CA2063591A1 - Environmentally Improved Process for Bleaching Lignocellulosic Materials - Google Patents
Environmentally Improved Process for Bleaching Lignocellulosic MaterialsInfo
- Publication number
- CA2063591A1 CA2063591A1 CA2063591A CA2063591A CA2063591A1 CA 2063591 A1 CA2063591 A1 CA 2063591A1 CA 2063591 A CA2063591 A CA 2063591A CA 2063591 A CA2063591 A CA 2063591A CA 2063591 A1 CA2063591 A1 CA 2063591A1
- Authority
- CA
- Canada
- Prior art keywords
- pulp
- delignifying
- improved process
- bleaching
- lignocellulosic materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004061 bleaching Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000012978 lignocellulosic material Substances 0.000 title 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 abstract 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004155 Chlorine dioxide Substances 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 235000019398 chlorine dioxide Nutrition 0.000 abstract 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Detergent Compositions (AREA)
Abstract
A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine by partially delignifying the pulp to a K No. of about 10 or less and a viscosity of greater than about 13 cps; and further delignifying the partially delignified pulp with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 5 or less, a viscosity of greater than about 10, and a GE
rightness of at least about 50 %. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65 %, preferably abovt 70 % to as high as 90 %.
Because of the absence of a elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.
rightness of at least about 50 %. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65 %, preferably abovt 70 % to as high as 90 %.
Because of the absence of a elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1990/002823 WO1991018145A1 (en) | 1990-05-17 | 1990-05-17 | Environmentally improved process for bleaching lignocellulosic materials |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2063591A1 true CA2063591A1 (en) | 1991-11-18 |
CA2063591C CA2063591C (en) | 1998-02-03 |
Family
ID=22220868
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002063591A Expired - Lifetime CA2063591C (en) | 1990-05-17 | 1990-05-17 | Environmentally improved process for bleaching lignocellulosic materials |
Country Status (16)
Country | Link |
---|---|
EP (1) | EP0483163B1 (en) |
JP (1) | JP2825346B2 (en) |
KR (1) | KR920703922A (en) |
CN (1) | CN1043798C (en) |
AT (1) | ATE122421T1 (en) |
AU (1) | AU638017B2 (en) |
BR (1) | BR9007533A (en) |
CA (1) | CA2063591C (en) |
DE (1) | DE69019350T2 (en) |
ES (1) | ES2073027T3 (en) |
NO (1) | NO300929B1 (en) |
PT (1) | PT98487B (en) |
RU (1) | RU2102547C1 (en) |
SE (1) | SE9200107L (en) |
WO (1) | WO1991018145A1 (en) |
ZA (1) | ZA915969B (en) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5472572A (en) * | 1990-10-26 | 1995-12-05 | Union Camp Patent Holding, Inc. | Reactor for bleaching high consistency pulp with ozone |
US5441603A (en) * | 1990-05-17 | 1995-08-15 | Union Camp Patent Holding, Inc. | Method for chelation of pulp prior to ozone delignification |
US5328564A (en) * | 1990-09-17 | 1994-07-12 | Kamyr, Inc. | Modified digestion of paper pulp followed by ozone bleaching |
BR9205490A (en) * | 1991-01-03 | 1994-04-05 | Union Camp Patent Holding | Processes for the manufacture of bleached pulp having a final GE britho of at least about 75 and for the delignification and bleaching of a lignocellulosic pulp |
