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスから成る絶縁基体1を製作する際、ガーナイト(ZnO・Al2 3 )、コージェライト(2MgO・2Al2 3 )、スピネル型結晶相(MgO・Al2 3 、ZnO・Al2 3 )等の結晶相が過剰に生成され、絶縁基体1が多孔質のものとなって配線基板として不向きとなり、また11重量%を超えると耐薬品性が大きく劣化して配線基板としての信頼性が大きく低下してしまう。従って、B2 3 の量は8〜11重量%の範囲としておくことが好ましい。
【0038】
更に前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスはその内部に無機物フィラー,具体的にはアルミナ、シリカ、窒化珪素、窒化アルミニウム等の粉末を外添加で10〜40重量部添加含有させておくと機械的強度が大幅に向上し、外力印加によって破損等を招来するのが有効に防止される。従って、絶縁基体1の機械的強度を向上させ、外力印加によって破損等を招来しないようにするのは前記SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスに無機物フィラーを外添加で10〜40重量部添加含有させて絶縁基体1を形成することが好ましい。
【0039】
前記無機物フィラーは更にその粒径を0.5〜5μmの範囲としておくとガラスセラミック焼結体中に均一に分散含有させて絶縁基体1の機械的強度を均一に向上させることができる。従って、前記無機物フィラーはその粒径を0.5〜5μmの範囲としておくことが好ましい。
【0040】
なお、本発明は上述の実施例に限定されるものではなく、本発明の要旨を逸脱しない範囲であれば種々の変更は可能である。
【0041】
また上述の実施例では複数のグリーンシートを積層した成形体を焼成して絶縁基体1を作成したが、これをプレス成形等によって成形した1つの成形体を焼成して作成してもよい。また同時に複数のグリーンシートを積層した成形体を焼成して絶縁基体1を作成する際、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスに磁性材料を含有させたものと、SiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスに無機物フィラーを含有させたものとを多層に配して作成してもよい。
【0042】
【発明の効果】
本発明の配線基板によれば、絶縁基体をSiOーAlーMgOーZnOーB系結晶性ガラスで形成するとともにZnFe、MnFe、FeFe、CoFe、NiFe、CuFeの少なくとも1種から成る磁性材料を含有させたことから絶縁基体に設けた配線層にノイズが伝搬した場合、そのノイズは磁性材料で熱エネルギーに変換されて吸収され、その結果、ノイズが半導体素子に入り込むことはなく、半導体素子を常に正常に作動させることが可能となる。
【0043】
また本発明の配線基板によれば、絶縁基体を形成するSiO2 ーAl2 3 ーMgOーZnOーB2 3 系結晶性ガラスの焼成温度が800〜1050℃であり、低いことからこの結晶性ガラス中に磁性材料を含有させて焼成しても磁性材料は磁性を失うことはなく、ノイズを良好に吸収することが可能となる。
【0044】
同時にガラスセラミック焼結体の焼成温度が低いことから銅、銀、金等の融点が低くく、導通抵抗の低い材料から成る配線層を同時焼成によって形成することが可能となり、配線層を電気信号が伝搬した際、電気信号に減衰等が生じるのを有効に防止して半導体素子を正確に作動させることもできる。
【0045】
更に絶縁基体に無機物フィラーを外添加で10〜40重量部の範囲で含有させると絶縁基体の機械的強度が強くなり、外力印加によって破損等が招来するのを有効に防止することもできる。
【図面の簡単な説明】
【図1】本発明の配線基板の一実施例を示す断面図である。
【符号の説明】
1・・・絶縁基体
2・・・配線層
2a・・上部接続パッド
2b・・下部接続パッド
3・・・貫通孔
4・・・半導体素子
4a・・半導体素子の電極
5・・・外部電気回路基板
5a・・外部電気回路基板の配線導体
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a wiring board on which a semiconductor element such as an LSI (Large Scale Integrated Circuit Element) is mounted and connected.
[0002]
[Prior art]
Conventionally, an external electric circuit board on which a semiconductor element is mounted and connected is formed on an insulating base made of an electric insulating material such as an aluminum oxide sintered body, and on the surface and inside of the insulating base, and a metal such as tungsten, molybdenum or manganese. It consists of a plurality of wiring conductors made of material.
[0003]
Such an external electric circuit board is generally formed by adopting a thick film forming technique such as a Mo-Mn method. Specifically, an organic binder, a solvent, etc. are added to a metal powder made of a refractory metal such as tungsten, molybdenum, or manganese. Is added to the outer surface of the raw or sintered ceramic body in a predetermined pattern to be a wiring conductor by screen printing, and then fired in a reducing atmosphere to obtain a high melting point. It is formed by sintering and integrating a metal and a ceramic body.
[0004]
Recently, in response to miniaturization of electronic devices, it has been demanded that an external electric circuit board be made smaller and that a wiring conductor be formed at a high density. An external electric circuit board formed by a thin film forming technique capable of fine wiring instead of forming a conductor by a thick film forming technique has also been used.
[0005]
An external electric circuit board in which this wiring conductor is formed by a thin film forming technology is formed on an insulating substrate, for example, an adhesive layer made of tantalum nitride, nickel-chromium alloy, etc., nickel-chromium alloy, titanium-tungsten alloy, nickel, palladium And the like, and a main conductor layer made of gold, copper, or the like are sequentially deposited by adopting a thin film forming technique such as an ion plating method, a sputtering method, a vapor deposition method, or a plating method. Each layer is formed by processing it into a predetermined pattern by a photolithography technique to form a wiring conductor.
[0006]
In such an external electric circuit board, a semiconductor element having an electrode on the lower surface is placed on the upper surface of the insulating base, and the wiring conductor on the upper surface of the insulating base and the electrode on the lower surface of the semiconductor element are joined via solder or the like. The semiconductor element is driven by inputting and outputting a predetermined electric signal to and from the semiconductor element through the wiring conductor.
[0007]
[Problems to be solved by the invention]
