JP2800833B2 - Double-sided adhesive tape for temporary fixing of tiles and tile sheets - Google Patents
Double-sided adhesive tape for temporary fixing of tiles and tile sheetsInfo
- Publication number
- JP2800833B2 JP2800833B2 JP63309147A JP30914788A JP2800833B2 JP 2800833 B2 JP2800833 B2 JP 2800833B2 JP 63309147 A JP63309147 A JP 63309147A JP 30914788 A JP30914788 A JP 30914788A JP 2800833 B2 JP2800833 B2 JP 2800833B2
- Authority
- JP
- Japan
- Prior art keywords
- sensitive adhesive
- pressure
- double
- support
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は、タイル、タイルシートの仮止め用に使用す
る両面粘着テープに関するものである。Description: TECHNICAL FIELD The present invention relates to a double-sided pressure-sensitive adhesive tape used for temporarily fixing tiles and tile sheets.
［従来の技術］ タイル貼り建築材料製造時のタイルやタイルシート
（タイルをポリプロピレン粘着シートに碁盤目状に貼り
つけ並べたもの）の仮止めに両面粘着テープが使用され
るようになっている。このような両面粘着テープとして
は、支持体が紙やレーヨン紙であるもの、ポリエステ
ル、ポリプロピレンなどのフィルムであるもの、ポリエ
ステル、ナイロン、ポリプロピレン繊維の不織布である
ものが使用されている。[Related Art] A double-sided adhesive tape has been used for temporary fixing of tiles and tile sheets (tiles attached in a grid pattern on a polypropylene adhesive sheet) at the time of producing a tiled building material. As such a double-sided pressure-sensitive adhesive tape, those whose support is paper or rayon paper, those which are films such as polyester and polypropylene, and those which are nonwoven fabrics of polyester, nylon and polypropylene fibers are used.
［発明が解決しようとする課題］ しかしながら、上記の様な両面粘着テープは、いろい
ろな問題点があり改善が望まれている。たとえば、タイ
ル貼り建築材料を製造するにあたって、あらかじめ鉄製
などの枠を組み立て、その内面に両面テープによりタイ
ルやタイルシートを貼り付けた後コンクリートを流し込
んで硬化させ、表面にタイルを有する建築材料を一工程
で製造した後に鉄などの枠を取り外す方法が開発されて
いる。しかし、このような工程に両面粘着テープを使用
すると、テープがタイル貼り建築材料の製造後も枠に粘
着して残り、その除去が困難で長時間が必要となること
が多々あり、作業性上問題があった。[Problems to be Solved by the Invention] However, the double-sided pressure-sensitive adhesive tape as described above has various problems, and improvement is desired. For example, in manufacturing a tiled building material, a frame made of iron or the like is assembled in advance, a tile or tile sheet is attached to the inner surface with double-sided tape, and then concrete is poured and cured, and the building material having the tile on the surface is removed. A method of removing a frame such as iron after manufacturing in a process has been developed. However, when a double-sided adhesive tape is used in such a process, the tape remains adhered to the frame even after the production of the tiled building material, and is often difficult to remove and requires a long time. There was a problem.
すなわち、紙やレーヨン紙を支持体とする両面粘着テ
ープの場合は、貼り付けた直後は再剥離可能であるが、
長時間経過後又は高温・高圧下では再剥離が不可能とな
る。そして強度が弱いため、無理に再剥離をしようとす
ると、粘着テープが切れて被着体に残ってしまい、作業
性上問題が大きい。ポリエステル、ポリプロピレンフィ
ルムを支持体とする場合やポリエステル、ナイロン、ポ
リプロピレン繊維の不織布の場合は強度が大きいため再
剥離にあたって切れることはないが、しかし逆に手切れ
性がないため接着作業の際カッターの使用が必要とな
り、作業性、安全性上の問題が生ずる。さらに前記不織
布の場合、支持体に粘着剤がしみ込みやすく、粘着剤の
性能を出すには多量の粘着剤を塗布する必要があり、加
工性、経済性に劣る。In other words, in the case of a double-sided adhesive tape using paper or rayon paper as a support, it can be removed again immediately after pasting,
After a long time or under high temperature and high pressure, re-peeling becomes impossible. And, since the strength is weak, if the peeling is forcibly performed, the adhesive tape is cut off and remains on the adherend, which is a serious problem in workability. In the case of using a polyester or polypropylene film as a support or in the case of a nonwoven fabric of polyester, nylon or polypropylene fiber, it is not cut when re-peeling because of its high strength. It requires use, which causes problems in workability and safety. Further, in the case of the nonwoven fabric, the pressure-sensitive adhesive easily permeates the support, and it is necessary to apply a large amount of the pressure-sensitive adhesive in order to obtain the performance of the pressure-sensitive adhesive.
