JP2825346B2 - リグノセルロース物質の環境上改良された漂白方法 - Google Patents
リグノセルロース物質の環境上改良された漂白方法Info
- Publication number
- JP2825346B2 JP2825346B2 JP2508269A JP50826990A JP2825346B2 JP 2825346 B2 JP2825346 B2 JP 2825346B2 JP 2508269 A JP2508269 A JP 2508269A JP 50826990 A JP50826990 A JP 50826990A JP 2825346 B2 JP2825346 B2 JP 2825346B2
- Authority
- JP
- Japan
- Prior art keywords
- pulp
- ozone
- consistency
- bleaching
- lignin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 124
- 238000000034 method Methods 0.000 title claims description 266
- 239000012978 lignocellulosic material Substances 0.000 title claims description 15
- 238000004537 pulping Methods 0.000 claims abstract description 60
- 238000005406 washing Methods 0.000 claims abstract description 39
- 150000002978 peroxides Chemical class 0.000 claims abstract description 15
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 177
- 230000008569 process Effects 0.000 claims description 159
- 229910052760 oxygen Inorganic materials 0.000 claims description 106
- 239000001301 oxygen Substances 0.000 claims description 104
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 103
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 76
- 229920005610 lignin Polymers 0.000 claims description 55
- 238000011282 treatment Methods 0.000 claims description 51
- 239000000126 substance Substances 0.000 claims description 45
- 239000004155 Chlorine dioxide Substances 0.000 claims description 38
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 38
- 239000007789 gas Substances 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 34
- 239000002245 particle Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000007844 bleaching agent Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 239000012670 alkaline solution Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
- 239000003513 alkali Substances 0.000 claims description 20
- 230000002829 reductive effect Effects 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- 239000002738 chelating agent Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 150000001805 chlorine compounds Chemical class 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 238000003801 milling Methods 0.000 claims description 5
- 150000002926 oxygen Chemical class 0.000 claims description 5
- 238000009827 uniform distribution Methods 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 230000003381 solubilizing effect Effects 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims 2
- 239000002351 wastewater Substances 0.000 claims 2
- 125000002081 peroxide group Chemical group 0.000 claims 1
- 239000002655 kraft paper Substances 0.000 abstract description 44
- 239000002023 wood Substances 0.000 abstract description 29
- 238000012216 screening Methods 0.000 abstract description 9
- 230000029087 digestion Effects 0.000 abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 53
- 239000000835 fiber Substances 0.000 description 42
- 239000000460 chlorine Substances 0.000 description 31
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 30
- 229910052801 chlorine Inorganic materials 0.000 description 29
- 229920002678 cellulose Polymers 0.000 description 23
- 239000001913 cellulose Substances 0.000 description 23
- 238000000605 extraction Methods 0.000 description 23
- 239000011121 hardwood Substances 0.000 description 22
- 230000008859 change Effects 0.000 description 19
- 238000012545 processing Methods 0.000 description 18
- 239000011122 softwood Substances 0.000 description 18
- 239000000123 paper Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- 238000006385 ozonation reaction Methods 0.000 description 13
- 238000010411 cooking Methods 0.000 description 12
- 230000008901 benefit Effects 0.000 description 11
