JP2718232B2 - Manufacturing method of square plate type thin film chip resistor - Google Patents

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a square plate type thin film chip resistor.

2. Description of the Related Art In recent years, as the demand for “light, thin and small” electronic devices has been increasing more and more, in order to increase the mounting density of resistor elements on circuit boards, there are many small and square-plate chip resistors that can be surface-mounted. It is being used. In recent years, the precision of parts and the noise have been reduced, and the demand for square-plate type chip resistors from a thick film type to a thin film type with high accuracy and low noise has been increasing.

FIG. 6 shows an example of a conventional method of manufacturing a small rectangular plate-type thin film chip resistor (quoted from Susumu Co., Ltd. DATABOOK).

First, the conventional manufacturing process starts a substrate receiving process A for receiving a heat-resistant insulating substrate 21 made of a high-purity alumina substrate or the like.
An etching process C for shaping the thin film resistor 22 into a resistance pattern 23 is performed through a sputtering process B for forming a thin film resistor 22 such as -Cr or the like. To perform an atmosphere heat treatment step D at a temperature of 350 ° C. to 400 ° C. Then, to correct the resistance value of the resistance pattern to a predetermined value, by laser trimming method, etc.
A resistance value correcting step E for forming a trimming groove 24 in the resistance pattern is performed. Further, in order to protect the resistance pattern 23, a protective coat forming step F for forming a thermosetting resin film 25 is performed. Next, as a preparation step for dividing the insulating substrate 21 and forming the end face electrode layer 26, a scribing step G of forming a groove 27 for division on the insulating substrate 21 and a strip-shaped substrate 21 ' A primary substrate dividing step H is performed, and an end face electrode forming step I for forming an end face electrode layer 26 is performed on the end face of the strip-shaped substrate 21 'by using sputtering or the like. Then, as a preparation step for applying the plating layer 27 to the exposed resistance pattern and the end face electrode surface, the strip-shaped substrate 21 ′
Is performed to separate the exposed resistance pattern and the end face electrode layer from soldering at the time of soldering, and to secure the reliability of solderability. An electrode plating step K for forming an electrode plating layer 27 is performed to complete a square plate type thin film chip resistor.

Problems to be Solved by the Invention However, the square-plate type thin film chip resistor according to this process has the following problems.

(1) Since the resistive film is formed by sputtering, continuous processing is difficult, and a large number of sputtering devices are required for mass production, and the cost is about twice as high as that of a thick-film chip resistor.

(2) Since the heat treatment of the resistive film is performed at 350 ° C to 400 ° C, about 50
Since a glass protective coat that requires heat treatment at 0 ° C. or higher cannot be used, a resin protective coat has to be used. Therefore, the heat resistance is inferior to that of a thick-film chip resistor.

(3) A substrate with a dividing groove, which is often used for a thick-film square plate type chip resistor, is difficult to form a thin film because of the unique undulation of the substrate between the dividing grooves. In a thin film chip resistor, grooves for division are formed by laser scribing on a substrate having no division grooves with little undulation. However, the laser scribe not only impairs the aesthetics of the chip resistor, but also tends to cause microcracks on the substrate due to the thermal shock of the laser, which may cause insulation deterioration.

(4) Since the end electrodes are formed by sputtering,
The adhesion strength of the electrode is weaker than the strength of the end face electrode of a conventional thick-film chip resistor obtained by applying and firing a thick-film silver electrode. On the other hand, in the conventional square plate type thin film chip resistor, a method of applying and firing a low-temperature fired thick film end electrode so as to overlap the thin film resistor as an end surface electrode has been studied. There was a problem that the thin film resistor was eaten at the time of firing, and it could not be realized.

The present invention solves such problems all at once, and is inexpensive, has good heat resistance due to the use of a glass coat, has excellent substrate insulation, and has a strong electrode strength during soldering. A chip resistor is provided.