［問題点を解決するための手段］ 本発明の両面粘着テープは、支持体の片面に第１粘着
層を形成し、他面には第２粘着層を形成して成る３層構
造から成り、粘着面の保護を目的としてセパレート紙
（両面など）と貼り合わせて成る。第１粘着層は仮止め
すべき対象側たとえば前に述べたタイル貼り建築材料の
場合にあっては鉄枠に接着すべき面であり、第２粘着層
は固定すべき対象側、すなわちタイルを粘着せしめるべ
き面である。[Means for Solving the Problems] The double-sided pressure-sensitive adhesive tape of the present invention has a three-layer structure in which a first pressure-sensitive adhesive layer is formed on one surface of a support and a second pressure-sensitive adhesive layer is formed on the other surface. For protection of the adhesive surface, it is laminated with separate paper (both sides etc.). The first adhesive layer is the target side to be temporarily fixed, for example, in the case of the tiled building material described above, the surface to be bonded to the iron frame, and the second adhesive layer is the target side to be fixed, that is, the tile. This is the surface to be adhered.
本発明者は鋭意研究を重ねた結果、このような両面粘
着テープは、支持体として特定の性能を有するクレープ
含浸紙又は平面含浸紙を使用する場合、仮止め用途にお
ける作業性を格段に高めることを見出し、本発明を完成
するに至った。As a result of the inventor's intensive studies, such a double-sided pressure-sensitive adhesive tape, when using crepe-impregnated paper or plane-impregnated paper having a specific performance as a support, significantly improves workability in temporary fixing applications. And completed the present invention.
さらに詳細に言えば、本発明のタイル、タイルシート
の仮止め用両面粘着テープは、支持体として、その引張
り強さが2.0〜7.0kgf/10mmの範囲内にあるクレープ含浸
紙もしくは平面含浸紙を使用し、前記支持体の片面に、
アクリル系粘着剤に硬化剤を用いてJIS Z 0237の方法で
測定した40℃の保持力が24時間後のずれで0.5mm以下で
あり、その粘着力が100〜500g f/10mmの範囲にある粘着
剤を使用した第１粘着層を設け、前記支持体の他面に
は、タイル面やポリプロピレン粘着シートとの粘着性に
優れたゴム系粘着剤を使用した第２粘着層を設けてな
る。More specifically, the tile of the present invention, the double-sided pressure-sensitive adhesive tape for temporarily fixing a tile sheet, as a support, a crepe-impregnated paper or a plane-impregnated paper having a tensile strength in the range of 2.0 to 7.0 kgf / 10 mm. Used, on one side of the support,
The holding power at 40 ° C. measured by the method of JIS Z 0237 using a curing agent for an acrylic adhesive is 0.5 mm or less after a shift of 24 hours, and the adhesive strength is in the range of 100 to 500 g f / 10 mm. A first pressure-sensitive adhesive layer using a pressure-sensitive adhesive is provided, and a second pressure-sensitive adhesive layer using a rubber-based pressure-sensitive adhesive excellent in adhesion to a tile surface or a polypropylene pressure-sensitive adhesive sheet is provided on the other surface of the support.