SE468355B (en) * | 1991-04-30 | 1992-12-21 | Eka Nobel Ab | CHEMISTRY OF CHEMICAL MASS THROUGH TREATMENT WITH COMPLEX PICTURES AND OZONE |
DE69221385T2 (en) * | 1991-05-24 | 1997-12-11 | Union Camp Patent Holding, Inc., Wilmington, Del. | Two-stage pulp bleaching reactor and method for bleaching with ozone |
US5364503A (en) * | 1992-02-20 | 1994-11-15 | Macmillan Bloedel Limited | Nitric oxide treatment for ozone bleaching |
CA2089516A1 (en) * | 1992-02-21 | 1993-08-22 | Kaj Henricson | Chlorine free pulping and bleaching sequence |
SE9201477L (en) * | 1992-05-11 | 1993-06-28 | Kamyr Ab | SEATING WHITE PILLOW WITHOUT USING CHLORIC CHEMICALS |
CA2144433A1 (en) * | 1992-10-01 | 1994-04-14 | Thomas P. Gandek | Improved bleaching of high consistency lignocellulosic pulp |
US5403441A (en) * | 1992-11-13 | 1995-04-04 | Union Camp Patent Holding, Inc. | Method for controlling an ozone bleaching process |
SE501613C2 (en) * | 1993-08-03 | 1995-03-27 | Kvaerner Pulping Tech | Method of integrating bleaching and recycling in pulp production |
WO1995006772A1 (en) * | 1993-09-02 | 1995-03-09 | Union Camp Patent Holding, Inc. | Improved method for bleaching lignocellulosic pulp |
BR9407457A (en) * | 1993-09-03 | 1996-11-12 | Union Camp Patent Holding | Process for the preparation of a targeted pulp having a certain luster and a certain resistance as indicated by a certain viscosity |
US5810973A (en) * | 1993-09-21 | 1998-09-22 | Beloit Technologies, Inc. | Apparatus for producing small particles from high consistency wood pulp |
SE502172C2 (en) * | 1993-12-15 | 1995-09-04 | Mo Och Domsjoe Ab | Process for the preparation of bleached cellulose pulp with a chlorine-free bleaching sequence in the presence of carbonate |
EP0831170A3 (en) * | 1994-06-27 | 1998-11-11 | Champion International Corporation | Improved process for recycling bleach plant filtrate |
US5672247A (en) * | 1995-03-03 | 1997-09-30 | Union Camp Patent Holding, Inc. | Control scheme for rapid pulp delignification and bleaching |
US5736004A (en) * | 1995-03-03 | 1998-04-07 | Union Camp Patent Holding, Inc. | Control scheme for rapid pulp delignification and bleaching |
US5944952A (en) * | 1995-07-26 | 1999-08-31 | Beloit Technologies, Inc. | Method for bleaching high consistency pulp with a gaseous bleaching reagent |
CN1050642C (en) * | 1996-06-25 | 2000-03-22 | 华南理工大学 | Everyday production 30-150 ton high concentration paper pulp bleaching method by using hydrogen peroxide |
US6077396A (en) * | 1997-05-16 | 2000-06-20 | Lariviere; Christopher J. | Apparatus for fluffing and contacting high consistancy wood pulp with a gaseous bleaching reagent |
ID23571A (en) * | 1997-08-25 | 2000-05-04 | Praxair Technology Inc | METHOD OF OZONE APPLICATION IN ECF BLEACHING |
FR2910027B1 (en) * | 2006-12-13 | 2009-11-06 | Itt Mfg Enterprises Inc | PROCESS FOR WHITENING CHEMICAL STRIPPING PASTES BY FINAL OZONE TREATMENT AT HIGH TEMPERATURE |
FI119062B (en) * | 2006-12-28 | 2008-07-15 | Upm Kymmene Corp | Process for the manufacture of mechanical pulp |
JP4973284B2 (en) * | 2007-03-30 | 2012-07-11 | 栗田工業株式会社 | Pulp cleaning agent, pulp manufacturing method, and pulp cleaning method |
US8497097B2 (en) * | 2010-08-11 | 2013-07-30 | Georgia Tech Research Corporation | Chlorine dioxide treatment of biomass feedstock |
CN104313933A (en) * | 2014-09-23 | 2015-01-28 | 华南理工大学 | Green bleaching method of sulfate bagasse slurry |
CN115584653B (en) * | 2022-12-12 | 2023-03-10 | 河南禾力能源有限公司 | Method for extracting alpha-cellulose by furfural residues |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1090510A (en) * | 1976-06-02 | 1980-12-02 | Arthur W. Kempf | Delignification and bleaching of a lignocellulosic pulp slurry with ozone |