However, in recent years, the performance of information processing devices has advanced rapidly, and with this, semiconductor elements have also been driven at high speed, making them extremely susceptible to noise. Conventional external electric circuit boards When the harmonic noise enters the wiring conductor of the wiring board because the wiring conductor made of tungsten, molybdenum, etc. easily propagates the harmonic noise, this noise directly enters the semiconductor element via the wiring conductor, The semiconductor device has a drawback of malfunctioning.
[0008]
The present invention has been devised in view of the above disadvantages, and its object is to arrange a semiconductor element between a semiconductor element and a conventional external electric circuit board, and the noise that enters the wiring conductor of the external electric circuit board remains as it is. An object of the present invention is to provide a wiring board that can effectively prevent the semiconductor element from entering and can operate the semiconductor element normally over a long period of time.
[0009]
[Means for Solving the Problems]
The present invention forms an insulating substrate having a plurality of through holes in the thickness direction, and an upper connection pad filled in the through holes, one end of which is led out to the upper surface of the insulating substrate and connected to an electrode of a semiconductor element. A wiring board comprising a plurality of wiring layers, the other end of which is led out to the lower surface of the insulating base to form a lower connection pad to which the wiring conductor of the external electric circuit board is connected, the insulating base being SiO 2− al 2 O 3 consists of over MgO over ZnO over B 2 O 3 based crystalline glass, and ZnFe 2 O 4, MnFe 2 O 4, FeFe 2 O 4, CoFe 2 O 4, NiFe 2 O 4, CuFe 2 O 4 The magnetic material which consists of at least 1 type of these is contained, It is characterized by the above-mentioned.
[0010]
The present invention is also characterized in that the content of the magnetic material is 50 to 90% by weight.
[0011]
Furthermore, the present invention is characterized in that 10 to 40 parts by weight of an inorganic filler is added to the insulating base by external addition.
[0012]
According to the wiring board of the present invention, ZnFe 2 O 4, MnFe 2 O 4, FeFe 2 O 4 with an insulating substrate with SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass , CoFe 2 O 4 , NiFe 2 O 4 , CuFe 2 O 4 containing a magnetic material, when noise propagates to the wiring layer provided on the insulating substrate, the noise is heated by the magnetic material. It is converted into energy and absorbed. As a result, noise does not enter the semiconductor element, and the semiconductor element can always operate normally.
[0013]
According to the wiring board of the present invention, the firing temperature of the SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass forming the insulating base is 800 to 1050 ° C., from this low that Even if a magnetic material is contained in the crystalline glass and baked, the magnetic material does not lose its magnetism and can absorb noise well.
[0014]
At the same time, since the firing temperature of the glass ceramic sintered body is low, it becomes possible to form a wiring layer made of a material with low melting point such as copper, silver, gold, etc. and low conduction resistance by simultaneous firing. When the signal propagates, it is possible to effectively prevent the electric signal from being attenuated and to operate the semiconductor device accurately.
[0015]
Furthermore, when an inorganic filler is added to the insulating substrate in an amount of 10 to 40 parts by weight, the mechanical strength of the insulating substrate is increased, and it is possible to effectively prevent breakage due to the application of external force.
[0016]
DETAILED DESCRIPTION OF THE INVENTION
Next, the present invention will be described in detail with reference to the accompanying drawings.
FIG. 1 shows an embodiment of a wiring board according to the present invention, where 1 is an insulating substrate and 2 is a wiring layer.
[0017]
The insulating substrate 1 is made of SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O 3 crystalline glass, and has a plurality of through holes 3 penetrating in the thickness direction. A wiring layer 2 made of a metal material having a small conduction resistance made of copper, silver, gold or the like is formed therein.
[0018]
The insulating substrate 1 made of the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass is composed of, for example, a glass component made of SiO 2 , Al 2 O 3 , MgO, ZnO, B 2 O 3. Add a suitable organic binder, solvent, plasticizer, etc. to the powder to make a slurry, and then form this into a sheet using a well-known doctor blade method, calendar roll method, etc. (Green sheet) is obtained, and then the green sheet is appropriately punched and laminated in a predetermined order to form a generated shape and the generated shape is fired at a temperature of 800 to 1050 ° C. Is done.