本発明で、両面粘着テープの支持体として使用する支
持体は含浸紙として定義されるものである。すなわち、
紙に、各種ラテックスたとえば、SBR（ブタジエン−ス
チレン共重合体ゴム）、NBR（ブタジエン−アクリロニ
トリル共重合体ゴム）、MBR（ブタジエン−メチルメタ
クリレート共重合体ゴム）、CR（クロロプレンゴム）、
NR（天然ゴム）、IR（合成ポリイソプレン）、アクリル
樹脂、ポリ酢酸ビニル、ポリ塩化ビニル、ウレタン樹脂
の１種類または２種類を含浸したものを意味する。含浸
紙としては、単純に含浸させただけのものすなわち、い
わゆる平面含浸紙であってもよい。又しわ付け加工をし
たもの、すなわち、いわゆるクレープ含浸紙であっても
よい。再剥離後裂けにくい後者の方がより好ましい。し
かも、含浸紙であるので、含浸紙の本来有する有利性、
たとえば粘着剤のしみ込みがないことから高価な粘着剤
を必要量以上に多量に塗布することを避けることができ
ることから経済性にすぐれ、又層間剥離がないことから
再剥離の時、テープを被着体に残すことなく剥離できる
などの利点が多い。このような含浸紙の数々の有利性に
も拘らず、本発明以前に両面粘着テープにおいて含浸紙
を支持体とする提案が全くなかったことはむしろ驚くべ
きことである。In the present invention, the support used as the support for the double-sided pressure-sensitive adhesive tape is defined as impregnated paper. That is,
Various latexes such as SBR (butadiene-styrene copolymer rubber), NBR (butadiene-acrylonitrile copolymer rubber), MBR (butadiene-methyl methacrylate copolymer rubber), CR (chloroprene rubber),
One impregnated with one or two of NR (natural rubber), IR (synthetic polyisoprene), acrylic resin, polyvinyl acetate, polyvinyl chloride, and urethane resin. The impregnated paper may be simply impregnated paper, that is, a so-called flat impregnated paper. Further, a paper subjected to a wrinkling process, that is, a so-called crepe impregnated paper may be used. The latter, which does not easily tear after re-peeling, is more preferable. Moreover, since it is impregnated paper, the inherent advantages of impregnated paper,
For example, since there is no soaking of the adhesive, it is possible to avoid applying an expensive adhesive in a larger amount than necessary. There are many advantages such as peeling without leaving the body. Despite the numerous advantages of such impregnated papers, it is rather surprising that prior to the present invention, there was no proposal to use impregnated papers as supports in double-sided adhesive tapes.
本発明では、このような含浸紙であって、引張り強さ
が2.0〜7.0kgf/10mm（JIS Z 0237の方法で測定した値）
の範囲内にあるものでなければならない。2.0kgf/10mm
より低い引張り強さでは、支持体の強度が十分でなく、
再剥離にあたってテープが切れて被着体に残ってしまい
作業性上満足なものではない。一方7.0kgf/10mmより高
いと手で切りにくく仮止め用両面粘着テープとしては実
用に供し得ない。In the present invention, such impregnated paper has a tensile strength of 2.0 to 7.0 kgf / 10 mm (a value measured by the method of JIS Z 0237).
Must be within the range. 2.0kgf / 10mm
At lower tensile strength, the strength of the support is not enough,
Upon re-peeling, the tape is cut off and remains on the adherend, which is not satisfactory in terms of workability. On the other hand, if it is higher than 7.0 kgf / 10 mm, it is difficult to cut by hand and cannot be practically used as a double-sided adhesive tape for temporary fixing.
さらに、両面粘着テープにおいて仮止め用途における
作業性を高めるためには、支持体の引張り強さと第１粘
着層の粘着力との関係が重要であることがわかった。す
なわち、支持体含浸紙の引張り強さは第１粘着層の粘着
力より大であるように配慮しなければならないのであ
る。このような相対的関係を実現することにより仮止め
後の再剥離性は一般に良好である。とくに第１粘着面の
粘着力を、JIS Z 0237の方法で測定した値で100〜500g
f/10mmとした場合すぐれた結果が得られる。接着作業時
にはすぐれた手切れ性を示し、物体を保持接着でき、か
つ再剥離の時粘着剤が支持体から剥がれて被着体に残っ
たり、粘着剤が凝集破壊を起こし被着体に残ったりする
ことがなかった。Further, it has been found that the relationship between the tensile strength of the support and the adhesive strength of the first adhesive layer is important in order to enhance the workability of the double-sided adhesive tape for temporary fixing. That is, care must be taken that the tensile strength of the support-impregnated paper is greater than the adhesive strength of the first adhesive layer. By realizing such a relative relationship, removability after temporary fixing is generally good. In particular, the adhesive strength of the first adhesive surface is 100 to 500 g as measured by the method of JIS Z 0237.
