JP3465103B2 - Cosmetic material having unevenness synchronized with pattern and its manufacturing method - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is applied to the surface of sundries, the surface of furniture, the outermost surface of building materials used indoors or outdoors, and is used for the purpose of surface decoration and protection of lower layers. It belongs to the technical field of artificial cosmetic materials.

[0002]

2. Description of the Related Art Conventionally, in the field of artificial cosmetic materials, the texture of a cosmetic material made of natural materials produced by a traditional manufacturing method is performed by giving unevenness to the surface or adjusting the gloss. Efforts are being made to bring them closer. For example, regarding marble, attempts have been made to express the transparent and deep appearance of marble. With respect to wooden boards, efforts are being made to express various luster and irregularities on the surface based on the internal structure of the tree. Further, in the case of a ceramic tile, efforts have been made to express the swelling of the hand-painted pattern, the matte state of the joint portion of the tile, and the depression.

Among them, many attempts have been made to express the depression of the conduit portion of the grain of wood, and various types have been conventionally available. For example,
Japanese Unexamined Patent Publication (Kokai) No. 48-20912 discloses a technique for expressing a feeling of unevenness by printing a non-glossy conduit and applying glossy printing to a portion other than the conduit. Further, in JP-A-49-16752, printing is performed by using three or more kinds of inks in which the content of a granular solid content is sequentially increased,
In particular, a technique is disclosed in which the conduit portion is printed with an ink or paint having the highest content of granular solids, and then a surface protective layer is provided on the entire surface. Furthermore, JP-A-2-108539
Japanese Patent Laid-Open Publication No. 2005-242242 describes a technique of matting the upper part of the pattern of the conduit part and the upper part of the other pattern and expressing the unevenness feeling by using a glossy ink.

When printing an ordinary wood grain pattern, a gravure printing method is often used, and a plate by a three-color separation method is also used, but rather, special printing using a special plate, that is, uniform printing A total of three plate cylinder rollers are used, namely, a plate cylinder roller for so-called solid printing, a plate cylinder roller for expressing the tone of the entire grain, and a plate cylinder roller for expressing the conduit portion. Relatively often do special printing. Since special fabrics that are easily stretchable are often used, such special printing is used, and even if the register in the flow direction of the fabric, that is, the length direction, is slightly misaligned, no significant defect is felt. So a special edition is used. In this special printing, it is usual to use a specially prepared special color ink instead of the usual yellow, magenta, cyan, and black process colors.

By the way, in order to express the depressed feeling of the conduit portion by using an ink different from that for forming the conduit portion, another plate cylinder roller may be added in addition to the above-mentioned three plate cylinder rollers. It is necessary to add another plate cylinder roller in order to express the swelling of the pattern other than the conduit portion. When one or two plate cylinder rollers other than the normal three plate cylinder rollers are used,
In order to match the registration of the patterns, you can not use a 3-color machine that can install up to 3 plate cylinders, a 4-color machine or a 5-color machine,
Or, it becomes necessary to use more multicolor machines, and the usable printing machines are limited. A printing machine can be used to form the surface protective layer, but a coater such as a roll coater is more suitable, so if possible, use a coater different from the printing machine. Is good. Note that if uniform coating is applied to the entire surface after printing, the registration between the printed pattern and the coating layer is unnecessary. It may be supplied and coated without considering the registration, but when coating after printing and printing again, it is necessary to register the printed patterns, and once printing and coating are completed The wound roll is fed again from the paper feed stand of the printing machine to print, but it is extremely difficult to register the pattern already printed and the pattern to be printed later. It is the reality.

[0006] Based on the above general knowledge, looking at the above-mentioned known techniques, there are drawbacks. In the first one, in addition to the usual printing of woodgrain patterns, two plate cylinder rollers are used for printing, and a positive plate with a pattern corresponding to the conduit at the time of printing, and this is a negative. It is necessary to precisely register the pattern with the related pattern and print it, and strict registration is required so that there is no gap between the two printed patterns. If there is a gap between the two patterns, the physical and chemical properties of the surface will not be sufficiently secured at that portion. The second type has a surface protective layer, so even if the physical and chemical properties of the surface are secured to a certain extent, the content of the granular solids, including the parts other than the conduit part, will be increased sequentially. It is necessary to use three or more kinds of inks that have been increased, which causes a restriction on the expression of texture, and the addition of granular solids promotes the penetration of the paint applied to the conduit section, and There is a lot of wasted paint that should be improved in performance, and there is considerable penetration of the paint even in areas other than the conduit, due to differences in the amount of granular solids retained. Further, although the third one is designed so that the registration accuracy is relaxed, it is necessary to form a pattern different from the wood grain pattern in order to form the unevenness like the first one. Therefore, in addition to the plate cylinder roller for expressing a normal pattern, it is necessary to prepare two other plate cylinder rollers.