[0019]
Further, the through hole 3 formed in the insulating base 1 is formed by adopting a conventionally known punching method using a mold in a green sheet (raw sheet) which becomes the insulating base 1 by firing, for example, a diameter of 80 μm. Formed to ˜250 μm.
[0020]
A wiring layer 2 is formed in the through hole 3 formed in the insulating base 1, and the wiring layer 2 electrically connects the wiring conductor 5a of the external electric circuit board 5 and the electrode 4a of the semiconductor element 4. One end of the wiring layer 2 is led to the upper surface of the insulating substrate 1 to form the upper connection pad 2a, and the other end is led to the lower surface of the insulating substrate 1 to form the lower connection pad 2b. An electrode 4a of the semiconductor element 4 is bonded to the pad 2a via a conductive bonding material 6 made of solder or the like, and a conductive bonding material 7 made of solder or the like is connected to the wiring conductor 5a of the external electric circuit board 5 to the lower connection pad 2b. The electrode 4a of the semiconductor element 4 is connected to the wiring conductor 5a of the external electric circuit board 5 through the wiring layer 2 by this, so that an electric signal is transferred to and from the semiconductor element 4 from the external electric circuit. ,semiconductor It is possible to operate the child 4.
[0021]
The wiring layer 2 is formed of a metal material having a low melting point such as copper, silver, and gold and having a low conduction resistance. An organic binder, a solvent, a plasticizer, and the like are added to and mixed with metal powder such as copper, silver, and gold. A metal paste is prepared, and this metal paste is filled into a through hole provided in a green sheet (raw sheet) to be the insulating base 1 by firing, and the through hole of the insulating base 1 is fired simultaneously with the firing of the green sheet. 3 is formed. In this case, since SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass the firing temperature is 800 to 1050 ° C. and lower, the metal powder of the metal paste during firing of the insulating base 1 Eat However, it can be formed in the through hole 3 of the insulating substrate 1 by simultaneous firing with the insulating substrate 1.
[0022]
Since the wiring layer 2 is made of a metal material having a low conduction resistance such as copper, silver, or gold, it is possible to effectively prevent the electric signal from being attenuated even if the electric signal propagates through the wiring layer 2. As a result, the semiconductor element 4 can be operated accurately.
[0023]
The insulating substrate 1 having the wiring layer 2 in the through hole 3 is made of ZnFe 2 O 4 , MnFe 2 O 4 , FeFe 2 O 4 , CoFe 2 O 4 , NiFe 2 O 4 , CuFe 2 O 4 . The magnetic material contains at least one kind of magnetic material, and when the magnetic material propagates harmonic noise that has entered the wiring layer 2 from an external electric circuit, it converts the noise into heat energy and absorbs it, and the noise is a semiconductor. This effectively prevents the device from entering the semiconductor device, so that the semiconductor device can always operate normally.
[0024]
The magnetic material is, for example, at least one of ZnFe 2 O 4 , MnFe 2 O 4 , FeFe 2 O 4 , CoFe 2 O 4 , NiFe 2 O 4 , and CuFe 2 O 4 on a green sheet that becomes the insulating base 1 by firing. It is contained in the insulating substrate 1 by adding a magnetic powder composed of seeds.
[0025]
The insulating substrate 1 containing the magnetic material, that is, the insulating substrate 1 made of SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass and a magnetic material is SiO 2 -Al 2 O 3. When the amount of —MgO—ZnO—B 2 O 3 crystalline glass is less than 10% by weight, in other words, the magnetic material exceeds 90% by weight, SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O Since the firing temperature of the 3 series crystalline glass becomes high, it becomes difficult to fire simultaneously with the wiring layer 2 made of a metal material such as copper, and SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O 3 When the amount of the crystalline glass exceeds 50% by weight, in other words, when the magnetic material becomes less than 50% by weight, noise enters the wiring layer 2 provided on the insulating substrate 1 from the wiring conductor 5a of the external electric circuit board 5. , Can not absorb the noise well Thereby to cause a malfunction in the semiconductor device 4. Accordingly, the insulating substrate 1 in which the magnetic material is contained in the SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O 3 crystalline glass is SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O. It is preferable to keep the amount of the 3 series crystalline glass in the range of 10 to 50% by weight and the amount of the magnetic material in the range of 50 to 90% by weight.