Excellent results are obtained with f / 10mm. It shows excellent hand-cutting properties during bonding work, and can hold and adhere objects, and when peeled off, the adhesive peels off from the support and remains on the adherend, or the adhesive causes cohesive failure and remains on the adherend. I never did.
第１粘着層に使用する粘着剤としては、アクリル系粘
着剤すなわちアクリル酸エステルと官能基を有するアク
リル系化合物の共重合体及び、ゴム系粘着剤すなわち天
然ゴムあるいは合成ゴムと粘着付与剤樹脂、軟化剤の混
合体などを使用する。又、粘着剤の特性としては、凝集
力が高い方がよく、硬化剤を用いて40℃の保持力（JIS
Z 0237の方法で測定した値）を24時間後のずれで0.5mm
以下にしたものを使用する。Examples of the pressure-sensitive adhesive used for the first pressure-sensitive adhesive layer include an acrylic pressure-sensitive adhesive, that is, a copolymer of an acrylic ester and an acrylic compound having a functional group, and a rubber-based pressure-sensitive adhesive, that is, a natural rubber or a synthetic rubber and a tackifier resin, A mixture of a softener and the like are used. As for the properties of the pressure-sensitive adhesive, it is better that the cohesive force is high.
0.5 mm after 24 hours shift)
Use the following.
第２粘着層の粘着剤としてはタイルシートの仮止め用
としては、ポリプロピレン粘着シートとの接着の良いゴ
ム系粘着剤を使用する。As the pressure-sensitive adhesive for the second pressure-sensitive adhesive layer, a rubber-based pressure-sensitive adhesive with good adhesion to the polypropylene pressure-sensitive adhesive sheet is used for temporarily fixing the tile sheet.
［実 施 例］ 以下実施例を比較例と対照して示すことにより本発明
を一層具体的に説明する。EXAMPLES Hereinafter, the present invention will be described more specifically by showing examples in comparison with comparative examples.
実 施 例 支持体として、坪量65g/m2のブタジエン・アクリロニ
トリル共重合体含浸クレープ紙（三木特種製紙（株）Ｃ
−40）を使用した。この支持体の引張り強さは4.5kgf/1
0mmであった。Example A crepe paper impregnated with a butadiene / acrylonitrile copolymer having a basis weight of 65 g / m 2 (Miki Tokushu Paper Co., Ltd.
−40) was used. The tensile strength of this support is 4.5kgf / 1
It was 0 mm.
支持体の片面にアクリル粘着剤（綜研化学SKダイン16
04 100部に硬化剤Ｌ−45 1.5部を混合したもの、40℃
の保持力（JIS Z 0237の方法で測定した値）の24時間後
のずれで0.3mmである。）を固形分として60g/m2の割合
で塗布し第１粘着層を形成した。第１粘着層の粘着力は
350g f/10mmであった。支持体の他面には、タイルシー
トに対して300g f/10mmの粘着力をもつようゴム系粘着
力を固形分として70g/m2塗布し第２粘着層を形成し、第
２粘着層面を両面セパレート紙と貼り合わせてロール状
に巻きとった。An acrylic adhesive (Soken Chemical SK Dyne 16)
04 Mixing 1.5 parts of curing agent L-45 with 100 parts, 40 ℃
Of the holding force (value measured by the method of JIS Z 0237) after 24 hours is 0.3 mm. ) Was applied at a rate of 60 g / m 2 as a solid content to form a first adhesive layer. The adhesive strength of the first adhesive layer is
It was 350 g f / 10 mm. On the other surface of the support, a rubber-based adhesive force of 70 g / m 2 is applied as a solid so as to have an adhesive force of 300 g f / 10 mm to the tile sheet to form a second adhesive layer. The sheet was laminated on a double-sided separate paper and wound into a roll.
