JP3051178U - Decorative door - Google Patents

Abstract

(57) [Problem] To provide a decorative door to which a highly practical olefin resin decorative sheet is adhered. SOLUTION: A door 100 is constituted by a decorative plate 30 in which a decorative sheet 10 is attached to at least one surface of a substrate 20. As the decorative sheet 10, the main material is made of either high-density polyethylene or polypropylene, and on a base sheet obtained by adding an elastomer, a colorant and an inorganic filler, a colorless or colored transparent ethylene-propylene- A decorative sheet obtained by laminating a surface sheet of a butene copolymer-based thermoplastic elastomer and, if necessary, applying a pattern to at least one of them is used. It has performance not inferior to a decorative door having a polyvinyl chloride-based film on the surface.

Description

[Detailed description of the invention]

[0001]

[Technical field to which the invention belongs]

 The present invention relates to a door used for a building or a fixture, and more particularly, to a decorative door having a surface on which a decorative sheet is attached.

[0002]

[Prior art]

 Conventionally, decorative doors used for the above applications have a decorative sheet adhered to the surface for decoration, waterproofing, or warpage prevention. As this decorative sheet, a decorative sheet (refer to Japanese Patent Publication No. 28-5036, Japanese Patent Publication No. 58-14312, etc.) which is formed by using a polyvinyl chloride film and decorated by printing, embossing or the like has been used. However, in recent years, as an alternative to this, (I) a decorative sheet using a polyolefin-based film such as polyethylene or polypropylene (see Japanese Patent Application Laid-Open No. 54-62255) has been proposed and further improved. (II) a mixture of a polyolefin resin having a polar functional group graft-polymerized with an olefin thermoplastic elastomer (see JP-A-6-210808 and JP-A-4-504384). Or a mixture of a polyolefin resin and a urethane resin using a compatibilizer (Japanese Unexamined Patent Publication No. 7-26038). Broadcast reference), etc. have also been proposed.

[0003]

[Problems to be solved by the invention]

 However, a decorative sheet using the polyolefin resin sheet as described above is not always satisfactory as a door surface material. In other words, a surface decorative sheet used for doors of buildings, furniture, and the like usually requires the following functions (1) to (10).

(1) Thermoformability comparable to polyvinyl chloride. In particular, the change in elongation at constant load with temperature change should be gradual and continuous, almost equivalent to that of polyvinyl chloride. In addition, deterioration of material mechanical properties such as a decrease in strength does not occur with heating → cooling. (2) creep deformation resistance. In many cases, a constant load is applied for a long time, especially to the fitting part of the door, and when the creep deformation occurs, the load part is turned over or peeled off. Therefore, it is required that the material does not cause creep deformation as much as possible. (3) Cold bending strength. When bending the door, such as V-cut processing, in cold weather, if the stress is not sufficiently relaxed, whitening, cracks, breakage, etc. are likely to occur in the bent portion. (4) Organic solvent resistance. Prevents the decorative sheet from swelling and deforming due to the solvent of the adhesive that bonds the decorative sheet and the substrate (adherend). (5) Elongation at break, impact resistance. This property is required to prevent cracks in the bent portion during V-cut processing. (6) moderate flexural modulus. This is necessary in order for the decorative sheet to follow the bent part sufficiently. (7) Good transparency. This is particularly required for topsheets. (8) Whitening and turbidity due to recrystallization should not occur even when heating and cooling accompanying embossing and the like are applied. (9) Easy adhesion. This is particularly required for substrate sheets. (10) Excellent weather resistance.

The decorative sheet having the specification (I) is difficult to mass-produce industrially, and the polyolefin resin has a high crystallinity. For example, as shown in a curve b in FIG. As compared with the polyvinyl chloride resin (curve a in FIG. 1), the change in physical properties before and after the melting point is steeper, and the range of conditions that can be processed is narrower than that of the conventional general-purpose polyvinyl chloride sheet. Among the conditions, particularly, the conditions (1) and (5) to (10) were not sufficiently satisfied. In the case of specification (II), the conditions of (1), (5) and (6) are improved by mixing an olefin-based thermoplastic elastomer, and the thermoformability and embossability are improved. However, transparency, weather resistance, and heat resistance were insufficient.