- 230000015556 catabolic process Effects 0.000 description 10
- 239000003518 caustics Substances 0.000 description 10
- 238000006731 degradation reaction Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 238000011084 recovery Methods 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- 230000002087 whitening effect Effects 0.000 description 9
- 241000218631 Coniferophyta Species 0.000 description 7
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 7
- 238000010025 steaming Methods 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000003628 erosive effect Effects 0.000 description 6
- 229920003043 Cellulose fiber Polymers 0.000 description 5
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 5
- 241000018646 Pinus brutia Species 0.000 description 5
- 230000000875 corresponding effect Effects 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000010865 sewage Substances 0.000 description 5
- 230000008719 thickening Effects 0.000 description 5
- 229920001131 Pulp (paper) Polymers 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 4
- 150000004056 anthraquinones Chemical class 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000003265 pulping liquor Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- 235000005018 Pinus echinata Nutrition 0.000 description 3
- 241001236219 Pinus echinata Species 0.000 description 3
- 235000017339 Pinus palustris Nutrition 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- MAYPHUUCLRDEAZ-UHFFFAOYSA-N chlorine peroxide Inorganic materials ClOOCl MAYPHUUCLRDEAZ-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005374 membrane filtration Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000006213 oxygenation reaction Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 235000008566 Pinus taeda Nutrition 0.000 description 2
- 241000218679 Pinus taeda Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000001223 reverse osmosis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012042 active reagent Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000005446 dissolved organic matter Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004710 electron pair approximation Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 238000005949 ozonolysis reaction Methods 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical group CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 1
- 239000011802 pulverized particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1990/002823 WO1991018145A1 (en) | 1990-05-17 | 1990-05-17 | Environmentally improved process for bleaching lignocellulosic materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05500243A JPH05500243A (ja) | 1993-01-21 |
| JP2825346B2 true JP2825346B2 (ja) | 1998-11-18 |
Family
ID=22220868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2508269A Expired - Lifetime JP2825346B2 (ja) | 1990-05-17 | 1990-05-17 | リグノセルロース物質の環境上改良された漂白方法 |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0483163B1 (de) |
| JP (1) | JP2825346B2 (de) |
| KR (1) | KR920703922A (de) |
| CN (1) | CN1043798C (de) |
| AT (1) | ATE122421T1 (de) |
| AU (1) | AU638017B2 (de) |
| BR (1) | BR9007533A (de) |
| CA (1) | CA2063591C (de) |
| DE (1) | DE69019350T2 (de) |
| ES (1) | ES2073027T3 (de) |
| NO (1) | NO300929B1 (de) |
| PT (1) | PT98487B (de) |
| RU (1) | RU2102547C1 (de) |
| SE (1) | SE9200107L (de) |
| WO (1) | WO1991018145A1 (de) |
| ZA (1) | ZA915969B (de) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5472572A (en) * | 1990-10-26 | 1995-12-05 | Union Camp Patent Holding, Inc. | Reactor for bleaching high consistency pulp with ozone |
| US5441603A (en) * | 1990-05-17 | 1995-08-15 | Union Camp Patent Holding, Inc. | Method for chelation of pulp prior to ozone delignification |