このようにして得られた両面粘着テープについて実用
テストを行った結果を比較例の両面粘着テープに関する
テスト結果とともにまとめて第１表に示す。Table 1 summarizes the results of practical tests performed on the double-sided pressure-sensitive adhesive tapes thus obtained, together with the test results on the double-sided pressure-sensitive adhesive tapes of Comparative Examples.
比較例 １ 実施例において、支持体として坪量14g/m2のレーヨン
紙（三木特種製紙（株）ミキロン＃805）を使用し、以
下実施例１と同じ処方により同様にして第1,第２粘着層
を形成した。この支持体の引張り強さは0.7kgf/10mmで
あった。Comparative Example 1 In the example, rayon paper having a basis weight of 14 g / m 2 (Mikiron # 805, Mikilon # 805) was used as a support. An adhesive layer was formed. The tensile strength of this support was 0.7 kgf / 10 mm.
比較例 ２ 実施例において、支持体として厚さ25μのポリエステ
ルフィルムを使用し、以下実施例１と同じ処方により同
様にして第1,第２粘着層を形成した。この支持体の引張
り強さは4.7kgf/10mmであった。Comparative Example 2 In the example, a 25 μm thick polyester film was used as a support, and the first and second adhesive layers were formed in the same manner as in Example 1 in the same manner. The tensile strength of this support was 4.7 kgf / 10 mm.
比較例 ３ 実施例において、支持体片面に設けるべき第１粘着層
を粘着剤として、より粘着力の高いアクリル粘着剤（東
亜合成化学工業製アロンタックＳ−3452 100部に対し
て硬化剤コロネートＬを0.3部を混合したもの）を使用
し、固形分として60g/m2の割合で塗布して形成した。第
１粘着層の粘着力は700g f/10mmであった。第２粘着層
は実施例１と同様に形成した。Comparative Example 3 In the example, the first adhesive layer to be provided on one side of the support was used as an adhesive, and an acrylic adhesive having higher adhesive strength (100 parts of Alontack S-3452 manufactured by Toa Gosei Chemical Industry Co., Ltd. was used as a curing agent coronate L). 0.3 parts) and applied at a rate of 60 g / m 2 as a solid content. The adhesive strength of the first adhesive layer was 700 g f / 10 mm. The second adhesive layer was formed in the same manner as in Example 1.
［評価］ 上記各両面粘着テープにつき、支持体の引張り強さ、
第１粘着層の粘着力及び、実用テストとしてタイルシー
ト仮止め作業時のテープの手切れ性・タイルの接着保持
性・再剥離性について評価を行った。その結果を第１表
に示す。[Evaluation] For each of the above double-sided adhesive tapes, the tensile strength of the support,
The adhesive strength of the first adhesive layer and, as a practical test, the hand-cutting property of the tape, the adhesion holding property of the tile, and the removability at the time of temporarily fixing the tile sheet were evaluated. Table 1 shows the results.