An object of the present invention is to solve the above-mentioned inconvenience of the conventional surface decorative sheet using an olefin resin as a door surface material, and specifically, to use an olefin resin. Another object of the present invention is to provide a decorative door to which a surface decorative sheet having the same thermoformability, weather resistance, and transparency as a decorative sheet using a polyvinyl chloride resin is adhered.

FIG. 1 is a graph showing the relationship between temperature and elongation under a constant load. Curve “a” shows a semi-rigid vinyl chloride sheet, curve “b” shows a sheet based on crystalline high-density polyethylene, Curve c shows the case of the laminated sheet used for the decorative door of the present invention described later.

[0008]

[Means for Solving the Problems]

 The present inventor has conducted a number of experiments and studies to solve the above-mentioned problems, and as a result, the decorative sheet to be attached to at least one side of the door surface is not a single-layer sheet, but at least a base sheet and a base sheet. By forming a two-layer structure of the surface sheets to be laminated, and by giving each sheet various conditions required for the decorative sheet, it is possible to obtain a highly practical olefin resin decorative sheet as a door surface material. And found the present invention.

[0009] Then, the base sheet is made to carry out the conditions (1) to (6) and (9) under the above conditions, and the top sheet laminated on the surface of the base sheet is subjected to the conditions (1) to (8). ) And (10).

[0010] Under the premise, as a polyolefin as a base for blending a base sheet, high-density polyethylene (HDPE) or polypropylene (PP) was selected as one having excellent basic performance. Table 1 shows the degree of satisfaction of the conditions (1) to (10) required for the decorative sheet of high-density polyethylene or polypropylene.

[0011]

[Table 1]

* 1: Steep change in elongation of the sheet around the melting point. Also, during embossing, the elongation is reduced due to the improvement of crystallization by cooling. * 2: Yield point stress is high. * 3: Curvature modulus is too high. * 4: Cloudiness due to fine crystal grains.

[0013] Therefore, an elastomer was added to inhibit crystallization and to absorb and relax stress during molding. As a result, each condition changed as shown in Table 2.

[0014]

[Table 2]

As a result, the conditions (1), (5) and (6) were satisfied, but the creep resistance of (2) was somewhat reduced. Therefore, an inorganic fine particle extender was further added. As a result, each condition changed as shown in Table 3. As a result, it was confirmed that the creep resistance was also improved, and that a material satisfying the performances (1) to (6) and (9) as the substrate sheet was obtained.

[0016]

[Table 3]

Next, an isotactic polypropylene sheet having high transparency and excellent weather resistance was selected as a surface sheet to be overlaid on the base sheet. The degree of satisfaction of the conditions (1) to (10) was examined for this sheet. Table 4 shows the degree.

[0018]

[Table 4]

* 5: Due to the high crystallinity of isotactic polypropylene. * 6: Recrystallization caused cloudiness.

Therefore, the degree of satisfaction of the above conditions (1) to (10) was examined using a thermoplastic elastomer obtained by copolymerizing ethylene and butene with propylene to lower the crystallinity of the polymer. Table 5 shows the degree.

[0021]

[Table 5]

As shown in Table 5, by using a thermoplastic elastomer composed of an ethylene-propylene-butene copolymer, the degree of sufficiency of (1) and (3) is somewhat insufficient. The layered sheet provides additional reinforcement, and the stress at the time of bending is partially dispersed in the base sheet layer, so whitening and cracks are not noticeable in the state of the laminated sheet. . In addition, although the easy adhesive property of (9) is not completely satisfied, in the case of a topsheet, a suitable adhesive is selected at the time of production of the decorative sheet, or the base sheet is bonded to the base sheet by using heat fusion. It was confirmed that it was sufficient to be able to adhere, and that it did not hinder the finished decorative sheet.