[0007]

SUMMARY OF THE INVENTION The problem to be solved by the present invention is to solve the above-mentioned drawbacks of the prior art in producing a decorative material having a feeling of unevenness in synchronization with a pattern, namely, An object of the present invention is to provide a method for producing a cosmetic material in which the increase in the number is minimized, the registration problem is less likely to occur, and the surface protective layer is uniform and has a sufficient protective function. A second problem to be solved by the present invention is to provide a method for producing a decorative material having a surface having physical and chemical properties improved while having a textured pattern. A third problem to be solved by the present invention is to provide a method for producing a decorative material having improved abrasion resistance of a surface protective layer.

[0008]

In order to achieve the above object, in the method for producing a decorative material of the present invention, a pattern having a lower air permeability than other portions is formed on the substrate, and then the entire surface is covered. The purpose is to form a protective layer.

[0009]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 shows an embodiment of a decorative material obtained by the manufacturing method of the present invention, in which a wood grain pattern 3 including a conduit pattern 2 on a base 1 and parts other than the conduit pattern 2 are covered. The pattern 4 having high air permeability is formed, and the conduit pattern 2 and the pattern 4 are formed.
The surface protection layer 5 is provided on the entire surface covering the. The wood grain pattern 3 is accompanied by a solid pattern as shown.

In this example, the grain pattern is taken up, and the portion corresponding to the grain pattern of the grain is made matt as compared with the surroundings, and the duct pattern is intended to give a concave appearance. First, a wood pattern 3 including a conduit pattern 2 corresponding to a wood conduit, and a pattern 4 having a high air permeability for covering the parts other than the conduit pattern 2 are provided on the substrate 1. The conduit pattern 2 and other wood grain patterns are formed by using a normal ink, and the pattern 4 is formed so that the air permeability thereof is lower than that of other portions, as described later. The wood grain pattern is an example in which the effect of the present invention is easily exhibited, but the present invention, as described in the section of the prior art, can be applied to any pattern as long as it expresses an unevenness feeling due to gloss difference. Is also applicable.

As the substrate 1, any material generally used for decorative materials can be used. Broadly speaking, various kinds of papers, plastic films or sheets, metal foils, metal sheets can be used. , Or metal plates, wood-based plates such as wood, and various ceramic-based materials. The materials included in each of these groups may be used alone, but a laminate made of any combination of these materials such as a composite of papers and a composite of paper and a plastic film can also be used. These substrates may be painted for the purpose of adjusting the colors, or may have a usual pattern formed in advance from the viewpoint of design. The surface may be smoothed prior to painting or normal pattern formation, or a base treatment may be performed to increase the adhesion of the pattern. After the painting or the usual pattern formation, an adhesion improving treatment for facilitating the subsequent processing may be performed.

The following are typical examples of various papers. That is, thin paper, kraft paper,
Titanium paper and resin-impregnated paper which has been impregnated with resin for the purpose of strengthening the space between papers can be used. In addition to these, a group of raw materials often used in the field of building materials, such as linter paper, paperboard, gypsum board raw paper, or vinyl wallpaper raw paper provided with a vinyl chloride resin layer on the surface of paper, can be mentioned. Furthermore, the following papers used in the business field, ordinary printing, packaging, etc. can also be used. That is, it is coated paper, art paper, sulfuric acid paper, glassine paper, parchment paper, paraffin paper, or Japanese paper. Further, although different from these papers, woven or non-woven fabrics of the following various fibers having the appearance and properties similar to paper are also used as the substrate 1.
Available as The various fibers are, for example, glass fibers, asbestos fibers, potassium titanate fibers, alumina fibers, silica fibers, inorganic fibers such as carbon fibers, or polyester fibers, or synthetic fibers such as vinylon fibers.