[0026]
When the magnetic material has a particle size of less than 0.5 μm, when the insulating substrate 1 is manufactured by firing, the reaction with the SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O 3 crystalline glass occurs. As a result, the residual rate of the magnetic material is reduced and noise cannot be effectively absorbed. When the thickness exceeds 10 μm, the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass It becomes difficult to fire at the same time as the wiring layer 2 made of a metal material such as copper due to the high firing temperature. Therefore, the magnetic material preferably has a particle size in the range of 0.5 μm to 10 μm.
[0027]
In the wiring board of the present invention, it is important to form the insulating base 1 by SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass.
[0028]
The SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass, for example, SiO 2: 40 to 46 wt%, Al 2 O 3: 25~30 wt%, MgO: 8 to 13 % By weight, ZnO: 6 to 9% by weight, B 2 O 3 : 8 to 11% by weight.
[0029]
The SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass, gahnite during firing (ZnO · Al 2 O 3) , cordierite (2MgO · 2Al 2 O 3) , spinel-type crystal phase Crystal phases such as (MgO · Al 2 O 3 , ZnO · Al 2 O 3 ) are generated, and the strength of the insulating substrate 1 is improved by the generation of these crystal phases.
[0030]
From The said SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass that the calcination temperature is 800 to 1050 ° C. and less, the wiring layer 2 of copper, silver, the melting point of gold or the like low In addition, even a material having a low conduction resistance can be formed by simultaneous firing with the insulating substrate 1, and when the electric signal propagates through the wiring layer 2, it is possible to effectively prevent the electric signal from being attenuated. 4 can be operated accurately.
[0031]
Further magnetism of the SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based magnetic material be allowed to contain a magnetic material at the time of firing because the firing temperature of the crystalline glass is 800 to 1050 ° C. and lower It is not lost, and this makes it possible to absorb the noise that has entered the wiring layer 2 satisfactorily.
[0032]
The SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass also a relative dielectric constant of about 5 (room temperature 1 MHz) and Hikukuku, therefore disposed in the through-hole 3 of the insulating base 1 Propagation delay is not caused even if an electric signal is propagated to the wiring layer 2, so that the electric signal can be propagated to the wiring layer 2 at a high speed.
[0033]
The SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass is SiO 2 -Al 2 O 3 -when the amount of SiO 2 is less than 40% by weight or more than 46% by weight. The firing temperature of the MgO—ZnO—B 2 O 3 crystalline glass becomes high, making it difficult to fire simultaneously with the wiring layer 2 made of a metal material such as copper. Therefore, the amount of SiO 2 is preferably in the range of 40 to 46% by weight.
[0034]
Moreover, if the amount of Al 2 O 3 is less than 25% by weight or more than 30% by weight, the firing temperature of the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass becomes high and copper It becomes difficult to fire simultaneously with the wiring layer 2 made of a metal material such as. Therefore, the amount of Al 2 O 3 is preferably in the range of 25 to 30% by weight.
[0035]
When the amount of MgO is less than 8% by weight, the cordierite (2MgO · 2) produced when the insulating substrate 1 made of SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass is produced by firing. 2Al 2 O 3) amount becomes less can not greatly improve the strength of the insulating substrate 1, also more than 13% by weight SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystals It becomes difficult to fire simultaneously with the wiring layer 2 made of a metal material such as copper due to the high firing temperature of the functional glass. Therefore, the amount of MgO is preferably in the range of 8 to 13% by weight.
[0036]
Also when manufacturing the insulating substrate 1 made of SiO 2 over Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass by baking the amount of ZnO is less than 6% by weight, produced gahnite (ZnO · Al When the amount of 2 O 3 ) decreases and the strength of the insulating substrate 1 cannot be greatly improved, and the content exceeds 9% by weight, the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystallinity It becomes difficult to fire at the same time as the wiring layer 2 made of a metal material such as copper due to the high firing temperature of the glass. Therefore, the amount of ZnO is preferably in the range of 6 to 9% by weight.