JPS5390402A (en) * | 1977-01-12 | 1978-08-09 | Kogyo Gijutsuin | Pulp bleaching method |
FI67413C (en) * | 1977-04-27 | 1985-03-11 | Myrens Verksted As | FOERFARANDE FOER BEHANDLING AV FINFOERDELAD FIBERHALTIG ELLER CELLULOSAHALTIG MASS SAMT ANORDNING FOER UTFOERANDE AV FOERFARANDET |
US4216054A (en) * | 1977-09-26 | 1980-08-05 | Weyerhaeuser Company | Low-consistency ozone delignification |
NO142091C (en) * | 1977-10-17 | 1980-06-25 | Myrens Verksted As | PROCEDURE FOR OZONE TREATMENT OF REFINO MECHANICAL AND THERMOMECHANICAL MASS. |
JPS5679797A (en) * | 1979-11-30 | 1981-06-30 | Weyerhaeuser Co | Bleaching of cellulose fiber |
US4619733A (en) * | 1983-11-30 | 1986-10-28 | Kooi Boon Lam | Pollution free pulping process using recycled wash effluent from multiple bleach stages to remove black liquor and recovering sodium hydroxide from the black liquor |
US4806203A (en) * | 1985-02-14 | 1989-02-21 | Elton Edward F | Method for alkaline delignification of lignocellulosic fibrous material at a consistency which is raised during reaction |
CA2015296C (en) * | 1989-05-31 | 2001-08-07 | Karnail Atwal | Pyranyl cyanoguanidine derivatives |
CA2053035C (en) * | 1990-10-12 | 1997-09-30 | Repap Enterprises Inc. | Chlorine-free wood pulps and process of making |
-
1990
- 1990-05-17 JP JP2508269A patent/JP2825346B2/en not_active Expired - Lifetime
- 1990-05-17 EP EP90908787A patent/EP0483163B1/en not_active Expired - Lifetime
- 1990-05-17 AU AU56768/90A patent/AU638017B2/en not_active Ceased
- 1990-05-17 RU SU5011189A patent/RU2102547C1/en active
- 1990-05-17 CA CA002063591A patent/CA2063591C/en not_active Expired - Lifetime
- 1990-05-17 DE DE69019350T patent/DE69019350T2/en not_active Expired - Fee Related
- 1990-05-17 AT AT90908787T patent/ATE122421T1/en not_active IP Right Cessation
- 1990-05-17 ES ES90908787T patent/ES2073027T3/en not_active Expired - Lifetime
- 1990-05-17 WO PCT/US1990/002823 patent/WO1991018145A1/en active IP Right Grant
- 1990-05-17 BR BR909007533A patent/BR9007533A/en not_active IP Right Cessation
- 1990-05-17 KR KR1019920700104A patent/KR920703922A/en active IP Right Grant
-
1991
- 1991-07-29 PT PT98487A patent/PT98487B/en not_active IP Right Cessation
- 1991-07-30 ZA ZA915969A patent/ZA915969B/en unknown
- 1991-08-07 CN CN91108650A patent/CN1043798C/en not_active Expired - Lifetime
-
1992
- 1992-01-15 SE SE9200107A patent/SE9200107L/en not_active Application Discontinuation
- 1992-01-16 NO NO920217A patent/NO300929B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1043798C (en) | 1999-06-23 |
SE9200107L (en) | 1992-03-13 |
AU5676890A (en) | 1991-12-10 |
DE69019350D1 (en) | 1995-06-14 |
EP0483163A1 (en) | 1992-05-06 |
WO1991018145A1 (en) | 1991-11-28 |
JPH05500243A (en) | 1993-01-21 |
NO300929B1 (en) | 1997-08-18 |
ZA915969B (en) | 1992-04-29 |
EP0483163A4 (en) | 1992-08-05 |
NO920217D0 (en) | 1992-01-16 |
CA2063591C (en) | 1998-02-03 |
PT98487B (en) | 1998-06-30 |
ES2073027T3 (en) | 1995-08-01 |
DE69019350T2 (en) | 1996-02-15 |
EP0483163B1 (en) | 1995-05-10 |
ATE122421T1 (en) | 1995-05-15 |
SE9200107D0 (en) | 1992-01-15 |
RU2102547C1 (en) | 1998-01-20 |
KR920703922A (en) | 1992-12-18 |
JP2825346B2 (en) | 1998-11-18 |
NO920217L (en) | 1992-03-05 |
PT98487A (en) | 1993-01-29 |
AU638017B2 (en) | 1993-06-17 |
BR9007533A (en) | 1992-04-28 |
CN1069304A (en) | 1993-02-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed | ||
MKEC | Expiry (correction) | ||
MKEC | Expiry (correction) |
Effective date: 20121202 |