Examples of the plastic film or plastic sheet include those made of various synthetic resins as exemplified below. Various synthetic resins include polyethylene resin, polypropylene resin, polymethylene resin, polymethylpentene resin, polyvinyl chloride resin, polyvinylidene chloride resin, polyvinyl alcohol resin, vinyl chloride-vinyl acetate copolymer resin, ethylene-vinyl acetate copolymer. Resin, ethylene-vinyl alcohol copolymer resin, polyethylene terephthalate resin, polybutylene terephthalate resin, polyethylene naphthalate-isophthalate copolymer resin, polymethyl methacrylate resin, polyethyl methacrylate resin, polybutyl acrylate resin, nylon 6 or Polyamide resin such as nylon 66,
Examples thereof include cellulose triacetate resin, cellophane, polystyrene resin, polycarbonate resin, polyarylate resin, and polyimide resin.

The metal foil, the metal sheet, or the metal plate is made of a metal as exemplified below. That is, it is aluminum, iron, stainless steel, copper or the like. Often plated and used. As various wooden boards, wood boards, plywood, particle boards,
Alternatively, a medium-density fiberboard called MDF may be used. Examples of the ceramic material include ceramic building materials such as gypsum board, calcium silicate board, and wood chip cement board, ceramics, glass, enamel, and fired tile. In addition to these, a composite body of various materials such as a fiber reinforced plastic plate, a paper honeycomb with iron plates attached to both sides, and a sandwich of polyethylene resin with two aluminum plates can also be used as the substrate 1.

In order to form the pattern 3 having a lower air permeability on the substrate 1, it is thickly printed with a synthetic resin composition having a high film-forming ability and dried or set to synthesize. Form a pattern consisting of a uniform and thick resin film with few air gaps and holes. When printing with a general gravure printing method, the shape of the cells of the gravure plate is reproduced, so ink does not transfer to the part other than the plate cells, so-called bank part, and a gap part is created, and in this gap part Air penetrates. Conversely, in order to suppress air permeation, it is necessary to perform printing that does not reproduce the cell shape of the plate.

For that purpose, an ink having a small content of an inorganic filler having a function of lowering air permeability and having a large resin solid content is selected or used, or when it is transferred onto the substrate 1 at the time of printing. Select an ink that is easy to spread laterally, or increase the plate depth to increase the amount of ink transfer so that the ink covers even the area corresponding to the bank by leveling. When the air permeability is measured by a Gurley densometer based on JIS-P8117, it is a value of 200 seconds to less than 1000 seconds in a paper stock for general building materials, and it does not have the purpose of adjusting the permeability of the top coating, The value of 1000 seconds to 2000 seconds is shown for the printed matter. As a preferable ink for forming a pattern with low air permeability, a resin binder is polyvinyl chloride resin, plastisol or urethane resin of acrylic resin,
The proportion of the resin binder in the solid content of the ink is 50% by weight to 100% by weight, preferably 60% by weight to 90% by weight, and the content of the inorganic filler is similar to the content in the ink forming other patterns. Compared with the other, it is 0.1% to 30% by weight, preferably 1% by weight to the solid content of the ink.
10% by weight, viscosity is 10 cps to 5000 cp
s, preferably 100 cps to 1000 cps. Among them, the ink using the plastisol of polyvinyl chloride resin can increase the solid content, and when the surface protective layer is formed using the synthetic resin composition or the ionizing radiation curable composition, the composition thereof is It is suitable because it does not penetrate much.

By the way, as an ink which is preferably used as an ink for printing a woodgrain pattern including a conduit pattern, a binder is nitrocellulose, a blended type of acrylic resin and nitrocellulose, a urethane type, an acrylic resin type, a polyvinyl chloride resin type or the like. The resin binder accounts for 50% to 95% by weight, preferably 60% to 90% by weight, and the inorganic filler accounts for 0.1% by weight of the ink solids. ˜50% by weight, preferably 1% to 30% by weight, viscosity 10 c
ps to 1000 cps, preferably 50 cps to 300
cps.

When a pattern having low air permeability is formed by using the gravure printing method, the depth of the plate is 20 μm to 10 μm.
0 μm, preferably 40 μm to 60 μm, and the number of lines is 100 lines / inch to 20 lines / inch, preferably 54 lines / inch to 40 lines / inch.

By the way, when printing a woodgrain pattern including a conduit pattern, the plate has a depth of 20 μm to 100 μm.
m, preferably 40 μm to 60 μm, and the number of lines of the plate is 100 lines / inch to 20 lines / inch, preferably 54 lines / inch to 40 lines / inch. In the range of the preferable plate depth and the range of the number of lines, since the amount of transfer of the ink is large as compared with the printing of a normal book, as described later, when the synthetic resin composition or the ionizing radiation curable composition is applied,
The synthetic tree composition penetrates into the wood grain pattern portion including the conduit pattern, which also has the effect of reducing the apparent film thickness.

In order to make the conduit pattern appear to be hollow, the conduit part is made matt as compared to other parts, and another is that the parts other than the conduit are projected so that they can be distinguished with the naked eye. It is even better to provide a thick resin film on the part. As the resin used for this purpose, among the above,
It is preferable that it is difficult to be crushed even when pressure is applied and that it has excellent workability such as adhesiveness. From these viewpoints, it is recommended to use an ink containing a polyvinyl chloride resin plastisol and having a high resin solid content. Further, by using a cross-linking agent such as trimethylolpropane triacrylate together, cross-linking occurs in the formed film and the performance of the film is improved.

After a pattern 3 including a conduit pattern 2 corresponding to a wood grain conduit and a pattern 4 having a low air permeability for covering a portion of the pattern 3 other than the conduit pattern 2 are provided on the substrate 1, the pattern 3 and The surface protective layer 5 is provided by applying the synthetic resin composition on the entire surface including the pattern 4. As described above, when the pattern 3 part and the pattern 4 part are compared, the air permeability of the pattern 4 part is lower, or the part of the pattern 4 is denser. The object does not penetrate, or does not substantially penetrate into, the pattern 4 part, and as a result, a smooth surface film is formed on the pattern 4 part by drying or setting. On the other hand, in the conduit pattern 2 portion, as described above, it is used when forming the surface protective layer because the cell shape of the plate at the time of printing is reproduced, and / or because it contains a large amount of filler. The synthetic resin composition to penetrate into the lower layer, as a result, the surface state is not smooth,
Compared with the film on the pattern 4 having a low air permeability, the film has a more matte state and gives a concave appearance corresponding to the conduit pattern 2.

In order to form the surface protective layer 5, the synthetic resin composition is used as described above, and the known coating method,
For example, roll coating is performed. As the synthetic resin composition, of the plastics constituting the film or sheet mentioned as the material of the substrate 1, those which become an ink composition by being dissolved or dispersed in water or an organic solvent can be used in principle. Even if the resin does not dissolve or disperse, for example, if it is a polyethylene resin, the surface protective layer 5 can be formed by heating and melting, extruding from a T die, and adhering at the same time as film formation. Even when applied by heating and melting, the surface condition of the lower layer affects the surface condition of the surface protective layer 5, and a smooth surface is formed in the upper part of the pattern 4 having low air permeability, and in other parts. , Lower conduit pattern 2
A film with an uneven surface that conforms to the surface shape of
It is possible to give a concave appearance according to the conduit pattern 2. In addition, when providing a surface protection layer using a T-die, if possible, if the pressure is reduced and sucked from the substrate side, the effect is promoted.

When forming the surface protective layer, a thermosetting resin composition using a thermosetting resin or an ionizing radiation curable resin composition is used in place of the usual synthetic resin composition, and the composition is heated after coating. Alternatively, the physical and chemical performance of the outermost surface can be further improved by irradiating with ionizing radiation to crosslink and cure. This type of decorative material has recently been expanding into the field where melamine decorative boards have been conventionally used, and therefore, durability of the surface of melamine decorative boards, especially abrasion resistance, is often demanded. A method of using an ionizing radiation-curable resin composition and irradiating it with ionizing radiation after application to crosslink and cure has been highlighted. The ionizing radiation curable resin composition is a mixture of a prepolymer, an oligomer and / or a monomer having a polymerizable unsaturated bond or an epoxy group in the molecule. The ionizing radiation refers to an electromagnetic wave or a charged particle beam having an energy quantum capable of polymerizing or cross-linking a molecule, and usually an ultraviolet ray or an electron beam is used.

Examples of prepolymers and oligomers in the ionizing radiation-curable resin composition include unsaturated polyesters such as condensation products of unsaturated dicarboxylic acids and polyhydric alcohols, polyester methacrylates, polyether methacrylates, polyol methacrylates, melamines. Methacrylates such as methacrylate, polyester acrylate,
Examples thereof include acrylates such as epoxy acrylate, urethane acrylate, polyether acrylate, polyol acrylate, and melamine acrylate, and cationic polymerization type epoxy compounds.

Examples of the monomer in the ionizing radiation curable resin composition include styrene, styrene-based monomers such as α-methylstyrene, methyl acrylate and acrylic acid-2-
Acrylic esters such as ethylhexyl, methoxyethyl acrylate, butoxyethyl acrylate, butyl acrylate, methoxybutyl acrylate, phenyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, methoxyethyl methacrylate, methacrylic acid Methacrylic acid esters such as ethoxymethyl, phenyl methacrylate, lauryl methacrylate, 2- (N, N-diethylamino) ethyl acrylate, 2- (N, N-dimethylamino) ethyl acrylate, acrylic acid-2 -(N, N-dibenzylamino) methyl, unsaturated substituted amino alcohol esters such as 2- (N, N-diethylamino) propyl acrylate, unsaturated carboxylic acid amides such as acrylamide and methacrylamide, ethylene Green Diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, 1,6-hexanediol diacrylate, triethylene glycol diacrylate, and other compounds, dipropylene glycol diacrylate, ethylene glycol diacrylate, propylene glycol dimethacrylate, diethylene glycol Polyfunctional compounds such as dimethacrylate and / or polythiol compounds having two or more thiol groups in the molecule, such as trimethylolpropane trithioglycolate, trimethylolpropane trithiopropylate, pentaerythritol tetrathioglycolate, etc. Is mentioned.

Usually, as the monomer in the ionizing radiation-curable resin composition, one kind or a mixture of two or more kinds of the above-mentioned compounds is used, if necessary. In order to provide suitability, it is preferable that the prepolymer or oligomer is 5% by weight or more and the monomer and / or polythiol compound is 95% by weight or less.

When flexibility is required when the ionizing radiation curable resin composition is applied and cured, the amount of the monomer may be reduced or an acrylate monomer having 1 or 2 functional groups may be used. . When abrasion resistance, heat resistance, and solvent resistance when an ionizing radiation curable resin composition is applied and cured are required, use an acrylate monomer having three or more functional groups, such as ionizing radiation. It is possible to design a curable resin composition. Where the functional group is 1
Examples thereof include 2-hydroxy acrylate, 2-hexyl acrylate, and phenoxyethyl acrylate. Examples of those having 2 functional groups include ethylene glycol diacrylate and 1,6-hexanediol diacrylate. Examples of functional groups having 3 or more groups include trimethylolpropane triacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, and dipentaerythritol hexaacrylate.

In order to adjust physical properties such as flexibility and surface hardness when an ionizing radiation curable resin composition is applied and cured, a resin which is not cured by irradiation with ionizing radiation is added to the ionizing radiation curable resin composition. It can also be added. The following are specific examples of the resin. It is a thermoplastic resin such as polyurethane resin, cellulose resin, polyvinyl butyral resin, polyester resin, acrylic resin, polyvinyl chloride resin, or polyvinyl acetate. Above all, the addition of polyurethane resin, cellulose resin, polyvinyl butyral resin and the like is preferable from the viewpoint of improving flexibility.

When the curing of the ionizing radiation-curable resin composition after application is carried out by ultraviolet irradiation, a photopolymerization initiator or a photopolymerization accelerator is added. As the photopolymerization initiator, in the case of a resin system having a radically polymerizable unsaturated group, acetophenones, benzophenones, thioxanthones, benzoin, benzoin methyl ether and the like are used alone or in combination. In the case of a resin system having a cationically polymerizable functional group, an aromatic diazonium salt, an aromatic sulfonium salt, an aromatic iodonium salt, a metacelone compound, a benzoin sulfonic acid ester or the like is used alone or as a mixture as a photopolymerization initiator. . The amount of photopolymerization initiator added is
With respect to 100 parts by weight of the ionizing radiation curable resin composition, 0.
It is 1 to 10 parts by weight.

In order to improve the wear resistance of the surface of the layer, the surface protective layer preferably contains inorganic spherical particles having a hardness higher than that of the crosslinked and cured resin. When the spherical particles having high hardness are added, further surface strengthening is realized. Here, the spherical particles do not have to be true spheres and may have smooth surfaces. The role of the spherical particles is to prevent abrasion of the lower layer by projecting a part of them from the surface of the surface protective layer and receiving the external force that causes wear on the surface of the spherical particles, and gradually wear the spherical particles themselves. Is. As spherical particles, there are α-alumina, silica, chromium oxide, iron oxide, diamond, graphite, etc. Among them, spherical α-alumina (spheres of Showa Denko K.K. Alumina AS-10 to AS5
0) can be recommended. The average particle size of the spherical particles is 5 to
100 μm is preferable. When the inorganic spherical particles are used in the surface protective layer, it may be pre-treated with a silane coupling agent or the like for the purpose of increasing the adhesiveness in the resin forming the surface protective layer.

[0031]

EXAMPLES Example 1 Resin impregnated paper (manufactured by Kojin Co., Ltd., GF60) preliminarily impregnated with an acrylic resin emulsion for the purpose of suppressing the permeation of the top coat and improving the inter-paper strength.
6, rice basis weight; 60 g) as a raw fabric, and on the surface of the ink for paper with a blend of an acrylic resin and a nitrocellulose resin (manufactured by Inktech, HAT), a gravure printing method, colored solid printing, pattern printing, After printing the wood and the wood grain pattern in succession on the same printing machine, continue printing on the same printing machine using a plastisol of polyvinyl chloride resin and a nearly transparent ink containing trimethylolpropane triacrylate as a cross-linking agent. Manufactured by Sol Co., Ltd., sol 100 medium), printing was performed with a plate having a plate depth of 120 μm, dried and wound. After printing, an electron beam curable resin coating material was applied to the entire printing surface by a roll coating method and irradiated with an electron beam to form a surface protective layer having a coating film thickness of 25 μm. The obtained decorative material is
While the conduit portion was matte, the surface other than the conduit portion was glossy because the surface was smooth, and it was a decorative material having a feeling of depression of the conduit portion.

Example 2 In an electron beam curable resin coating material,
A decorative material was obtained in the same manner as in Example 1 except that spherical α-alumina particles were used in an amount of 20% of the resin content. As a result of the abrasion resistance test, the obtained decorative material was able to withstand 600 consecutive abrasions.

[0033]

As described above, according to the present invention, it is sufficient to print the convex portion of the concavo-convex by adding one plate copper roller in addition to the normal pattern formation, and therefore the restriction by the printing machine is less likely to occur. Moreover, according to the present invention, since the areas of both the concave portion and the convex portion are defined only by forming the pattern having low air permeability on the convex portion, the registration difficulty is eliminated. Moreover, since the normal pattern and the pattern of the convex portion can be continuously formed, the registration is relatively easy. Further, in the present invention, since a continuous surface protective layer is formed, the surface protecting function is sufficient.

Further, when the surface protective layer is formed by using the ionizing radiation curable resin composition, the physical and chemical performance of the outermost surface can be improved. Further, when the surface protection layer contains high hardness spherical particles represented by spherical alumina, the abrasion resistance is further improved by the action of the spherical particles.

[Brief description of drawings]

FIG. 1 is a schematic cross-sectional view of a decorative material obtained by the present invention.

[Explanation of symbols]

1 base 2 conduit pattern 3 wood pattern 4 Highly permeable pattern 5 Surface protection layer

Continuation of front page (56) Reference JP-A-51-60713 (JP, A) JP-A-57-160607 (JP, A) JP-A-59-114091 (JP, A) JP-A-8-183147 (JP , A) JP 10-24545 (JP, A) JP 63-171677 (JP, A) JP 57-160635 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB (Name) B32B 33/00 B32B 27/00-27/42 B41M 3/06

Claims (8)

(57) [Claims] 1. A resin binder is provided on a desired substrate
Vinyl chloride resin, acrylic resin plastisols, or
A decorative material comprising a urethane resin ink having a pattern having a lower air permeability than other portions and having a surface protective layer on the entire surface having the pattern. 2. The decorative material according to claim 1, wherein the surface protective layer contains spherical particles of high hardness which improve wear resistance. 3. The decorative material according to claim 2, wherein the high hardness spherical particles are spherical α-alumina. 4. A resin binder is provided on a desired substrate
Vinyl chloride resin, acrylic resin plastisols, or
Having a pattern of urethane resin ink having a lower air permeability than other parts, and then forming a surface protective layer on the entire surface including the pattern, having a feeling of unevenness in synchronization with the pattern. Manufacturing method of cosmetic materials. 5. The method for producing a decorative material according to claim 4, wherein the surface protective layer is formed by applying a synthetic resin composition. 6. The method for producing a cosmetic material according to claim 5, wherein a surface protective layer is formed by using an ionizing radiation-curable resin composition as the synthetic resin composition, applying the coating composition, and then irradiating it with ionizing radiation to crosslink and cure it. 7. The method for producing a decorative material according to claim 5 or 6, wherein the synthetic resin composition contains spherical particles having high hardness for improving abrasion resistance. 8. The method for producing a decorative material according to claim 7, wherein the high hardness spherical particles are spherical α-alumina.