Means for Solving the Problems In order to solve the above problems, a method of manufacturing a square plate type thin film chip resistor according to the present invention is a method for forming a pair of upper surface electrodes on a heat resistant insulating substrate. Printing and baking a material, and undercoating glass using a pattern having a length equal to or less than the length of the upper surface electrode in order to smooth the surface of the heat resistant insulating substrate between at least the pair of upper electrodes. Printing and baking, and printing and baking a resistive material made of a metal organic material to form a thin-film resistor that partially overlaps the undercoat glass and the upper surface electrode, and coating the resistor. A step of printing and firing an overcoat glass for protection, a step of correcting a resistance value to make the characteristics of the resistor uniform, and a step of preparing a primary substrate for forming an end face electrode. And an end surface electroprinting firing process for forming electrodes on the end surfaces of the divided substrate, a secondary substrate dividing process which is a preparation process for electrode plating, and prevention of electrode erosion by soldering and reliability of solderability. And an electrode plating step for performing the same.

Operation As a result, the following operation is obtained.

(1) Since a thin film resistance film can be continuously formed by a printing machine and a belt type continuous firing furnace without using a sputtering apparatus,
The manufacturing cost is reduced, and an inexpensive square-plate thin-film chip resistor comparable to a thick-film square-chip chip resistor can be provided.

(2) Since the thin-film resistor is formed by printing a resistance material made of a metal organic material, a glass coat can be used as a protective coat, and the heat resistance is improved as compared with a conventional square-plate thin-film chip resistor. I can do it.

(3) The undercoat glass absorbs the undulation of the substrate between the divided grooves peculiar to the divided grooved substrate, and makes the surface smooth. For this reason, it is not necessary to form a dividing groove by performing laser scribing on a smooth substrate having no undulation as in the related art, so that the insulating property of the substrate is improved.

(4) Since the thin-film resistor is printed and fired after firing the thick-film electrode on the upper surface, the thin-film resistor is not eaten by the upper electrode when firing the end-face electrode, and the thick-film end-face electrode is firmly formed by firing. Therefore, the strength of the end face electrode can be made equal to that of the conventional thick film chip resistor.

An embodiment of the present invention will be described below with reference to the drawings.

FIG. 1 is a process drawing showing a first embodiment of a method of manufacturing a square plate type thin film chip resistor according to the present invention, FIG. 2 is a sectional view of a product manufactured by the process of FIG. 1, and FIG. FIG. 4 is an explanatory view showing the heat resistance of the square plate type thin film chip resistor, FIG. 4 is an explanatory view showing the end face electrode tensile strength of the square plate type thin film chip resistor of the present invention, and FIG. It is explanatory drawing which shows the resistance value change by a moisture resistance load test at the time of using a thin film conductive material.