The present invention is based on the above experimental results. Basically, the decorative door of the present invention (hereinafter, also simply referred to as a door) has a decorative sheet attached to at least one surface of a substrate. Composed of decorative veneers. Here, the decorative sheet to be attached to the door surface is made of a high-density polyethylene or polypropylene as a main material, and a base sheet obtained by adding an elastomer, a coloring agent, and an inorganic filler to the base sheet. A colorless or colored transparent thermoplastic elastomer surface sheet made of an ethylene-propylene-butene copolymer is laminated, and if necessary, a pattern is applied to either or both the base sheet and the topsheet. It is characterized by being a decorative sheet.

[0024]

[Embodiment of the invention]

 The high-density polyethylene according to the present invention is preferably a polyethylene having a specific gravity of 0.94 to 0.96, which is a polymer having a high degree of crystallinity obtained by a low-pressure method and having a high degree of crystallinity and having a small structure. Density polyethylene is used. Further, as the polypropylene, preferably, isotactic polypropylene is used.

As the elastomer in the present invention, a diene rubber, a hydrogenated diene rubber, an olefin elastomer or the like is used. The hydrogenated diene rubber is obtained by adding a hydrogen atom to at least a part of the double bond of the diene rubber molecule, and suppresses the crystallization of the polyolefin resin (high-density polyethylene in the present invention). Increase flexibility. Examples of the diene rubber include isoprene rubber, butadiene rubber, butyl rubber, propylene / butadiene rubber, acrylonitrile / butadiene rubber, acrylonitrile / isoprene rubber, and styrene butadiene rubber. The olefin elastomer is an elastic copolymer obtained by adding at least one kind of polyene that can be copolymerized with two or more kinds of olefins. As the olefin, ethylene, propylene, α-olefin or the like is used. For 1,4 hexadiene, cyclic diene, norbornene and the like are used. Preferred olefin copolymer rubbers include, for example, elastic copolymers containing olefin as a main component such as ethylene-propylene copolymer rubber, ethylene-propylene-nonconjugated diene rubber, and ethylene-butadiene copolymer rubber. . In addition, these elastomers may be appropriately cross-linked by using a cross-linking agent such as an organic peroxide or sulfur, if necessary.

The addition amount of these elastomers is about 10 to 60% by weight, preferably about 30% by weight. If the amount is less than 10% by weight, the change in elongation at a constant load becomes too steep, and the elongation at break, impact resistance, and easy adhesion decrease. If the amount is more than 60% by weight, transparency, weather resistance and A decrease in creep resistance occurs.

As the inorganic filler in the present invention, powder having an average particle size of about 0.1 to 10 μm such as calcium carbonate, barium sulfate, clay, talc, or the like is used. The amount of addition is about 1 to 60% by weight, preferably about 5 to 30% by weight. If the amount is less than 1% by weight, the creep deformation resistance and the adhesion will decrease. If the amount is more than 60% by weight, the elongation at break and the impact resistance will decrease.

The coloring agent in the present invention is for imparting a necessary color to the base sheet as a decorative sheet, and includes titanium white, zinc white, red stalk, vermilion, ultramarine, cobalt blue, titanium yellow, and graphite. Inorganic pigments such as carbon black, organic pigments or dyes such as isoindolinone, Hansa Yellow A, quinacridone, permanent red 4R, and phthalocyanine blue; metal pigments composed of foil powder such as aluminum and brass; titanium dioxide-coated mica; Pearlescent pigments made of foil powder such as zinc carbonate are used. The coloring may be either transparent coloring or opaque (concealing) coloring, but opaque coloring is generally preferred in order to cover the adherend.