[0037]
Also when the amount of B 2 O 3 is to fabricate the insulating substrate 1 made of SiO 2 over Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass by firing less than 8 wt%, gahnite (ZnO · Al 2 O 3), cordierite (2MgO · 2Al 2 O 3) , the crystalline phase such as a spinel-type crystal phase (MgO · Al 2 O 3, ZnO · Al 2 O 3) is excessively formed, the insulating base 1 It becomes porous and unsuitable as a wiring board, and if it exceeds 11% by weight, the chemical resistance is greatly deteriorated and the reliability as a wiring board is greatly lowered. Therefore, the amount of B 2 O 3 is preferably in the range of 8 to 11% by weight.
[0038]
Further, the SiO 2 —Al 2 O 3 —MgO—ZnO—B 2 O 3 crystalline glass has an inorganic filler, specifically, powder of alumina, silica, silicon nitride, aluminum nitride, etc. added to the inside thereof. Addition of ˜40 parts by weight significantly improves the mechanical strength and effectively prevents breakage and the like due to the application of external force. Accordingly, it is the inorganic filler in the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass that improves the mechanical strength of the insulating substrate 1 and prevents damage due to the application of external force. It is preferable to form the insulating substrate 1 by adding 10 to 40 parts by weight of an external additive.
[0039]
When the particle size of the inorganic filler is further in the range of 0.5 to 5 μm, the mechanical strength of the insulating substrate 1 can be improved uniformly by uniformly dispersing and containing it in the glass ceramic sintered body. Therefore, the inorganic filler preferably has a particle size in the range of 0.5 to 5 μm.
[0040]
In addition, this invention is not limited to the above-mentioned Example, A various change is possible if it is a range which does not deviate from the summary of this invention.
[0041]
In the above-described embodiment, the insulating substrate 1 is formed by firing a formed body in which a plurality of green sheets are laminated. However, it may be formed by firing a single formed body formed by press molding or the like. At the same time, when the insulating substrate 1 is formed by firing a molded body in which a plurality of green sheets are laminated, a magnetic material is contained in the SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass. It is also possible to make a multilayer structure composed of an inorganic filler and an SiO 2 -Al 2 O 3 -MgO-ZnO-B 2 O 3 crystalline glass.
[0042]
【The invention's effect】
According to the wiring board of the present invention, ZnFe 2 O 4, MnFe 2 O 4, FeFe 2 O 4 with an insulating substrate with SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass , CoFe 2 O 4 , NiFe 2 O 4 , CuFe 2 O 4 containing a magnetic material, when noise propagates to the wiring layer provided on the insulating substrate, the noise is heated by the magnetic material. It is converted into energy and absorbed. As a result, noise does not enter the semiconductor element, and the semiconductor element can always operate normally.
[0043]
According to the wiring board of the present invention, the firing temperature of the SiO 2 chromatography Al 2 O 3 over MgO over ZnO over B 2 O 3 based crystalline glass forming the insulating base is 800 to 1050 ° C., from this low that Even if a magnetic material is contained in the crystalline glass and baked, the magnetic material does not lose its magnetism and can absorb noise well.
[0044]
At the same time, since the firing temperature of the glass ceramic sintered body is low, it becomes possible to form a wiring layer made of a material with low melting point such as copper, silver, gold, etc. and low conduction resistance by simultaneous firing. When the signal propagates, it is possible to effectively prevent the electric signal from being attenuated and to operate the semiconductor device accurately.
[0045]
Furthermore, when an inorganic filler is added to the insulating substrate in an amount of 10 to 40 parts by weight, the mechanical strength of the insulating substrate is increased, and it is possible to effectively prevent breakage due to the application of external force.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing an embodiment of a wiring board according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Insulation base | substrate 2 ... Wiring layer 2a ... Upper connection pad 2b ... Lower connection pad 3 ... Through-hole 4 ... Semiconductor element 4a ... Semiconductor element electrode 5 ... External electric circuit Substrate 5a ... Wiring conductor of external electric circuit board