An embodiment of the present invention will be described with reference to FIG.
First, a process A for receiving a 96-alumina substrate 1 having excellent heat resistance and insulation properties was performed. In order to divide the alumina substrate 1 into strips and individual pieces, grooves 2 (molding at the time of a green sheet) for division are formed.
Next, a thick-film silver paste was screen-printed on the 96-alumina substrate 1 and baked in a belt-type continuous sintering furnace at a temperature of 600 ° C. with a peak time of 6 minutes and an IN-OUT of 45 minutes. Step B of forming the upper electrode layer 4 was performed. Next, in order to smooth the undulations and projections of the substrate between the pair of upper electrode layers 4, an undercoat glass paste was screen-printed, and a belt-type continuous firing furnace was used at a temperature of 900 ° C. for 15 minutes at a peak of IN−. Step C of firing under the profile of OUT for 2 hours to form the undercoat glass layer 3 was performed. Next, a resistance paste made of a metal organic material containing RuO ₂ as a main component was screen-printed so as to overlap a part of the undercoat glass layer 3 and a part of the upper electrode layer 4. Then, in order to blow off only the organic components of the metal organic resistance paste and bake only the metal components onto the undercoat glass layer, a belt-type continuous firing furnace was used.
Step D of forming a resistor layer 5 by baking at a temperature of 0 ° C. with a profile of a peak time of 10 minutes and an IN-OUT time of 45 minutes was performed. Furthermore, in order to protect the resistor layer 4, an overcoat glass paste is screen-printed so as to completely cover the resistor layer 4, and a belt-type continuous firing furnace is used at a temperature of 600 ° C. for a peak time of 15 minutes. The step E of baking according to a baking profile of IN-OUT 90 minutes to form the overcoat glass layer 6 was performed. Next, in order to make the resistance value of the resistor layer 4 between the upper electrode layers 5 uniform, the resistance layer 4 is irradiated with a laser beam (oscillation frequency: 5 kHz, output: 0.3 W) through the overcoat glass layer 6. Only the resistance value correcting step F for breaking only was performed. Next, as a preparation process for forming the end surface electrodes, a primary substrate dividing step G was performed in which the alumina substrate 1 was divided into strips to obtain strip alumina substrates 1 'in order to expose the end surface electrodes. Further, a thick-film silver paste is applied to the side surface of the strip-shaped alumina substrate 1 ′ so as to overlap a part of the upper electrode layer 5 with a roller, and is heated to 600 ° C. by a belt-type continuous firing furnace.
The end face conductor paste printing / firing step H of firing at the temperature of 6 hours to form the end face electrode layer 8 by the firing profile of IN-OUT 45 minutes for a peak time of 6 minutes was performed. Next, as a preparation step of the electrode plating step K, a secondary substrate dividing step J of dividing the strip-shaped alumina substrate 1 ′ on which the end face electrode layer 8 has been formed into individual pieces is performed. I got
Finally, in order to prevent electrode erosion at the time of soldering of the exposed upper surface electrode layer 5 and end surface electrode layer 8 and to secure the reliability of soldering, Ni, Sn-Pb is electrolytically plated.
An electrode plating step K for forming the plating layer 9 was performed.

Through the steps described above, a square plate type thin film chip resistor according to the embodiment of the present invention was experimentally manufactured.

The resistance variation of the square plate type thin film chip resistor according to the embodiment of the present invention, the resistance temperature characteristic (TCR), the current noise characteristic, and the resistance change due to the heat resistance test (450 ° C. for 10 minutes) are compared with the conventional square plate type thin film chip. Compared with a resistor. As a result, it was found that the resistance variation, TCR, and current noise characteristics were equivalent to those of the conventional square-plate thin-film chip resistor. Also, the third
As shown in FIG. 4 and FIG. 4, it can be said that the heat resistance and the electrode strength are superior to the conventional square plate type thin film chip resistor.

Further, since the undercoat glass layer is formed between the pair of upper electrodes, the thickness of the upper electrode layer and the thickness of the undercoat glass layer are almost the same, and the resistor layer is formed on a flat surface compared to the first embodiment. It is formed. Thereby, the variation of the resistance value was improved.

(5% at 3σ /) In the embodiment, the upper surface electrode layer 4 is formed by printing and firing a silver-based thick film conductive material. When a square plate type thin film chip resistor having the layer 4 formed thereon was prototyped, the resistance value hardly changed even after a long-time (10000 hours) moisture resistance load test as shown in FIG.

In the examples, the firing temperature of the undercoat was set to 900
℃, the sintering temperature of the metal organic resistance paste is 640 ℃, the sintering temperature of the upper surface conductor is 600 ℃, the sintering temperature of the overcoat glass paste is 600 ℃, the sintering temperature of the end surface conductor paste is 6
The temperature was set to 00 ° C., but this does not limit the firing temperature.

In addition, the metal organic resistance paste used was a resistance paste containing RuO ₂ as a main component, but the metal organic resistance paste is not limited.

The electrode layer and the end face electrode layer are made of a silver-based thick film electrode paste, but may be a noble metal-based thick film electrode paste such as gold or platinum.

In addition, as shown in FIG. 5, by using a gold-based thin film conductive material for the upper electrode layer, it is possible to greatly reduce a change in resistance value due to a long-time (10000 hours) moisture resistance load test.