Further, if necessary, a heat stabilizer, a flame retardant, a radical scavenger and the like are added. The heat stabilizer is a known one such as a phenol type, a sulfite type, a phenylalkane type, a phosphite type and an amine type, and is used when the prevention of deterioration such as thermal discoloration during thermal processing is further improved. As the flame retardant, powders such as aluminum hydroxide and magnesium hydroxide are used, and these are added when it is necessary to impart flame retardancy.

[0030] A blend of these materials is formed into a film by a conventional method such as a calendering method to obtain an opaque colored base sheet. As described above, the obtained base sheet satisfies the conditions (1) to (6) and (9) required for the base sheet of the decorative sheet. The thickness of the base sheet is about 50 to 200 μm, preferably about 100 μm.

The surface of the base sheet is preferably subjected to an easy-adhesion treatment such as application of an easy-adhesion layer, corona discharge treatment, plasma treatment, and ozone treatment. Acrylic resin, vinyl chloride-vinyl acetate copolymer, polyester resin, urethane resin, chlorinated polypropylene, and chlorinated polyethylene are used for the easy-adhesion layer (also called a primer layer or an anchor layer). Particularly, a urethane resin is desirable.

Examples of the acrylic resin include poly (methyl) methacrylate, poly (meth) ethyl acrylate, poly (meth) acrylate, butyl poly (meth) acrylate, and methyl (meth) acrylate / (meth) acrylate. ) Butyl acrylate copolymer, Ethyl (meth) acrylate / butyl (meth) acrylate copolymer, Ethylene / methyl (meth) acrylate, Styrene / methyl (meth) acrylate copolymer For example, an acrylic resin made of a homo- or copolymer containing a (meth) acrylic ester (here, (meth) acryl means acryl or methacryl) is used.

The urethane resin is a polyurethane containing a polyol (polyhydric alcohol) as a main component and isocyanate as a crosslinking agent (curing agent). The polyol has two or more hydroxyl groups in the molecule, and examples thereof include polyethylene glycol, polypropylene glycol, acrylic polyol, polyester polyol, and polyether polyol.

As the isocyanate, a polyvalent isocyanate having two or more isocyanate groups in a molecule is used. For example, aromatic isocyanates such as 2-4 tolylene diisocyanate, xylene diisocyanate, and 4-4 diphenylmethane diisocyanate; (Cyclic) isocyanates are used. Alternatively, adducts or multimers of these isocyanates can also be used.

A pattern layer is formed as necessary on the surface subjected to the easy adhesion treatment. The pattern layer is formed on one or both of the base sheet and the topsheet. FIG. 2A is an example in which an easy-adhesion layer is formed. As shown in FIG. 2 (D), the easy-adhesion layer 4 may be provided on the side of the base sheet 1 facing the adherend 20. The pattern processing includes printing of the pattern layer 3 as shown in FIG. 2A, embossing (heating press) as shown in FIG. Further, the concave portions of the concave and convex pattern 5 may be filled with the coloring ink 6 by a known wiping method.

As the pattern printing, a pattern is formed with ink (or paint) using a known printing method such as gravure printing, offset printing, silk screen printing, and transfer printing from a transfer sheet. Examples of the pattern include a wood grain pattern, a stone grain pattern, a cloth grain pattern, a leather crest pattern, a geometric figure, a character, a symbol, and a solid surface.

As the ink (or paint), a chlorinated polyolefin resin such as chlorinated polyethylene or chlorinated polypropylene, a polyester resin, a urethane resin, an acrylic resin, polyvinyl acetate, a vinyl chloride / vinyl acetate copolymer may be used as a binder. One type or a mixture of two or more types is used by using coalescing, cellulose resin or the like. To this, those obtained by adding known pigments as listed above are used.

When printing directly on the base sheet, chlorinated polyolefin, urethane resin, or the like is preferable as the binder in terms of adhesiveness. However, if a layer is formed by appropriately selecting an easy-adhesion primer, other binders may be used. Even give sufficient adhesion.

The embossing is performed by heating and softening a base sheet, pressurizing and shaping with an embossing plate, and cooling and fixing, and a known sheet-fed or rotary embossing machine is used. . Examples of the uneven shape include a wood grain board conduit groove, a stone board surface unevenness (granite cleavage plane, etc.), a cloth surface texture, a satin finish, a grain, a hairline, a linear groove, and the like. The same coloring ink as described above can be used. However, from the viewpoint of abrasion resistance, it is preferable to use a two-component curable urethane resin as a binder.

The metal thin film is formed using a metal such as aluminum, chromium, gold, silver, and copper by a method such as vacuum evaporation and sputtering. Alternatively, a combination of these may be used. The metal thin film may be provided on the entire surface or partially in a pattern.

[0041] The decorative sheet constituting the decorative door of the present invention is a colorless or colored ethylene-propylene-butene copolymer formed on the surface of the base sheet, which has been subjected to a pattern treatment as required, as described above. Laminate a top sheet of transparent thermoplastic elastomer.

The ethylene-propylene-butene copolymer resin used as the surface sheet may be any one of three structural isomers of 1-butene, 2-butene and isobutylene. As the copolymer, a random copolymer which contains a part of an amorphous portion and becomes a thermoplastic elastomer is used. Preferred specific examples of the ethylene-propylene-butene copolymer include the following.

As described in JP-A-9-111055. This is a random copolymer of a terpolymer of ethylene, propylene and butene. The weight ratio of the monomer components is 90% by weight or more of propylene. Melt flow rate is 230 ° C, 2. It is preferable that the weight is 16 kg and 1 to 50 g / 10 minutes. Then, with respect to 100 parts by weight of such a tertiary random copolymer, 0.01 to 50 parts by weight of a transparent nucleating agent containing an aryl phosphate compound as a main component and 0 to 12 parts of a fatty acid amide having 12 to 22 carbon atoms are used. . 003 to 0.3 parts by weight are melt-kneaded.

As described in JP-A-5-77371. This is a terpolymer of ethylene, propylene and 1-butene, in which 20 to 100% by weight of an amorphous polymer having a propylene content of 50% by weight or more and 80 to 0% by weight of crystalline polypropylene. % Is added.

As described in JP-A-7-316358. This is a terpolymer of ethylene, propylene and 1-butene, wherein the content of propylene and / or 1-butene is 50% by weight or more and 20 to 100% by weight of a low crystalline polymer, and isotactic polypropylene is used. About 0.5 part by weight of an oil gelling agent such as an N-acylamino acid amine salt or an N-acylamino acid ester is added to 100 parts by weight of a composition obtained by mixing 80 to 0% by weight of a crystalline polyolefin such as It becomes.

The ethylene-propylene-butene copolymer resin may be used alone, or may be used as a mixture of the above or, if necessary, another polyolefin resin.

The ethylene-propylene-butene copolymer resin composition may optionally contain various additives, reinforcing agents, and fillers, such as ultraviolet rays, in order to reinforce the functions required for the surface layer of the decorative sheet. Absorbers, light stabilizers, heat stabilizers, antioxidants, antistatic agents, flame retardants, etc. are added.

The UV absorber and the light stabilizer are for imparting good weather resistance (light resistance) to the resin, and the amount of the UV absorber and the light stabilizer is usually 0.5 to 0.5% of the UV absorber and the light stabilizer. It is about 5% by weight. Generally, it is preferable to use an ultraviolet absorber and a light stabilizer in combination. As the ultraviolet absorber, organic substances such as benzotriazole, benzophenone, and salicyl ester, or inorganic substances such as zinc oxide, cerium oxide, and titanium oxide having a diameter of 0.2 μm or less can be used. As a light stabilizer, a radical scavenger such as a hindered amine diameter radical scavenger such as bis- (2,2,6,6-tetramethyl-4-piperidinyl) sebacate and a piperidine-based radical scavenger can be used. . The flame retardant may be the same as in the case of the base sheet.

A blend of these materials is formed into a film by a conventional method such as a calendering method to obtain a colorless or colored transparent ethylene-propylene-butene copolymer-based thermoplastic elastomer. As described above, the obtained sheet satisfies the conditions (1) to (8), particularly (7) and (8), required for the topsheet of the decorative sheet. The thickness of the surface sheet is about 50 to 200 μm, preferably about 100 μm.

The contact surface of the top sheet with the base sheet is preferably applied in the same manner as in the case of the base sheet, by application of an easy-adhesion layer, corona discharge treatment, plasma treatment, ozone treatment, or the like. An adhesion process is performed.

The base sheet which is the above-mentioned colored film and the surface sheet which is the above-mentioned colorless or colored transparent ethylene-propylene-butene copolymer-based thermoplastic elastomer are laminated by ordinary means. The lamination method may be melt extrusion coating (extrusion coating), fusion by hot pressing, or dry lamination using an adhesive such as a two-component curable urethane resin or a polyester resin.

Further, a pattern layer is formed on the surface of the laminated sheet on the surface sheet side as necessary. The pattern processing may be embossing (heating press) as shown in FIG. 2 (C), irregular pattern shaping 7 by hairline processing, or printing of a pattern. At that time, if necessary, the embossed surface is subjected to the above-mentioned easy adhesion treatment such as the corona treatment, and the coloring ink is filled.

The pattern printing method, the type of pattern, the type of ink (or) paint, the binder, and the like may be the same as in the case of the base sheet. Further, if necessary, the concave portions of the concavo-convex pattern can be filled with a coloring ink by a known wiping method.

Preferably, a gloss adjusting protective coat layer is further formed thereon. As the binder, a chlorinated polyolefin, a two-component curable urethane resin or the like is preferable, and an ionizing radiation-curable resin can also be used. The ionizing radiation-curable resin is, specifically, a prepolymer, a polymer and / or a monomer having a polymerizable unsaturated bond or a cationically polymerizable functional group in a molecule, and a composition curable by ionizing radiation appropriately mixed. Preferably used. Here, the ionizing radiation means an electromagnetic wave or a charged particle beam having an energy quantum capable of polymerizing or cross-linking a molecule, and usually an ultraviolet ray (UV) or an electron beam (EB) is used.

The ionizing radiation-curable resin forming the hard coating film includes, specifically, a radically polymerizable unsaturated group such as a (meth) acryloyl group and a (meth) acryloyloxy group in a molecule, and a cation such as an epoxy group. It consists of a monomer, prepolymer or polymer having two or more polymerizable functional groups or thiols. These monomers, prepolymers or polymers may be used alone or as a mixture of two or more. Here, for example, the (meth) acryloyl group means an acryloyl group or a methacryloyl group.

Examples of the prepolymer having a radical polymerizable unsaturated group include polyester (meth) acrylate, urethane (meth) acrylate, epoxy (meth) acrylate, melamine (meth) acrylate, and triazine (meth) acrylate. Can be used. A molecular weight of about 250 to 10,000 is usually used. As the polymer having a radical polymerizable unsaturated group, a polymer having a polymerization degree of about 10,000 or more is used.

Examples of the prepolymer having a cationically polymerizable functional group include epoxy resins such as bisphenol epoxy resins and novolak epoxy resins, and vinyl ether resins such as aliphatic vinyl ethers and aromatic vinyl ethers. There are polymers.

Examples of the monomer having a radical polymerizable unsaturated group include monofunctional monomers of a (meth) acrylate compound, for example, methyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, Phenoxyethyl (meth) acrylate and the like.

Examples of the polyfunctional monomer having a radical polymerizable unsaturated group include diethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, and trimethylolpropane ethylene. There are oxide tri (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate and the like.

As an example of the monomer having a cationically polymerizable functional group, the above-mentioned prepolymeric monomer having a cationically polymerizable functional group can be used. Examples of the monomer having a thiol group include trimethylolpropane trithioglycolate and dipentaerythritol tetrathioglycolate.

When curing with ultraviolet light or visible light, a photopolymerization initiator is added to the ionizing radiation-curable resin. In the case of a resin having a radical polymerizable unsaturated group, acetophenones, benzophenones, thioxanthones, benzoin, benzoin methyl ether and the like can be used alone or in combination as a photopolymerization initiator. In the case of a resin having a cationically polymerizable functional group, an aromatic diazonium salt, an aromatic sulfonium salt, an aromatic iodonium salt, a metatheron compound, a benzoinsulfonic acid ester, or the like may be used alone or as a mixture as a photopolymerization initiator. Can be used. The addition amount of these photopolymerization initiators is about 0.1 to 10% by weight based on 100% by weight of the ionizing radiation-curable resin.

For matting, a matting (light diffusion) agent is added. As the matting agent, fine particles having a particle diameter of about 1 to 30 μm, such as calcium carbonate, silica, alumina, barium sulfate, urethane resin beads, and polycarbonate resin beads, are effective. The thickness is preferably about 1 to 100 μm.

In the present invention, as the laminated sheet (decorative sheet) to be adhered to the surface of the substrate, any of stretched and unstretched sheets can be used. Therefore, an unstretched sheet is more preferable.

As shown in FIG. 2 (D), the decorative sheet used for the decorative door of the present invention is laminated on a substrate 20 which is an adherend to form a decorative plate 30 first. Doors of various structures are configured as part of the material. In this case, when the decorative sheet 10 itself does not adhere to the substrate 20, the decorative sheet 10 is laminated via an appropriate easy-adhesion layer and the adhesive layer 4. When the decorative sheet 10 itself can be bonded to the substrate 20 (by heat fusion or the like), the adhesive layer may be omitted.

As the substrate, various shapes such as a flat plate and a columnar body of various materials are applicable. Materials used for the board include wood veneer, wood plywood, particle board, wood board such as wood fiber board such as medium density fiber board (MDF), metal such as iron and aluminum, acrylic, polycarbonate, polyester and polystyrene. , Polyolefin, ABS, phenolic resin, polyvinyl chloride and the like.

As a method of laminating a decorative sheet on these various substrates, for example, a method of laminating a plate-like substrate by pressing with a pressure roller with an adhesive layer interposed therebetween is disclosed in Japanese Patent Publication No. 50-19132. As described in JP-B-43-27488, etc., a decorative sheet was inserted between the male and female molds for injection molding, the molds were closed, and the molten resin was injected and filled from the male mold gate. Thereafter, the resin sheet is cooled and, at the same time, a decorative sheet is adhered and laminated on the surface of the resin molded article at the same time. The so-called simultaneous injection molding laminating method is described in Japanese Patent Publication Nos. As described above, a decorative sheet is placed on the surface of a molded article facing or placed with an adhesive layer between them, and the decorative sheet is laminated on the surface of the molded article by a pressure difference caused by vacuum suction from the molded article side. Stacking method, As described in JP-B-61-5895, JP-B-3-2666, etc., a decorative sheet is supplied in the longitudinal direction of a columnar substrate such as a column or a polygon through an adhesive layer. A so-called lapping method, in which a decorative sheet is sequentially adhered and laminated on a plurality of side surfaces constituting a columnar body by a plurality of rollers having different directions, a so-called lapping method, Japanese Utility Model Publication No. 15-31122, As described in Japanese Patent Publication No. 48-47972, a decorative sheet is first laminated on a plate-like base material via an adhesive layer, and then a decorative sheet is placed on the surface of the plate-like base material opposite to the decorative sheet. A groove having a V-shaped or U-shaped cross section which reaches the interface between the sheet and the plate-shaped substrate is cut, and then an adhesive is applied to the groove, and the groove is bent to form a box or column. , A so-called V-cut or U-cut processing method.

The decorative plate is subjected to a predetermined molding process and the like, and these are combined to form doors of various known structures. FIGS. 3 and 4 show typical examples of the door structure. In each of the figures, (A) is a partially cutaway perspective view of the door, and (B) is a front view in a state where the door is mounted on a door frame surrounding four rounds thereof.

FIG. 3 shows what is called a “flash door”. The illustrated flash door 100 has a decorative structure 30 laminated and covered on the front and back sides of a skeleton composed of a ridge 40 provided on the four sides around it and, if necessary, also inside. Have been. The decorative sheet 10 may be attached to at least the front side of the substrate 20. In addition, the decorative board is used for the ridges 40 and the edge material 41 on the four sides as necessary. However, in this case, the decorative board will be a columnar body. The flash door 100 further has a handle 51 attached thereto, and is pivotally attached to the door frame 50 using a pair of upper and lower hinges 52 as shown in FIG.

FIG. 4 shows what is called a “frame door”. Although there are many types of frame doors, typical ones are exemplified here. The illustrated frame door 200 has a mirror plate 60 in the center, a pair of horizontal frames 61 above and below the mirror plate 60 and a pair of vertical frames 62 on the left and right sides, and surrounds four sides around the mirror plate 60. Thus, the upper and lower horizontal stiles 61 and the left and right vertical stiles 62 are fitted together as shown in FIG. The end plate 60, the horizontal frame 61, and the vertical frame 62 have a solid structure, and the decorative sheet 10 is all stuck on the exposed surface. This frame door 200 is further provided with a handle 51, and is pivotally attached to the door frame 50 using a pair of upper and lower hinges 52 as shown in FIG.

The door structure of the present invention includes various known structures such as folding doors (closet doors) in addition to those shown in FIGS.

[0071]

[Effect of the invention]

 The decorative door of the present invention is configured as described above, and the temperature-elongation dependency of the decorative sheet adhered to the surface thereof has a high temperature range of about 15 ° C. Since it has the same temperature-elongation dependence as a decorative sheet mainly composed of a vinyl chloride sheet, the elongation rate, tear resistance, and the elongation that can be formed by door processing such as embossing, V-cut, and lapping, It is flexible, has good heat resistance, and has the effect of improving design by applying printing.Moreover, it has creep deformation compared to a decorative door with a general polyvinyl chloride film on the surface. When the door is constructed by assembling and fitting members, even if a static stress is applied to the decorative sheet part of each member, defects such as the decorative sheet around the mating part may be turned up. Hard.

[Brief description of the drawings]

FIG. 1 is a graph showing the relationship between temperature and elongation of various decorative sheets made of different materials.

FIG. 2 is a sectional view of the decorative sheet constituting the decorative door of the present invention.

FIG. 3 is an explanatory view of a flash door which is one of the decorative doors of the present invention.

FIG. 4 is an explanatory view of a frame door which is one of the decorative doors of the present invention.

[Explanation of symbols]

 REFERENCE SIGNS LIST 1 base sheet 2 top sheet 3 pattern layer 4 easy-adhesion layer 5 uneven pattern 6 colored ink 7 uneven pattern 10 decorative sheet 20 substrate 30 decorative board 40 edge 41 edge material 50 door frame 51 handle 52 hinge 60 mirror plate 61 horizontal frame 62 vertical Frame 100 Flash door 200 Frame door

Claims (3)

[Utility model registration claims] 1. A door composed of a decorative plate obtained by attaching a decorative sheet to at least one surface of a substrate, wherein the decorative sheet is made of a high-density polyethylene or polypropylene as a main material, Elastomer,
On a base sheet obtained by adding a coloring agent and an inorganic filler,
A decorative sheet obtained by laminating a colorless or colored transparent ethylene-propylene-butene copolymer-based thermoplastic elastomer surface sheet and, if necessary, patterning one or both of the base sheet and the surface sheet. A decorative door characterized by that. 2. The decorative door according to claim 1, wherein the door structure is a flash door. 3. The decorative door according to claim 1, wherein the door structure is a frame door.