| US5328564A (en) * | 1990-09-17 | 1994-07-12 | Kamyr, Inc. | Modified digestion of paper pulp followed by ozone bleaching |
| BR9205490A (pt) * | 1991-01-03 | 1994-04-05 | Union Camp Patent Holding | Processos para a fabricacao de pasta branqueada tendo um britho GE final de pelo menos cerca de 75 e para a deslignificacao e branqueamento de uma pasta lignocelulosica |
| SE468355B (sv) * | 1991-04-30 | 1992-12-21 | Eka Nobel Ab | Blekning av kemisk massa genom behandling med komplexbildare och ozon |
| DE69221385T2 (de) * | 1991-05-24 | 1997-12-11 | Union Camp Patent Holding, Inc., Wilmington, Del. | Zweistufiger Reaktor zum Bleichen von Zellstoff und Verfahren zum Bleichen mit Ozon |
| US5364503A (en) * | 1992-02-20 | 1994-11-15 | Macmillan Bloedel Limited | Nitric oxide treatment for ozone bleaching |
| CA2089516A1 (en) * | 1992-02-21 | 1993-08-22 | Kaj Henricson | Chlorine free pulping and bleaching sequence |
| SE9201477L (sv) * | 1992-05-11 | 1993-06-28 | Kamyr Ab | Saett vid blekning av massa utan anvaendning av klorkemikalier |
| CA2144433A1 (en) * | 1992-10-01 | 1994-04-14 | Thomas P. Gandek | Improved bleaching of high consistency lignocellulosic pulp |
| US5403441A (en) * | 1992-11-13 | 1995-04-04 | Union Camp Patent Holding, Inc. | Method for controlling an ozone bleaching process |
| SE501613C2 (sv) * | 1993-08-03 | 1995-03-27 | Kvaerner Pulping Tech | Sätt vid integrering av blekning och återvinning vid framställning av massa |
| WO1995006772A1 (en) * | 1993-09-02 | 1995-03-09 | Union Camp Patent Holding, Inc. | Improved method for bleaching lignocellulosic pulp |
| BR9407457A (pt) * | 1993-09-03 | 1996-11-12 | Union Camp Patent Holding | Processo para a preparação de uma polpa alvejada possuindo um certo brilho e uma certa resistência como indicado por uma certa viscosidade |
| US5810973A (en) * | 1993-09-21 | 1998-09-22 | Beloit Technologies, Inc. | Apparatus for producing small particles from high consistency wood pulp |
| SE502172C2 (sv) * | 1993-12-15 | 1995-09-04 | Mo Och Domsjoe Ab | Förfarande för framställning av blekt cellulosamassa med en klorfri bleksekvens i närvaro av karbonat |
| EP0831170A3 (de) * | 1994-06-27 | 1998-11-11 | Champion International Corporation | Verbessertes Verfahren zum Wiedergewinnen von Filtraten aus Bleichanlage |
| US5672247A (en) * | 1995-03-03 | 1997-09-30 | Union Camp Patent Holding, Inc. | Control scheme for rapid pulp delignification and bleaching |
| US5736004A (en) * | 1995-03-03 | 1998-04-07 | Union Camp Patent Holding, Inc. | Control scheme for rapid pulp delignification and bleaching |
| US5944952A (en) * | 1995-07-26 | 1999-08-31 | Beloit Technologies, Inc. | Method for bleaching high consistency pulp with a gaseous bleaching reagent |
| CN1050642C (zh) * | 1996-06-25 | 2000-03-22 | 华南理工大学 | 高浓纸浆过氧化氢漂白方法 |
| US6077396A (en) * | 1997-05-16 | 2000-06-20 | Lariviere; Christopher J. | Apparatus for fluffing and contacting high consistancy wood pulp with a gaseous bleaching reagent |
| ID23571A (id) * | 1997-08-25 | 2000-05-04 | Praxair Technology Inc | Metoda penerapan ozon dalam pemutihan ecf |
| FR2910027B1 (fr) * | 2006-12-13 | 2009-11-06 | Itt Mfg Enterprises Inc | Procede de blanchiment des pates papeteries chimiques par traitement final a l'ozone a haute temperature |
| FI119062B (fi) * | 2006-12-28 | 2008-07-15 | Upm Kymmene Corp | Menetelmä mekaanisen massan valmistamiseksi |
| JP4973284B2 (ja) * | 2007-03-30 | 2012-07-11 | 栗田工業株式会社 | パルプ洗浄剤、パルプ製造方法、及びパルプ洗浄方法 |
| US8497097B2 (en) * | 2010-08-11 | 2013-07-30 | Georgia Tech Research Corporation | Chlorine dioxide treatment of biomass feedstock |
| CN104313933A (zh) * | 2014-09-23 | 2015-01-28 | 华南理工大学 | 一种硫酸盐蔗渣浆绿色漂白方法 |
| CN115584653B (zh) * | 2022-12-12 | 2023-03-10 | 河南禾力能源有限公司 | 一种利用糠醛渣提取α-纤维素的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1090510A (en) * | 1976-06-02 | 1980-12-02 | Arthur W. Kempf | Delignification and bleaching of a lignocellulosic pulp slurry with ozone |
| JPS5390402A (en) * | 1977-01-12 | 1978-08-09 | Kogyo Gijutsuin | Pulp bleaching method |
| FI67413C (fi) * | 1977-04-27 | 1985-03-11 | Myrens Verksted As | Foerfarande foer behandling av finfoerdelad fiberhaltig eller cellulosahaltig massa samt anordning foer utfoerande av foerfarandet |
| US4216054A (en) * | 1977-09-26 | 1980-08-05 | Weyerhaeuser Company | Low-consistency ozone delignification |
| NO142091C (no) * | 1977-10-17 | 1980-06-25 | Myrens Verksted As | Fremgangsmaate ved ozonbehandling av raffinoermekanisk og termomekanisk masse. |
| JPS5679797A (en) * | 1979-11-30 | 1981-06-30 | Weyerhaeuser Co | Bleaching of cellulose fiber |
| US4619733A (en) * | 1983-11-30 | 1986-10-28 | Kooi Boon Lam | Pollution free pulping process using recycled wash effluent from multiple bleach stages to remove black liquor and recovering sodium hydroxide from the black liquor |
| US4806203A (en) * | 1985-02-14 | 1989-02-21 | Elton Edward F | Method for alkaline delignification of lignocellulosic fibrous material at a consistency which is raised during reaction |
| CA2015296C (en) * | 1989-05-31 | 2001-08-07 | Karnail Atwal | Pyranyl cyanoguanidine derivatives |
| CA2053035C (en) * | 1990-10-12 | 1997-09-30 | Repap Enterprises Inc. | Chlorine-free wood pulps and process of making |
-
1990
- 1990-05-17 JP JP2508269A patent/JP2825346B2/ja not_active Expired - Lifetime
- 1990-05-17 EP EP90908787A patent/EP0483163B1/de not_active Expired - Lifetime
- 1990-05-17 AU AU56768/90A patent/AU638017B2/en not_active Ceased
- 1990-05-17 RU SU5011189A patent/RU2102547C1/ru active
- 1990-05-17 CA CA002063591A patent/CA2063591C/en not_active Expired - Lifetime
- 1990-05-17 DE DE69019350T patent/DE69019350T2/de not_active Expired - Fee Related
- 1990-05-17 AT AT90908787T patent/ATE122421T1/de not_active IP Right Cessation
- 1990-05-17 ES ES90908787T patent/ES2073027T3/es not_active Expired - Lifetime
- 1990-05-17 WO PCT/US1990/002823 patent/WO1991018145A1/en active IP Right Grant
- 1990-05-17 BR BR909007533A patent/BR9007533A/pt not_active IP Right Cessation
- 1990-05-17 KR KR1019920700104A patent/KR920703922A/ko active IP Right Grant
-
1991
- 1991-07-29 PT PT98487A patent/PT98487B/pt not_active IP Right Cessation
- 1991-07-30 ZA ZA915969A patent/ZA915969B/xx unknown
- 1991-08-07 CN CN91108650A patent/CN1043798C/zh not_active Expired - Lifetime
-
1992
- 1992-01-15 SE SE9200107A patent/SE9200107L/xx not_active Application Discontinuation
- 1992-01-16 NO NO920217A patent/NO300929B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1043798C (zh) | 1999-06-23 |
| SE9200107L (en) | 1992-03-13 |
| AU5676890A (en) | 1991-12-10 |
| DE69019350D1 (de) | 1995-06-14 |
| CA2063591A1 (en) | 1991-11-18 |
| EP0483163A1 (de) | 1992-05-06 |
| WO1991018145A1 (en) | 1991-11-28 |
| JPH05500243A (ja) | 1993-01-21 |
| NO300929B1 (no) | 1997-08-18 |
| ZA915969B (en) | 1992-04-29 |
| EP0483163A4 (en) | 1992-08-05 |
| NO920217D0 (no) | 1992-01-16 |
| CA2063591C (en) | 1998-02-03 |
| PT98487B (pt) | 1998-06-30 |
| ES2073027T3 (es) | 1995-08-01 |
| DE69019350T2 (de) | 1996-02-15 |
| EP0483163B1 (de) | 1995-05-10 |
| ATE122421T1 (de) | 1995-05-15 |
| SE9200107D0 (sv) | 1992-01-15 |
| RU2102547C1 (ru) | 1998-01-20 |
| KR920703922A (ko) | 1992-12-18 |
| NO920217L (no) | 1992-03-05 |
| PT98487A (pt) | 1993-01-29 |
| AU638017B2 (en) | 1993-06-17 |
| BR9007533A (pt) | 1992-04-28 |
| CN1069304A (zh) | 1993-02-24 |
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