Effects of the Invention As is clear from the above description, the present invention provides a step of printing and firing an undercoat glass to smooth the surface of a heat-resistant insulating substrate, and an upper surface electrode overlapping a part of the undercoat glass. A step of printing and baking a chemically stable conductive material to form a resistive material comprising a metal organic material to form a thin film resistor overlapping a part of the upper surface electrode on the undercoat glass. A step of printing and firing, a step of printing and firing an overcoat glass to cover and protect the resistor, a resistance correction step for aligning the characteristics of the resistor, and an end face electrode A primary substrate dividing step as a preparation step, an end face electrode printing and firing step for forming an electrode on an end face of the divided substrate, and a secondary substrate dividing step as an electrode plating preparation step. And an electrode plating step for preventing electrode erosion due to soldering and ensuring the reliability of solderability, so that the following effects can be obtained.

(1) Since a thin film resistance film can be continuously formed by a printing machine and a belt type continuous firing furnace without using a sputtering apparatus,
The productivity is enhanced, and an inexpensive square-plate thin-film chip resistor comparable to a thick-film square-plate chip resistor can be provided.

(2) Since the thin-film resistor is printed and fired with a resistance material made of a metal organic substance, a glass coat can be used as a protective coat, and the heat resistance can be improved as compared with a conventional square-plate thin-film chip resistor. .

(3) In the conventional thin film chip resistor, it was necessary to form a dividing groove by performing laser scribing on a smooth substrate having no undulation, but according to the present invention, by forming an undercoat glass layer, the undulation is provided. Since a substrate with a divided groove having a groove can also be used, the insulating property of the substrate is improved.

(4) Since the electrodes can be formed firmly by applying and baking a thick-film end surface paste, the strength of the end surface electrodes can be made equal to that of a conventional thick-film chip resistor.

(5) Further, by using a gold-based thin film conductive material for the upper electrode layer, a change in resistance value due to a long-time (10000 hours) moisture resistance load test can be significantly reduced.

[Brief description of the drawings]

FIG. 1 is an explanatory view showing a manufacturing process of a square plate type thin film chip resistor according to one embodiment of the present invention, and FIG. 2 is a diagram of a sample manufactured by the method of manufacturing a square plate type thin film chip resistor of FIG. FIG. 3 is an explanatory view showing the heat resistance of the rectangular thin-film chip resistor of the present invention. FIG. 4 is an explanatory view showing the strength of the end face electrode of the rectangular thin-film chip resistor of the present invention. FIG. 5 is an explanatory view showing a change in resistance value by a long-time (10000 hours) moisture resistance load test when a gold-based thin film conductive material is used for an upper electrode, and FIG. 6 shows a conventional square plate type thin film chip resistor. It is explanatory drawing which shows an example of a manufacturing process. 1 ... 96-alumina substrate, 1 '... strip-shaped 96-alumina substrate, 1 "... individual-piece 96-alumina substrate, 2 ... grooves for division, 3 ... undercoat glass layer, 4 ... resistor Layer 5, top electrode layer, 6 overcoat glass layer, 7 trimming groove, 8 end electrode layer, 9 electrode plating layer.

Claims (3)

(57) [Claims] A step of printing and baking a chemically stable conductive material to form a pair of upper surface electrodes on the heat resistant insulating substrate; A step of printing and firing an undercoat glass using a pattern having a length equal to or less than the length of the upper surface electrode in order to smooth the surface, and a thin film resistor overlapping a part of the undercoat glass and the upper surface electrode A step of printing and baking a resistance material made of a metal organic material to form a body, a step of printing and baking an overcoat glass to cover and protect the resistor, and a step of aligning the characteristics of the resistor A resistance value correcting step, a primary substrate dividing step which is a preparation step for forming an end face electrode, and an end face electrode printing and firing step for forming an electrode on an end face portion of the split board; Characterized by sequentially passing through a secondary substrate dividing step, which is a preparatory step, and an electrode plating step for preventing electrode erosion by soldering and ensuring the reliability of solderability. Production method. 2. The method according to claim 1, wherein the upper surface electrode is formed by printing and firing a gold-based thin film conductive material. 3. The square plate type thin film chip resistor according to claim 1, wherein the resistance value is corrected by destroying the resistor covered with the overcoat by a laser beam transmitted through the overcoat glass. Manufacturing method.