JP3491747B2 - カーボンナノコイルの製造方法及び触媒 - Google Patents
カーボンナノコイルの製造方法及び触媒Info
- Publication number
- JP3491747B2 JP3491747B2 JP37736399A JP37736399A JP3491747B2 JP 3491747 B2 JP3491747 B2 JP 3491747B2 JP 37736399 A JP37736399 A JP 37736399A JP 37736399 A JP37736399 A JP 37736399A JP 3491747 B2 JP3491747 B2 JP 3491747B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon
- catalyst
- iron
- carbon nanocoil
- nanocoil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 112
- 229910052799 carbon Inorganic materials 0.000 title claims description 96
- 239000003054 catalyst Substances 0.000 title claims description 66
- 238000004519 manufacturing process Methods 0.000 title claims description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 83
- 229910052742 iron Inorganic materials 0.000 claims description 41
- 239000010409 thin film Substances 0.000 claims description 39
- 239000000758 substrate Substances 0.000 claims description 35
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 17
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 17
- 239000002041 carbon nanotube Substances 0.000 claims description 15
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 239000011521 glass Substances 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 10
- 229910001887 tin oxide Inorganic materials 0.000 claims description 10
- 229910052718 tin Inorganic materials 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 8
- 229910003437 indium oxide Inorganic materials 0.000 claims description 8
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 8
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 7
- GFBZUOBHZYBBBR-UHFFFAOYSA-N [Fe].[In].[Sn] Chemical compound [Fe].[In].[Sn] GFBZUOBHZYBBBR-UHFFFAOYSA-N 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 16
- 239000010408 film Substances 0.000 description 12
- 229920000049 Carbon (fiber) Polymers 0.000 description 9
- 125000004429 atom Chemical group 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000004917 carbon fiber Substances 0.000 description 9
- 239000011295 pitch Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000010453 quartz Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- 239000001307 helium Substances 0.000 description 6
- 229910052734 helium Inorganic materials 0.000 description 6
- 229910006404 SnO 2 Inorganic materials 0.000 description 5
- 150000001721 carbon Chemical class 0.000 description 5
- 238000000635 electron micrograph Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000003917 TEM image Methods 0.000 description 4
- 230000004323 axial length Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000003421 catalytic decomposition reaction Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 150000002371 helium Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- -1 methane and ethane Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1273—Alkenes, alkynes
- D01F9/1275—Acetylene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- General Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Textile Engineering (AREA)
- Thermal Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Inorganic Fibers (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37736399A JP3491747B2 (ja) | 1999-12-31 | 1999-12-31 | カーボンナノコイルの製造方法及び触媒 |
| US09/901,991 US6558645B2 (en) | 1999-12-31 | 2001-07-10 | Method for manufacturing carbon nanocoils |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37736399A JP3491747B2 (ja) | 1999-12-31 | 1999-12-31 | カーボンナノコイルの製造方法及び触媒 |
| US09/901,991 US6558645B2 (en) | 1999-12-31 | 2001-07-10 | Method for manufacturing carbon nanocoils |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001192204A JP2001192204A (ja) | 2001-07-17 |
| JP3491747B2 true JP3491747B2 (ja) | 2004-01-26 |
| JP2001192204A5 JP2001192204A5 (enExample) | 2004-08-05 |
Family
ID=26582844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP37736399A Expired - Fee Related JP3491747B2 (ja) | 1999-12-31 | 1999-12-31 | カーボンナノコイルの製造方法及び触媒 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US6558645B2 (enExample) |
| JP (1) | JP3491747B2 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4064514B2 (ja) * | 1998-02-19 | 2008-03-19 | 栖二 元島 | コイル状炭素繊維の気相製造方法及びその製造装置 |
| JP3734400B2 (ja) * | 2000-02-25 | 2006-01-11 | 双葉電子工業株式会社 | 電子放出素子 |
| JP3585033B2 (ja) * | 2000-04-29 | 2004-11-04 | 喜萬 中山 | カーボンナノコイル生成用のインジウム・スズ・鉄系触媒の製造方法 |
| JP3822806B2 (ja) * | 2001-07-11 | 2006-09-20 | 喜萬 中山 | カーボンナノコイルの量産方法 |
| JP3847589B2 (ja) * | 2001-08-29 | 2006-11-22 | 独立行政法人科学技術振興機構 | ビーズ付きカーボンナノチューブの製造方法 |
| JP2003165100A (ja) * | 2001-11-30 | 2003-06-10 | Sony Corp | らせん構造体およびその製造方法ならびに機能材料およびその製造方法ならびに磁気感応素子およびその製造方法ならびに一次元伝導体およびその製造方法ならびに電子装置およびその製造方法 |
| JP4020410B2 (ja) * | 2001-12-28 | 2007-12-12 | 大研化学工業株式会社 | 炭素物質製造用触媒 |
| JP4404961B2 (ja) * | 2002-01-08 | 2010-01-27 | 双葉電子工業株式会社 | カーボンナノ繊維の製造方法。 |
| US6718834B1 (en) * | 2002-11-29 | 2004-04-13 | Indian Institute Of Science | Carbon nanotube flow sensor device and method |
| WO2005118473A1 (ja) * | 2004-06-04 | 2005-12-15 | Japan Science And Technology Agency | 原料吹き付け式高効率カーボンナノ構造物製造方法及び装置 |
| JP3962773B2 (ja) * | 2002-12-05 | 2007-08-22 | 独立行政法人科学技術振興機構 | 原料吹き付け式カーボンナノ構造物の製造方法及び装置 |
| US20040265212A1 (en) * | 2002-12-06 | 2004-12-30 | Vijay Varadan | Synthesis of coiled carbon nanotubes by microwave chemical vapor deposition |
| KR100875861B1 (ko) * | 2003-05-29 | 2008-12-24 | 도쿠리쓰교세이호징 가가쿠 기주쓰 신코 기코 | 카본 나노 코일 제조용 촉매, 그 제조방법 및 카본 나노 코일 제조방법 |
| JP2004107863A (ja) * | 2003-07-14 | 2004-04-08 | Nippon Magnetic Dressing Co Ltd | カーボンナノファイバー |
| JP4301362B2 (ja) * | 2003-08-12 | 2009-07-22 | 株式会社日本製鋼所 | 低級炭化水素直接分解反応用触媒および低級炭化水素直接分解反応器ならびに低級炭化水素直接分解反応装置 |
| JP2005255506A (ja) * | 2004-03-15 | 2005-09-22 | Seiji Motojima | 活性酸素種の製造方法、被浄化物の浄化方法及び癌治療剤 |
| EP1790613A4 (en) * | 2004-07-16 | 2009-05-27 | Japan Science & Tech Agency | METHOD OF CARBON NANOSTRUCTURE MANUFACTURING, CYLINDER CONTROL OF CATALYST PARTICLE DIAMETERS, MANUFACTURING DEVICE THEREFOR AND CARBON NANOSTRUCTURE |
| KR100862416B1 (ko) | 2004-09-24 | 2008-10-08 | 재팬 사이언스 앤드 테크놀로지 에이젼시 | 카본나노구조물의 제조방법 및 제조장치 |
| US7754183B2 (en) * | 2005-05-20 | 2010-07-13 | Clemson University Research Foundation | Process for preparing carbon nanostructures with tailored properties and products utilizing same |
| TWI306834B (en) * | 2005-05-27 | 2009-03-01 | Ind Tech Res Inst | A method for manufacturing carbonaceous nanofiber |
| DE102005032072A1 (de) * | 2005-07-08 | 2007-01-11 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung e.V. | Kohlenstoff-Nanopartikel, deren Herstellung und deren Verwendung |
| KR100682952B1 (ko) * | 2005-08-31 | 2007-02-15 | 삼성전자주식회사 | 나노탄성 메모리 소자 및 그 제조 방법 |
| US9771264B2 (en) * | 2005-10-25 | 2017-09-26 | Massachusetts Institute Of Technology | Controlled-orientation films and nanocomposites including nanotubes or other nanostructures |
| US20080259976A1 (en) * | 2005-11-30 | 2008-10-23 | The Governors Of The University Of Alberta | Organic Columnar Thin Films |
| JP5072244B2 (ja) * | 2006-03-20 | 2012-11-14 | 公立大学法人大阪府立大学 | カーボンナノコイル製造用触媒粒子およびその製造方法ならびにカーボンナノコイルの製造方法 |
| WO2007136755A2 (en) * | 2006-05-19 | 2007-11-29 | Massachusetts Institute Of Technology | Continuous process for the production of nanostructures including nanotubes |
| US8337979B2 (en) | 2006-05-19 | 2012-12-25 | Massachusetts Institute Of Technology | Nanostructure-reinforced composite articles and methods |
| US20080188825A1 (en) * | 2007-02-01 | 2008-08-07 | Liliana Atanasoska | Catheters and medical balloons |
| TWI378897B (en) * | 2007-12-27 | 2012-12-11 | Univ Nat Taiwan | Method for producing carbon nanocoils |
| DE102008064579B4 (de) | 2008-12-22 | 2012-03-15 | Siemens Aktiengesellschaft | Verfahren und Trägerzylinder zur Herstellung einer elektrischen Wicklung |
| JP5560060B2 (ja) * | 2010-02-16 | 2014-07-23 | 国立大学法人大阪大学 | カーボンナノコイル製造用触媒、その製造方法及びカーボンナノコイル |
| CN102372255B (zh) | 2010-08-23 | 2013-11-20 | 清华大学 | 碳纳米管复合线状结构的制备装置及其制备方法 |
| JP5710185B2 (ja) * | 2010-09-10 | 2015-04-30 | 株式会社Cmc総合研究所 | 微小コイルの製造方法及び製造装置 |
| JP5269037B2 (ja) * | 2010-11-08 | 2013-08-21 | 公立大学法人大阪府立大学 | カーボンナノ構造物製造方法及び装置 |
| CN102024636B (zh) * | 2010-11-29 | 2012-10-10 | 清华大学 | 电子发射体及电子发射元件 |
| CN102013376B (zh) | 2010-11-29 | 2013-02-13 | 清华大学 | 场发射单元及场发射像素管 |
| CN102074442B (zh) * | 2010-12-21 | 2012-11-21 | 清华大学 | 场发射电子器件 |
| EP2718228A1 (en) * | 2011-06-13 | 2014-04-16 | University of Dayton | Receptor-catalyst growth process for carbon nanotubes |
| CN103013441B (zh) * | 2013-01-10 | 2014-03-19 | 贵州大学 | 原位催化生长低螺旋碳纳米复合物微波吸收材料的方法 |
| KR101820099B1 (ko) | 2013-01-18 | 2018-01-18 | 에스프린팅솔루션 주식회사 | 저항 발열체, 이를 채용한 가열 부재, 및 정착 장치 |
| US10195797B2 (en) | 2013-02-28 | 2019-02-05 | N12 Technologies, Inc. | Cartridge-based dispensing of nanostructure films |
| JP6365547B2 (ja) | 2013-09-30 | 2018-08-01 | 日本ゼオン株式会社 | 炭素ナノ構造体の製造方法及びカーボンナノチューブ |
| WO2017210238A1 (en) | 2016-05-31 | 2017-12-07 | Massachusetts Institute Of Technology | Composite articles comprising non-linear elongated nanostructures and associated methods |
| EP4516846A3 (en) | 2017-09-15 | 2025-12-24 | Massachusetts Institute of Technology | Low-defect fabrication of composite materials |
| US11031657B2 (en) | 2017-11-28 | 2021-06-08 | Massachusetts Institute Of Technology | Separators comprising elongated nanostructures and associated devices and methods, including devices and methods for energy storage and/or use |
| CN109201068B (zh) * | 2018-10-12 | 2021-04-16 | 大连理工大学 | 一种减少副产物碳层的碳纳米线圈合成用催化剂的制备方法及其应用 |
| JP6853230B2 (ja) * | 2018-11-12 | 2021-03-31 | 中外炉工業株式会社 | アセチレンガス濃度推定装置、アセチレンガス適量推定装置および該装置を備える真空浸炭装置 |
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| US5413866A (en) * | 1990-10-23 | 1995-05-09 | Baker; R. Terry K. | High performance carbon filament structures |
| JPH0669494A (ja) * | 1992-08-20 | 1994-03-11 | Hitachi Ltd | カーボン分子とその集合体の製造方法 |
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| Jpn.J.Appl.Phys.Part.2;Letters,1999年 7月15日,vol.38,7B,L836−L838 |
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| JP2001192204A (ja) | 2001-07-17 |
| US20030012721A1 (en) | 2003-01-16 |
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