［発明の効果］ 本発明により物体の接着保持に十分な性能を持つばか
りでなく、接着作業時のテープの手切れ性、及び剥離作
業時の再剥離性に優れ、仮止め作業の作業性を高めたタ
イル、タイルシートの仮止め用両面粘着テープを提供す
ることができた。 [Effects of the Invention] The present invention not only has sufficient performance for holding an object by bonding, but also has excellent hand-cutting property of a tape at the time of bonding work and excellent re-peelability at the time of peeling work. It was possible to provide a double-sided pressure-sensitive adhesive tape for temporarily fixing tiles and tile sheets.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭57−44687（ＪＰ，Ａ) 特開 昭61−89279（ＪＰ，Ａ) 実開 昭51−136354（ＪＰ，Ｕ) 実開 昭62−71343（ＪＰ，Ｕ) 実開 昭58−148045（ＪＰ，Ｕ) 実開 昭58−131933（ＪＰ，Ｕ) 特公 昭63−42251（ＪＰ，Ｂ２) (58)調査した分野(Int.Cl.6，ＤＢ名) C09J 7/00 - 7/04──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-57-44687 (JP, A) JP-A-61-89279 (JP, A) Actually open Showa 51-136354 (JP, U) Actually open Showa 62- 71343 (JP, U) Japanese Utility Model Showa 58-148045 (JP, U) Japanese Utility Model Application Showa 58-131933 (JP, U) Japanese Patent Publication No. 63-4251 (JP, B2) (58) Fields surveyed (Int. 6 , DB name) C09J 7/00-7/04
Claims (1)
f/10mmの範囲内にあるクレープ含浸紙もしくは平面含
浸紙を使用し、前記支持体の片面に、アクリル系粘着剤
に硬化剤を用いてJIS Z 0237の方法で測定した40℃の保
持力が24時間後のずれで0.5mm以下であり、その粘着力
が100〜500g f/10mmの範囲内にある粘着剤を使用した第
１粘着層を設け、前記支持体の他面には、タイル面やポ
リプロピレン粘着シートとの粘着性に優れたゴム系粘着
剤を使用した第２粘着層を設けてなる、タイル、タイル
シートの仮止め用両面粘着テープ。1. The support has a tensile strength of 2.0 to 7.0 kg.
Using a crepe impregnated paper or a flat impregnated paper within the range of f / 10 mm, the holding power at 40 ° C. measured by the method of JIS Z 0237 using a curing agent for an acrylic adhesive on one surface of the support is used. A first pressure-sensitive adhesive layer using a pressure-sensitive adhesive having a deviation of not more than 0.5 mm after 24 hours and an adhesive force within a range of 100 to 500 g f / 10 mm is provided, and the other surface of the support is provided with a tile surface. Double-sided pressure-sensitive adhesive tape for temporary fixing of tiles and tile sheets, provided with a second pressure-sensitive adhesive layer using a rubber-based pressure-sensitive adhesive excellent in adhesiveness to polypropylene and pressure-sensitive adhesive sheets.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309147A JP2800833B2 (en) | 1988-12-07 | 1988-12-07 | Double-sided adhesive tape for temporary fixing of tiles and tile sheets |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309147A JP2800833B2 (en) | 1988-12-07 | 1988-12-07 | Double-sided adhesive tape for temporary fixing of tiles and tile sheets |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02155971A JPH02155971A (en) | 1990-06-15 |
| JP2800833B2 true JP2800833B2 (en) | 1998-09-21 |
Family
ID=17989477
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63309147A Expired - Fee Related JP2800833B2 (en) | 1988-12-07 | 1988-12-07 | Double-sided adhesive tape for temporary fixing of tiles and tile sheets |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2800833B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991002120A1 (en) * | 1989-08-08 | 1991-02-21 | Nakamura Seishisho Co., Ltd. | Heat-bondable paper sheet |
| JPH0473948U (en) * | 1990-11-05 | 1992-06-29 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5353470U (en) * | 1976-10-09 | 1978-05-08 | ||
| JPS5744687A (en) * | 1980-09-01 | 1982-03-13 | Toshiko Momokawa | Adhesive paper having weak tackiness |
| JPS58131933U (en) * | 1982-03-02 | 1983-09-06 | 大福製紙株式会社 | Single-sided crepe adhesive tape |
| JPS58148045U (en) * | 1982-03-30 | 1983-10-05 | 大福製紙株式会社 | Smooth crepe adhesive tape |
| JPS6189279A (en) * | 1984-10-09 | 1986-05-07 | Nippon Kako Seishi Kk | Pressure-sensitive adhesive sheet for titled display label |
| JPS6342251A (en) * | 1986-08-07 | 1988-02-23 | Seiko Epson Corp | Receive buffer control method |
| JPS63183248U (en) * | 1987-05-13 | 1988-11-25 |
-
1988
- 1988-12-07 JP JP63309147A patent/JP2800833B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02155971A (en) | 1990-06-15 |
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