Claims (3)

厚み方向に複数個の貫通孔を有する絶縁基体と、前記貫通孔内に充填され、一端が絶縁基体の上面に導出されて半導体素子の電極が接続される上部接続パッドを形成し、他端が絶縁基体の下面に導出されて外部電気回路基板の配線導体が接続される下部接続パッドを形成する複数個の配線層とから成る配線基板であって、前記絶縁基体はSiOーAlーMgOーZnOーB系結晶性ガラスから成り、かつZnFe 、MnFe 、FeFe 、CoFe 、NiFe 、CuFe の少なくとも1種から成る磁性材料が含有されていることを特徴とする配線基板。An insulating substrate having a plurality of through holes in the thickness direction, an upper connection pad that is filled in the through holes, one end is led to the upper surface of the insulating substrate, and an electrode of the semiconductor element is connected, and the other end is formed A wiring board comprising a plurality of wiring layers which are led out to the lower surface of the insulating base and form a lower connection pad to which a wiring conductor of an external electric circuit board is connected, wherein the insulating base is SiO 2 -Al 2 O 3 -MgO -ZnO-B 2 O 3 based crystalline glass and at least one of ZnFe 2 O 4 , MnFe 2 O 4 , FeFe 2 O 4 , CoFe 2 O 4 , NiFe 2 O 4 , CuFe 2 O 4 A wiring board comprising a magnetic material comprising: 前記磁性材料の含有量が50〜90重量%であることを特徴とする請求項1に記載の配線基板。  2. The wiring board according to claim 1, wherein the content of the magnetic material is 50 to 90% by weight. 前記絶縁基体に、外添加で10〜40重量部の無機物フィラーを含有させたことを特徴とする請求項1又は2に記載の配線基板。  The wiring board according to claim 1 or 2, wherein the insulating base contains 10 to 40 parts by weight of an inorganic filler by external addition.
JP33730297A 1997-12-08 1997-12-08 Wiring board Expired - Fee Related JP3716088B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33730297A JP3716088B2 (en) 1997-12-08 1997-12-08 Wiring board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33730297A JP3716088B2 (en) 1997-12-08 1997-12-08 Wiring board

Publications (2)

Publication Number Publication Date
JPH11176998A JPH11176998A (en) 1999-07-02
JP3716088B2 true JP3716088B2 (en) 2005-11-16

Family

ID=18307353

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33730297A Expired - Fee Related JP3716088B2 (en) 1997-12-08 1997-12-08 Wiring board

Country Status (1)

Country Link
JP (1) JP3716088B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0720049A2 (en) 1990-05-09 1996-07-03 Fuji Photo Film Co., Ltd. Photographic processing composition and processing method using the same
EP1914594A2 (en) 2004-01-30 2008-04-23 FUJIFILM Corporation Silver halide color photographic light-sensitive material and color image-forming method

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG10201403905YA (en) 2003-04-15 2014-10-30 Sensors For Med & Science Inc System and method for attenuating the effect of ambient light on an optical sensor
KR20060111449A (en) * 2003-09-24 2006-10-27 이비덴 가부시키가이샤 Interposer and multilayer printed wiring board
JP4489491B2 (en) * 2004-04-28 2010-06-23 イビデン株式会社 Interposer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0720049A2 (en) 1990-05-09 1996-07-03 Fuji Photo Film Co., Ltd. Photographic processing composition and processing method using the same
EP1914594A2 (en) 2004-01-30 2008-04-23 FUJIFILM Corporation Silver halide color photographic light-sensitive material and color image-forming method

Also Published As

Publication number Publication date
JPH11176998A (en) 1999-07-02

Similar Documents

Publication Publication Date Title
JP3426926B2 (en) Wiring board and its mounting structure
JP2002198660A (en) Circuit board and method of manufacturing the same
KR100922079B1 (en) Multilayer ceramic substrate
JP3716088B2 (en) Wiring board
JP2007273914A (en) Wiring board and method of manufacturing same
JPH04212441A (en) Ceramic wiring board
JP2002043758A (en) Multilayer board and manufacturing method
JP3860425B2 (en) Circuit board, manufacturing method thereof, and electronic circuit device for automobile
JP3582975B2 (en) Wiring board
JP3314130B2 (en) Low temperature firing porcelain composition
JP4077625B2 (en) Low temperature fired porcelain composition and method for producing low temperature fired porcelain
JP4587617B2 (en) Ceramic wiring board
JP2001015878A (en) High-frequency wiring board and its manufacture
JPH11135899A (en) Ceramic circuit board
JPH11186727A (en) Wiring board and manufacture thereof
JP3441924B2 (en) Wiring board and its mounting structure
JP3526526B2 (en) Package for storing semiconductor elements
JP4646362B2 (en) Conductor composition and wiring board using the same
JP2004235347A (en) Insulating ceramics and multilayer ceramic substrate using the same
JP2605306B2 (en) Multilayer circuit board
JP3323074B2 (en) Wiring board, package for housing semiconductor element and its mounting structure
JP3314131B2 (en) Wiring board
JPH0555718A (en) Circuit board
JPH11130533A (en) Circuit board and its mounting structure
JP2738601B2 (en) Manufacturing method of ceramic wiring board

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050526

A131 Notification of reasons for refusal

Effective date: 20050531

Free format text: JAPANESE INTERMEDIATE CODE: A131

A521 Written amendment

Effective date: 20050801

Free format text: JAPANESE INTERMEDIATE CODE: A523

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20050823

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20050829

R150 Certificate of patent (=grant) or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees